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Journal of environmental Sciences 2010年第8期22卷 1189-1194页

作者： Jianjie Fu, Yawei Wang, Qunfang Zhou, Guibin Jiang State key laboratory of environmental chemistry and ecotoxicology, Research Center for Eco-environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China. State key laboratory of environmental chemistry and ecotoxicology Research Center for Eco-Environmental Sciences Chinese Academy of Sciences Beijing 100085 China

Gaobeidian Lake, located in Beijing, China, serves as a recipient lake for efluents from a large municipal sewage treatment plant （MSTP）. In order to evaluate the effects of discharging MSTP efluent on the mercury contamination of the local aquatic ecosystem, sediment cores, water, plankton, fish, and turtle samples were collected from Gaobeidian Lake for mercury speciation analysis. High concentrations of total mercury （T-Hg） were detected in sediment cores （5.24–17.0 μg/g dry weight （dw）, average： 10.1 μg/g）. The ratio of methylmercury （MeHg） to T-Hg was less than 0.3% in sediments and ranged from 35% to 76% in biota samples. The highest level of T-Hg and MeHg were found in aquatic bryophyte and crucian carp （3673 and 437 ng/g dw, respectively）. The relative contents of MeHg were significantly correlated with trophic levels （R2 = 0.5506, p 0.001）, which confirmed that MeHg can be bio-transferred and biomagnified via food chain in this aquatic ecosystem.

关键词： methylmercury total mercury trophic levels aquatic ecosystem municipal sewage treatment plants

Effects of maize root exudates and organic acids on the desorption of phenanthrene from soils

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Journal of environmental Sciences 2009年第7期21卷 920-926页

作者： ZHU Yanhong, ZHANG Shuzhen, HUANG Honglin, WEN Bei State key laboratory of environmental chemistry and ecotoxicology, Research Center for Eco-environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China. State key laboratory of environmental chemistry and ecotoxicology Research Center for Eco-Environmental Sciences Chinese Academy of Sciences Beijing 100085 China

The effects of maize root exudates and low-molecular-weight-organic anions （LMWOAs） on the desorption of phenanthrene from eight artificially contaminated soils were evaluated. A significant negative correlation was observed between the amounts of phenanthrene desorbed and the soil organic carbon （SOC） contents （P 〈 0.01）, and the influences of soil pH and clay content on phenanthrene desorption were insignificant （P 〉 0.1）. Neither maize root exudates nor oxalate and citrate anions influenced desorption of phenanthrene with the addition of NaN3. A faster phenanthrene desorption occurred without the addition of NaN3 in the presence of maize root exudates than oxalate or citrate due to the enhanced degradation by root exudates. Without the addition of NAN3, oxalate or citrate at different concentrations could inhibit phenanthrene desorption to different extents and the inhibiting effect by citrate was more significant than by oxalate. This study leads to the conclusion that maize root exudates can not enhance the desorption under abiotic condition with the addition of NaN3 and can promote the desorption of phenanthrene in soils without the addition of NaN3.

关键词： phenanthrene desorption low-molecular-weight-organic anions (LMWOAs) root exudates soils

Levels and distributions of polychlorinated biphenyls in sewage sludge of urban wastewater treatment plants

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Journal of environmental Sciences 2009年第4期21卷 468-473页

作者： GUO Li, ZHANG Bing, XIAO Ke, ZHANG Qinghua, ZHENG Minghui State key laboratory of environmental chemistry and ecotoxicology, Research Center for Eco-environmental Sciences, Chinese Academy of Sciences,Beijing 100085, China State key laboratory of environmental chemistry and ecotoxicology Research Center for Eco-Environmental Sciences Chinese Academy of Sciences Beijing 100085 China

Concentrations of polychlorinated biphenyls （PCBs） have been measured in sewage sludge samples from 8 urban wastewater treatment plants in Beijing, China. The PCB congeners were analyzed by isotope dilution high resolution gas chromatography/high resolution mass spectrometry method. The concentration of PCBs ranged from 65.6 to 157 ng/g dry weight （dw）, with a mean value of 101 ng/g dw. The dioxin-like PCB WHO-TEQs （World Health Organization-Toxic Equivalents） of the sludge were lower than 1 pg /g dw. Consequently, all the concentrations of PCBs in sludge samples were below the upper limit for land application according to the Chinese legislation law for agriculture use. The PCB homologue profiles in sludge samples were dominated by tri-CBs and tetra- CBs. Similar distributions have been found in one of the Chinese PCB commercial products. The patterns of dioxin-like and indicator congeners observed in this study were quite similar in all samples. The predominant congener for dioxin-like and indicator PCBs were PCB-118 and PCB-28, respectively, while PCB-126 had the highest TEQ value.

关键词： polychlorinated biphenyls wastewater treatment plant sewage sludge distribution

Influence of organic amendments on the sorption of pentachlorophenol on soils

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Journal of environmental Sciences 2009年第4期21卷 474-480页

作者： LI Ruijuan, WEN Bei, ZHANG Shuzhen, PEI Zhiguo, SHAN Xiaoquan State key laboratory of environmental chemistry and ecotoxicology, Research Center for Eco-environmental Sciences, Chinese Academy of Sciences,Beijing 100085, China State key laboratory of environmental chemistry and ecotoxicology Research Center for Eco-Environmental Sciences Chinese Academy of Sciences Beijing 100085 China

The influence of pH on the sorption of pentachlorophenol （PCP） onto three organic amendments, char, humic acid （HA） and peat, and the effect of organic amendments on PCP sorption to three kinds of soils were evaluated. The sorption of PCP on these sorbents fitted the Freundlich model well, suggesting that PCP sorption isotherms were nonlinear with exponential coefficient （N） value lower than 1. The PCP sorption capacity on three organic amendments and the N values increased with decreasing pH. The sorption capacities were in the order： char 〉 HA 〉 peat. Organic amendments resulted in an enhancement of sorption capacities of soils. The N values of PCP sorption on soils were decreased by char amendment and increased by HA and peat amendments. This study demonstrated that application of traditional organic amendments led to the enhancement of PCP sorption by soils. This information may aid both in predicting environmental fates of hydrophobic ionizable organic compounds and in developing remediation strategies for them.

关键词： sorption pentachlorophenol char peat humic acid pH

Seasonal trend of ambient PCDD/Fs in Tianjin City, northern China using active sampling strategy

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Journal of environmental Sciences 2012年第11期24卷 1966-1971页

作者： Lei Ding Yingming Li Pu Wang Xiaomin Li Zongshan Zhao Qinghua Zhang Ting Tuan Guibin Jiang State key laboratory of environmental chemistry and ecotoxicology Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China

The spatial concentrations, seasonal trends, profiles and congener pairs of ambient polychlorinated dibenzo-p-dioxins （PCDDs） and polychlorinated dibenzofurans （PCDFs） were investigated within a seasonally active sampling scheme during Jun 2008 and Jan 2009 in Tianjin City, northern China. The PCDD/F concentrations ranged 14.2-172 fg I-TEQ/m3 （average 69.3 fg I-TEQ/m3） in summer and （89.8-1.01） x 103 fg I-TEQ/m3 （average 509 fg I-TEQ/m3） in winter, respectively, except for the E-waste dismantling site where much higher values were observed （1.04 x 103 fg I-TEQ]m3 in summer and 7.123 x 103 fg I-TEQ/m3 in winter）. The results indicated a significantly seasonal trend with higher TEQ values in winter as compared with summer, which could be related to increased emission sources and seasonal variations of the atmospheric boundary layer height. 2,3,4,7,8-PeCDF was the dominant contributor to the total PCDD/F toxic equivalents, and 2,3,7,8-TCDD was detected at almost all the sampling sites in winter. Most of the similarly substituted PCDD/F congener pairs exhibited high correlations, suggesting that they might have similar environmental fate or sources. But different seasonal and spatial distributions of PCDD/F concentrations indicated that the emission sources might be intermittent.

关键词： PCDD/Fs seasonal trend Tianjin high-volume air sampling

Intraspecific differences in effects of co-contamination of cadmium and arsenate on early seedling growth and metal uptake by wheat

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Journal of environmental Sciences 2007年第10期19卷 1221-1227页

作者： LIU Xiao-li ZHANG Shu-zhen State key laboratory of environmental chemistry and ecotoxicology Research Center for Eco-Environmental Sciences Chinese Academy of Sciences Beijing 100085 China

A hydroponic experiment was carried out to study intraspecific differences in the effects of different concentrations of cadmium （Cd）（0-10 mg/L） and arsenate （As（V））（0-8 mg/L） on the growth parameters and accumulation of Cd and As in six wheat varieties Jing- 9428, Duokang- 1, Jingdong- 11, Jing-411, Jingdong-8 and Zhongrnai-8. The endpoints of wheat seedlings, including seed germination, biomass, root length and shoot height, decreased with increasing the Cd and As concentrations. Significant differences in seed germination, biomass, root length, shoot height and the accumulation of Cd and As were observed between the treatments and among the varieties （p 〈 0.05）. The lethal dosage 50% were about 20, 80, 60, 60, 80 and 20 mg As/L for Jing-9428, Duokang-1, Jingdong-11, Jing-411, Jingdong-8 and Zhongrnai-8, respectively, and the corresponding values for Cd were about 30, 80, 20, 40, 60 and 10 mg Cd/L, respectively. Among the six varieties, Duokang-1 was found to be the most resistant to Cd and As toxicity, and Zhongrnai-8 was the most sensitive to Cd and As co-contamination. The resistance of the six varieties was found dependant on the seedling uptake of Cd and As. Duokang-1 was the most suitable for cultivation in Cd and As co-contaminated soils.

关键词： Cd As varieties co-contamination wheat seedling

Advanced molecular-fingerprinting analysis of dissolved organic sulfur by electrospray ionization-Fourier transform ion cyclotron resonance mass spectrometry using optimal spray solvent

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Journal of environmental Sciences 2020年第11期32卷 67-74页

作者： Dong Cao Ziyu Rao Fanglan Geng Hongyun Niu Yali Shi Yaqi Cai Yuehui Kang State key laboratory of environmental chemistry and ecotoxicology Research Center for Eco-Environmental ScienceChinese Academy of SciencesBeijing 100085China

Molecular level characterization of dissolved organic sulfur(DOS)by electrospray ionizationFourier transform ion cyclotron resonance mass spectrometry(ESI-FTICR MS)is necessary for further understanding of the role of DOS in the ***,ESI spray solvent,a key parameter for ion production during ESI process,was investigated for its effect on the molecular characterization of DOS by ESI-FTICR MS.100%MeOH as spray solvent was found for the first time to remarkably enhance the ionization efficiency of the majority of CHOS-molecules in NOM,which facilitated a total of 1473 CHOS-molecular formulas with one sulfur atom to be *** number of CHOS-molecular formulas obtained using 100%MeOH as spray solvent increased notably over 740 in comparison with those using 50%MeOH aqueous solution(731)or 50%ACN aqueous solution(653).Moreover,due to the enhancement of ionization efficiency of DOS during ESI processes,the tandem mass spectra of the NOM CHOS-molecules could be easily obtained using 100%MeOH as spray solvent,which were hardly obtained using 50%MeOH aqueous solution as spray *** results of the tandem mass spectra suggested the first discovery of organosulfates or sulfonic acids in Suwannee River NOM sample.A simple method based on 100%MeOH as ESI spray solvent for advanced molecular characterization of DOS by ESI-FTICR MS was proposed and applied,and the results revealed more molecular information of DOS in sea DOM samples.

关键词： Natural organic matter Fourier transform ion cyclotron resonance mass spectrometry Spray solvent Dissolved organic sulfur

Toxicity-based assessment of the treatment performance of wastewater treatment and reclamation processes

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Journal of environmental Sciences 2012年第6期24卷 969-978页

作者： Dongbin Wei Zhuowei Tan Yuguo Du State key laboratory of environmental chemistry and ecotoxicology Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China

The reclamation and reuse of wastewater is one of the possible ways to relieve the serious fresh water resource crisis in China. Efficient reclamation treatment technologies ensure the safe reuse of reclaimed water. In order to screen out and evaluate technologies appropriate for reclamation treatment, a great deal of efforts have been brought to bear. In the present study, a toxicity-based method including a Photobacterium phosphoreum test for acute toxicity and SOS/umu test for genotoxicity, accompanied by the traditional physicochemical parameters DOC （dissolved organic carbon） and UV254 （absorbance at 254 nm）, was used to measure the treatment performance of different reclamation processes, including the anaerobic-anoxic-oxic biological process （A^2O） and subsequent physical/chemical reclamation processes （ultrafiltration, ozonation, chlorination）. It was found that for the secondary effluent after the Aao process, both the toxicity and physicochemical indices had greatly decreased compared with those of the influent. However, chemical reclamation processes such as ozonation and chlorination could possibly raise toxicity levels again. Fortunately, the toxicity elevation could be avoided by optimizing the ozone dosage and using activated carbon after ozonation. It was noted that by increasing the ozone dosage to 10 mg/L and employing activated carbon with more than 10 min hydraulic retention time, toxicity elevation was controlled. Furthermore, it was shown that pre-ozonation before activated carbon and chlorination played an important role in removing organic compounds and reducing the toxicity formation potential. The toxicity test could serve as a valuable tool to evaluate the performance of reclamation processes.

关键词： wastewater reclamation acute toxicity genotoxicity toxicity assessment

Glucose production from hydrolysis of cellulose over a novel silica catalyst under hydrothermal conditions

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Journal of environmental Sciences 2012年第3期24卷 473-478页

作者： Huayu Wang Changbin Zhang Hong He Lian Wang State key laboratory of environmental chemistry and ecotoxicology Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China

A novel silica catalyst was synthesized by evaporation-induced self-assembly （EISA） method and tested for the catalytic selective hydrolysis of cellulose to glucose. This silica catalyst exhibited a higher catalytic activity than other oxides prepared by the same method, such as ZrO2, TiO2, and Al2O3. Using silica as a catalyst, cellulose was selectively hydrolyzed into glucose with a glucose yield as high as 50% under hydrothermal conditions without hydrogen gas. The silica catalyst was characterized by Brunauer-Emmett-Teller （BET）, X-ray diffraction （XRD） and transmission electron microscopy （TEM）. The results of temperature-programmed desorption of ammonia （NH3-TPD） and textural properties indicated that the synergistic effect between strong acidity and a suitable pore diameter of the silica catalyst may be responsible for its high activity. In addition, the catalyst was recyclable and showed excellent stability during the recycle catalytic runs.

关键词： cellulose glucose silica catalyst hydrolysis hydrothermal biomass

Effect of SO_2 on the performance of Ag-Pd/Al_2O_3 for the selective catalytic reduction of NOx with C_2H_5OH

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Journal of environmental Sciences 2006年第5期18卷 973-978页

作者： XIE Shu-xia YU Yun-bo WANG Jin HE Hong State key laboratory of environmental chemistry and ecotoxicology Research Center for Eco-Environmental Sciences Chinese Academy of Sciences Beijing 100085 China

The influence of SO2 on the performance of Ag-Pd/Al2O3 for the selective catalytic reduction （SCR） of NOx with C2H5OH was investigated experimentally. The activity test results suggest that Ag-Pd/Al2O3 shows a small activity loss in the presence of SO2 when using C2H5OH as a reductant. In situ DRIFTS spectra show that the activity loss originates from the formation of surface sulphate species on the Ag-Pd/Al2O3. The surface sulphate species formation inhibits the formation of nitrate, whereas hardly changes the partial oxidation of C2H5OH. Compared with the NOx reduction by C3H6, an obvious suppression of the surface sulphate species formation was observed by DRIFTS experiment when using C2H5OH as a reductant. This phenomenon reveals the better catalytic performance and strong SO2 tolerance of Ag-Pd/Al2O3-C2H50H system.

关键词： sulphate SCR nitrate enolic species isocyanate reaction mechanism