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Residual levels and health risk assessment of trace metals in Chinese resident diet

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Journal of Environmental sciences 2024年第2期136卷 451-459页

作者： Yubing Dai Shuai Sun Rong Cao Haijun Zhang Jiping Chen Ningbo Geng CAS Key Laboratory of Separation Science for Analytical Chemistry Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023China Shenyang Pharmaceutical University Shenyang 110016China University of Chinese Academy of sciences Beijing 100049China

Large-scale metal contamination across the food web is an intractable problem due to increasing pollutant emissions,atmospheric transport,and dry and wet deposition of *** present study focus on several trace metals that are rarely studied but have special toxicity,including tin(Sn),antimony(Sb),gold(Au),hafnium(Hf),palladium(Pd),platinum(Pt),ruthenium(Ru),tellurium(Te)and iridium(Ir).We investigated trace metals residues and distribution characteristics,and further evaluated the potential health risks from major daily food intakes in 33 cities in ***,Sb,Ir,Hf,and Au were frequently detected in food samples with the concentrations ranged from ND(not detected)to 24.78μg/kg ww(wet weight).Eggs exhibited the highest residual level of all detected metals(13.70±14.70μg/kg ww in sum),while the lowest concentrations were observed in vegetables(0.53±0.17μg/kg ww in sum).Sn accounting for more than 50%of the total trace metals concentration in both terrestrial and aquatic animal origin *** terrestrial plant origin foods,Sn and Ir were the most abundant *** and Au were the most abundant elements in egg *** addition,Sb and Ir showed a clear trophic dilution effect in terrestrial environments,while in aquatic ecosystems,Sn,Hf,and Au exhibited obvious trophic amplification *** calculated average estimated daily intake(EDI)via food consumption in five regions of China was 0.09μg/(kg·day),implying the health risk of aforementioned elements was acceptable.

关键词： Trace metals Accumulation characteristics Dietary exposure Estimated daily intake(EDI)

Theoretical study of aromaticity reversal in dimethyldihydropyrene derivatives

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结构化学 2024年第5期43卷 8-10页

作者： Fangwen Peng Zhen Luo Yingjin Ma Haibo Ma School of Chemistry and chemical Engineering Nanjing UniversityNanjing210023China Computer Network Information Center Chinese Academy of SciencesBeijing100190China School of Chemistry and chemical Engineering Nanjing UniversityNanjing210023China Computer Network Information Center Chinese Academy of SciencesBeijing100190China Qingdao Institute for Theoretical and Computational sciences School of Chemistry and Chemical EngineeringShandong UniversityQingdaoShandong266237China

Aromaticity has always been an intriguing chemistry topic,which is considered to have close relations with materials'stability and chemical reactivity due to special energy *** conjugated cycles,Hückel's rule,proposed in 1931,suggests that annulenes having[4n+2]and[4n]π electrons present aromatic and antiaromatic characters with closed and open electronic configurations,respectively[1].

关键词： Hückel aromatic reactivity

Use of oilseed crops biomass for heavy metal treatment in water

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Oil Crop Science 2024年第3期9卷 177-186页

作者： Peña-Guzmán C. Otálvaro-Álvarez Á. Jiménez-Ariza T. Environmental and Sanitation Engineering program Faculty of Engineering Universidad de La Salle Bogotá 111711 Colombia chemical Enineering program Facultuy of Engineering Universidad de La Salle Bogotá 111711 Colombia Food Engineering program Faculty of Engineering Universidad de La Salle Bogotá 111711 Colombia

The treatment of heavy metals in water is of high importance worldwide, and different treatment types have been developed. The use of plant material is becoming more and more important, and oilseed crops biomass have been investigated in terms of phytoremediation and biosorption processes. This article is a review of the literature reporting the applications in 10 different plants and evaluating the removal efficiencies for 12 metals, including the findings of 81 publications. Moringa olifera and Helianthus annuus are the most studied plants, whereas Cu (21.9%), Cd (18.5%), and Pb (19.9%) are the most studied metals. As a result, it was found that more than 90% of Pb, Cu, Cd, Fe, Zn, Ni, Cr, Sr and Mn showed removals in their experiments. At the same time, the variables most related to the efficiency of metal removal are pH, temperature, and contact time. This article includes a review of the biosorption isotherms used in the different studies. © 2024 the Oil Crop Research Institute, Chinese Academy of Agriculture sciences

关键词： Biosorption Heavy metals Oilseed crops Phytoremediation

New Strategy for Boosting Cathodic Performance of Protonic Ceramic Fuel Cells Through Incorporating a Superior Hydronation Second Phase

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Energy & Environmental Materials 2024年第4期7卷 83-92页

作者： Chuan Zhou Xixi Wang Dongliang Liu Meijuan Fei Jie Dai Daqin Guan Zhiwei Hu Linjuan Zhang Yu Wang Wei Wang Ryan O'Hayre San Ping Jiang Wei Zhou Meilin Liu Zongping Shao State Key Laboratory of Materials-Oriented chemical Engineering College of Chemical Engineering Nanjing Tech University Max Planck Institute for chemical Physics of Solids Key Laboratory of Interfacial Physics and Technology Shanghai Institute of Applied Physics Chinese Academy of Sciences Department of Metallurgical and Materials Engineering Colorado School of Mines WA School of Mines: Minerals Energy and Chemical Engineering (WASM-MECE) Curtin University Suzhou Laboratory School of Materials Science and Engineering Georgia Institute of Technology

For protonic ceramic fuel cells,it is key to develop material with high intrinsic activity for oxygen activation and bulk proton conductivity enabling water formation at entire electrode ***,a higher water content which benefitting for the increasing proton conductivity will not only dilute the oxygen in the gas,but also suppress the O2adsorption on the electrode surface.

关键词： cathode high-hydrating capability proton conductivity protonic ceramic fuel cells

Aggregation-regulated bioreduction process of graphene oxide by Shewanella bacteria

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Chinese Journal of chemical Engineering 2024年第5期69卷 56-62页

作者： Kaixin Han Yibo Zeng Yinghua Lu Ping Zeng Liang Shen Department of chemical and Biochemical Engineering College of Chemistry and Chemical EngineeringXiamen UniversityXiamen 361005China Pen-Tung Sah Institute of Micro-Nano Science and Technology Xiamen UniversityXiamen 361005China Chinese Research Academy of Environmental sciences Beijing 100012China

The bioreduction of graphene oxide(GO)using environmentally functional bacteria such as Shewanella represents a green approach to produce reduced graphene oxide(rGO).This process differs from the chemical reduction that involves instantaneous molecular *** bioreduction,the contact of bacterial cells and GO is considered the rate-limiting *** reveal how the bacteria-GO integration regulates rGO production,the comparative experiments of GO and three Shewanella strains were carried ***-transform infrared spectroscopy,X-ray photoelectron spectroscopy,Raman spectroscopy,and atomic force microscopy were used to characterize the reduction degree and the aggregation *** results showed that a spontaneous aggregation of GO and Shewanella into the condensed entity occurred within 36 h.A positive linear correlation was established,linking three indexes of the aggregation potential,the bacterial reduction ability,and the reduction degree(ID/IG)comprehensively.

关键词： Graphene oxide Reduced graphene oxide Bioreduction Aggregation Shewanella

Approaches to Improving Selectivity During Photoelectrochemical Transformation of Small Molecules

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Transactions of Tianjin University 2024年第2期30卷 167-177页

作者： Sipeng Yang Jie Yang Mengyu Duan Shirong Kang Shaohua He Chuncheng Chen Key Laboratory of Photochemistry CAS Research/Education Center for Excellence in Molecular SciencesInstitute of ChemistryChinese Academy of SciencesBeijing 100190China School of chemical sciences University of Chinese Academy of SciencesBeijing 100190China

Photoelectrochemical (PEC) small-molecule oxidation can selectively transform substrates into high-value-added fine chemicals and increase the rate of cathode hydrogen evolution. Nevertheless, achieving high-selectivity PEC oxidation of small molecules to produce specific products is a very challenging task. In general, selectivity can be improved by changing the surface catalyticsites of the photoanode and modulating the interfacial environments of the reactions. Herein, recent advances in approaches to improving selective PEC oxidation of small molecules are introduced. We first briefly discuss the basic concept and fundamentals of small-molecule PEC oxidation. The reported approaches to improving the performance of selective PEC oxidation of small molecules are highlighted from two aspects: (1) changing the surface properties of photoanodes by selecting suitable materials or modifying the photoanodes and (2) mediating the oxidation reactions using redox mediators. The PEC oxidation mechanism of these studies is emphasized. We also discuss the challenges in this research direction and offer a perspective on the further development of selective PEC-based small-molecule transformation.

关键词： Photoelectrocatalytic Small-molecule oxidation Improving selectivity Surface properties Mediating

A facile strategy to construct MOF-based nanocatalyst with enhanced activity and selectivity in oxytetracycline degradation

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Nano Research 2024年第7期17卷 5863-5871页

作者： Yanjing Ke Jiaxing Zhang Xin Peng Zhiyi Zhang Xu Wang Wei Qi Mengfan Wang School of Life sciences Faculty of MedicineSchool of Chemical Engineering and TechnologyTianjin UniversityTianjin 300072China The Co-Innovation Centre of Chemistry and chemical Engineering of Tianjin Tianjin 300072China Tianjin Key Laboratory of Membrane Science and Desalination Technology Tianjin 300350China

Recently,many efforts have been dedicated to construct artificial catalysts with enzyme-like ***,it is still a big challenge to endow artificial catalysts with specific substrate *** this study,we developed a facile strategy to construct a MIL-53(Fe)-based nanocatalyst with designable selectivity in the degradation of oxytetracycline(OTC).Through the Fe–O–P conjunction,oxytetracycline aptamer(OA)can be easily anchored on MIL-53(Fe)to provide the specific site for OTC *** verified that the obtained MIL-53(Fe)-Apt nanocatalyst displayed enhanced catalytic ability in the degradation of OTC,whereas obvious suppression toward other substrate *** performance therefore brings about an anticipated selectivity toward ***,we highlighted that the configuration of aptamers on MIL-53(Fe)can be modulated through varying conjunction ***–function analysis revealed that aptamer configuration affects the local concentration of substrate around catalytic site,which thus decides the catalytic performance toward *** work presented a facile and promising strategy for developing artificial catalysts with designable selectivity.

关键词： MIL-53(Fe) aptamer Fe-O-P catalytic selectivity oxytetracycline

Realizing efficient electrochemical oxidation of 5-hydroxymethylfurfural on a freestanding Ni(OH)_(2)/nickel foam catalyst

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Chinese Journal of Catalysis 2024年第8期63卷 282-291页

作者： Yunying Huo Cong Guo Yongle Zhang Jingyi Liu Qiao Zhang Zhiting Liu Guangxing Yang Rengui Li Feng Peng School of Chemistry and chemical Engineering Guangzhou UniversityGuangzhou 510006GuangdongChina State Key Laboratory of Catalysis Dalian National Laboratory for Clean EnergyDalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023LiaoningChina

With the continuous improvement of solar energy production capacity,how to effectively use the electricity generated by renewable solar energy for electrochemical conversion of biomass is a hot *** conversion of 5-hydroxymethylfurfural(HMF)to biofuels and value-added oxygenated commodity chemicals provides a promising and alternative pathway to convert re-newable electricity into *** nickel-based eletrocatalysts are well-known for HMF oxidation,their relatively low intrinsic activity,poor conductivity and stability still limit the poten-tial ***,we report the fabrication of a freestanding nickel-based electrode,in which Ni(OH)2 species were in-situ constructed on Ni foam(NF)support using a facile ac-id-corrosion-induced *** Ni(OH)2/NF electrocatalyst exhibits stable and efficient electro-chemical HMF oxidation into 2,5-furandicarboxylic acid(FDCA)with HMF conversion close to 100%with high Faraday ***-situ formation strategy results in a compact interface between Ni(OH)2 and NF,which contributes to good conductivity and stability during electrochemical *** superior performance benefits from dynamic cyclic evolution of Ni(OH)2 to NiOOH,which acts as the reactive species for HMF oxidation to FDCA.A scaled-up device based on a continu-ous-flow electrolytic cell was also established,giving stable operation with a high FDCA production rate of 27 mg h^(-1)cm^(−2).This job offers a straightforward,economical,and scalable design strategy to design efficient and durable catalysts for electrochemical conversion of valuable chemicals.

关键词： Acid-corrosion-induced 5-Hydroxymethylfurfural Electrocatalytic oxidation Ni electrocatalysis

Spectroscopic Observations of Ten Galactic Wolf–Rayet Stars at Bosscha Observatory:Determination of Stellar Parameters and Mass-loss Rates

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Research in Astronomy and Astrophysics 2024年第9期24卷 9-29页

作者： Hakim Luthfi Malasan Bakuh Danang Setyo Budi Department of Astronomy Faculty of Mathematics and Natural Sciences Institut Teknologi Bandung Bosscha Observatory Institut Teknologi Bandung Master program in Astronomy Faculty of Mathematics and Natural Sciences Institut Teknologi Bandung

We present optical spectra of 10 Galactic Wolf–Rayet（WR） stars that consist of five WN and five WC stars. The optical observation was conducted using a low-resolution spectrograph NEO-R1000（λ/Δλ1000） at GAO-ITB RTS（27.94 cm, F/10.0）, Bosscha Observatory, Lembang. We implemented stellar atmosphere Postdam Wolf–Rayet（PoWR） grid modeling to derive stellar parameters. The normalized optical spectrum can be used to find the best model from the available PoWR grid, then we could derive stellar temperature and transformation radius. To derive luminosity, stellar radius and color excess, we conducted a Spectral Energy Distribution（SED） analysis with additional data on the near-ultraviolet spectrum from the International Ultraviolet Explorer（IUE） database, and UBV and 2MASS JHK broadband filter data. Additional analysis to derive asymptotic terminal wind velocity was conducted from the P-Cygni profile analysis of the high-resolution IUE ultraviolet spectrum. With previously derived parameters, we could determine the mass loss rate of the WR stars. Furthermore, we compared our results with previous work that used PoWR code and the differences are not more than 20%. We conclude that the PoWR spectral grid is sufficient to derive WR stellar parameters quickly and could provide more accurate initial parameter input to the PoWR program code.

关键词： outflows stars: atmospheres stars: mass-loss stars: massive stars: winds stars: Wolf-Rayet