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Pd/N-doped carbon dots@dendritic mesoporous silica nanospheres:A highly efficient catalyst for the hydrogenation of 4-nitrophenol

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Nano research 2024年第9期17卷 7967-7974页

作者： Weiruo Liu Yanbin Zhu Jiwei Wang Haisong Feng Yunpu Zhai Wei Li dongyuan Zhao College of Chemistry Zhengzhou University100 Kexue AvenueZhengzhou 450001China department of Chemistry Laboratory of Advanced MaterialsShanghai Key Laboratory of Molecular Catalysis and Innovative Materialsand State Key Laboratory of Molecular Engineering of PolymersFudan UniversityShanghai 200433China State Key laboratory of Chemical resource Engineering Beijing Advanced Innovation Center for Soft Matter Science and EngineeringBeijing University of Chemical TechnologyBeijing 100029China

Highly dispersed Pd/N-doped carbon dots(Pd/NCds)were successfully immobilized in the mesoporous channels of amino-functionalized dendritic mesoporous silica nanospheres(NMS).The synthesized Pd/NCds@NMS catalyst exhibits outstanding performance in the catalytic reduction of 4-nitrophenol(4-NP),achieving a turnover frequency of 1461.8 mol·molPd^(-1)·h^(-1),with the conversion rate remaining above 80%after 11 *** and density functional theory calculations reveal that the NCds significantly affect the electronic structure of Pd nanoparticles,leading to changes in the energy barriers for the adsorption of 4-NP at the Pd sites and the conversion of 4-NP reaction intermediates,which is a key factor contributing to the catalytic *** study offers a new strategy for synthesizing carbon-dot-modified metal-based catalysts.

关键词： palladium nanoparticles nitrogen-doped carbon dots dendritic mesoporous silica catalytic hydrogenation 4-nitrophenol reduction

Physicochemical characterization of dendrobium officinale polysaccharides and regulation of immunometabolic homeostasis in Sub-health mice based on the Cd4-Th17/Treg immunity axis

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Food Science and Human Wellness 2024年

作者： Bo Li Ze-Hua Zhang Hao-ru Guan Xing-Li-Shang He Ning Wang Ying-Jie dong Mei rong Jiu-Jie Jia Ting-Ting Chen Zhi-Yuan Li Gui-Yuan Lv Lin-Nan Zhang Su-Hong Chen Collaborative Innovation Center of Yangtze river delta region Green Pharmaceuticals Zhejiang University of Technology Zhejiang Provincial Key laboratory of TCM for innovative r & d and digital Intelligent Manufacturing of TCM Great Health Products.Huzhou College of Pharmaceutical Science Zhejiang Chinese Medical University

The aim of this study was to investigate the role of dOPS and dOPS100 in attenuating immune dysfunction in subfertile mice. The results of the study revealed several noteworthy findings. First， dOPS and dOPS100 treatments led to significant improvement in weight gain and reversal of fatigue-related behaviors compared to the normal group. Second， both dOPS and dOPS100 showed effectiveness in reducing immune organ swelling， modulating immunoglobulin （IgA and IgM） levels， and restoring complement （C3c and C4） levels. In addition， they demonstrated a significant ability to enhance the integrity of the intestinal mechanical barrier by differentially upregulating the tight junction proteins Occludin and ZO-1. In addition， it was found that dOPS100 specifically enhanced the Cd4+-Th17/Treg immune axis in the gut， as evidenced by increased expression of Foxp3 as well as decreased expression of rOrγt， and further modulation of IL-10， IL-22， and IL-17A expression levels of inflammatory factors. These findings collectively suggest that dOPS100 holds significant potential in improving sub-healthy status by repairing the intestinal barrier， restoring local immune homeostasis， and activating the intestinal immune regulatory network. The study's outcomes provide valuable insights into the therapeutic implications of dOPS and dOPS100 in addressing immune dysfunction in sub-healthy conditions.

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Heterovalent ion exclusion principle in atomically single site metal(hydr)oxide catalysts design

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Science Bulletin 2024年第13期69卷 2009-2012页

作者： daojin Zhou Fengmei Wang Yun Kuang Xiaoming Sun State Key laboratory of Chemical resource Engineering Beijing University of Chemical TechnologyBeijing 100029China Ocean Hydrogen Energy r&d Center Research Institute of Tsinghua University in ShenzhenShenzhen 518057China

Single-atom catalysts(SACs)are a series of catalysts in which all metal species are atomically dispersed on oxides,zeolites,sulfides,carbons,and so *** concept describing how atoms arrange with their nearest neighbors was proposed in 1969 by Van Hardeveld and co-workers[1],and researchers witness the growing popularity of SACs[2].However,the first long-standing issue in SACs is that the low concentration of active sites on the ***,weak chemical bonds between active sites with supports cannot sustain the functionalities of the SACs during long-term reactions,especially ones run at harsh conditions(high temperature or humidity,strong oxidative conditions).The loss or aggregation of active sites in SACs require substantial efforts to address the existing drawbacks in traditional SACs.

关键词： atomic bonds valent

Performance improvements in complementary metal oxide semiconductor devices and circuits based on fin field-effect transistors using 3-nm ferroelectric Hf0.5Zr0.5O2

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rare Metals 2024年第7期43卷 3242-3249页

作者： Zhao-Hao Zhang Yan-Na Luo Gao-Bo Xu Jia-Xin Yao Zhen-Hua Wu Hong-Bin Zhao Qing-Zhu Zhang Hua-Xiang Yin Jun Luo Wen-Wu Wang Hai-Ling Tu Integrated Circuit Advanced r&d Center Institute of Microelectronics of Chinese Academy of Sciences School of Integrated Circuits University of Chinese Academy of Sciences State Key laboratory of Advanced Materials for Smart Sensing General Research Institute for Nonferrous Metals

In this work,a conventional HfO2gate dielectric layer is replaced with a 3-nm ferroelectric（Fe） HZO layer in the gate stacks of advanced fin field-effect transistors（FinFETs）.Fe-induced characteristics,e.g.,negative drain induced barrier lowering（N-dIBL） and negative differential resistance（Ndr）,are clearly observed for both p-and n-type HZO-based *** characteristics are attributed to the enhanced ferroelectricity of the 3-nm hafnium zirconium oxide（HZO） film,caused by Al doping from the TiAlC capping *** mechanism is verified for capacitors with structures similar to the *** to the enhanced ferroelectricity and N-dIBL phenomenon,the drain current(IdS)of the HZO-FinFETs is greater than that of HfO2-FinFETs and obtained at a lower operating ***,circuits based on HZO-FinFET achieve higher performance than those based on HfO2-FinFET at a low voltage drain(Vdd),which indicates the application feasibility of the HZO-FinFETs in the ultralow power integrated circuits.

关键词： FinFET Ferroelectric Hafnium zirconium oxide Subthreshold swing Low power

Cytoplasmic FKBPs are involved in molting and metamorphosis through regulating the nuclear localization of Ecr

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Insect Science 2024年第3期31卷 759-772页

作者： Xian Zhang Qiao-ran Wang Qian Wu Jun Gu Li-Hua Huang Guangdong Provincial Key laboratory of Insect developmental Biology and Applied Technology School of Life SciencesSouth China Normal UniversityGuangzhouChina Guangmeiyuan r&d Center Guangdong Provincial Key Laboratory of Insect Developmental Biology and Applied TechnologySouth China Normal UniversityMeizhouChina

Molting and metamorphosis are important physiological processes in insects that are tightly controlled by ecdysone receptor(Ecr)through the 20-hydroxyecdysone(20E)signaling *** is a steroid nuclear receptor(Sr).Several FK506-binding proteins(FKBPs)have been identified from the mammal Sr complex,and are thought to be involved in the subcellular trafficking of ***,their roles in insects are poorly *** explore whether FKBPs are involved in insect molting or metamorphosis,we injected an FKBP inhibitor(FK506)into a lepidopteran insect,Spodoptera litura,and found that molting was inhibited in 61.11%of the larvae,and that the time for larvae to pupate was significantly extended.A total of 10 FKBP genes were identified from the genome of *** and were clustered into 2 distinct groups,according to their subcellular localization,with FKBP13 and FKBP14 belonging to the endoplasmic reticulum(Er)group and with the other members belonging to the cytoplasmic(Cy)*** the CyFKBPs were significantly upregulated in the prepupal or pupal stages,with the opposite being observed for the Er group ***506 completely blocked the transfer of Ecr to the nucleus under 20E induction,and significantly downregulated the transcriptional expression of many 20E signaling genes.A similar phenomenon was observed after rNA interference of2 CyFKBPs(FKBP45 and FKBP12b),but not for *** together,our data indicate that the cytoplasmic FKBPs,especially FKBP45 and FKBP12b,mediate the nuclear localization of Ecr,thereby regulating the 20E signaling and ultimately affecting molting and metamorphosis in insects.

关键词： Ecr FKBP metamorphosis molting rNAi subcellular localization

Effect of cis/trans molecular structures on pyrolysis performance and heat sink of decalin isomers

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Frontiers of Chemical Science and Engineering 2024年第1期18卷 51-60页

作者： Qing Liu Kang Xue Tinghao Jia Zhouyang Shen Zehao Han Lun Pan Ji-Jun Zou Xiangwen Zhang Key laboratory for Green Chemical Technology of the Ministry of Education School of Chemical Engineering and TechnologyTianjin UniversityTianjin 300072China Collaborative innovative Center of Chemical Science and Engineering(Tianjin) Tianjin 300072China Haihe laboratory of Sustainable Chemical Transformations Tianjin 300192China Zhejiang Institute of Tianjin University Ningbo 315201China

decalin is considered as an important compound of high-energy-density endothermic fuel,which is an ideal on-board coolant for thermal management of advanced ***,decalin contains two isomers with a tunable composition,and their effects on the pyrolysis performance,such as the heat sink and coking tendency have not been ***,we investigated the pyrolysis of decalin isomers,i.e.,cis-decalin,trans-decalin and their mixtures(denoted as mix-decalin),in order to clarify the effects of the cis-/trans-structures on the pyrolysis performance of decalin *** pyrolysis results confirmed that conversion of the tested fuels(600–725℃,4 MPa)decreased in the order cis-decalin>mix-decalin>*** analyses of the pyrolysis products were used to compare the product distributions from cis-decalin,mix-decalin and trans-decalin,and the yields of some typical components(such as cyclohexene,1-methylcyclohexene,benzene and toluene)showed significant differences,which could be ascribed to deeper cracking of ***,the heat sinks and coking tendencies of the decalins decreased in the order cis-decalin>mix-decalin>*** work demonstrates the relationship between the cis/trans structures and the pyrolysis performance of decalin,which provides a better understanding of the structure-activity relationships of endothermic hydrocarbon fuels.

关键词： endothermic fuel decalin pyrolysis heat sink molecular structure

recent Advances in Biomass-derived Porous Carbon Materials:Synthesis,Composition and Applications

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Chemical research in Chinese Universities 2024年第1期40卷 3-19页

作者： ZHAI Ziqi LU Yumiao LIU Guangyong dING Wei-Lu CAO Bobo HE Hongyan CAS Key laboratory of Green Process and Engineering State Key Laboratory of Mesoscience and EngineeringBeijing Key Laboratory of Ionic Liquids Clean ProcessInstitute of Process EngineeringChinese Academy of SciencesBeijing 100190P.R.China University of Chinese Academy of Sciences Beijing 100049P.R.China Longzihu New Energy laboratory Zhengzhou Institute of Emerging Industrial TechnologyZhengzhou 450000P.R.China

Porous carbon materials(PCMs)play a pivotal role in diverse applications,such as energy storage,adsorption,catalysis,environmental remediation,and microwave *** selection of carbon precursors,in particular,is crucial for tailoring porous structures with specific ***,with its rich carbon feedstock,abundant availability,renewability,and versatile structures,has emerged as a promising precursor for porous carbon material *** review comprehensively summarizes the recent advances in biomass-derived porous carbon materials(BPCMs)encompassing synthetic strategy,morphology,structural composition,and multiple *** first review synthetic approaches aiming at regulating porosity,followed by morphological and composition features of BPCMs,with a special emphasis on elucidating the dimensional clarification and heteroatom doping *** discussion then extends to the wide-ranging applications of BPCMs,covering energy-related applications and CO_(2) adsorption to environmental ***,the review outlines the existing challenges and prospects in the *** summary,this review systematically describes BPCMs and provides valuable guidance for researchers to select and synthesize BPCMs that meet specific functional requirements.

关键词： Biomass Porous carbon Pyrolysis Heteroatom-doping Supercapacitor CO_(2)adsorption

Staphylococcus aureus and biofilms:transmission, threats, and promising strategies in animal husbandry

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Journal of Animal Science and Biotechnology 2024年第4期15卷 1408-1423页

作者： Mengda Song Qi Tang Yakun ding Peng Tan Yucheng Zhang Tao Wang Chenlong Zhou Shenrui Xu Mengwei Lyu Yueyu Bai Xi Ma State Key laboratory of Animal Nutrition and Feeding College of Animal Science and TechnologyChina Agricultural UniversityBeijing 100193China Key laboratory of innovative Utilization of Local Cattle and Sheep Germplasm resources(Co‑Construction by Ministry and Province) Ministry of Agriculture and Rural AffairsSchool of Agricultural SciencesZhengzhou UniversityZhengzhou 450001China

Staphylococcus aureus(S. aureus) is a common pathogenic bacterium in animal husbandry that can cause diseases such as mastitis, skin infections, arthritis, and other ailments. The formation of biofilms threatens and exacerbates S. aureus infection by allowing the bacteria to adhere to pathological areas and livestock product surfaces, thus triggering animal health crises and safety issues with livestock products. To solve this problem, in this review, we provide a brief overview of the harm caused by S. aureus and its biofilms on livestock and animal byproducts(meat and dairy products). We also describe the ways in which S. aureus spreads in animals and the threats it poses to the livestock industry. The processes and molecular mechanisms involved in biofilm formation are then explained. Finally, we discuss strategies for the removal and eradication of S. aureus and biofilms in animal husbandry, including the use of antimicrobial peptides, plant extracts, nanoparticles, phages, and antibodies. These strategies to reduce the spread of S. aureus in animal husbandry help maintain livestock health and improve productivity to ensure the ecologically sustainable development of animal husbandry and the safety of livestock products.

关键词： Animal husbandry Biofilm Mastitis Mitigation strategies Staphylococcus aureus

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dynamic Location Method for Shallow Ocean Bottom Nodes Using the Levenberg-Marquart Algorithm

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Journal of Ocean University of China 2024年第4期23卷 953-960页

作者： TONG Siyou LI Junjie XU Xiugang FANG Yunfen WANG Zhongcheng Key laboratory of Submarine Geosciences and Prospecting Techniques MOEOcean University of ChinaQingdao 266100China laboratory for Marine Mineral resources Qingdao Marine Science and Technology CenterQingdao 266237China r&d Center of BGP CNPCZhuozhou 072751China Insitute of Shengli Oilfield SINOPECDongying 257022China

Ocean bottom node(OBN)data acquisition is the main development direction of marine seismic exploration;it is widely promoted,especially in shallow sea ***,the OBN receivers may move several times because they are easily affected by tides,currents,and other factors in the shallow sea environment during long-term *** uncorrected,then the imaging quality of subsequent processing will be *** conventional secondary positioning does not consider the case of multiple movements of the receivers,and the accuracy of secondary positioning is *** first arrival wave of OBN seismic data in shallow ocean mainly comprises refracted *** this study,a nonlinear model is established in accordance with the propagation mechanism of a refracted wave and its relationship with the time interval curve to realize the accurate location of multiple receiver *** addition,the Levenberg-Marquart algorithm is used to reduce the influence of the first arrival pickup error and to automatically detect the receiver movements,identifying the accurate dynamic relocation of the *** simulation and field data show that the proposed method can realize the dynamic location of multiple receiver movements,thereby improving the accuracy of seismic imaging and achieving high practical value.

关键词： OBN dynamic location method Levenberg-Marquart algorithm seismic exploration of shallow sea

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