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ZnO/ZnS heterostructure in N-doped porous carbon for anchoring-diffusion-conversion of polysulfides for high-performance lithium-sulfur batteries

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Rare Metals 2024年第8期43卷 3661-3676页

作者： Fei Wang Rong-Wei Huang Wen-Chang Han Chun-Man Yang Wen-Hao Yang Peng Dong Chao-Ling Wu Yi-Yong Zhang Xue Li Ying-Jie Zhang National Local Joint Engineering research center for LithiumIon Batteries and materials Preparation technology Key Laboratory of Advanced Batteries Materials of Yunnan ProvinceFaculty of Metallurgical and Energy EngineeringKunming University of Science and TechnologyKunming 650093China Engineering research center of Alternative energy materials and Devices Sichuan UniversityMinistry of EducationChengdu 610065China

The shuttle effect of polysulfides is one of the key factors hindering the commercialization of lithiumsulfur batteries(LSBs).Owing to their high conductivity and advantageous structure,heterostructures can be used in sulfur fixation and catalysis of *** this study,a flower-shaped ZnO/ZnS heterostructure on a nitrogendoped porous carbon(NPC) sulfur host was *** ZnO/ZnS heterostructure regulates the electronic structure of the material and exhibits higher metal-like ***,the ZnO/ZnS heterostructure combines the strong adsorption property of ZnO and the high catalytic ability of ZnS to realize the anchoring-diffusionconversion of lithium poly sulfides(LiPSs).Results reveal that the developed ZnO/ZnS@NPC/S cathode has excellent electrochemical performance in LSBs,achieving a high discharge specific capacity of 1365.3 mAh·g^(-1) at 0.1C and excellent rate capability(719 mAh·g^(-1) at 2C;the capacity decay rate is only 0.042% per cycle after 1000 cycles).Even under a high sulfur loading-E/S(electrolyte/sulfur)ratio of 5.1 mg·cm^(-2)-6 μl·mg^(-1),a high specific capacity of 723.7 mAh·g^(-1) is maintained after 60 *** study provides a new strategy for a multifunctional sulfur host that can effectively alleviate the shuttle effect of LiPSs and improve the utilization of sulfur active substances.

关键词： ZnO/ZnS heterostructure Lithium-sulfur batteries Density functional theory Anchor Conversion

Sisyphus effects in hydrogen electrochemistry on metal silicides enabled by silicene subunit edge

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Science Bulletin 2019年第9期64卷 617-624页

作者： Zechao Zhuang Yong Li Jiazhao Huang Zilan Li Kangning Zhao Yunlong Zhao Lin Xu Liang Zhou Lyudmila V. Moskaleva Liqiang Mai State Key Laboratory of advanced technology for materials Synthesis and Processing International School of Materials Science and EngineeringWuhan University of Technology Institute of Applied and Physical Chemistry and center for environmental research and Sustainable technology University of Bremen advanced technology Institute University of Surrey Department of Chemistry University of the Free State

Nonmetal elements strictly govern the electrochemical performance of molybdenum ***,the exact role played by nonmetals during electrocatalysis remains largely *** intermetallic MoSi_2comprising silicene subunits,we present an unprecedented hydrogen evolution reaction(HER)behavior in aqueous alkaline *** continuous operation,the HER activity of MoSi_2shows a more than one order of magnitude improvement in current density from 1.1 to 21.5 mA cm^(à2)at 0.4 V ***,this activation behavior is highly reversible,such that voltage withdrawal leads to catalyst inactivation but another operation causes ***,the system shows dynamics strikingly analogous to the legendary Sisyphus’labor,which drops and recovers in a stepwise manner repeatedly,but never succeeds in reaching the top of the *** WSi_2behaves almost the same as MoSi_2,whereas other metal silicides with silicyne subunits,including CrSi_2and TaSi_2,do not exhibit any anomalous behavior.A thin amorphous shell of MoSi_2is observed after reaction,within which the Si remains partially oxidized while the oxidation state of Mo is basically ***-principles calculations further reveal that the adsorption of hydroxide ions on silicene subunit edges and the subsequent Si vacancy formation in MoSi_2jointly lead to the anomalous HER kinetics of the adjacent Mo active *** work demonstrates that the role of nonmetal varies dramatically with the electronic and crystallographic structures of silicides and that silicene structural subunit may serve as a promoter for boosting HER in alkaline media.

关键词： Sisyphus effect Electrochemistry Metal silicides Silicene subunit Hydrogen evolution reaction

Self-transforming ultrathin α-Co(OH)2 nanosheet arrays from metal-organic framework modified graphene oxide with sandwichlike structure for efficient electrocatalytic oxygen evolution

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Nano research 2020年第3期13卷 810-817页

作者： Mengqiu Huang Weiwei Liu Lei Wang Jiwei Liu Guanyu Chen Wenbin You Jie Zhang Lijun Yuan Xuefeng Zhang Renchao Che Laboratory of advanced materials Department of Materials Science and Collaborative Innovation Center of Chemistry for Energy Materials(iChetn)Fudan UniversityShanghai 200438China College of materials and environmental Engineering Hangzhou Dianzi UniversityHangzhou 310012China Laboratory of advanced materials Department of Materials Science and Collaborative Innovation Center of Chemistry for Energy Materials(iChem)Fudan UniversityShanghai 200438China

Developing efficient and low-cost electrocatalysts for oxygen evolution reaction(OER)with high electrochemical activity and durability for diverse renewable and sustainable energy technologies remains ***,an ultrasonic-assisted and coordination modulation strategy is developed to construct sandwich-like metal-organic framework(MOF)derived hydroxide nanosheet(NS)arrays/graphene oxide(GO)composite via one-step self-transformation *** from unsteady state,the dodecahedral ZIF-67 with Co^2+in tetrahedral coordination auto-converts into defect-rich ultrathin layered hydroxides with the interlayered ion NO3-.The self-transforming a-Co(OH)2/GO nanosheet arrays from ZIF-67(Co(OH)2-GNS)change the coordination mode of Co^2+and bring about the exposure of more metal active sites,thereby enhancing the spatial utilization ratio within the *** monometal-based electrocatalyst,the optimized Co(OH)2-GNS exhibits remarkable OER catalytic performance evidenced by a low overpotential of 259 mV to achieve a current density of 10 mA·cm-2 in alkaline medium,even exceeding commercial *** the oxygen evolution process,electron migration can be accelerated by the interfacial/in-plane charge polarization and local electric field,corroborated by the off-axis electron *** functional theory(DFT)calculations further studied the collaboration between ultrathin Co(OH)2 NS and GO,which leads to lower energy barriers of intermediate products and greatly promotes electrocatalytic property.

关键词： metal-organic framework oxygen evolution reaction ultrathin nanosheet arrays cobaltous hydroxide charge transfer

Densification and anticorrosion performances of vacuum evaporated aluminium coatings on NdFeB magnets

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Journal of Rare Earths 2021年第10期39卷 1238-1245,I0003页

作者： Jun Huang Qing Liu Zhenyu Yang Guangqing Xu Pengjie Zhang Jun Lv Wei Sun Bingshan Li Dongmei Wang Yucheng Wu School of materials Science and Engineering Hefei University of TechnologyHefei 230009China China International S&T Cooperation Base for advanced energy and environmental materials Hefei University of TechnologyHefei 230009China Key Laboratory of advanced Functional materials and Devices of Anhui Province Anhui Provincial International S&T Cooperation Base for Advanced Energy MaterialsHefei University of TechnologyHefei 230009China BGRIMM technology Group Co. Ltd.Beijing 102600China National Engineering research center for Magnetic materials Beijing 102600China

Al coated NdFeB magnets obtained by vacuum evaporation technique were densified by high energy ball milling *** surface morphology,metal composition and micro structure of the coatings were characterized by scanning electron microscopy,X-ray diffraction and X-ray photoelectron spectroscopy,*** anticorrosive properties were investigated by potentiodynamic polarization curves and neutral salt spray *** pores in the Al coatings of columnar crystals(Al) induced by the evaporation technique,were apparently filled in the following ball milling process,leading to the densification of Al coatings and the evident improvement of the anticorrosive *** treated with ball milling for 30 min,the sample achieves the best anticorrosive performances with the self-corrosion potential of-0.87 V,self-corrosion current density of 1.65 μA/cm^(2) and the neutral salt spray(NSS) time of 144 h(red rust).The improvement of the anticorro sive performances of vacuum evaporated Al coating mainly lies in the densification effect of the coating,which depends on different loading conditions of ball milling process.

关键词： Sintered NdFeB magnet Al coating Anticorrosive performances Vacuum evaporation Densification Rare earths

P(VDF-HFP)-poly(sulfur-1,3-diisopropenylbenzene) functional polymer electrolyte for lithium–sulfur batteries

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Journal of energy Chemistry 2020年第7期29卷 114-122,I0004页

作者： Jiang-Hui Jiang An-Bang Wang Wei-Kun Wang Zhao-Qing Jin Li-Zhen Fan Beijing advanced Innovation center for materials Genome Engineering Institute of Advanced Materials and TechnologyUniversity of Science and Technology BeijingBeijing 100083China Military Power Sources research and Development center Research Institute of Chemical DefenseBeijing 100191China

Lithium–sulfur(Li–S)battery as a high-energy density electrochemical energy storage system has attracted many researchers’***,the shuttle effect of Li–S batteries and the challenges associated with lithium metal anode caused poor cycle *** this work,the organosulfide poly(sulfur-1,3-diisopropenylbenzene)(PSD)was prepared as cathode material and additive of P(VDFHFP)polymer electrolyte(P(VDF-HFP)).It was verified that P(VDF-HFP)polymer electrolyte with 10%PSD(P(VDF-HFP)-10%PSD)showed a higher ionic conductivities than that of liquid electrolyte up to2.27×10-3 S cm-1 at room *** quasi-solid-state Li-S batteries fabricated with organosulfide cathode material PSD and P(VDF-HFP)based functional polymer electrolyte delivered good cycling stability(780 m Ah g-1 after 200 th cycle at 0.1 C)and rate performance(613 m Ah g-1 at 1 C).The good cycling performance could be attributed to the synergistic effect of components,including the interaction between polysulfides and polymer main chain in the organosulfide cathode,the sustained organic/inorganic hybrid stable SEI layer formed by polymer electrolyte additive PSD,the improved cathode/electrolyte interface and the good affinity between P(VDF-HFP)based functional polymer electrolyte and Li metal *** strategy herein may provide a new route to fabricate high-performance Li–S batteries through the organosulfide cathode and functional polymer electrolyte.

关键词： Organosulfide cathode Functional polymer electrolyte Stable SEI layer Quasi-solid-state Li–S batteries

Anhydride type film-forming electrolyte additives for high-temperature LiNi0.6Co0.2Mn0.2O2//graphite pouch cells

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Progress in Natural Science:materials International 2023年第3期33卷 320-327页

作者： Anwei Zhang Chengyun Wang Weizhen Fan Jingwei Zhao Yanping Huo Xijun Xu GAC Automotive research &Development center Guangdong Provincial Key Laboratory of advanced energy Storage materials School of Materials Science and Engineering South China University of Technology research and Development center Guangzhou Tinci Materials Technology Co. Ltd. College of Chemical Engineering and Light Industry Guangdong University of Technology

LiNi0.6Co0.2Mn0.2O2//graphite full cell, due to its high energy density as the most promising candidate for power batteries received increased attention, but the severe capacity loss under high-temperature conditions prevents their large-scale application. Here, glutaric anhydride(GA) and succinic anhydride(SA) as electrolyte additives are investigated to overcome the high-temperature problem of LiNi0.6Co0.2Mn0.2O2//graphite cells. Due to the unique film-forming features and high-temperature stability, the cells containing 0.5% GA and 0.5% SA can retain capacity retention of 91.2% and 92.4% stored at 60°C for 15 days, corresponding to a negligible capacity loss of 4.6 and 0.8 m Ah g-1after 200 cycles, respectively. In addition, the lifespans of cells under 25°C are also significantly extended by introducing GA and SA into the electrolytes. Electrochemical and spectroscopic techniques results indicate the full cell capacity loss is predominantly caused by the unstable anode solid electrolyte interphase(SEI) layer and a stable SEI film derived from GA and SA is formed on the graphite electrode *** SEI film can effectively inhibit the consumption of electrolytes and enhance the high-temperature performance of cells. This work paves a way for moderating high energy density cells’ work under high-temperature operation by developing special anodic film-forming electrolyte additives.

关键词： Anhydride-based Electrolyte additives Film-forming LiNi0.6Co0.2Mn0.2O2//graphite High-temperature performance

Enhancing interfacial stability in solid-state lithium batteries with polymer/garnet solid electrolyte and composite cathode framework

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Journal of energy Chemistry 2021年第1期30卷 210-217,I0007页

作者： Long Chen Xiaoming Qiu Zhiming Bai Li-Zhen Fan Beijing advanced Innovation center for materials Genome Engineering Beijing Key Laboratory for Advanced Energy Materials and TechnologiesUniversity of Science and Technology BeijingBeijing 100083China Beijing Key Laboratory of advanced Chemical energy Storage Technologies and materials Research Institute of Chemical DefenseBeijing 100191China Shanxi Key Laboratory of New energy materials and Devices Taiyuan University of Technology030024China School of materials Science and Engineering Beihang UniversityBeijing 100191China

The solid-state lithium battery is considered as an ideal next-generation energy storage device owing to its high safety,high energy density and low ***,the poor ionic conductivity of solid electrolyte and low interfacial stability has hindered the application of solid-state lithium ***,a flexible polymer/garnet solid electrolyte is prepared with poly(ethylene oxide),poly(vinylidene fluoride),Li6.75La3 Zr1.75Ta0.25O12,lithium bis(trifluoromethanesulfonyl)imide and oxalate,which exhibits an ionic conductivity of 2.0 ×10^(-4) S cm^(-1) at 55℃,improved mechanical property,wide electrochemical window(4.8 V ***/Li+),enhanced thermal *** acidic OX was introduced to inhibit the alkalinity reactions between Li6.75La3 Zr1.75Ta0.25O12 and poly(vinylidene fluoride).In order to improve the interfacial stability between cathode and electrolyte,an Al2 O3@LiNi0.5Co0.2Mn0.3O2 based composite cathode framework is also fabricated with poly(ethylene oxide) polymer and lithium salt as *** solid-state lithium battery assembled with polymer/garnet solid electrolyte and composite cathode framework demonstrates a high initial discharge capacity of 150.6 mAh g^(-1) and good capacity retention of 86.7% after 80 cycles at 0.2 C and 55℃,which provides a promising choice for achieving the stable electrode/electrolyte interfacial contact in solid-state lithium batteries.

关键词： Li6.75La3Zr1.75Ta0.25O12 Polymer/garnet solid electrolyte Interfacial stability Composite cathode framework Lithium metal batteries

Rapid removal of bisphenol A on highly ordered mesoporous carbon

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Journal of environmental Sciences 2011年第2期23卷 177-182页

作者： Qian Sui Jun Huang Yousong Liu Xiaofeng Chang Guangbin Ji Shubo Deng Tao Xie Gang Yu Department of environmental Science and Engineering Tsinghua University - VEOLIA Environnement Joint Research Center for Advanced Environmental Technology Tsinghua University Beijing 100084 Nanomaterials research Institute College of Materials Science and TechnologyNanjing University of Aeronautics and Astronautics Nanjing 210016 China

Bisphenol A （BPA） is of global concern due to its disruption of endocrine systems and ubiquity in the aquatic environment. It is important, therefore, that efforts are made to remove it from the aqueous phase. A novel adsorbent, mesoporous carbon CMK-3, prepared from hexagonal SBA- 15 mesoporous silica was studied for BPA removal from aqueous phase, and compared with conventional powdered activated carbon （PAC）. Characterization of CMK-3 by transmission electron microscopy （TEM）, X-ray diffraction, and nitrogen adsorption indicated that prepared CMK-3 had an ordered mesoporous structure with a high specific surface area of 920 m^2/g and a pore-size of about 4.9 nm. The adsorption of BPA on CMK-3 followed a pseudo second-order kinetic model. The kinetic constant was 0.00049 g/（***）, much higher than the adsorption of BPA on PAC. The adsorption isotherm fitted slightly better with the Freundlich model than the Langmuir model, and adsorption capacity decreased as temperature increased from 10 to 40℃. No significant influence of pH on adsorption was observed at pH 3 to 9; however, adsorption capacity decreased dramatically from pH 9 to 13.

关键词： mesoporous carbon CMK-3 powdered activated carbon bisphenol A endocrine disrupting chemicals

On-demand engineerable visible spectrum by fine control of electrochemical reactions

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National Science Review 2024年第3期11卷 239-249页

作者： Qirong Liu Lei Liu Yongping Zheng Min Li Baofu Ding Xungang Diao Hui-Ming Cheng Yongbing Tang advanced energy Storage technology research center Shenzhen Institute of Advanced TechnologyChinese Academy of Sciences Institute of technology for Carbon Neutrality Shenzhen Institute of Advanced Technology Chinese Academy of Sciences School of energy and Power Engineering North University of China School of Resource Environment and Safety EngineeringHunan University of Science and Technology School of energy and Power Engineering Beihang University Shenzhen Key Laboratory of energy materials for Carbon Neutrality Shenzhen Institute of Advanced Technology Chinese Academy of Sciences Shenyang National Laboratory for materials Science Institute of Metal Research Chinese Academy of Sciences

Tunability of optical performance is one of the key technologies for adaptive optoelectronic applications,such as camouflage clothing, displays, and infrared shielding. High-precision spectral tunability is of great importance for some special applications with on-demand adaptability but remains challenging. Here we demonstrate a galvanostatic control strategy to achieve this goal, relying on the finding of the quantitative correlation between optical properties and electrochemical reactions within materials. An electrochromic electro-optical efficiency index is established to optically fingerprint and precisely identify electrochemical redox reactions in the electrochromic device. Consequently, the charge-transfer process during galvanostatic electrochemical reaction can be quantitatively regulated, permitting precise control over the final optical performance and on-demand adaptability of electrochromic devices as evidenced by an ultralow deviation of research in a wide range of spectroelectrochemistry, electrochemical energy storage, electrocatalysis, and material chemistry.

关键词： electrochromics fine control spectral tunability high precision galvanostatic control