检索结果-南通市图书馆

Elucidating elusive quaternary selenide EuCeCuSe3:Synthesis,crystal structure,properties and theoretical studies

Journal of Rare Earths 2024年第1期42卷 163-171,I0006页

作者： Maxim V.Grigoriev Anna V.Ruseikina Maxim S.Molokeev Vladimir A.Chernyshev Aleksandr S.Aleksandrovsky Alexander S.Krylov Svetlana N.Krylova Nikolai P.Shestakov Dmitriy A.Velikanov Alexander A.Garmonov Alexey V.Matigorov Evgeny A.Ostapchuk Thomas Schleid Damir A.Safin Laboratory of Theory and Optimization of Chemical and Technological Processes University of TyumenVolodarskogo Str.6625003TyumenRussian Federation Kirensky institute of physics Federal Research Center KSC SB RASAkademgorodok 50 Bld.38660036KrasnoyarskRussian Federation Department of physics Far Eastern State Transport UniversitySerysheva Str.47680021KrasnoyarskRussian Federation institute of Natural Sciences and Mathematics Ural Federal University Named After the First President of Russia B.N.YeltsinMira Str.19620002EkaterinburgRussian Federation Department of Photonics and Laser Technology Siberian Federal UniversitySvobodnii Ave.79660079KrasnoyarskRussian Federation institute of physics and Technology University of TyumenVolodarskogo Str.6625003 TyumenRussian Federation institute for Inorganic Chemistry University of StuttgartPfaffenwaldring 55D-70569StuttgartGermany Scientific and Educational and Innovation center for Chemical and Pharmaceutical Technologies Ural Federal University named after the First President of Russia B.N.YeltsinMira Str.19620002 EkaterinburgRussian Federation University of Tyumen Volodarskogo Str.6625003TyumenRussian Federation

We report on the novel heterometallic quaternary selenide EuCeCuSe3,the fabrication of which has been a challenge until this *** structure of the reported selenide was elucidated from the powder X-ray diffraction data,which revealed the formation of EuCeCuSe3with excellent yield(96.7%)accompanied with a minor fraction of CeSe2(3.3%),and was best solved in orthorhombic space group Pnma with the BaLaCuS3structural ***,the crystal structure of the title compound completes the row of the heterometallic quaternary selenides EuRECuSe3(RE=La,Pr,Nd,Sm,Eu,Gd,Tb,Dy,Ho,Er,Tm,Yb,Lu,Y),of which the cerium-based derivative exclusively belongs to the BaLaCuS3structural *** distortion of the CuSe4polyhedron was compared for the whole series of EuRECuSe3compounds using theτ4-descriptor for four coordinated ions,which revealed the highest degree of distortion for the Ce3+-containing selenide,followed by the La3+-based ***,the crystallographic and geometrical parameters of the reported selenide were discussed in comparison to the Ce3+-based sulfides SrCeCuS3and *** initio calculations of the crystal structure,a phonon spectrum and elastic constants for the crystal of EuCeCuSe3were also *** types and wavenumbers of fundame ntal modes were determined and the involvement of ions participating in the phonon modes was *** experimental IR spectrum of the reported selenide was interpreted and found to be in agreement with the calculated *** experimental direct band gap of EuCeCuSe3was measured to be 1.36 eV that is consistent with the concept of its origin due to interband transitions between orbitals emerging mainly from 4f(valence band)and 5d(conduction band)levels of the Eu2+*** dependence of the Young’s modulus on the direction demonstrates the anisotropy of the elastic properties,while the Vickers hardness for EuCeCuSe3was calculated to be 5.2 ***,the title compound is paramagnetic above 4 K.

关键词： Quaternary selenide Synthesis Crystal structure Ab initio calculations Magnetic measurements Spectroscopy

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Expanded Porphyrin Exhibiting Off-centered Out-of-Plane Coordination to Dysprosium

引用

CCS Chemistry 2024年第7期6卷 1731-1738页

作者： Dmitry I.Nazarov Jorge Labella Alexey V.Kuzmin Maxim A.Faraonov Evgenii N.Ivanov Salavat S.Khasanov Tomas Torres Mikhail K.Islyaikin Dmitri V.Konarev federal research center of Problems of Chemical physics and Medicinal Chemistry RAS 142432 Chernogolovka Department of Organic Chemistry Universidad Autonoma de Madrid28049 Madrid institute of Solid-State physics RAS 142432 Chernogolovka research institute of Macroheterocycles Ivanovo State University of Chemistry and Technology15300 Ivanovo G.A.Krestov institute of Solution Chemistry of the russian Academy of Sciences 153045 Ivanovo institute for Advanced research in Chemical Sciences Universidad Autonoma de Madrid28049 Madrid IMDEA-Nanociencia 28049 Madrid

The complexation of high-spin lanthanides to porphyrinoids is a powerful strategy for the development of advanced molecular *** this context,the use of expanded porphyrinoids remains elusive since their coordination chemistry is challenging to ***,taking inspiration from on-surface chemistry,we explored the coordination of Dy^(3+)to a six-membered porphyrinoid,namely,the hemihexaphyrazine ***,we observed the selective formation of a mono-nuclear off-centered,out-of-plane H_(2)Hhp-Dy^(3+)complex when performing the complexation under reductive *** this reaction,the oxidation state of the macrocycle did not *** X-ray diffraction analysis,we found that the coordination number of Dy in this complex was *** macrocycle cocrystallized with decamethylcobaltocene(Cp_(2)^(*)Co)molecules,giving rise to a wellordered solid-state packing,governed byπ-π*** a result of this organization,a small magnetic coupling between the neighboring molecules was *** in all,this work provides key insights into the coordination of magnetically active metals with expanded porphyrinoids,thus motivating the development of advanced spintronic devices.

关键词： porphyrins dysprosium macrocycle coordination chemistry magnetism

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Optimization of performance of the KM2A full array using the Crab Nebula

引用

Chinese physics C 2024年第6期48卷 169-178页

作者：曹臻 F.Aharonian 安琪阿西克古白云翔包逸炜 D.Bastieri 毕效军毕玉江蔡金庭曹晴曹文羽曹喆常进常劲帆陈尚明陈恩生陈亮陈林陈龙陈明君陈玛丽陈起辉陈素弘陈天禄陈阳程宁程耀东崔明阳崔树旺崔晓红崔昱东戴本忠代洪亮戴子高单增罗布 D.della Volpe 董绪强段凯凯樊军辉范一中方军方堃冯存峰封莉冯少辉丰晓婷冯有亮 S.Gabici 高博高川东高林青高启高卫高伟康葛茂茂耿利斯 G.Giacinti 龚光华苟全补顾旻皓郭福来郭晓磊郭义庆郭莹莹韩毅昂何会海贺昊宁何佳银何新波何钰 M.Heller 贺远强侯博文侯超侯贤胡红波胡铨胡世聪黄代绘黄天奇黄文俊黄性涛黄晓渊黄勇黄志成季筱璐贾焕玉贾康江琨姜晓巍姜泽军金敏康明铭柯通 D.Kuleshov.K.Kurinov 李兵兵李澄李骢李丹李飞李海波李会财李华阳李军李剑李捷李凯李文龙李文莲李秀荣李昕李一卓李哲黎卓梁恩维梁云峰林苏杰刘冰刘成刘栋刘虎刘海东刘佳刘江来刘金艳刘茂元柳若愚刘四明刘伟刘怡刘以农鲁睿罗晴吕洪魁马伯强马玲玲马欣华毛基荣闵振 W.Mitthumsiri 穆慧君南云程 A.Neronov 区子维庞彬宇 P.Pattarakijwanich 裴致远齐孟尧祁业情乔冰强秦家军 D.Ruffolo A.Sáiz D.Semikoz 邵澄宇邵琅 O.Shchegolev 盛祥东舒富文宋慧超 Yu.V.Stenkin V.Stepanov 苏扬孙秦宁孙晓娜孙志斌谭柏轩唐庆文唐泽波田文武王超王昌贝王广威王洪光王惠惠王建成汪凯王利苹王玲玉王培汉王冉王为王祥高王祥玉王阳王玉东王岩谨王忠海王仲翔王振王铮韦大明魏俊杰魏永健文韬吴超勇吴含荣武莎吴雪峰吴雨生席邵强夏捷夏君集项光漫肖迪泫肖刚辛广广辛玉良邢祎熊峥徐东莲徐仁峰徐仁新徐伟立薛良闫大海颜景志颜田杨朝文杨帆杨冯帆杨何文杨佳盈杨莉莉杨明洁杨睿智杨深邦姚玉华姚志国叶一锰尹丽巧尹娜游晓浩游智勇于艳红袁强岳华曾厚敦曾婷轩曾玮查敏张彬彬张丰张海明张恒英张建立张丽霞张力张鹏飞张佩佩张瑞张少博张少如张寿山张潇张笑鹏张云峰张毅张勇赵兵赵静赵雷赵立志赵世平郑福周斌周浩周佳能周猛周平周荣周勋秀祝成光祝凤荣朱辉朱科军左雄 LHAASO Collaboration Key Laboratory of Particle Astrophyics&experimental physics Division&Computing center Institute of High Energy PhysicsChinese Academy of SciencesBeijing 100049China University of Chinese Academy of Sciences Beijing 100049China Tianfu Cosmic Ray research center Chengdu 610000China Dublin institute for Advanced Studies 31 Fitzwilliam Place2 DublinIreland Max-Planck-Institut for nuclear physics P.O.Box 10398069029 HeidelbergGermany State Key Laboratory of Particle Detection and Electronics China University of Science and Technology of China Hefei 230026China School of Physical Science and Technology&School of Information Science and Technology Southwest Jiaotong UniversityChengdu 610031China School of Astronomy and Space Science Nanjing UniversityNanjing 210023China center for Astrophysics Guangzhou UniversityGuangzhou 510006China Hebei Normal University Shijiazhuang 050024China Key Laboratory of Dark Matter and Space Astronomy&Key Laboratory of Radio Astronomy Purple Mountain ObservatoryChinese Academy of SciencesNanjing 210023China Tsung-Dao Lee institute&School of physics and Astronomy Shanghai Jiao Tong UniversityShanghai 200240China Key Laboratory for research in Galaxies and Cosmology Shanghai Astronomical ObservatoryChinese Academy of SciencesShanghai 200030China Key Laboratory of Cosmic Rays(Tibet University) Ministry of EducationLhasa 850000TibetChina National Astronomical Observatories Chinese Academy of SciencesBeijing 100101China School of physics and Astronomy(Zhuhai)&School of physics(Guangzhou)&Sino-French institute of nuclear Engineering and Technology(Zhuhai) Sun Yat-sen UniversityZhuhai 519000&Guangzhou 510275China School of physics and Astronomy Yunnan UniversityKunming 650091China Département de Physique Nucléaire et Corpusculaire Facultéde SciencesUniversitéde Genève24 Quai Ernest Ansermet1211 GenevaSwitzerland institute of Frontier and Interdisciplinary Science Shandong UniversityQingdao 266237China APC Universit'e Paris Cit'eCNRS/IN2P3CEA/IRFUObservat

The full array of the Large High Altitude Air Shower Observatory(LHAASO)has been in operation since July *** its kilometer-square array(KM2A),we optimized the selection criteria for very high and ultrahigh energyγ-rays using data collected from August 2021 to August 2022,resulting in an improvement in significance of the detection in the Crab Nebula of approximately 15%,compared with that of previous *** the implementation of these new selection criteria,the angular resolution was also significantly improved by approximately 10%at tens of *** aspects of the full KM2A array performance,such as the pointing error,were also calibrated using the Crab *** resulting energy spectrum of the Crab Nebula in the energy range of 10-1000 TeV are well fitted by a log-parabola model,which is consistent with the previous results from LHAASO and other experiments.

关键词： γ-ray Crab Nebula significance

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Flash Lamps as Ignition and Initiation Sources of the VS-2 Pyrotechnic Composition

引用

含能材料 2022年第4期30卷 370-378页

作者： Sergey I.Gerasimov Mikhail A.Ilyushin Sergey M.Putis Sergey A.Dushenok Irina V.Shugalei Andrey M.Sudarikov russian federal nuclear center‑All‑russian research institute of experimental physics SarovRussia sarov institute of physics and Technology is a Branch of the Scientific research nuclear University MEPhI SarovRussia Nizhny Novgorod State Technical University Named after R.E.Alekseev Nizhny NovgorodRussia RAS institute for Studying Problems in Mechanical Engineering ‑is a Branch of the RAS Applied Physics InstituteNizhny NovgorodRussia "Technologist"Special Design and Technological Bureau St.PetersburgRussia Saint‑Petersburg State institute of Technology(Technical University) St.PetersburgRussia russian State Hydro‑meteorological University St.PetersburgRussia

In the present work it is found that the pyrotechnic composition VS⁃2 can be initiated with flash lamps IFC⁃500 and ***⁃2 pyrotechnic composition contains 90%of mercury(Ⅱ)5⁃hydrazinotetrazolate perchlorate and 10%of optically trans⁃parent copolymer of 2⁃methyl⁃5⁃vinyltetrazole and methacrylic acid(PVMT).We have found that the flash lamps make it possi⁃ble to initiate combustion of VS⁃2 composition with its transition to detonation both in cylindrical charges placed in brass caps of 5 mm diameter and 2 mm high,and film charges with 10 mm×80 mm in size and surface weights of 60 mg·cm^(-2)and 90 mg·cm^(-2),showing ignition delay times 10μs and 3μs,*** also measured detonation velocities for VS⁃2 composition film charges,which were 4375-4505 m·s^(-1)(of the charge being surface mass 60 mg·cm^(-2))and 4221-4281 m·s^(-1)(of the charge be⁃ing surface mass 90 mg·cm^(-2))and their blasting action on the aluminum *** depths of the normal shock wave imprints at the charge⁃barrier interface were 0.6-0.7 mm(for surface mass of the film charges 60 mg·cm^(-2))and 1.2-1.3 mm(for surface mass of the film charges 90 mg·cm^(-2))

关键词： VS⁃2 pyrotechnic composition flash lamps ignition transition of combustion to detonation blasting action

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Numerical 3D-modeling of spall and shear fractures in shells of austenitic 12Kh18N10T steel and 30KhGSA steel under their spherical and quasi-spherical explosive loading

引用

International Journal of Modeling, Simulation, and Scientific Computing 2015年第1期6卷 173-211页

作者： Evgeny A.Kozlov Oleg V.Ol’khov Ekaterina V.Shuvalova russian federal nuclear center–Zababakhin research institute of Technical physics Snezhinsk Russia russian federal nuclear center–research institute of experimental physics sarov Russia

To pursue VNIIEF–VNIITF joint investigations,this paper briefly describes the experimental setup and provides numerical 3D-computation results(LEGAK-3D technique)on special features in the convergence dynamics of steel shells under their quasi-spherical explosive loading in the system with the 40-mm outer radius of the explosive *** computation results were compared with the data experimentally registered for shells of the 30KhGSA steel,both as-received and quenched to HRC 35...40,and the austenitic 12Kh18N10T stainless *** comparison was also made with laserinterferometry results obtained directly under explosive loading,as well as with gammatomography and scanning electron microscopy investigations of the recovered shells.

关键词： Convergence dynamics of shell spall and shear damages explosive loading

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Ignition of nanothermites by a laser diode pulse

引用

Defence Technology（防务技术） 2022年第2期18卷 194-204页

作者： Alexander Yu.Dolgoborodov Vladimir G.Kirilenko Michael A.Brazhnikov Leonid I.Grishin Michael L.Kuskov Georgii E.Valyano Joint institute for High Temperatures Russian Academy of SciencesRussia N.Semenov federal research center for Chemical physics Russian Academy of SciencesRussia National research nuclear University MEPhI Moscow Russia

experimental investigation has been carried out for laser ignition and combustion of nanothermites based on aluminum and oxides of copper,bismuth and *** mixing of nanosized powders was used to produce *** thermite ignition,initiating laser pulse with a maximum intensity of 770 W/cm2 was generated by a laser diode with a wavelength of 808 *** ignition delay times,the minimum initiation energy density,and the average burning rate at various thermite densities and mass fractions of components were determined by recording the emission of radiation of the reaction products using a multichannel pyrometer jointly with a high-speed video *** effect of adding carbon black on the threshold parameters of a laser pulse was also *** on the obtained results,certain assumptions were put forward with regard to the mechanism of nanothermites’ignition by laser radiation and their *** particular,the assumptions were made on the two-stage process of the reaction initiation and jet burning mechanism of porous nanothermites.

关键词： Nanothermites Laser ignition Burning rate Ignition delay

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Simulations of ALT-like explosive magnetic devices for ramp compression of materials by magnetically imploded liners

引用

Matter and Radiation at Extremes 2020年第4期5卷 16-22页

作者： A.M.Buyko G.G.Ivanova I.V.Morozova FSUE Russian Federal Nuclear Center–All-Russian Research Institute of Experimental Physics(RFNC-VNIIEF)SarovNizhny Novgorod RegionRussia

Revised simulations of ALT-like devices are *** results from these simulations closely match those from experiments and demonstrate the capabilities of the devices as applied to ramp compression of metals to pressures of 20 Mbar by imploding liners driven by∼10 MG azimuthal magnetic fields(with currents up to 55 MA).These results can be applied to the design of experiments on isentropic compression of materials.

关键词： materials. magnetic Simulation

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Ionization balance of non-LTE plasmas from an average-atom collisional-radiative model

引用

Matter and Radiation at Extremes 2022年第6期7卷 3-18页

作者： A.A.Ovechkin P.A.Loboda A.S.Korolev S.V.Kolchugin I.Yu.Vichev A.D.Solomyannaya D.A.Kim A.S.Grushin russian federal nuclear center Zababakhin All-Russian Research Institute of Technical Physics(RFNC-VNIITF)Chelyabinsk RegionSnezhinskRussia Moscow Engineering physics institute(MEPhI) National Research Nuclear UniversityMoscowRussia Keldysh institute of Applied Mathematics RAS MoscowRussia

We present a simplified version of an average-atom collisional-radiative model employing both local-thermodynamic-equilibrium averageatom and isolated-ion atomic *** simplifications introduced do not lead to any substantial errors,and they significantly speed up calculations compared with the basic average-atom model involving direct solution of the self-consistent-field *** ion charges,charge state distributions,and emission spectra of non-local-thermodynamic-equilibrium(NLTE)gold plasmas calculated using various modifications of the average-atom collisional-radiative model are compared with those obtained using the THERMOS model with the detailed configuration accounting *** also propose an efficient method to calculate thermodynamic functions of NLTE plasmas in the context of the simplified average-atom collisional-radiative model.

关键词： equations radiative thermodynamic

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

A Modified Method for Deriving Self-Conjugate Dirac Hamiltonians in Arbitrary Gravitational Fields and Its Application to Centrally and Axially Symmetric Gravitational Fields

引用

Journal of Modern physics 2015年第3期6卷 303-326页

作者： M. V. Gorbatenko V. P. Neznamov russian federal nuclear center All-Russian Research Institute of Experimental Physics Sarov Russia

We have proposed previously a method for constructing self-conjugate Hamiltonians Hh in the h-representation with a flat scalar product to describe the dynamics of Dirac particles in arbitrary gravitational fields. In this paper, we prove that, for block-diagonal metrics, the Hamiltonians Hh can be obtained, in particular, using “reduced” parts of Dirac Hamiltonians, i.e. expressions for Dirac Hamiltonians derived using tetrad vectors in the Schwinger gauge without or with a few summands with bispinor connectivities. Based on these results, we propose a modified method for constructing Hamiltonians in the h-representation with a significantly smaller amount of required calculations. Using this method, here we for the first time find self-conjugate Hamiltonians for a number of metrics, including the Kerr metric in the Boyer-Lindquist coordinates, the Eddington-Finkelstein, Finkelstein-Lemaitre, Kruskal, Clifford torus metrics and for non-stationary metrics of open and spatially flat Friedmann models.

关键词： Self-Conjugate Hamiltonian Dirac Particle Arbitrary Gravitational Field Schwinger Gauge Kerr Metric

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Cumulation of a spherically converging shock wave in metals and its dependence on elastic-plastic properties, phase transitions, spall and shear fractures

引用

International Journal of Modeling, Simulation, and Scientific Computing 2015年第1期6卷 26-38页

作者： Evgeny A.Kozlov Alexsander V.Petrovtsev russian federal nuclear center-Zababakhin research institute of Technical physics Snezhinsk Chelyabinsk RegionRussia

Consideration is given to results of experimental and theoretical investigations how alpha-epsilon phase transition in the unalloyed iron and the 30 KhGSA steel and its absence in the austenitic 12Kh18N10T stainless steel influence processes under explosive deformation of spheres made of these *** transition is shown to significantly effect on:amount of explosion-products energy transferred to a sphere,evolution of the converging-wave structure and its parameters,profiles of stress wave and temperature T(R,t)for some Lagrangian particles along the sphere radius,character of energy cumulation under spherical convergence of waves.

关键词： Cumulation spherically converging shock wave elastic-plastic properties phase transitions spall and shear fractures

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：