检索结果-南通市图书馆

Nano Research 2024年第8期17卷 7726-7736页

作者： Ning Cao Yanhui Feng Kening Yan Zihan Liu Jiawei Wan Lin Qiu School of Energy and environmental engineering University of Science and Technology BeijingBeijing 100083China State key laboratory of Biochemical engineering Key Laboratory of Biopharmaceutical Preparation and DeliveryInstitute of Process EngineeringChinese Academy of SciencesBeijing 100190China

When nano-fillers are used to enhance the thermal conductivity of organic phase change materials(PCMs),the naturally formed interface is considered to hinder thermal transport of the composite ***,the effect of the interface on the thermal properties of surrounding PCM has not been fully *** this paper,three composite PCMs(Ery@SiC,Ery@SiO_(2)and Ery@Si_(3)N_(4))were prepared by melt-blending *** local thermal conductivity and reduced Young’s modulus(E^(*))of the erythritol at the interface and far away from the interface in the composite PCMs were simultaneously measured by scanning thermal microscopy(SThM).The results revealed significant enhancement in local thermal conductivity of erythritol at the interface and its obvious positive correlation with E^(*).For different composite PCMs,molecular dynamics(MD)simulations suggested that the increase in intrinsic thermal conductivity and E^(*)of erythritol is attributed to the increase in interaction energy between erythritol and nanoparticles,as more erythritol phonon vibrations transform from localized mode to delocalized mode and erythritol has a higher density at the *** findings will provide new ideas for the design of PCM for energy storage.

关键词： scanning thermal microscopy phase change materials thermal conductivity reduced Young’s modulus interaction energy phonon participation ratio

考虑生态系统服务价值基于混合双主体代理和元胞自动机建模的高密度人口流域土地利用/土地覆盖动态模拟方法研究（英文）

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

engineering 2024年第6期 182-195页

作者：李雨桐蔡宴朋付强张晓东万航杨志峰 Guangdong provincial key laboratory of Water Quality Improvement and Ecological Restoration for Watersheds Institute of Environmental and Ecological Engineering Guangdong University of Technology School of Water Conservancy and Civil engineering Northeast Agricultural University School of environmental Science and engineering Shandong University

Land use/land cover represents the interactive and comprehensive influences between human activities and natural conditions, leading to potential conflicts among natural and human-related issues as well as among stakeholders. This study introduced economic standards for farmers. A hybrid approach(CA-ABM)of cellular automaton(CA) and an agent-based model(ABM) was developed to effectively deal with social and land-use synergic issues to examine human–environment interactions and projections of land-use conversions for a humid basin in south China. Natural attributes and socioeconomic data were used to analyze land use/land cover and its drivers of change. The major modules of the CA-ABM are initialization, migration, assets, land suitability, and land-use change decisions. Empirical estimates of the factors influencing the urban land-use conversion probability were captured using parameters based on a spatial logistic regression(SLR) model. Simultaneously, multicriteria evaluation(MCE) and Markov models were introduced to obtain empirical estimates of the factors affecting the probability of ecological land conversion. An agent-based CA-SLR-MCE-Markov(ABCSMM) land-use conversion model was proposed to explore the impacts of policies on land-use conversion. This model can reproduce observed land-use patterns and provide links for forest transition and urban expansion to land-use decisions and ecosystem services. The results demonstrated land-use simulations under multi-policy scenarios, revealing the usefulness of the model for normative research on land-use management.

关键词：

Pollution characteristics and source apportionment of heavy metal(loid)s in soil and groundwater of a retired industrial park

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Journal of environmental Sciences 2024年第9期143卷 23-34页

作者： Zijing Xiang Shijin Wu Lizhong Zhu Kun Yang Daohui Lin Zhejiang provincial key laboratory of Organic Pollution Process and Control Department of Environmental SciencesZhejiang UniversityHangzhou 310058China Zhejiang Ecological Civilization Academy Anji 313300China

Heavy metal(loid)s(HMs)pollution has become a common and complex problem in industrial parks due to rapid industrialization and ***,soil and groundwater were sampled from a retired industrial park to investigate the pollution characteristics of *** show that Ni,Pb,Cr,Zn,Cd,and Cu were the typical HMs in the *** analysis with the positive matrix factorization model indicates that HMs in the topsoil stemmed from industrial activities,traffic emission,and natural source,and the groundwater HMs originated from industrial activities,groundwater-soil interaction,groundwater-rock interaction,and atmosphere *** sequential extraction of soil HMs reveals that As and Hg were mainly distributed in the residue fraction,while Ni,Pb,Cr,Zn,Cd,and Cu mainly existed in the mobile *** HMs either in the total concentration or in the bioavailable fraction preferred to retain in soil as indicated by their high soil-water partitioning coefficients(K_(d)),and the K_(d) values were correlated with soil pH,groundwater redox potential,and dissolved *** relative stable soil-groundwater circumstance and the low active fraction contents limited the vertical migration of soil HMs and their release to *** findings increase our knowledge about HMs pollution characteristics of traditional industrial parks and provide a protocol for HMs pollution scrutinizing in large zones.

关键词： Heavy metal(loid)s Industrial park Source apportionment Chemical fraction Soil-groundwater partitioning

A novel and promising engineering application of carbon dots:Enhancing the chloride binding performance of cement

在线全文

学校读者我要写书评

暂无评论

Chinese Chemical Letters 2024年第6期35卷 409-416页

作者： Wu-Jian Long Yang Yu Chuang He Guangdong provincial key laboratory of Durability for Marine Civil engineering Key Lab of Coastal Urban Resilient InfrastructureMOECollege of Civil and Transportation EngineeringShenzhen UniversityShenzhen 518060China

Corrosion of reinforcement induced by chloride invasion is extensively considered as the dominating deterioration mechanism of reinforced concrete(RC)structures,leading to serious safety hazards and tremendous economic ***,it still lacks well dispersive and cost-efficient nanomaterials to improve the anti-chloride-corrosion ability of RC ***,specific carbon dots(CDs)with high dispersity and low cost are deliberately designed,successfully prepared by hydrothermal processing,and then firstly applied to immensely enhance chloride binding performance of cement,thereby contributing to suppressing the corrosion of ***,the tailored CDs are composed of the carbon core with highly crystalline sp^(2)C structures and oxygen-containing groups connecting on the carbon core;The typical equilibrium test confirms that with respect to that of the blank cement paste,the chloride binding capacity of cement paste involving 0.2 wt%(by weight of cement)CDs is increased by 109% after 14-day exposure to 3 mol/L Na Cl solution;according to comprehensive analyses of phase compositions,the chloride binding mechanism of CDs-modified cement is rationally attributed to the fact that the incorporation of CDs advances the formation of calcium silicate hydrate(C-S-H)gels and Friedel's salt(Fs),thus enormously enhancing the physically adsorbed and chemically bound chloride ions of cement *** work not only firstly provides a novel high-dispersity and low-cost nanomaterial toward the durability enhancement of RC structures,but also broadens the application of CDs in the field of engineering,conducing to stimulating their industrialization development.

关键词： Carbon dots Chloride binding Cement Chloride binding mechanism Friedel’s salt

Recent progress in CdS-based S-scheme photocatalysts

在线全文

学校读者我要写书评

暂无评论

Journal of Materials Science & Technology 2024年第4期171卷 162-184页

作者： Yajing Ren Yunfeng Li Guixu Pan Ning Wang Yan Xing Zhenyi Zhang College of environmental and Chemical engineering Xi’an Polytechnic UniversityXi’an 710048China Jilin provincial key laboratory of Advanced Energy Materials Department of ChemistryNortheast Normal UniversityChangchun 130024China key laboratory of New Energy and Rare Earth Resource Utilization of State Ethnic Affairs Commission Key Laboratory of Photosensitive Materials and Devices of Liaoning ProvinceSchool of Physics and Materials EngineeringDalian Minzu UniversityDalian 116600China

Photocatalytic technology with sunlight as driving force can convert solar energy into other energy sources for storage and further *** sulfide(CdS),as a typical reducing semiconductor of metal sulfides,represents an interesting research hotspot in photocatalysis due to its suitable bandgap(2.4 eV)for utilizing visible light and strong reducing ability for inducing surface catalytic ***,the photocatalytic performance of CdS is still limited by its fast carrier recombination and serious *** far,CdS semiconductor has been widely developed as a typical reducing photocatalyst in constructing novel S-scheme heterojunction to overcome the above *** this review,the de-sign concepts,basic principles,and charge transfer characteristics of CdS-based S-scheme heterojunction photocatalysts have been comprehensively *** advanced and effective characterization methods for studying the mechanism of CdS-based S-scheme heterojunction are analyzed in ***-thermore,we also summarize the typical applications of CdS-based S-scheme heterojunctions for water splitting,CO_(2) reduction,pollutant degradation,***,according to the current investigation sta-tus,some drawbacks in the current synthetic strategy,mechanism exploration,and application prospect of CdS-based S-scheme heterojunction are proposed,which need to be addressed by further expansion and innovative research.

关键词： Photocatalysis CdS semiconductor Heterojunction S-scheme Metal sulfide

Transcriptomics and physiological analyses reveal that sulfur alleviates mercury toxicity in rice(Oryza sativa L.)

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Journal of environmental Sciences 2024年第1期135卷 10-25页

作者： Yingmei Huang Jicai Yi Xiaomin Li Fangbai Li National-Regional Joint engineering Research Center for Soil Pollution Control and Remediation in South China Guangdong Key Laboratory of Integrated Agro-Environmental Pollution Control and ManagementInstitute of Eco-Environmental and Soil SciencesGuangdong Academy of SciencesGuangzhou 510650China Guangzhou Institute of Geochemistry Chinese Academy of SciencesGuangzhou 510640China University of Chinese Academy of Sciences Beijing 100049China College of Life Sciences South China Agricultural UniversityGuangzhou 510642China SCNU environmental Research Institute Guangdong Provincial Key Laboratory of Chemical Pollution and Environmental Safety&MOE Key Laboratory of Theoretical Chemistry of EnvironmentSouth China Normal UniversityGuangzhou 510006China

Mercury(Hg)is one of the most dangerous contaminants and has sparked global concern since it poses a health risk to humans when consumed through ***(S)is a crucial component for plant growth,and S may reduce Hg accumulation in rice ***,the detailed effects of S and the mechanisms underlying S-mediated responses in Hg-stressed rice plants remain ***,to investigate the effects of S addition on rice growth,Hg accumulation,physiological indexes,and gene expression profiles,rice seedlings were hydroponically treated with Hg(20μmol/L Hg Cl_(2))and Hg plus elemental sulfur(100 mg/L).S application significantly reduced Hg accumulation in Hg-stressed rice roots and alleviated the inhibitory effects of Hg on rice growth.S addition significantly reduced Hg-induced reactive oxygen species generation,membrane lipid peroxidation levels,and activities of antioxidant enzymes while increasing glutathione content in *** analysis of roots identified 3,411,2,730,and 581 differentially expressed genes in the control(CK)***,CK ***+S,and Hg ***+S datasets,*** pathway of S-mediated biological metabolism fell into six groups:biosynthesis and metabolism,expression regulation,transport,stimulus response,oxidation reduction,and cell wall *** majority of biological process-related genes were upregulated under Hg stress compared with CK treatment,but downregulated in the Hg+S *** results provide transcriptomic and physiological evidence that S may be critical for plant Hg stress resistance and will help to develop strategies for reduction or phytoremediation of Hg contamination.

关键词： Sulfur Mercury Transcriptomics Detoxification

Low-temperature NH_(3) abatement via selective oxidation over a supported copper catalyst with high Cu^(+) abundance

在线全文

学校读者我要写书评

暂无评论

Journal of environmental Sciences 2024年第9期143卷 12-22页

作者： Zhiming Yang Lin Peng Leneng Yang Mingli Fu Daiqi Ye Peirong Chen Guangdong provincial key laboratory of Atmospheric Environment and Pollution Control National Engineering Laboratory for VOCs Pollution Control Technology and EquipmentSchool of Environment and EnergySouth China University of TechnologyGuangzhou 510006China Guangdong Chengyi environmental Technology Corp. Shaoguan 512158China

Selective catalytic NH_(3)-to-N_(2) oxidation(NH_(3)-SCO)is highly promising for abating NH_(3) emissions slipped from stationary flue gas after-treatment *** practical application,however,is limited by the non-availability of low-cost catalysts with high activity and N_(2) ***,using defect-rich nitrogen-doped carbon nanotubes(NCNT-AW)as the support,we developed a highly active and durable copper-based NH_(3)-SCO catalyst with a high abundance of cuprous(Cu^(+))*** obtained Cu/NCNT-AW catalyst demonstrated outstanding activity with a T_(50)(*** temperature to reach 50% NH_(3) conversion)of 174℃ in the NH_(3)-SCO reaction,which outperformed not only the Cu catalyst supported on N-free O-functionalized CNTs(OCNTs)or NCNT with less surface defects,but also those most active Cu catalysts in open *** kinetics measurements and temperature-programmed surface reactions using NH_(3)as a probe molecule revealed that the NH_(3)-SCO reaction on Cu/NCNT-AW follows an internal selective catalytic reaction(i-SCR)route involving nitric oxide(NO)as a key *** to mechanistic investigations by X-ray photoelectron spectroscopy,Raman spectroscopy,and X-ray absorption spectroscopy,the superior NH_(3)-SCO performance of Cu/NCNT-AW originated from a synergy of surface defects and ***,surface defects promoted the anchoring of Cu O nanoparticles on N-containing sites and,thereby,enabled efficient electron transfer from N to Cu O,increasing significantly the fraction of SCR-active Cu^(+)sites in the *** study puts forward a new idea for manipulating and utilizing the interplay of defects and N-dopants on carbon surfaces to fabricate Cu^(+)-rich Cu catalysts for efficient abatement of slip NH_(3)emissions via selective oxidation.

关键词： NH_(3)-SCO XANES Localized etching N-doping N_(2) selectivity i-SCR

One-pot synthesis of N-doped petroleum coke-based microporous carbon for high-performance CO_(2) adsorption and supercapacitors

在线全文

学校读者我要写书评

暂无评论

Journal of environmental Sciences 2024年第5期139卷 93-104页

作者： Wenfu Zhu Yuqin Wang Fan Yao Xiaohong Wang Haoming Zheng Guangzheng Ye Hairong Cheng Junliang Wu Haomin Huang Daiqi Ye School of Environment and Energy South China University of TechnologyGuangzhou 510006China National engineering laboratory for VOCs Pollution Control Technology and Equipment Guangzhou 510006China Guangdong provincial key laboratory of Atmospheric Environment and Pollution Control(SCUT) Guangzhou 510006China Guangdong provincial engineering and Technology Research Centre for environmental Risk Prevention and Emergency Disposal South China University of TechnologyGuangzhou 510006China

Waste resource utilization of petroleum coke is crucial for achieving global carbon emission ***,a series of N-doped microporous carbons were fabricated from petroleum coke using a one-pot synthesis *** as-prepared samples had a large specific surface area(up to 2512 m^(2)/g),a moderate-high N content(up to 4.82 at.%),and high population(55%)of ultra-micropores(<0.7 nm).Regulating the N content and ultra-microporosity led to efficient CO_(2)adsorption and *** ambient pressure,the optimal N-doped petroleum coke-based microporous carbon exhibited the highest CO_(2)uptake of 4.25 mmol/g at 25℃ and 6.57 mmol/g at 0℃.These values are comparable or even better than those of numerous previously reported adsorbents prepared by multistep synthesis,primarily due to the existence of *** sample exhibited excellent CO_(2)/N_(2)selectivity at 25℃ owing to the abundant basic pyridinic and pyrrolic N species;and showed superior CO_(2)adsorption-desorption cycling performance,which was maintained at 97% after 10 cycles at 25℃.Moreover,petroleum coke-based microporous carbon,with a considerably high specific surface area and hierarchical pore structure,exhibited excellent electrochemical performance over the N-doped sample,maintaining a favorable specific capacitance of 233.25F/g at 0.5 A/g in 6 mol/L KOH aqueous *** study provides insight into the influence of N-doping on the porous properties of petroleum coke-based ***,the as-prepared carbons were found to be promising adsorbents for CO_(2)adsorption,CO_(2)/N_(2)separation and electrochemical application.

关键词： One-pot synthesis N-doped microporous carbon CO_(2)adsorption CO_(2)/N_(2)selectivity Electrochemical performance

Effect of the mixing of s-wave and chiral p-wave pairings on electrical shot noise properties of normal metal/superconductor tunnel junctions

在线全文

学校读者我要写书评

暂无评论

Chinese Physics B 2024年第7期33卷 538-545页

作者：胡雨辰胡梁宾 Guangdong provincial key laboratory of Quantum engineering and Quantum Materials School of PhysicsSouth China Normal UniversityGuangzhou 510631China

We study theoretically the electrical shot noise properties of tunnel junctions between a normal metal and a superconductor with the mixture of singlet s-wave and chiral triplet p-wave pairing due to broken inversion symmetry. We investigate how the shot noise properties vary as the relative amplitude between the two parity components in the pairing potential is changed. It is demonstrated that some characteristics of the electrical shot noise properties of such tunnel junctions may depend sensitively on the relative amplitude between the two parity components in the pairing potential, and some significant changes may occur in the electrical shot noise properties when the relative amplitude between the two parity components is varied from the singlet s-wave pairing dominated regime to the chiral triplet p-wave pairing dominated regime. In the chiral triplet p-wave pairing dominated regime, the ratio of noise power to electric current is close to 2e both in the in-gap and in the out-gap region. In the singlet s-wave pairing dominated regime, the value of this ratio is close to 4e in the inner gap region but may reduce to about 2e in the outer gap region as the relative amplitude of the chiral triplet pairing component is increased. The variations of the differential shot noise with the bias voltage also exhibit some significantly different features in different regimes. Such different features can serve as useful diagnostic tools for the determination of the relative magnitude of the two parity components in the pairing potential.

关键词： normal metal/superconductor tunnel junctions shot noise mixing of s-wave and chiral p-wave pairing spin–orbit coupling

Erosion-induced recovery CO_(2) sink offset the horizontal soil organic carbon removal at the basin scale

在线全文

学校读者我要写书评

暂无评论

Science China Earth Sciences 2024年第6期67卷 2019-2033页

作者： Lingxia WANG Xiaodong NIE Jiaqi LI Yaojun LIU Hui WANG Yazhe LI Zhongwu LI School of Geographic Science Hunan Normal UniversityChangsha 410081China Institute of Interdisciplinary Studies Hunan Normal University and Hunan Provincial Key Laboratory for Eco-environmental Changes and Carbon Sequestration of the Dongting Lake BasinChangsha 410081China College of environmental Science and engineering Hunan University and Key Laboratory of Environmental Biology and Pollution Control(Hunan University)Ministry of EducationChangsha 410082China

To improve soil carbon sequestration capacity,the full soil carbon cycle process needs to be understood and *** is essential to evaluate whether water erosion acts as a net source or sink of atmospheric CO_(2)at the basin scale,which encompasses the entire hydrological *** study introduced an approach that combined a spatially distributed sediment delivery model and biogeochemical model to estimate the lateral and vertical carbon fluxes by water erosion at the basin *** this coupling model to the Dongting Lake Basin,the results showed that the annual average amount of soil erosion during 1980-2020 was 1.33×10^(8)t,displaying a decreasing trend followed by a slight *** 12% of the soil organic carbon displacement was ultimately lost in the riverine systems,and the rest was deposited downhill within the *** average lateral soil organic carbon loss induced by erosion was 8.86×10^(11)g C in 1980 and 1.50×10^(11)g C in 2020,with a decline rate of 83%.A net land sink for atmospheric CO_(2)of 5.54×1011g C a^(-1)occurred during erosion,primarily through sediment burial and dynamic ***,ecological restoration projects and tillage practice policies are still significant in reducing erosion,which could improve the capacity of the carbon sink for recovery beyond the rate of horizontal carbon ***,our model enables the spatial explicit simulation of erosion-induced carbon fluxes using costeffective and easily accessible input data across large spatial scales and long ***,it offers a valuable tool for predicting the interactions between carbon dynamics,land use changes,and future climate.

关键词： Water erosion Sediment transfer Lateral soil carbon loss Land-atmosphere CO_(2) flux Dongting Lake Basin