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Science China Chemistry 2025年第1期68卷 337-349页

作者： Meiyun Xu Song Gu Fulong Chen Zhe Zhao Peng Liu Daoben Hua State Key Laboratory of Radiation Medicine and Protection School of Radiological and Interdisciplinary Sciences(RAD-X)Collaborative Innovation Center of Radiological Medicine of Jiangsu Higher Education InstitutionsSoochow UniversitySuzhou 215123China

The efficient separation of fission products,such as TcO_(4)^(-)and I^(-),holds strategic significance for the management of radioactive wastes and environmental *** this study,we propose an ultrafast strategy for scalable preparation of a highly quaternized organic network to facilitate efficient and synchronous separation of iodide and *** network can be prepared within a few minutes at room temperature,using polyethylenimine and 1,2,4,5-tetrakis(bromomethyl)benzene as building *** chlorine replacement,the network,abundantly decorated with quaternary ammonium groups(Cl@QPN),exhibits an ultrahigh positive charge density of 7.6 mmol/*** enables the rapid and efficient enrichment of target anions through strong electrostatic Coulomb *** a result,Cl@QPN exhibits significantly higher adsorption rate constants of 0.830 g/(mg min)for ReO_(4)^(-)(a nonradioactive surrogate of TcO_(4)^(-))and 0.677 g/(mg min)for I-compared to other ***,it possesses high adsorption capacities,reaching 1,681 mg/g for ReO_(4)^(-)and 917.4 mg/g for I-.Cl@QPN also demonstrates good selectivity towards target ions and shows efficient adsorption for^(99)TcO_(4)^(-).Additionally,Cl@QPN exhibits high dynamic processing capacities,handling up to 3,100 and 7,400 kg of simulated streams per kilogram of material for I-and ReO_(4)^(-),respectively.

关键词： quaternized polymer networks adsorption pertechnetate iodide liquid radioactive streams

Recent progress in metal-organic frameworks(Part II—material application)

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Science China Chemistry 2025年

作者： Jiandong Pang Wentao Jiang Xue-Wen Zhang Hao-Long Zhou Yuxiu Sun Wei Gong Bin Wang Fuyin Ma Linwei He Long Chen Qiang Chen He-Qi Zheng Yuanjing Cui Wen-Jie Shi Chao Zhang Mei Wang Yue-Biao Zhang Jie-Peng Zhang Chongli Zhong Yong Cui Shuao Wang Jian-Rong Li Guodong Qian Tong-Bu Lu Huan Pang Xian-He Bu Institute for New Energy Materials and Low Carbon Technologies School of Materials Science and Engineering Tianjin University of Technology School of Chemistry and Chemical Engineering Yangzhou University School of Materials Science and Engineering Nankai University School of Physical Science and technology ShanghaiTech University MOE Key Laboratory of Bioinorganic and Synthetic Chemistry GBRCE for Functional Molecular Engineering School of Chemistry IGCMESun Yat-sen University Department of Chemistry Shantou University School of Chemical Engineering and technology Tiangong University School of Chemistry and Chemical Engineering Shanghai Jiao Tong University State Key Laboratory of Radiation Medicine and Protection School for Radiological and Interdisciplinary Sciences Soochow University College of Materials Science & Engineering Beijing University of Technology State Key Laboratory of Silicon and Advanced Semiconductor Materials Cyrus Tang Center for Sensor Materials and ApplicationsSchool of Materials Science & Engineering Zhejiang University

As a class of functional crystalline porous materials, metal-organic frameworks(MOFs) gained rapid development in the past three decades and a large number of MOFs with ordered structures, high surface areas, and functionalized channels have been investigated. MOFs and MOF-derived/composite materials show great potential in many application fields. In this review, we discussed the main applications of MOFs and MOF-derived/composite materials in small molecule storage, separation, luminescence, sensing, multitype catalysis, and energy storage. In addition, challenges and problems in the future research of MOFsrelated fields are also discussed.

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Construction of a novel cationic polymeric nanotrap using valence and configuration matching strategy for benchmark removal of selenium oxoanions from nuclear waste streams

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Science China Chemistry 2025年

作者： Yunnan Tao Kui Tan Hongliang Huang Long Chen Bin Wang Chunyu Bao Junchang Chen Zhifang Chai Shuao Wang State Key Laboratory of Radiation Medicine and Protection School for Radiological and Interdisciplinary Sciences (RAD-X) and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions Soochow University Department of Chemistry University of North Texas State Key Laboratory of Separation Membranes and Membrane Processes Tiangong University

The persistent need for sorbents capable of efficiently extracting selenium from radioactive wastewater has been a significant challenge. Herein, we introduce SCU-CPN-5, a robust and saleable adsorbent designed through principles of valence and configuration matching, which achieves remarkable removal of selenium oxo-anions from nuclear waste liquids. SCU-CPN-5 demonstrates unprecedented adsorption capacities, with 617 mg/g for SeO42-and 333 mg/g for SeO32-. Additionally, it exhibits a removal efficiency of up to 99.7% for environmentally relevant concentrations of SeO42-. Notably, we employed in-situ Fouriertransform infrared spectroscopy to monitor the sorption process of selenium oxo-anions into the pores of the sorbent in real time,marking a significant advancement. This research not only introduces a novel approach to the design of functional materials for nuclear wastewater management but also provides a molecular-level understanding of the adsorption mechanism.

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Tunable and wideband high-performance rare earth-doped Ni-Mg-Cu-Zn nano ferrite-based meta-absorbers for C-band application

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Journal of Rare Earths 2025年第1期43卷 124-132,I0005页

作者： Majid Niaz Akhtar Magbool Alelyani Fatimah Mohammed AAlzahrani Abdullah Almohammedi Sabih Qamar MABaqir MIrfan Muhammad Azhar Khan Kheir SAlbarkaty ZAAlrowaili MSAl-Buriahi Institute of Physics The Islamia University of Bahawalpur63100BahawalpurPakistan Department of radiological Sciences College of Applied Medical ScienceKing Khalid University61421bhaSaudi Arabia Department of Chemistry College of SciencePrincess Nourah bint Abdulrahman UniversityP.O.Box 84428Riyadh11671Saudi Arabi Department of Physics Faculty of ScienceIslamic University of Madinah42352.Saudi Arabia Department of Chemical Engineering Muhammad Nawaz Sharif University of Engineering and Technology(MNSUET)60000MultanPakistan Department of Electrical and Computer Engineering COMSATS University IslamabadSahiwal Campus57000Pakistan Department of Physics Umm Al-Qura UniversityMakkah24382Saudi Arabia Department of Physics College of ScienceJouf UniversityP.O.Box:201474331SakakaSoudi Arabia Department of Physics Sakarya University6900SakaryaTurkey

Due to advanced technology,electromagnet interference and dissipation problems in the electronic and portable devices at GHz range are increasing *** absorbing materials with outstanding electromagnetic properties,wide bandwidth,and strong absorption are highly *** present investigation deals with the preparation of Ni-Mg-Cu-Zn(NMCZ)substituted nano ferrites with composition of Ni_(0.3)Mg_(0.2)Cu_(0.3)Zn_(0.2)X_(0.02)Fe_(1.98)O_(4)(X=Nd,Ho,Pr,Gd,Yb).X-ray diffraction(XRD),Fourier transform infrared spectroscopy(FTIR),field emission scanning electron microscopy(FESEM),transmission electron microscopy(TEM),a vibratory sample magnetometer(VSM),and a Vector network analyzer(VNA)were used to investigate these rare earth-doped nanocrystalline ferrites'*** reveals the single spinel phase structure in all Ni-Mg-Cu-Zn *** spectroscopy shows the presence of tetrahedral and octahedral bands of spinel *** images reveal the lowest agglomeration for the Ho-doped NMCZ nano-spinel ferrites *** images show the hexagon shapes of the Yb-and Nd-doped NMCZ ***-doped NMCZ ferrites show more coercivity than other rare earth metals substituted NMCZ nanocrystalline *** analysis was used to calculate the magnetic features like initial permeability,magnetic anisotropy constant,remanence,coercivity,and magnetic ***-frequency switching field distributions(SFD)analyses were also *** characteristics such as losses,permittivity,modulus,Q,ac conductivity,and impedance of the Nd^(-),Ho^(-),Pr^(-),Gd^(-),Yb-doped Ni-Mg-Cu-Zn ferrites were *** minimum reflection loss(-57.3 dB)is found at 1.4 GHz for Pr-doped Ni-Mg-Cu-Zn ferrite ***,the reflection loss(RL)of-53.9 dB at 2.9 GHz is observed for Ho-doped Ni-Mg-Cu-Zn ferrite *** magnetization,low coercivity,outstanding magnetodielectric,and absorption properties of theNd^(-),Ho^(-),Pr^(-),Gd^(-)and Yb^(-)doped Ni-Mg

关键词： Rare earths Reflection loss Cubic phase Magnetodielectric Ni-Mg-Cu-Zn(NMCZ)meta-absorber

Optical and structural properties of Ge-ion-implanted fused silica after annealing in different ambient conditions

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Chinese Physics B 2010年第1期19卷 551-556页

作者：向霞陈猛陈美艳祖小涛朱莎王鲁闽 Department of Applied Physics University of Electronic Science and Technology of China Department of Nuclear Engineering and radiological Sciences University of Michigan

Ge^＋ ions are implanted into fused silica glass at room temperature and a fluence of 1 × 10^17 cm^-2. The as-implanted samples are annealed in O2, N2 and Ar atmospheres separately. Ge^0, GeO and GeO2 coexist in the as-implanted and annealed samples. Annealing in different atmospheres at 600℃ leads each composite to change its content. After annealing at 1000℃, there remains some amount of Ge^0 in the substrates. However, the content of Ge decreases due to out-diffusion. After annealing in N2, Si N composite is formed. The absorption peak of GeO appears at 240 nm after annealing in O2 atmosphere, and a new absorption peak occurs at 418 nm after annealing in N2 atmosphere, which is attributed to the Si N composite. There is no absorption peak appearing after annealing in Ar atmosphere. Transmission electron microscopic images confirm the formation of Ge nanoparticles in the as-implanted sample and GeO2 nanoparticles in the annealed sample. In the present study, the GeO content and the GeO2 content depend on annealing temperature and atmosphere. Three photolumineseence emission band peaks at 290, 385 and 415 nm appear after ion implantation and they become strong with the increase of annealing temperature below 700℃ and their photoluminescences recover to the values of as-grown samples after annealing at 700℃. Optical absorption and photoluminescence depend on the annealing temperature and atmosphere.

关键词： nanoparticles optical absorption photoluminescence ion implantation

Luminescence and low temperature trap centers in mixed rare earth borate crystal

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Journal of Rare Earths 2018年第10期36卷 1024-1029页

作者： D.Joseph Danie Indra Raj Panday H.J.Kim Sunghwan Kim U.Fawad Department of Physics Kyungpook National University Department of radiological Science Cheongju University Department of Physics Kohat University of Science and Technology

The single crystal of this compound has been grown from melt by using a conventional Czochralski technique. The temperature dependent luminescence spectra were measured using a 265 nm laser as an exciting source in the range of 10-300 K. The scintillation decay time profile was measured and found to have three components. The influence of the trap centers on the luminescence properties was studied by means of thermoluminescence（TL） glow peak analysis. Low temperature TL glow peaks were measured in the temperature range of 10-300 K at the heating rate of 0.1 K/s for X-ray irradiated sample. The TL glow peak consists of two dominant peaks at 88 and 109 K. Several glow peaks with a complex nature causes the decrease in the light yield at temperatures below 250 K, and along with long scintillation decay components were observed. The trap parameters such as activation energy（E）, frequency factor（s）and order of kinetics（b） were calculated using various standard methods such as peak shape（PS）,variable heating rate（VHR）, initial rise（IR） and computerized glow curve deconvolution（CGCD）.

关键词： Rare earth Decay time Thermoluminescence Kinetic parameters

Cluster size and substrate temperature affecting thin film formation during copper cluster deposition on a Si(001) surface

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Chinese Physics B 2012年第11期21卷 190-197页

作者：龚恒风吕炜王鲁闽李公平 School of Nuclear Science and technology Lanzhou University Department of Mechanical Engineering University of Michigan Department of Nuclear Engineering and radiological Science University of Michigan

The soft deposition of Cu clusters on a Si （001） surface was studied by molecular dynamics simulations. The embedded atom method, the Stillinger-Weber and the Lennar-Jones potentials were used to describe the interactions between the cluster atoms, between the substrate atoms, and between the cluster and the substrate atoms, respectively. The Cu13, Cu55, and Cu147 clusters were investigated at different substrate temperatures. We found that the substrate temperature had a significant effect on the Cn147 cluster. For smaller Cu13 and Cu55 clusters, the substrate temperature in the range of study appeared to have little effect on the mean center-of-mass height. The clusters showed better degrees of epitaxy at 800 K. With the same substrate temperature, the Cu55 cluster demonstrated the highest degree of epitaxy, followed by Cu147 and then Cu13 clusters. In addition, the Cu55 cluster showed the lowest mean center-of-mass height. These results suggested that the Cu55 cluster is a better choice for the thin-film formation among the clusters considered. Our studies may provide insight into the formation of desired Cu thin films on a Si substrate.

关键词： copper cluster deposition epitaxy diffusion

Performances of different efficiency calibration methods of high-purity-germanium gamma-ray spectrometry in an inter-comparison exercise

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Nuclear Science and Techniques 2019年第3期30卷 9-14页

作者： Bao-Lu Yang Qiang Zhou Jing Zhang Shuai-Mo Yao Ze-Shu Li Wen-Hong Li Fei Tuo Key Laboratory of radiological Protection and Nuclear Emergency National Institute for Radiological ProtectionChinese Center for Disease Control and Prevention

This study reports the performances of efficiency calibrations for high-purity-germanium gamma-ray spectrometry using the source-, Laboratory Sourceless Object Calibration Software(LabSOCS)-and ANGLE-based methods in an inter-comparison exercise. Although the results of LabSOCS and ANGLE for ^(241)Am emitting lowenergy gamma rays were not very satisfactory, all of the three efficiency calibration methods passed acceptance criteria. The results confirmed the reliability of the calculation codes ANGLE and LabSOCS as alternative efficiency calibration methods in high-purity-germanium gamma spectrometry. This study is likely to promote the further application of the ANGLE and LabSOCS calculation codes in radioactivity measurements.

关键词： Efficiency calibration ANGLE Laboratory Sourceless Object Calibration Software (LabSOCS) Gamma-ray spectrometry

Near-infrared photoimmunotherapy of pancreatic cancer using an indocyanine green-labeled anti-tissue factor antibody

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World Journal of Gastroenterology 2018年第48期24卷 5491-5504页

作者： Winn Aung Atsushi B Tsuji Aya Sugyo Hiroki Takashima Masahiro Yasunaga Yasuhiro Matsumura Tatsuya Higashi Department of Molecular Imaging and Theranostics National Institute of Radiological SciencesNational Institutes for Quantum and Radiological Science and Technology (QST-NIRS) Division of Developmental Therapeutics Exploratory Oncology Research and Clinical Trial CenterNational Cancer Center

AIM To investigate near-infrared photoimmunotherapeutic effect mediated by an anti-tissue factor(TF) antibody conjugated to indocyanine green(ICG) in a pancreatic cancer *** Near-infrared photoimmunotherapy(NIR-PIT) is a highly selective tumor treatment that utilizes an antibody-photosensitizer conjugate administration, followed by NIR light exposure. Anti-TF antibody 1849-ICG conjugate was synthesized by labeling of rat IgG2 b anti-TF monoclonal antibody 1849(anti-TF 1849) to a NIR photosensitizer,ICG. The expression levels of TF in two human pancreatic cancer cell lines were examined by western blotting. Specific binding of the 1849-ICG to TF-expressing BxPC-3 cells was examined by fluorescence microscopy. NIR-PITinduced cell death was determined by cell viability imaging assay. In vivo longitudinal fluorescence imaging was used to explore the accumulation of 1849-ICG conjugate in xenograft tumors. To examine the effect of NIRPIT, tumor-bearing mice were separated into 5 groups:(1) 100 μg of 1849-ICG i.v. administration followed by NIR light exposure(50 J/cm2) on two consecutive days(Days 1 and 2);(2) NIR light exposure(50 J/cm2) only on two consecutive days(Days 1 and 2);(3) 100 μg of 1849-ICG i.v. administration;(4) 100 μg of unlabeled antiTF 1849 i.v. administration; and(5) the untreated control. Semiweekly tumor volume measurements, accompanied with histological and immunohistochemical(IHC) analyses of tumors, were performed 3 d after the 2nd irradiation with NIR light to monitor the effect of treatments. RESULTS High TF expression in BxPC-3 cells was observed via western blot analysis, concordant with the observed preferential binding with intracellular localization of 1849-ICG via fluorescence microscopy. NIR-PIT-induced cell death was observed by performing cell viability imaging assay. In contrast to the other test groups, tumor growth was significantly inhibited by NIR-PIT with a statistically significant difference in relative tumor volumes for

关键词： Pancreatic cancer Anti-tissue factor antibody Indocyanine green Photoimmunotherapy Near-infrared

Facile Synthesis of the Magnetic Metal Organic Framework Fe_3O_4@UiO-66-NH_2 for Separation of Strontium

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Biomedical and Environmental Sciences 2018年第6期31卷 483-488页

作者： YIN Liang Liang KONG Xiang Yin ZHANG Yao JI Yan Qin Key Laboratory of radiological Protection and Nuclear Emergency National Institute for Radiological ProtectionChinese Center for Disease Control and Prevention

A magnetic metal organic framework（MMOF） was synthesized and used to separate Sr^2＋ in aqueous solution. The shape and structure of prepared Fe3O4@UiO-66-NH2 were characterized, and the absorbed concentration of strontium was determined through inductively coupled plasma mass spectrometry. The results indicated that Fe3O4 and UiO-66-NH2 combined through chemical bonding. The experimental adsorption results for separation of Sr^2＋ in aqueous solution indicated that the adsorption of Sr^2＋ to Fe3O4@UiO-66-NH2 increased drastically from pH 11 to pH 13. The adsorption isotherm model indicated that the adsorption of Sr^2＋ conformed to the Freundlich isotherm model（R2 = 0.9919）. The MMOF thus inherited the superior qualities of magnetic composites and metal organic frameworks, and can easily be separated under an external magnetic field. This MMOF thus has potential applications as a magnetic adsorbent for low level radionuclide （90）Sr.

关键词： Magnetic metal organic framework(MMOF) Fe3O4@UiO-66-NH2 Radioactivity Strontium Adsorbents