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Combinations of electron and proton donors in transition-metal complex mediated nitrogen reduction reactions

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science China Chemistry 2024年第7期67卷 2136-2154页

作者： Delong Han Li Yang Hao Huang Priyanka Chakraborty Shashikant U.Dighe Kuo-Wei Huang KAUST Catalysis Center and Division of Physical science and Engineering King Abdullah University of Science and TechnologyThuwal 23955Saudi Arabia Agency for science Technologyand ResearchInstitute of Materials Research and Engineering and Institute of Sustainability for ChemicalsEnergy and EnvironmentSingapore 138634Singapore

Nitrogen fixation is a complex process involving the transfer of six electrons and *** from the conventional Haber-Bosch process,which relies on hydrogen(H_(2))to provide both electrons and protons to reduce nitrogen(N_(2)),homogeneous transition metal complex-catalyzed N_(2)reduction reactions(NRR)employ an array of electron and proton donors or even electron donors combined with *** the synthesis of diverse catalytic progress,the categories of donors have seen rapid ***,existing literature only provides summaries regarding the metal,ligands,and *** the significance of electron and proton donor combinations in nitrogen reduction reactions,no literature has thoroughly reviewed this ***,we hereby compiled a comprehensive list of commonly used reagents in N_(2)reduction and classified them according to their specific donor *** review presents clear and organized information about these combinations,along with a summary of their general performance trend in NRR with related ***,we conclude the discussion by highlighting key points for researchers to consider when selecting catalysts and donor combinations,with the ultimate goal of advancing the field of nitrogen fixation.

关键词： dinitrogen reduction reaction reducing donor combination transition metal complexes homogeneous catalysis

Direct capture and separation of CO_(2) from air

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Green Energy & Environment 2024年第3期9卷 413-416页

作者： Siew Ping Teong Yugen Zhang Institute of sustainability for Chemicals Energy and Environment(ISCE2)Agency for ScienceTechnology and Research(A*STAR)1 Pesek Road Jurong Island627833SingaporeRepublic of Singapore

Direct air capture(DAC)has attracted increasing interest and investment over the past few *** are a fast-growing number of companies that entered the field and demonstrated DAC carbon removal setups and ***,current DAC methods are still based on solid absorbents or alkali solutions approaches which have low capture efficiency and low energy *** highlight proposed a promising CO_(2) capture technology,an electric energy driven closed-loop system for the direct removal of CO_(2) from ambient air which are based on two individual technologies:Polyam-N-Cu hybrid system promoted CO_(2) capture with ocean as anthropogenic CO_(2) sink and a chloride-mediated electrochemical pH swing system to remove CO_(2) from oceanwater.

关键词： system separation companies

Multi-scale hash encoding based neural geometry representation

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Computational Visual Media 2024年第3期10卷 453-470页

作者： Zhi Deng Haoyao Xiao Yining Lang Hao Feng Juyong Zhang School of Mathematical sciences University of Science and Technology of ChinaHefei 230026China Alibaba Artiﬁcial Intelligence governance Laboratory Alibaba GroupHangzhou 310017China

Recently, neural implicit function-basedrepresentation has attracted more and more attention,and has been widely used to represent surfacesusing differentiable neural networks. However, surfacereconstruction from point clouds or multi-view imagesusing existing neural geometry representations stillsuffer from slow computation and poor accuracy. Toalleviate these issues, we propose a multi-scale hashencoding-based neural geometry representation whicheffectively and efficiently represents the surface asa signed distance ﬁeld. Our novel neural networkstructure carefully combines low-frequency Fourierposition encoding with multi-scale hash encoding. Theinitialization of the geometry network and geometryfeatures of the rendering module are accordinglyredesigned. Our experiments demonstrate that theproposed representation is at least 10 times faster forreconstructing point clouds with millions of *** also signiﬁcantly improves speed and accuracyof multi-view reconstruction. Our code and modelsare available at https://***/Dengzhi-USTC/Neural-Geometry-Reconstruction.

关键词： neural geometry representation hash encoding point cloud reconstruction multi-view reconstruction

Highly dispersive tetrahedral vanadium species on pure silica ZSM-12 zeolite boosting the selective oxidation of cyclohexane into cyclohexanone

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science China Chemistry 2024年第7期67卷 2206-2214页

作者： Menglin Xie Ting Li Chao Wu Xiaoling Liu Jinling Ni Siqin Yao Yu Zhou Shibo Xi Jun Wang State Key Laboratory of Materials-Oriented Chemical Engineering College of Chemical EngineeringNanjing Tech UniversityNanjing 211816China Institute of sustainability for Chemicals Energy and Environment(ISCE2)Agency for ScienceTechnology and Research(A*STAR)Singapore 627833Republic of Singapore College of Materials science and Engineering Sichuan UniversityChengdu 610065China

The selective oxidation of cyclohexane is a promising green route for the production of KA oil(cyclohexanol and cyclohexanone),but remains a huge challenge to design high-performing heterogeneous catalysts under mild ***,a pure silica ZSM-12(MTW topology)zeolite was applied as the support to immobilize highly dispersive tetrahedrally coordinated vanadium(V)species and the constructed catalyst 1%V/SZ-12 exhibited high efficiency in the fast and selective oxidation of cyclohexane into cyclohexanone with H_(2)O_(2).The reaction completed within 30 s,affording the selectivity of 99%towards cyclohexanone and the extremely high turnover frequency(TOF)of 5,891 h^(-1).1%V/SZ-12 was facilely reused with stable activity and feasibly extended to the oxidation of various cyclohexane *** one-dimensional 12-membered ring microchannels contributed to the formation and accessibility of tetrahedrally coordinated high valent V5+species as the robust active centers,which activated H_(2)O_(2) to generate V–O–O·,the active oxygen species for the electrophilic attack on cyclohexane to produce cyclohexanone as the sole product.

关键词： zeolite metal doping cyclohexane oxidation heterogeneous catalysis

A Systematic Analysis of Systems Approach and Flood Risk Management research:Trends,Gaps,and Opportunities

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International Journal of Disaster Risk science 2024年第1期15卷 45-57页

作者： Lum Sonita Awah Johanes Amate Belle Yong Sebastian Nyam Israel Ropo Orimoloye Disaster Management Training and Education centre for Africa University of the Free StateBloemfontein 9300South Africa School of Environment Geographyand SustainabilityWestern Michigan UniversityKalamazooMI 49008USA

Flooding is a global threat,necessitating a comprehensive management *** to the complexity of managing flood hazards and risks,researchers have advocated for holistic,comprehensive,and integrated *** study,employing a systems thinking perspective,assessed global flood risk management research trends,gaps,and opportunities using132 published documents in BibTeX format.A systematic review of downloaded documents from the Scopus and Web of science databases revealed slow progress of approximately 11.61% annual growth in applying systems thinking and its concomitant approaches to understanding global flood risk management over the past two decades compared to other fields like water resource management and business management systems.A significant gap exists in the application of systems thinking methodologies to flood risk management research between developed and developing countries,particularly in Africa,highlighting the urgency of reoriented research and policy *** application gaps of the study methodology are linked to challenges outlined in existing literature,such as issues related to technical expertise and resource *** study advocates a shift from linear to holistic approaches in flood risk management,aligned with the Sendai Framework for Disaster Risk Reduction 2015-2023 and the Sustainable Development *** among researchers,institutions,and countries is essential to address this global challenge effectively.

关键词： Flood risk management research Gaps and opportunities Global trends in flood research Systematic review.Systems thinking

A Fluctuation Test for Structural Change Detection in Heterogeneous Panel Data Models

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Journal of Systems science & Complexity 2024年第3期37卷 1184-1208页

作者： LI Fuxiao XIAO Yanting CHEN Zhanshou Department of Applied Mathematics Xi'an University of TechnologyXi'an 710048China School of Mathematics and Statistics Qinghai Normal UniversityXining 810008China Academy of Plateau science and sustainability Xining 810008China

Structural change in panel data is a widespread phenomena. This paper proposes a fluctuation test to detect a structural change at an unknown date in heterogeneous panel data models with or without common correlated effects. The asymptotic properties of the fluctuation statistics in two cases are developed under the null and local alternative hypothesis. Furthermore, the consistency of the change point estimator is proven. Monte Carlo simulation shows that the fluctuation test can control the probability of type I error in most cases, and the empirical power is high in case of small and moderate sample sizes. An application of the procedure to a real data is presented.

关键词： Common correlated effects fuctuation test heterogeneous panel data models structural change detection

Which Neighborhoods Have Easier Access to Online Home Delivery Services?A Spatiotemporal Accessibility Analysis in Nanjing,China

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Chinese Geographical science 2024年第4期34卷 722-738页

作者： KONG Yu ZHEN Feng ZHANG Shanqi SHEN Lizhen School of Architecture and Urban Planning Nanjing UniversityNanjing 210093China Provincial Engineering research Center of Smart City Planning and Digital governance Nanjing 210093China

The rise in online home delivery services(OHDS)has had a significant impact on how urban services are supplied and used in recent *** on the spatial accessibility of OHDS are emerging,but few is known about the temporal dimension of OHDS accessibility as well as the geographic and socioeconomic differences in the spatiotemporal accessibility of *** study measures the spatiotemporal accessibility of four types of OHDS,namely leisure,fresh and convenient,medical,and catering *** geographic and socioeconomic disparities in the spatiotemporal accessibility of these four types of OHDS are then identified using spatial statistical methods and the Kruskal-Wallis test(K-W test).The case study in Nanjing,China,suggests that:1)spatiotemporal accessibility better reflects the temporal variation of OHDS accessibility and avoids overestimation of OHDS accessibility when only considering its spatial dimension.2)The spatiotemporal accessibility of OHDS varies geographically and *** located in the main city or neighborhoods with higher housing prices,higher population density,and higher point of interest(POI)mix have better OHDS spatiotemporal *** study contributes to the understanding of OHDS accessibility from a spatiotemporal perspective,and the empirical insights can assist policymakers in creating intervention plans that take into account variations in OHDS spatiotemporal accessibility.

关键词： online home delivery services(OHDS) spatiotemporal accessibility neighborhoods accessibility differences Nanjing City China

The role ofγ-C2H5NO2 as a new transient liquid phase in cold sintering process of BaTiO3 composites

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Journal of Advanced Ceramics 2024年第7期13卷 942-955页

作者： Jitrawan Noisak Pimchanok Ieamviteevanich Thitirat Charoonsuk Phakkhananan Pakawanit Nattapong Pinpru Wanwilai Vittayakorn Tosapol Maluangnont Panpailin Seeharaj Theerachai Bongkarn Te-Wei Chiu Naratip Vittayakorn Advanced Materials research Unit School of ScienceKing Mongkut’s Institute of Technology LadkrabangBangkok 10520Thailand Department of Chemistry School of ScienceKing Mongkut’s Institute of Technology LadkrabangBangkok 10520Thailand Department of Materials science Faculty of ScienceSrinakharinwirot UniversityBangkok 10110Thailand Synchrotron research and Applications Division Synchrotron Light Research InstituteNakhon Ratchasima 30000Thailand sustainability centre Plastics Market Intelligent DepartmentPlastics Institute of ThailandBangkok 10110Thailand Electroceramics research Laboratory College of Materials Innovation and TechnologyKing Mongkut's Institute of Technology LadkrabangBangkok 10520Thailand Department of Physics Faculty of ScienceNaresuan UniversityPhitsanulok 65000Thailand research Center for Academic Excellence in Applied Physics Faculty of ScienceNaresuan UniversityPhitsanulok 65000Thailand Department of Materials and Mineral Resources Engineering "National"Taipei University of TechnologyTaipei 106TaiwanChina

Dielectric materials,such as barium titanate(BT)-based materials,have excellent dielectric properties but require high temperatures(above 1300℃)for ceramic fabrication,leading to high costs and energy *** cold sintering process(CSP)offers a solution to these issues and is gaining worldwide attention as an innovative fabrication *** this work,we proposed an alternative organic ferroelectric phase,gamma-glycine(γ-GC),which acts as a transient liquid phase to fabricate high-density composites with barium titanate(BT)at low temperatures through *** findings show that the density of 15γ-GC/85BT reached 96.7%±1.6%when it was sintered at 120℃for 6 h under 10 MPa uniaxial *** electron microscopy‒energy dispersive X-ray spectroscopy(SEM‒EDS)mappings of the composite suggested thatγ-GC completely underwent the precipitation-dissolution process and,therefore,filled between BT ***,X-ray diffraction(XRD)and Fourier-transform infrared spectroscopy(FTIR)confirmed the preservation ofγ-GC without undesired phase *** addition,the ferroelectric and dielectric properties ofγ-GC/BT composites have been *** high dielectric constant(εr)was 3600,and the low dielectric loss(tanδ)was 1.20 at 200℃and 100 kHz for the 15γ-GC/85BT *** hysteresis loop showed a remanent polarization(Pr)of 0.55µC·cm^(−2)and a coercive field(Ec)of 7.25 kV·cm^(−1).Our findings reaffirmed that an organic ferroelectric material(γ-GC)can act as a transient liquid phase in a CSP that can successfully and sustainably fabricateγ-GC/BT composites at low temperatures while delivering outstandingly high performance.

关键词： gamma-glycine(γ-GC) barium titanate(BT) cold sintering process organic ferroelectric materials dielectric properties ferroelectric properties

Recent Advances in Nanoengineering of Electrode-Electrolyte Interfaces to Realize High-Performance Li-Ion Batteries

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Energy & Environmental Materials 2024年第3期7卷 5-17页

作者： Na-Yeong Kim Ilgyu Kim Behnoosh Bornamehr Volker Presser Hiroyuki Ueda Ho-Jin Lee Jun Young Cheong Ji-Won Jung School of Materials science and Engineering University of Ulsan INM-Leibniz Institute for New Materials Germany Department of Materials science and Engineering saarene-Saarland Center for Energy Materials and sustainability Institute for Frontier Materials (IFM) Deakin University Battery research and Innovation Hub Deakin University Bavarian Center for Battery Technology (BayBatt) and Department of Chemistry University of Bayreuth

A suitable interface between the electrode and electrolyte is crucial in achieving highly stable electrochemical performance for Li-ion batteries,as facile ionic transport is required. Intriguing research and development have recently been conducted to form a stable interface between the electrode and electrolyte. Therefore,it is essential to investigate emerging knowledge and contextualize it. The nanoengineering of the electrode-electrolyte interface has been actively researched at the electrode/electrolyte and interphase levels. This review presents and summarizes some recent advances aimed at nanoengineering approaches to build a more stable electrodeelectrolyte interface and assess the impact of each approach ***,future perspectives on the feasibility and practicality of each approach will also be reviewed in detail. Finally,this review aids in projecting a more sustainable research pathway for a nanoengineered interphase design between electrode and electrolyte,which is pivotal for high-performance,thermally stable Li-ion batteries.

关键词： battery electrode electrolyte interface lithium nanoengineering