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A rational preparation strategy of phase tuned MoO_(3) nanostructures for high-performance all-solid asymmetric supercapacitor

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Journal of Energy Chemistry 2023年第12期87卷 192-206,I0006页

作者： M.Kundu D.Mondal I.Mondal A.Baral P.Halder S.Biswas B.K.Paul N.Bose R.Basu S.Das Department of Physics Jadavpur UniversityKolkata 700032India Department of Physics Jogamaya Devi CollegeKolkata 700026India rescon india pvt.ltd Kolkata 700034India School of Advanced Materials Green Energy and Sensor Systems(SAMGESS)IIESTShibpurHowrah 711103India Bangabasi College Kolkata 700009India University of Engineering and Management Kolkata 700160India

In this work,phase and morphology-tuned MoO_(3) nanostructures are synthesized through a novel modified co-precipitation method,and their electrochemical properties are *** the first time,such a simple surfactant-assisted synthesis process aided by minor temperature variations is reported which results in phase transition of the nanoparticles from h-MoO_(3) nano-rods to a-MoO_(3) *** nanostructures thus developed are highly porous and crystalline with significantly large specific surface area as compared to previous *** theoretical bandgap energy of the optimized sample calculated using Perdew-Zunger local density approximation(LDA) is in good agreement with the experimental *** overall structural,morphological,and surface-behavioural analysis predicts the electrochemical superiority in 2D a-MoO_(3).The cyclic voltammetry and galvano-potentiometry measurements of 2D a-MoO_(3) in the potential window of-0.6 V to +0.2 V present the highest pseudosupercapacitive response with a maximum specific capacitance of 829 F g^(-1)at 2 A g^(-1)as compared to h-MoO_(3) (452 F g^(-1)) and h@a-MoO_(3) (783 F g^(-1)).Thus,the MoO_(3) 2D nanostructures synthesized through our novel synthesis technique display excellent specific capacitance as compared to previous reported ***,a-MoO_(3) exhibits a galvanostatic charging-discharging cyclic stability of about 91%after 2000 cycles,indicating that it can serve as an excellent electrode material for supercapacitors.A solid-state asymmetric supercapacitor device is successfully constructed using a-MoO_(3) which can light up 4 red LEDs for 10 *** specific energy density of the device reaches a maximum value of 36.3 W h kg^(-1)at the power density of 50 W kg^(-1).

关键词： MoO_(3)nanoparticles Asymmetric solid-state supercapacitor Electrochemical performance Low-temperature novel synthesis technique Density functional calculations

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