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A novel manganese tungstate nanorod catalyst for the oxidation of styrene with tert-butyl hydroperoxide as oxidant

Tungsten 2024年第4期6卷 845-858页

作者： Shanmugam Manimaran Arumugam Pandurangan Gopalakrishnan Govindasamy Department of Chemistry Anna University energy Cluster School of Engineering University of Petroleum and Energy Studies (UPES)

Catalyst,solvent and process parameters are the keys for the selective oxidation of styrene and other olefins to value added *** MnWO4was synthesized by the one-pot hydrothermal method using Pluronic F127 as a surfactant,characterized and evaluated for the oxidation of styrene and different olefins,using tert-butyl hydroperoxide（TBHP） as oxidant.X-ray diffractogram confirmed the phase purity of MnWO4which became further evident from the near surface equimolar proposition of Mn and W in+2 and+6 oxidation states,respectively,as inferred from X-ray photoelectron spectra.N2sorption followed type Ⅳa isotherm with H3 hysteresis loop,starting at the relative pressure（P/P_o） of 0.9,typically of mesoporous materials containing macropores as further confirmed by pore-size *** electron microscope images of MnWO4revealed its nanorod *** the absence of catalyst,styrene conversion was 35%with benzaldehyde as the sole product and addition of 75 g of MnWO4increased the styrene conversion to 97.3%,and the styrene oxide selectivity from 0% to 85% demonstrated its activity and *** the maximum conversion and styrene oxide selectivity optimum temperature,styrene:TBHP molar ratio,catalyst amount and solvent were found to be 70 ℃,1:2,75 mg,and acetonitrile,***4catalyst retained its activity and selectivity for five recycles,confirming its recoverability and *** the kinetic studies,pre-exponential factor and apparent activation energy were found to be 0.206 s-1and 31.5 kJ·mol-1,respectively,and a reaction mechanism was ***4catalyst was active for oxidation of alkenes,cycloolefins and alkenyl aromatics with high selectivity for epoxides.

关键词： Epoxidation Manganese tungstate nanorod Styrene oxidation

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Recent advances and future prospects on Ni_(3)S_(2)-Based electrocatalysts for efficient alkaline water electrolysis

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Green energy & Environment 2024年第4期9卷 659-683页

作者： Shiwen Wang Zhen Geng Songhu Bi Yuwei Wang Zijian Gao Liming Jin Cunman Zhang Clean energy Automotive Engineering Center School of Automotive StudiesTongji UniversityShanghai201804China

Green hydrogen(H_(2))produced by renewable energy powered alkaline water electrolysis is a promising alternative to fossil fuels due to its high energy density with zero-carbon ***,efficient and economic H_(2) production by alkaline water electrolysis is hindered by the sluggish hydrogen evolution reaction(HER)and oxygen evolution reaction(OER).Therefore,it is imperative to design and fabricate high-active and low-cost non-precious metal catalysts to improve the HER and OER performance,which affects the energy efficiency of alkaline water ***_(3)S_(2) with the heazlewoodite structure is a potential electrocatalyst with near-metal conductivity due to the Ni–Ni metal ***,the review comprehensively presents the recent progress of Ni_(3)S_(2)-based electrocatalysts for alkaline water ***,the HER and OER mechanisms,performance evaluation criteria,preparation methods,and strategies for performance improvement of Ni_(3)S_(2)-based electrocatalysts are *** challenges and perspectives are also analyzed.

关键词： Alkaline water electrolysis Hydrogen Electrocatalysts Ni_(3)S_(2)

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Impact of a Magnetic Dipole on Heat Transfer in Non-Conducting Magnetic Fluid Flow over a Stretching Cylinder

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Fluid Dynamics & Materials Processing 2024年第3期20卷 475-486页

作者： Anupam Bhandari Department of Mathematics School of EngineeringUniversity of Petroleum&Energy Studies(UPES)Energy Acres BuildingBidholi DehradunUttarakhand248007India

The thermal behavior of an electrically non-conducting magnetic liquid flowing over a stretching cylinder under the influence of a magnetic dipole is *** governing nonlinear differential equations are solved numerically using a finite element approach,which is properly validated through comparison with earlier results available in the *** results for the velocity and temperature fields are provided for different values of the Reynolds number,ferromagnetic response number,Prandtl number,and viscous dissipation *** influence of some physical parameters on skin friction and heat transfer on the walls of the cylinder is also *** applicability of this research to heat control in electronic devices is discussed to a certain extent.

关键词： Ferrofluid stretching cylinder finite element method heat transfer magnetic dipole

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Development of advanced anion exchange membrane from the view of the performance of water electrolysis cell

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Journal of energy Chemistry 2024年第3期90卷 348-369,I0009页

作者： Chao Liu Zhen Geng Xukang Wang Wendong Liu Yuwei Wang Qihan Xia Wenbo Li Liming Jin Cunman Zhang Clean energy Automotive Engineering Center Tongji UniversityShanghai 201804China school of Automotive studies Tongji UniversityShanghai 201804China

Green hydrogen produced by water electrolysis combined with renewable energy is a promising alternative to fossil fuels due to its high energy density with zero-carbon *** water electrolysis technologies,the anion exchange membrane(AEM) water electrolysis has gained intensive attention and is considered as the next-generation emerging technology due to its potential advantages,such as the use of low-cost non-noble metal catalysts,the relatively mature stack assembly process,***,the AEM water electrolyzer is still in the early development stage of the kW-level stack,which is mainly attributed to severe performance decay caused by the core component,i.e.,***,the review comprehensively presents the recent progress of advanced AEM from the view of the performance of water electrolysis ***,fundamental principles and critical components of AEM water electrolyzers are introduced,and work conditions of AEM water electrolyzers and AEM performance improvement strategies are *** challenges and perspectives are also analyzed.

关键词： Hydrogen Water electrolysis Anion exchange membrane Electrolysis cell

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High-lattice-adapted surface modifying Na_(4)MnV(PO_(4))_(3) for better sodium storage

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Nano Research 2024年第4期17卷 2728-2735页

作者： Chongran Song Shiyu Li Ying Bai International Joint Research Laboratory of New energy Materials and Devices of Henan Province School of Physics and ElectronicsAcademy for Advanced Interdisciplinary StudiesHenan UniversityKaifeng 475004China

Sodium-ion batteries(SIBs)are required to possess long cycle life when used for large-scale energy *** polyanionic Na_(4)MnV(PO_(4))_(3)(NMVP)reveals good cyclic stability due to its unique three-dimensional(3D)frame structure,but it still faces the challenge of interfacial degradation in practical *** this work,NASICON-type Na_(1.3)Al_(0.7)Ti_(1.3)(PO_(4))_(3)(NATP)was deposited on the surface of NMVP to promote interface stability by surface modification and gradient *** a result,the optimized NMVP@2%NATP released a capacity retention of 44.8%after 1000 cycles at 5 C,much higher than that of the initial NMVP(28.9%).The enhanced electrochemical performance was mainly attributed to NATP coating acting as a fast ion transport carrier and physical barrier,significantly facilitating the Na^(+)diffusion and isolating side reaction at the electrode/electrolyte *** the other hand,Ti_(4)^(+)and Al^(3+)cations from the NATP were partially doped inside the NMVP surface to boost the transport of Na^(+),and the perfect lattice matching of NVMP and NATP improved the interface and structural stability accompanying long *** work demonstrated the effectiveness of surface modification with high lattice match material and provided new perspectives for high energy density solid-state SIBs.

关键词： high-lattice-adapted cathode surface modification sodium-ion batteries

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Effect of catalyst diesel particulate filter aging and catalyst loadings on particulate emission characteristics from a diesel vehicle

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Journal of Environmental Sciences 2024年第2期136卷 35-44页

作者： Yunhua Zhang Diming Lou Piqiang Tan Zhiyuan Hu Liang Fang school of Automotive studies Tongji UniversityShanghai 201804China

In this study,the effect of new and used catalyzed diesel particulate filter(CDPF)with different catalyst loadings on the particulate emissions including the particle mass(PM),particle number(PN),particle size distribution(PSD)and geometric mean diameter(GMD)from a diesel vehicle were investigated based on a heavy chassis *** showed that more than 97.9%of the PN and 95.4%of the PM were reduced by the CDPF,and the reduction efficiency was enhanced by the catalyst *** using the CDPF,the PSD transformed from bimodal to trimodal with the peak shifting towards smaller particle size,more nucleation mode particles were reduced compared with accumulation mode ones,but the reduction effect on the accumulation mode particles was more significantly influenced by the catalyst ***,the CDPF increased the accumulation mode particles proportion,producing a larger *** the used CDPF,its reduction effect on the particulate emissions enhanced,especially for the PM in accumulation *** PSD returned to bimodal,but the peak at accumulation mode began to be higher than that at nucleation mode,illustrating that more nucleation mode particles was *** aging of the CDPF resulted in greater effect on the PN-based PSD than that of PM-based PSD,but the effect of catalyst loading on the PN and PM emission factors was *** used CDPF further increased the GMD,and the effect of catalyst loading on the GMD was strengthened,a higher catalyst loading led to a reduction in the GMD.

关键词： Catalyzed diesel particulate filter (CDPF) Catalyst loading Aging Particle Particle size distribution Geometric mean diameter

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Smart electrochemical sensing of amyloid-beta to manage total Alzheimer's diseases

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Neural Regeneration Research 2024年第6期19卷 1185-1186页

作者： Ajeet Kaushik NanoBioTech Laboratory Department of Environmental EngineeringFlorida Polytechnic UniversityLakelandFLUSA school of Engineering University of Petroleum and Energy Studies(UPES)DehradunIndia

Need for Alzheimer's disease progression monitoring:Alzheimer's disease(AD)is an irreversible progressive brain disorder that causes severe and incurable *** World Health Organization estimates that 55 million people are affected by AD dementia by 2020 which may exceed 78 million by 2030 and 139 in *** estimated cost to manage AD is above US$1.3 trillion,which will further increase to US$2.8 trillion by 2030.

关键词： Alzheimer amyloid diseases

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CdTe QDs@SiO2 composite material for efficient photocatalytic degradation of tetracycline composites

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Green Chemical Engineering 2024年第4期5卷 533-542页

作者： Taihang Zhou Fen Qiao Sen Qian Shoaib Muhammad Haitao Li Yanzhen Liu school of energy & Power Engineering Jiangsu University Institute for energy Research Jiangsu University

In the contemporary context,tetracycline is widely utilized as a prevalent antibiotic in various facets of ***,the excessive use of antibiotics has caused visible environmental ***,the scientific community has increasingly focused on developing catalysts that exhibit exceptional efficacy in the proficient degradation of *** this study,a novel nanomaterial was developed to encapsulate Cd Te quantum dots （QDs） with a *** distinct synthesis approach generated a composite material that showed heterogeneity and considerably increased the contact area with ***,the transfer of photoelectron to the SiO2spheres was significantly improved,leading to a more efficient separation during the catalytic *** study investigated how different factors,such as the loading of the catalyst,the initial concentration of tetracycline,p H levels,and the wight ratio of Cd Te QDs （SiO2+Cd Te QDs） affected the effectiveness of photocatalytic tetracycline *** findings indicated that the optimal degradation efficiency was observed at a catalyst concentration of 0.25 g/L and a solution p H of 9,leading to an impressive degradation rate of 96%within a mere 2 h timeframe.

关键词： Photocatalysis Silica-based catalyst Photocatalytic degradation Photocatalytic mechanism

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Thermal characteristic evolution of lithium-ion batteries during the whole lifecycle

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Journal of energy Chemistry 2024年第5期92卷 534-547页

作者： Guangxu Zhang Xuezhe Wei Donghai Chen Xueyuan Wang Siqi Chen Jiangong Zhu Haifeng Dai school of Materials Science and Engineering Tongji UniversityShanghai 201804China Clean energy Automotive Engineering Center Tongji UniversityShanghai 201804China school of Automotive studies Tongji UniversityShanghai 201804China

This work extensively investigates the thermal characteristic evolution of lithium-ion batteries under different degradation paths,and the evolution mechanism through multi-angle characterization is *** different degradation paths,the evolution trend of temperature rise rate remains unchanged with respect to depth of discharge during the adiabatic discharge process,albeit to varying degrees of *** temperature rise rate changes significantly with aging during the adiabatic discharge process under low-temperature cycling and high-rate cycling *** total heat generation rate,irreversible heat generation rate,and reversible heat generation rate exhibit similar evolution behavior with aging under different degradation *** interval range of endothermic process of reversible electrochemical reactions increases and the contribution of irreversible heat to the total heat increases with *** further standardize the assessment of different degradation paths on the thermal characteristics,this work introduces the innovative concept of“Ampere-hour temperature rise”.In low-temperature cycling and high-rate cycling paths,the ampere-hour temperature rise increases significantly with aging,particularly accentuated with higher discharge ***,in high-temperature cycling and high-temperature storage paths,the ampere-hour temperature rise remains relatively stable during the initial stages of aging,yet undergoes a notable increase in the later stages of *** multi-angle characterization reveals distinct thermal evolution behavior under different degradation paths primarily attributed to different behavior changes of severe side reactions,such as lithium *** findings provide crucial insights for the safe utilization and management of lithium–ion batteries throughout the whole lifecycle.

关键词： Lithium-ion batteries Adiabatic discharge Thermal characteristics Ampere-hour temperaturerise Degradation

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Nano-Ni-Induced Electronic Modulation of MoS_(2) Nanosheets Enables energy-Saving H_(2) Production and Sulfide Degradation

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energy & Environmental Materials 2024年第3期7卷 228-235页

作者： Fan Liu Xinghong Cai Yang Tang Wenqian Liu Qianwei Chen Peixin Dong Maowen Xu Yangyang Tan Shujuan Bao Institute for Clean energy&Advanced Materials School of Materials and EnergySouthwest UniversityChongqing 400715China

Electrocatalytic hydrogen evolution and sulfion(S^(2-))recycling are promising strategies for boosting H_(2)production and removing environmental ***,a nano-Ni-functionalized molybdenum disulfide(MoS_(2))nanosheet was assembled on steel mesh(Ni-MoS_(2)/SM)for use in sulfide oxidation reaction-assisted,energy-saving H_(2)*** and theoretical calculation results revealed that anchoring nano-Ni on high-surface-area slack MoS_(2)nanosheets not only optimized catalyst adsorption of polysulfides but also played an important role in promoting hydrogen evolution reaction kinetics by absorbing OH_(ad),thereby greatly enhancing the catalytic performance toward sulfide oxidation reaction and hydrogen evolution ***,the Ni/MoS^(2-)based hydrogen evolution reaction+sulfide oxidation reaction system achieved nearly 100%hydrogen production efficiency and only consumed 61%less power per kWh than the oxygen evolution reaction+hydrogen evolution reaction system,which suggested our proposed Ni-MoS_(2)and novel hydrogen production system are promising for sustainable energy production.

关键词： hydrogen evolution reaction low energy consumption molybdenum disulfide sulfide oxidation reaction

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