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Nano Research 2024年第6期17卷 5224-5232页

作者： Jianmei Han Hua Zhang Peng Wang Ning Song Xuguang An Baojuan Xi Shenglin Xiong College of chemistry and Chemical engineering Taishan UniversityTai’an 271021China Key Laboratory of the Colloid and Interface chemistry Ministry of Educationand School of Chemistry and Chemical EngineeringShandong UniversityJinan 250100China school of Mechanical engineering Chengdu UniversityChengdu 610106China

The application of light-weight current collectors is preferred because of the increased energy density of the *** it in mind,the cathode is designed with self-made paperlike memberane as current collector coupled with another interlayer to enable the high-energy-density lithium-sulfur *** a facile and green step-by-step methodology,the hybrid membrane is finalized successfully,consisting of reduced graphene oxide sheets covering paper-derived carbon(GPC)bearing Fe@Fe2O3 and Fe1−xS@Fe2O3 core-shell nanoparticles(FeFeO/FeSFeO@GPC).The film works as the current collector and interlayer simultaneously considering the porous and conductive *** demonstrated by the electrochemical testing,the FeFeO/FeSFeO@GPC hybrid cell exhibits attractive cycling stability and superior rate *** cell configuration and structural/composition merits of FeFeO/FeSFeO@GPC film facilitate the faster reaction kinetics,conducive to the improvement of capacity *** view of the effective cathode design,the areal sulfur loading is increased to 10.46 mg·cm^(−2)and a reversible capacity of 6.67 mAh·cm^(−2)can be retained after 60 cycles at 0.1 C.

关键词： light-weight self-made current collector core-shell high-areal-sulfur lithium-sulfur batteries

Advanced 3D ordered electrodes for PEMFC applications: From structural features and fabrication methods to the controllable design of catalyst layers

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Green Energy & Environment 2024年第09期9卷 1336-1365页

作者： Kaili Wang Tingting Zhou Zhen Cao Zhimin Yuan Hongyan He Maohong Fan Zaiyong Jiang school of chemistry & Chemical engineering and environmental engineering Weifang University Beijing Key Laboratory of Ionic Liquids Clean Process State Key Laboratory of Multiphase Complex Systems CAS Key Laboratory of Green Process and Engineering Institute of Process Engineering Chinese Academy of Sciences College engineering and Physical Sciences and School of Energy Resources University of Wyoming

The catalyst layers(CLs) electrode is the key component of the membrane electrode assembly(MEA) in proton exchange membrane fuel cells(PEMFCs). Conventional electrodes for PEMFCs are composed of carbon-supported, ionomer, and Pt nanoparticles, all immersed together and sprayed with a micron-level thickness of CLs. They have a performance trade-off where increasing the Pt loading leads to higher performance of abundant triple-phase boundary areas but increases the electrode cost. Major challenges must be overcome before realizing its wide commercialization. Literature research revealed that it is impossible to achieve performance and durability targets with only high-performance catalysts, so the controllable design of CLs architecture in MEAs for PEMFCs must now be the top priority to meet industry goals. From this perspective, a 3D ordered electrode circumvents this issue with a support-free architecture and ultrathin thickness while reducing noble metal Pt loadings. Herein, we discuss the motivation in-depth and summarize the necessary CLs structural features for designing ultralow Pt loading electrodes. Critical issues that remain in progress for 3D ordered CLs must be studied and characterized. Furthermore, approaches for 3D ordered CLs architecture electrode development, involving material design, structure optimization, preparation technology, and characterization techniques, are summarized and are expected to be next-generation CLs for PEMFCs. Finally, the review concludes with perspectives on possible research directions of CL architecture to address the significant challenges in the future.

关键词： PEMFC 3D ordered electrode Structural features Preparation technology Ultralow Pt loading

Quasi-static and dynamic compressive behaviour of additively manufactured Menger fractal cube structures

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Defence Technology（防务技术） 2024年第7期37卷 39-49页

作者： Damith Mohotti Dakshitha Weerasinghe Madhusha Bogahawaththa Hongxu Wang Kasun Wijesooriya Paul JHazell school of engineering and Technology UNSWCanberraACT2600Australia school of Civil Mining and Environmental EngineeringFaculty of Engineering and Information SciencesUniversity of WollongongWollongongNSWAustralia

This paper presents the first-ever investigation of Menger fractal cubes'quasi-static compression and impact *** cubes with different void ratios were 3D printed using polylactic acid(PLA)with dimensions of 40 mm×40 mm×40 *** different orders of Menger cubes with different void ratios were considered,namely M1 with a void ratio of 0.26,M2 with a void ratio of 0.45,and M3with a void ratio of ***-static Compression tests were conducted using a universal testing machine,while the drop hammer was used to observe the behaviour under impact *** fracture mechanism,energy efficiency and force-time histories were *** the structured nature of the void formation and predictability of the failure modes,the Menger geometry showed some promise compared to other alternatives,such as foams and *** the increasing void ratio,the Menger geometries show force-displacement behaviour similar to hyper-elastic materials such as rubber and *** third-order Menger cubes showed the highest energy absorption efficiency compared to the other two geometries in this *** findings of the present work reveal the possibility of using additively manufactured Menger geometries as an energy-efficient system capable of reducing the transmitting force in applications such as crash barriers.

关键词： Additive manufacturing Fractal geometries Menger cube Energy absorption Quasi-static

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A 30-year overview of sodium-ion batteries

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Carbon Energy 2024年第6期6卷 56-98页

作者： Yun Gao Hang Zhang Jian Peng Lin Li Yao Xiao Li Li Yang Liu Yun Qiao Shu-Lei Chou school of environmental and Chemical engineering Shanghai UniversityShanghaiChina College of chemistry and Materials engineering Wenzhou UniversityWenzhouZhejiangChina Institute for Superconducting and Electronic Materials University of WollongongWollongongNew South WalesAustralia

Sodium-ion batteries(NIBs)have emerged as a promising alternative to commercial lithium-ion batteries(LIBs)due to the similar properties of the Li and Na elements as well as the abundance and accessibility of Na *** of the current research has been focused on the half-cell system(using Na metal as the counter electrode)to evaluate the performance of the cathode/anode/*** relationship between the performance achieved in half cells and that obtained in full cells,however,has been neglected in much of this ***,the trade-off in the relationship between electrochemical performance and cost needs to be given more ***,systematic and comprehensive insights into the research status and key issues for the full-cell system need to be gained to advance its ***,this review evaluates the recent progress based on various cathodes and highlights the most significant challenges for full *** strategies have also been proposed to enhance the electrochemical performance of NIBs,including designing electrode materials,optimizing electrolytes,sodium compensation,and so ***,perspectives and outlooks are provided to guide future research on sodium-ion full cells.

关键词： commercial application electrode electrolyte sodium-ion full cell strategies

S-scheme heterojunction in photocatalytic hydrogen production

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Journal of Materials Science & Technology 2024年第2期169卷 82-104页

作者： Teng Li Noritatsu Tsubaki Zhiliang Jin school of chemistry and Chemical engineering North Minzu UniversityYinchuan 750021China Department of Applied chemistry Graduate School of EngineeringUniversity of ToyamaGofuku 3190Toyama 930-8555Japan

As an ideal secondary energy source,hydrogen has the title of clean energy and the product of its complete combustion is only water,which is not polluting to the *** hydrogen production technology is an environmentally friendly,safe,and low-cost strategy that requires only an inexhaustible amount of solar energy and water as *** paper provides a detailed and detailed review of S-scheme heterojunction photocatalysts for photocatalytic hydrogen production,mainly including TiO_(2)-based,Perovskite-based,CdS-based,Graphitic phase carbon nitride-based,COF-based graphdiyne-based,ZnO-based,and ZnIn_(2)S_(4)-based S-scheme heterojunction *** classification of S-scheme heterojunctions is ***’s more,various characterizations for direct verification of the charge migration mechanism of S-scheme heterojunctions are *** on the present study,the future potential challenges and future research trends for S-scheme heterojunctions in photocatalytic hydrogen evolution technology are pointed out,which provides feasible strategies for the development and design of S-scheme heterojunction photocatalysts in the field of photocatalytic hydrogen evolution.

关键词： S-scheme heterojunction Photocatalysis Charges migration Hydrogen evolution

In-situ interfacial passivation and self-adaptability synergistically stabilizing all-solid-state lithium metal batteries

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Journal of Energy chemistry 2024年第1期88卷 282-292,I0007页

作者： Huanhui Chen Xing Cao Moujie Huang Xiangzhong Ren Yubin Zhao Liang Yu Ya Liu Liubiao Zhong Yejun Qiu Shenzhen engineering Lab of Flexible Transparent Conductive Films School of Materials Science and EngineeringHarbin Institute of TechnologyShenzhen 518055GuangdongChina Guangdong Provincial Key Laboratory of Semiconductor Optoelectronic Materials and Intelligent Photonic Systems School of Materials Science and EngineeringHarbin Institute of TechnologyShenzhen 518055GuangdongChina College of chemistry and environmental engineering Shenzhen UniversityShenzhen 518060GuangdongChina school of Resource and environmental Sciences Wuhan UniversityWuhan 430072HubeiChina

The function of solid electrolytes and the composition of solid electrolyte interphase(SEI)are highly significant for inhibiting the growth of Li ***,we report an in-situ interfacial passivation combined with self-adaptability strategy to reinforce Li_(0.33)La_(0.557)TiO_(3)(LLTO)-based solid-state ***,a functional SEI enriched with LiF/Li_(3)PO_(4) is formed by in-situ electrochemical conversion,which is greatly beneficial to improving interface compatibility and enhancing ion *** the polarized dielectric BaTiO_(3)-polyamic acid(BTO-PAA,BP)film greatly improves the Li-ion transport kinetics and homogenizes the Li *** expected,the resulting electrolyte offers considerable ionic conductivity at room temperature(4.3 x 10~(-4)S cm^(-1))and appreciable electrochemical decomposition voltage(5.23 V)after electrochemical *** Li-LiFePO_(4) batteries,it shows a high specific capacity of 153 mA h g^(-1)at 0.2C after 100 cycles and a long-term durability of 115 mA h g^(-1)at 1.0 C after 800 ***,a stable Li plating/stripping can be achieved for more than 900 h at 0.5 mA cm^(-2).The stabilization mechanisms are elucidated by ex-situ XRD,ex-situ XPS,and ex-situ FTIR techniques,and the corresponding results reveal that the interfacial passivation combined with polarization effect is an effective strategy for improving the electrochemical *** present study provides a deeper insight into the dynamic adjustment of electrode-electrolyte interfacial for solid-state lithium batteries.

关键词： Solid-state lithium batteries Composite solid electrolyte In-situ polymerization Interfacial passivation layer Self-adaptability

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Development of gradient boosting-assisted machine learning data-driven model for free chlorine residual prediction

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Frontiers of environmental Science & engineering 2024年第2期18卷 35-46页

作者： Wiley Helm Shifa Zhong Elliot Reid Thomas Igou Yongsheng Chen school of Civil and environmental engineering Georgia Institute of TechnologyAtlantaGA 30332USA school of Ecological and environmental Sciences East China Normal UniversityShanghai 200241China

Chlorine-based disinfection is ubiquitous in conventional drinking water treatment (DWT) and serves to mitigate threats of acute microbial disease caused by pathogens that may be present in source water. An important index of disinfection efficiency is the free chlorine residual (FCR), a regulated disinfection parameter in the US that indirectly measures disinfectant power for prevention of microbial recontamination during DWT and distribution. This work demonstrates how machine learning (ML) can be implemented to improve FCR forecasting when supplied with water quality data from a real, full-scale chlorine disinfection system in Georgia, USA. More precisely, a gradient-boosting ML method (CatBoost) was developed from a full year of DWT plant-generated chlorine disinfection data, including water quality parameters (e.g., temperature, turbidity, pH) and operational process data (e.g., flowrates), to predict FCR. Four gradient-boosting models were implemented, with the highest performance achieving a coefficient of determination, R2, of 0.937. Values that provide explanations using Shapley’s additive method were used to interpret the model’s results, uncovering that standard DWT operating parameters, although non-intuitive and theoretically non-causal, vastly improved prediction performance. These results provide a base case for data-driven DWT disinfection supervision and suggest process monitoring methods to provide better information to plant operators for implementation of safe chlorine dosing to maintain optimum FCR.

关键词： Machine learning Data-driven modeling Drinking water treatment Disinfection Chlorination

Imide-based covalent organic framework with excellent cyclability as an anode material for lithium-ion battery

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Chinese Chemical Letters 2024年第6期35卷 206-210页

作者： Yue Qian Zhoujia Liu Haixin Song Ruize Yin Hanni Yang Siyang Li Weiwei Xiong Saisai Yuan Junhao Zhang Huan Pang school of environmental&Chemical engineering Jiangsu University of Science and TechnologyZhenjiang 212003China school of chemistry&Chemical engineering Yangzhou UniversityYangzhou 225009China Shandong Key Laboratory of Biochemical Analysis College of Chemistry and Molecular EngineeringQingdao University of Science and TechnologyQingdao 266042China

Covalent organic frameworks(COFs)exhibiting reversible redox behaviors have been identified as promising candidates for constructing electrode materials in lithium-ion batteries(LIBs).However,their extensive application has been limited due to finite redox sites and poor structural *** this study,we design and synthesize a novel polyimide covalent organic framework(PI-COF)using the traditional solvothermal method and successfully apply it as an anode material for *** large conjugated structure of PI-COF accelerates charge transfer,while its large surface area provides more active sites,making PI-COF an attractive anode material for ***,the PI-COF anode material demonstrates high reversible specific capacity and excellent long-term cycling stability due to its COF ***,the PI-COF electrodes deliver a specific capacity of 800 m Ah/g at a current density of 200 m A/g after 200 cycles,while a specific capacity of 450 m Ah/g at a current density of 1000 m A/g is sustained after 800 *** outstanding lithium storage capacity,particularly the satisfactory long-term cycling stability,establishes PI-COF as a promising material for LIBs.

关键词： Ethylenediaminetetraacetic dianhydride Covalent organic frameworks Polyimide Lithium-ion battery Anode material

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Recent Progress and Regulation Strategies of Layered Materials as Cathode of Aqueous Zinc-Ion Batteries

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Energy & environmental Materials 2024年第3期7卷 18-35页

作者： Yuan Yuan Si Wu Xiaoxue Song Jin Yong Lee Baotao Kang school of chemistry and Chemical engineering University of Jinan Department of chemistry Sungkyunkwan University Shandong Hi-Speed engineering Test Co. Ltd.

Aqueous zinc-ion batteries （ZIBs） have shown great potential in the fields of wearable devices,consumer electronics,and electric vehicles due to their high level of safety,low cost,and multiple electron transfer. The layered cathode materials of ZIBs hold a stable structure during charge and discharge reactions owing to the ultrafast and straightforward （de）intercalation-type storage mechanism of Zn2+ions in their tunable interlayer spacing and their abilities to accommodate other guest ions or ***,the challenges of inadequate energy density,dissolution of active materials,uncontrollable byproducts,increased internal pressure,and a large de-solvation penalty have been deemed an obstacle to the development of ZIBs. In this review,recent strategies on the structure regulation of layered materials for aqueous zinc-ion energy storage devices are systematically summarized. Finally,critical science challenges and future outlooks are proposed to guide and promote the development of advanced cathode materials for ZIBs.

关键词： layered cathode materials modifying strategies structure regulation zinc-ion batteries

Research progresses on cathode materials of aqueous zinc-ion batteries

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Journal of Energy chemistry 2024年第10期97卷 237-264页

作者： Zengyuan Fan Jiawei Wang Yunpeng Wu Xuedong Yan Dongmei Dai Xing-Long Wu Jilin Provincial Science and Technology Innovation Centre of Optical Materials and chemistry Jilin Provincial International Joint Research Center of Photo-functional Materials and Chemistry School of Chemistry and Environmental Engineering Changchun University of Science and Technology Chongqing Research Institute Changchun University of Science and Technology Institute of Energy Storage and Conversion Technology College of Chemical EngineeringNingbo Polytechnic school of chemistry and Chemical engineering Henan Normal University MOE Key Laboratory for UV Light-Emitting Materials and Technology School of Physics Northeast Normal University

Electrochemical energy storage and conversion techniques that exhibit the merits such as high energy density,rapid response kinetics,economical maintenance requirements and expedient installation procedures will hold a pivotal role in the forthcoming energy storage technologies *** recent years,aqueous zinc-ion batteries（AZIBs） have garnered substantial attention as a compelling candidate for large-scale energy storage systems,primarily attributable to their advantageous featu res encompassing cost-effectiveness,environmental sustainability,and robust safety ***,one of the primary factors hindering the further development of AZIBs originates from the challenge of cathode ***,the three mainstream types of mainstream cathode materials,in terms of manganese-based compounds,vanadium-based compounds and Prussian blue analogues,surfer from the dissolution of Mn2+,in the low discharge voltage,and the low specific capacity,*** strategies have been developed to compensation the above intrinsic defects for these cathode materials,including the ionic doping,defect engineering,and materials ***,this review first provides a systematic summarization of the zinc storage mechanism in AZIBs,following by the inherent merit and demerit of three kind of cathode materials during zinc storage analyzed from their structure characteristic,and then the recent development of critical strategies towards the intrinsic insufficiency of these cathode *** this review,the methodologies aimed at enhancing the efficacy of manganese-based and vanadium-based compounds are emphasis ***,the article outlines the future prospective directions as well as strategic proposal for cathode materials in AZIBs.

关键词： Aqueous zinc−ion batteries Cathode materials Optimization strategies