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Emerging trends in the selective production of value-added aromatics

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Science China Chemistry 2025年第1期68卷 15-20页

作者： Yuchao Wu Houliang Dai Weisheng Yang Yaxing Li Lichen Liu Petrochemical Research Institute Company Limited China National Petroleum Corporation Engineering Research Center of advanced Rare Earth Materials Department of Chemistry Tsinghua University

1 Introduction Aromatics (mainly benzene, toluene, and xylenes, BTX) are essential intermediates in the chemical industry. They are employed in the synthesis of a broad spectrum of chemicals and materials, e.g., various polymers, plastics, resins, solvents, dyes, pharmaceuticals [1]. The manufacturing pathway of BTX mainly includes petroleum reforming of naphtha, coal-to-aromatics, methanol-to-aromatics [2].

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Swelling of Spherical Polyelectrolyte Gels

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Chinese Journal of Polymer Science 2024年第9期42卷 1386-1392,I0009页

作者： Ming-Yu Duan Jia-Dong Chen Yi-Ming Liu Zhao-Feng Peng Guang Chen department of advanced manufacturing and robotics College of EngineeringPeking UniversityBeijing 100871China

Polyelectrolyte(PE)gels,distinguished by their unique stimuli-responsive swelling behavior,serve as the basis of broad applications,such as artificial muscles and drug *** this work,we present a theoretical model to analyze the electrostatics and its contribution to the swelling behavior of PE gels in salt *** minimizing the free energy of PE gels,we obtain two distinct scaling regimes for the swelling ratio at equilibrium with respect to the salt *** compare our predictions for the swelling ratio with experimental measurements,which show excellent *** addition,we employ a finite element method to assess the applicability range of our theoretical model and *** anticipate that our model will also provide valuable insights into drug adsorption and release,deformation of red blood cells,4D printing and soft robotics,where the underlying mechanism of swelling remains enigmatic.

关键词： Gels Polyelectrolytes Swelling Stimuli-responsive Electrostatic interaction Cell model

Topological dependence of mechanical responses of solidification microstructures in aluminum brazed joints

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中国有色金属学会会刊：英文版 2003年第6期13卷 1296-1300页

作者：高峰钱乙余 D.P.Sekulic 马鑫 F.Yoshida State Key Laboratory of advanced Production Technology Center for robotics and manufacturing Systems department of Mechanical System Engineering

The main objective is to provide an evidence of spatial dependence of mechanical responses of a heterogeneous aluminum brazed joint re-solidified clad, and to confirm a sufficient sensitivity of a nano-indentation—load curve method for identifying the dependence. Topological features of a network of solidification microstructures(α phase and eutectic), formed during quench in a brazing process of aluminum alloy, influence significantly dynamic mechanical responses of resulting heterogeneous material. Nano/micro indentation depth vs load characteristics of differing phases suggest a spatially sensitive mechanical response of a re-solidified fillet in the joint zone. Hence, a spatial distribution, pattern formations and other morphological characteristics of microstructures have a direct impact on an ultimate joint integrity. Topology-induced variations of indentation—load curves was presented. A hypothesis involving microstructures’ spatial distribution vs mechanical response was formulated.

关键词：铝铜焊显微结构凝固拓扑相关机械响应焊接铝合金

Editorial for the Special Issue on"Origami/Kirigami Structures and Engineering Applications"

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Acta Mechanica Solida Sinica 2023年第4期36卷 477-478页

作者： Yihui Zhang Ke Liu department of Engineering Mechanics Tsinghua UniversityBeijing 100084China department advanced manufacturing and robotics Peking UniversityBeijing 100871China

Origami and kirigami structures originate from the ancient art of paper folding and *** offer the opportunity to achieve superior performances and unusual function-alities brought by complex three-dimensional geometri... 详细信息

关键词： unusual function Issue

In-hand manipulation of a circular dynamic object by soft fingertips without angle measurement

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Science China(Information Sciences) 2021年第5期64卷 193-208页

作者： R.GARCIA-RODRIGUEZ V.PARRA-VEGA Aeronautical Engineering Program and Postgraduate Program in Aerospacial Engineering Universidad Politecnica Metropolitana de Hidalgo robotics and advanced manufacturing department Research Center for Advanced Studies (CINVESTAV)

A multi-fingered robotic hand with curved fingertips enables contact re-positioning without reattaching at the expense of fingertip rolling. This rolling stands for a characteristic that facilitates dexterous manipulation but results in an algebraically complex dynamic model subject to such constraints. The hemispherical shape of fingertips allows a dexterous manipulation when controlling the tangent forces, which are essential to rotate object. However, the measurement of the object angle in practice requires tactile-optical sensing. In this paper, considering robotic fingers with curved soft tips, we propose a feedback control that ensures optimal dynamical grasping of a circular rigid object. It is shown that the collaboration of the contact forces, to get a minimum pose of internal forces, and the tangential forces, to induce the conditions for assuring the grasp closure, is necessary to get a skillful manipulation. In this case, the orientation control of a circular object to the desired angle while avoiding direct measurement of the object angle is presented. Stability conditions of the system are presented in the sense of stability-in-the-manifold. Finally, representative simulations are shown and discussed.

关键词： optimal grasping manipulation soft-fingertips circular object stability-in-the-manifold

High-temperature-tolerant flexible supercapacitors: Gel polymer electrolytes and electrode materials

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Journal of Energy Chemistry 2025年第1期100卷 426-457页

作者： Chong Peng Xinyi Huang Mingwei Zhao Shuling Liao Quanhong Yang Nianjun Yang Siyu Yu School of Chemistry & Chemical Engineering Southwest University Nanoyang Group Tianjin Key Laboratory of Advanced Carbon and Electrochemical Energy Storage School of Chemical Engineering and Technology and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin) Tianjin University department of Chemistry & IMO-IMOMEC Hasselt University

The development of flexible supercapacitors(FSCs) capable of operating at high temperatures is crucial for expanding the application areas and operating conditions of supercapacitors. Gel polymer electrolytes and electrode materials stand as two key components that significantly impact the efficacy of hightemperature-tolerant FSCs(HT-FSCs). They should not only exhibit high electrochemical performance and excellent flexibility, but also withstand intense thermal stress. Considerable efforts have been devoted to enhancing their thermal stability while maintaining high electrochemical and mechanical performance. In this review, the fundamentals of HT-FSCs are outlined. A comprehensive overview of state-of-the-art progress and achievements in HT-FSCs, with a focus on thermally stable gel polymer electrolytes and electrode materials is provided. Finally, challenges and future perspectives regarding HT-FSCs are discussed, alongside strategies for elevating operational temperatures and *** review offers both theoretical foundations and practical guidelines for designing and manufacturing HT-FSCs, further promoting their widespread adoption across diverse fields.

关键词： Polymer membrane electrodes

On the use of positive feedback for improved torque control

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Control Theory and Technology 2015年第3期13卷 266-285页

作者： Houman DALLALI Gustavo A.MEDRANO-CERDA Michele FOCCHI Thiago BOAVENTURA Marco FRIGERIO Claudio SEMINI Jonas BUCHLI Darwin G.CALDWELL department of advanced robotics Istituto Italiano di Tecnologia(IIT) Agile and Dexterous robotics Lab Institute of Robotics and Intelligent SystemsETH

This paper considers the torque control problem for robots with flexible joints driven by electrical actuators. It is shown that the achievable closed-loop tracking bandwidth using PI torque controllers may be limited due to transmission zeros introduced by the load dynamics. This limitation is overcome by using positive feedback from the load motion in unison with PI torque controllers. The positive feedback is given in terms of load velocity, acceleration and jerk. Stability conditions for designing decentralized PI torque controllers are derived in terms of Routh-Hurwitz criteria. Disturbance rejection properties of the closed system are characterized and an analysis is carried out investigating the use of approximate positive feedback by omitting acceleration and/or jerk signals. The results of this paper are illustrated for a two DoF （degrees of freedom） system. Experimental results for a one DoF system are also included.

关键词： Force-torque control load motion compensation decentralized control

Exploring Nanoscale Perovskite Materials for Next‑Generation Photodetectors:A Comprehensive Review and Future Directions

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Nano-Micro Letters 2025年第2期17卷 46-108页

作者： Xin Li Sikandar Aftab Maria Mukhtar Fahmid Kabir Muhammad Farooq Khan Hosameldin Helmy Hegazy Erdi Akman State Key Laboratory of Pulsed Power Laser Technology National University of Defense TechnologyHefei 230037AnhuiPeople’s Republic of China Anhui Laboratory of advanced Laser Technology Hefei 230037AnhuiPeople’s Republic of China Nanhu Laser Laboratory Changsha 410015HunanPeople’s Republic of China department of Semiconductor Systems Engineering and Clean Energy Sejong UniversitySeoul 05006Republic of Korea department of Artificial Intelligence and robotics Sejong UniversitySeoul 05006Republic of Korea School of Engineering Science Simon Fraser UniversityBurnabyBC V5A 1S6Canada department of Electrical Engineering Sejong UniversitySeoul 05006South Korea department of Physics Faculty of ScienceKing Khalid UniversityP.O.Box 9004AbhaSaudi Arabia Central Labs King Khalid UniversityAlQura’aP.O.Box 96061413 AbhaSaudi Arabia Scientific and Technological Research and Application Center Karamanoglu Mehmetbey University70100 KaramanTurkey

The rapid advancement of nanotechnology has sparked much interest in applying nanoscale perovskite materials for photodetection *** materials are promising candidates for next-generation photodetectors(PDs)due to their unique optoelectronic properties and flexible synthesis *** review explores the approaches used in the development and use of optoelectronic devices made of different nanoscale perovskite architectures,including quantum dots,nanosheets,nanorods,nanowires,and *** a thorough analysis of recent literature,the review also addresses common issues like the mechanisms underlying the degradation of perovskite PDs and offers perspectives on potential solutions to improve stability and scalability that impede widespread *** addition,it highlights that photodetection encompasses the detection of light fields in dimensions other than light intensity and suggests potential avenues for future research to overcome these obstacles and fully realize the potential of nanoscale perovskite materials in state-of-the-art photodetection *** review provides a comprehensive overview of nanoscale perovskite PDs and guides future research efforts towards improved performance and wider applicability,making it a valuable resource for researchers.

关键词： Nanoscale perovskites Photodetectors Nanosheets Nanorods Nanowires Quantum dots Nanocrystals

Intelligent interaction system based on multimodal conformal triboelectric nanogenerator patch for disabled sports and life

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Science China Technological Sciences 2025年

作者： Yuzhang WEN Mengqi ZHANG Zhenning XIE Zida AN Bing LIU Fengxin SUN Tianming ZHAO Zuojun YU Fei WANG Yupeng MAO Physical Education department Northeastern University(Shenyang) Faculty of Robot Science and Engineering Northeastern University Criminal Investigation Police University of China State Key Laboratory of robotics Shenyang Institute of Automation Chinese Academy of Sciences China Ice Sports College Beijing Sport University

Intelligent interaction technology based on advanced sensing units has become a research hotspot. In this paper, an intelligent interaction system (IIS) based on a multimodal conformal triboelectric nanogenerator patch (MCTP) is reported for sports monitoring and life promotion of the disabled. This IIS consists of a cloud-based smart sports recognition program and a smart life application. The porous micro-reinforced structure of polyurethane (PU) Sponge&Ecoflex, and the surface modification of PTFE by coating it with MXene endows the MCTP with excellent electrical properties. It shows good angle and force sensitivities of 1.1 V/°and 1.61 V/N, respectively, and has an ultra-fast response time of 15 ms, meeting the needs of human motion monitoring. The MCTP can also capture the mechanical energy, producing a maximum output power of 139μ*** with the commercial inertial measuring unit (IMU), the MCTP shows better consistency in human joint angle sensing. A precise analysis of wheelchair curling sports monitoring points is achieved by combining the MCTP and the human anatomy model. The cloud-based smart sports recognition program utilizes machine learning to achieve visual feedback on the three throwing technologies of draw, takeout and clearing. In addition, the developed smart life application uses a highsensitivity MCTP-sensor array design to achieve a variety of smart home interactions through simple finger touches. Overall,the IIS integrates the three major functions of smart sports sensing, energy capture, and smart home control, providing important application prospects in the fields of smart sports and human-computer interaction for the disabled.

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