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Distributions of Electromagnetic Fields and Forced Flow and Their Relevance to the Grain Refinement in Al–Si Alloy Under the Application of Pulsed Magneto-Oscillation

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Acta Metallurgica Sinica(English Letters) 2022年第2期35卷 254-274页

作者： Yan-Yi Xu Jing Zhao Chun-Yang Ye Yan-Ping Shen Xin-Cheng Miao Yun-Hu Zhang Qi-Jie Zhai Center for Advanced Solidification technology Shanghai UniversityShanghai 200072China Key Lab of Intelligent equipment Digital Design and process Simulation Tangshan UniversityTangshan 063000Hebei ProvinceChina School of Materials Science and Engineering University of Science and Technology LiaoningAnshan 114051China

Distributions of electromagnetic fields and induced forced flow inside a metal melt are crucial to understand the grain refinement of the metal driven by pulsed magneto-oscillation(PMO).In the present study,PMO-induced electromagnetic fields and forced flow in Ga-20 wt%In-12 wt%Sn liquid metal have been systematically investigated by performing numerical simulations and corresponding experimental *** numerical simulations have been confirmed by magnetic and melt flow *** to the simulated distribution of electromagnetic fields under the application of PMO,the strongest magnetic field,electric eddy current and Lorentz force with inward radial direction inside the melt are concentrated adjacent the sidewall of cylindrical melt at the cross section of middle height of *** a result,a global forced flow throughout the whole cylindrical column filled with Ga-20 wt%In-12 wt%Snmelt is initiated with a flow structure of two pair of symmetric *** PMO-induced electromagnetic fields and forced flow in Al-7 wt%Si melt have been numerically *** contribution of electromagnetic fields and forced flow to the grain refinement of Al-7 wt%Sialloy under the application of PMO is *** indicates that the forced flow may play a key role in the grain size reduction.

关键词： Pulsed magneto-oscillation(PMO) Electromagnetic field Forced flow Solidification Grain refinement

Online soft measurement for wastewater treatment system based on hybrid deep learning

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Frontiers of Environmental Science & Engineering 2024年第2期18卷 77-89页

作者： Wenjie Mai Zhenguo Chen Xiaoyong Li Xiaohui Yi Yingzhong Zhao Xinzhong He Xiang Xu Mingzhi Huang SCNU Environmental Research Institute Guangdong Provincial Key Laboratory of Chemical Pollution and Environmental Safety&MOE Key Laboratory of Theoretical Chemistry of EnvironmentSchool of EnvironmentSouth China Normal UniversityGuangzhou 510006China Fujian Environmental Protection Design Institute Co.Ltd. Fuzhou 350000China Huashi(Fujian)Environment technology Co.Ltd. Quanzhou362001China SCNU Qingyuan Institute of Science and technology Innovation Co.Ltd. Qingyuan 511517China Econ technology Co.Ltd. Yantai 265503China

The existing automated wastewater treatment control systems encounter challenges such as the utilization of specialized testing instruments, equipment repair complications, high operational costs, substantial operational errors, and low detection accuracy. An effective soft measure model offers a viable approach for real-time monitoring and the development of automated control in the wastewater treatment process. Consequently, a novel hybrid deep learning CNN-BNLSTM-Attention (CBNLSMA) model, which incorporates convolutional neural networks (CNN), bidirectional nested long and short-term memory neural networks (BNLSTM), attention mechanisms (AM), and Tree-structure Parzen Estimators (TPE), has been developed for monitoring effluent water quality during the wastewater treatment process. The CBNLSMA model is divided into four stages: the CNN module for feature extraction and data filtering to expedite operations;the BNLSTM module for temporal data’s temporal information extraction;the AM module for model weight reassignment;and the TPE optimization algorithm for the CBNLSMA model’s hyperparameter search optimization. In comparison with other models (TPE-CNN-BNLSTM, TPE-BNLSTM-AM, TPE-CNN-AM, PSO-CBNLSTMA), the CBNLSMA model reduced the RMSE for effluent COD prediction by 25.4%, decreased the MAPE by 32.9%, and enhanced the R2 by 14.9%. For the effluent SS prediction, the CBNLSMA model reduced the RMSE by 26.4%, the MAPE by 21.0%, and improved the R2 by 35.7% compared to other models. The simulation results demonstrate that the proposed CBNLSMA model holds significant potential for real-time effluent quality monitoring, indicating its high potential for automated control in wastewater treatment processes.

关键词： Prediction model Soft measurement CNN-BNLSTM-AM model TPE optimization algorithm

Basic regulatory science behind drug substance and drug product specifications of monoclonal antibodies and other protein therapeutics

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Journal of Pharmaceutical Analysis 2024年第6期14卷 785-804页

作者： Patanachai K.Limpikirati Sorrayut Mongkoltipparat Thinnaphat Denchaipradit Nathathai Siwasophonpong Wudthipong Pornnopparat Parawan Ramanandana Phumrapee Pianpaktr Songsak Tongchusak Maoxin Tim Tian Trairak Pisitkun Department of Food and Pharmaceutical Chemistry Faculty of Pharmaceutical SciencesChulalongkorn UniversityPathumwanBangkok10330Thailand Pharmaceutical Sciences and technology(PST)Graduate Program Faculty of Pharmaceutical SciencesChulalongkorn UniversityPathumwanBangkok10330Thailand Center of Excellence in Systems Biology(CUSB) Faculty of MedicineChulalongkorn UniversityPathumwanBangkok10330Thailand Department of Pharmaceutical Chemistry Faculty of Pharmaceutical SciencesHuachiew Chalermprakiet UniversityBang PhliSamut Prakan10540Thailand division of Research Affairs Faculty of MedicineChulalongkorn UniversityPathumwanBangkok10330Thailand

In this review,we focus on providing basics and examples for each component of the protein therapeutic specifications to interested pharmacists and biopharmaceutical scientists with a goal to strengthen understanding in regulatory science and *** specifications comprise a list of important quality attributes for testing,references to use for test procedures,and appropriate acceptance criteria for the tests,and they are set up to ensure that when a drug product is administered to a patient,its intended therapeutic benefits and safety can be rendered *** of drug substance or drug product to the specifications is achieved by testing an article according to the listed tests and analytical methods and obtaining test results that meet the acceptance *** attributes are chosen to be tested based on their quality risk,and consideration should be given to the merit of the analytical methods which are associated with the acceptance criteria of the *** criteria are set forth primarily based on efficacy and safety profiles,with an increasing attention noted for patient-centric *** in this work are related guidelines that support the biopharmaceutical specification setting,how to set the acceptance criteria,and examples of the quality attributes and the analytical methods from 60 articles and 23 pharmacopeial *** are also explored on process analytical technologies and other orthogonal tools which are on-trend in biopharmaceutical characterization and quality control.

关键词： Biopharmaceutical analysis Biopharmaceutical quality control Biopharmaceutical specifications Monoclonal antibodies Protein therapeutics Regulatory science

A Discrete Multi‑Objective Artificial Bee Colony Algorithm for a Real‑World Electronic Device Testing Machine Allocation Problem

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Chinese Journal of Mechanical Engineering 2022年第6期35卷 136-150页

作者： Jin Xie Xinyu Li Liang Gao State Key Laboratory of Digital Manufacturing equipment and technology Huazhong University of Science and TechnologyWuhan 430074China

With the continuous development of science and technology,electronic devices have begun to enter all aspects of human life,becoming increasingly closely related to human *** have higher quality requirements for electronic *** device testing has gradually become an irreplaceable engineering process in modern manufacturing enterprises to guarantee the quality of products while preventing inferior products from entering the *** the large output of electronic devices,improving the testing efficiency while reducing the testing cost has become an urgent problem to be *** study investigates the electronic device testing machine allocation problem(EDTMAP),aiming to improve the production of electronic devices and reduce the scheduling distance among testing machines through reasonable machine ***,a mathematical model was formulated for the EDTMAP to maximize both production and the scheduling distance among testing ***,we developed a discrete multi-objective artificial bee colony(DMOABC)algorithm to solve EDTMAP.A crossover operator and local search operator were designed to improve the exploration and exploitation of the algorithm,*** experiments were conducted to evaluate the performance of the proposed *** experimental results demonstrate the superiority of the proposed algorithm compared with the non-dominated sorting genetic algorithm II(NSGA-II)and strength Pareto evolutionary algorithm 2(SPEA2).Finally,the mathematical model and DMOABC algorithm were applied to a real-world factory that tests radio-frequency *** results verify that our method can significantly improve production and reduce the scheduling distance among testing machines.

关键词： Electronic device Machine allocation Multi-objective optimization Artificial bee colony algorithm

Highly selective kinetic resolution of D/L-syn-p-sulfone phenylserine catalyzed by D-threonine aldolase in two-phase ionic solvent

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Green Chemical Engineering 2023年第2期4卷 212-216页

作者： Fengfan Liu Zhihao Shi Jinmei Zhu Xiaobin Liang Mingming Liang Yuanyuan Xie Weike Su Jiequn Wu National Engineering Research Center for process development of Active Pharmaceutical Ingredients Collaborative Innovation Center of Yangtze River Delta Region Green PharmaceuticalsZhejiang University of TechnologyHangzhou310014China Key Laboratory for Green Pharmaceutical Technologies and Related equipment of Ministry of Education and Pharmaceutical Engineering of Zhejiang Province College of Pharmaceutical SciencesZhejiang University of TechnologyHangzhou310014China

In the chemical synthesis of L-syn-p-methylsulfoxide phenylserine ethyl ester(D-ethyl ester),L-tartaric acid or enzymatic resolution is employed to resolve the racemate,and thus obtain the target compound,and the remaining isomer can be recycled to obtain the raw *** this study,high-purity L-syn-p-methylsulfoxide phenylserine(L-syn-MPS)was *** kinetics of the D-threonine aldolase enzymatic hydrolysis reaction reveals that D-syn-p-sulfoxylphenylserine resolves well in[BMIM][BF 4]ionic *** D/L-syn-MPS racemate was resolved using a two-phase ionic solvent[BMIM][NTf 2]to afford L-syn-MPS(ee(enantiomeric excess)>99%)and a white solid in 41.7%***,this system is suitable for the separation of insoluble aldehydes and successfully avoids the condensation of hydroxyl aldehydes to form D-anti-MPS.

关键词： Kinetic resolution Ionic solvent Enzymatic resolution D/L-p-sulphoxyl phenylserine ethyl ester Biphasic reaction system

Bio-inspired manufacturing of superwetting surfaces for fog collection and anti-icing applications

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Science China(Technological Sciences) 2022年第9期65卷 1975-1994页

作者： ZHANG XuNing GAN Lang SUN Bo LIU ZhiYong LIAO GuangLan SHI TieLin State key Laboratory of Digital Manufacturing equipment and technology Huazhong University of Science and TechnologyWuhan 430074China

As a century-old concept,superwettability has aroused the interest of researchers in the past decades,attributed to the discoveries of the mechanisms of special wetting phenomena in ***-inspired manufacturing of superwetting surfaces for fog collection and anti-icing applications has become mainstream research,potentially alleviating the problem of water shortage and ice *** surfaces for fog collection and anti-icing applications involve a reverse process,in which the former gathers water spontaneously,while the latter repels *** analysis of the two is essential for the comprehensive understanding of superhydrophilic/superhydrophobic surfaces and boosting their ***,wetting theories and basic mechanisms for fog collection and anti-icing are briefly ***,manufacturing methods of bionic structures and surfaces are systematically reviewed after discussing the typical organisms with ***,conclusions are drawn and prospects for future development are proposed.

关键词： bionic manufacturing superwettability fog collection anti-icing

Room-temperature phonon-coupled single-photon emission in hexagonal boron nitride

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Science China(Physics,Mechanics & Astronomy) 2024年第5期67卷 109-114页

作者： Jia-Min Lai Qing-Hai Tan Feilong Song Haonan Chang Yanpei Lv Xue-Lu Liu Jinghua Teng Weibo Gao Ping-Heng Tan Jun Zhang State Key Laboratory of Superlattices and Microstructures Institute of SemiconductorsChinese Academy of SciencesBeijing100083China Key Laboratory of Magnetic Molecules and Magnetic Information Materials of Ministry of Education&Research Institute of Materials Science Shanxi Normal UniversityTaiyuan 030000China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China division of Physics and Applied Physics School of Physical and Mathematical SciencesNanyang Technological UniversitySingapore 637371Singapore Institute of Materials Research and Engineering(IMRE) Agency for ScienceTechnology and Research(A*STAR)Singapore 138634Singapore

Photon-lattice(phonon)coupling is fundamental to light-matter interaction,particularly when it reaches the quantum limit of the phonon-coupled single-photon emission,which holds great potential for quantum manipulation and quantum information ***,we report single defect state-phonon coupling in hexagonal boron nitride(h BN)at room *** ultrabroad spectrum of single-photon emissions can be achieved by selecting the excitation *** photoluminescence excitation spectroscopy,we observe single-phonon-assisted resonance-enhanced single-photon emission,along with multiple phonon replicas that herald the creation of phonon Fock *** also develop a transition model to gain insight into the physical process behind the single defect state-phonon *** work sets the stage for manipulating electron-phonon coupling state with single quantum-level precision at room temperature.

关键词： temperature phonon hexagonal

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Research on Hydrogen Environment Fatigue Test System and Correlative Fatigue Test of Hydrogen Storage Vessel

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Journal of Shanghai Jiaotong university(Science) 2014年第1期19卷 88-94页

作者：李蓉郑传祥陈冰冰周威威王亮 Institute of Chemical Machinery and process equipment Zhejiang University Institute of process equipment and Control Engineering Zhejiang University of Technology

A 70 MPa hydrogen environment fatigue test system has been designed and applied in the manufacture of a hydrogen storage vessel. Key equipment is the 80 MPa flat steel ribbon wound high pressure hydrogen storage vessel. A reasonable stress distribution has been realized, that is low stress in the liner of the pressure vessel and even stress in the flat ribbon layers. This optimal stress distribution is achieved through the adjustment of the prestress in flat steel ribbons. A control system for the fatigue test system has also been designed. It consists of a double control model, i.e. manual control and automatic control, to satisfy diffierent experimental *** system is the unique one that can be used in the real hydrogen environmental fatigue test system in *** experiment for the 70 MPa onboard composite material hydrogen vessel has been carried out on the *** experimental result from this test is in close agreement with the practical operating conditions.

关键词： hydrogen storage vessel fatigue hydrogen environment experiment

Facilitating prelithiation of silicon carbon anode by localized high-concentration electrolyte for high-rate and long-cycle lithium storage

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Carbon Energy 2024年第6期6卷 216-233页

作者： Yuanxing Zhang Borong Wu Jiaying Bi Xinyu Zhang Daobin Mu Xin-Yu Zhang Ling Zhang Yao Xiao Feng Wu School of Materials Science and Engineering Beijing Institute of TechnologyBeijingChina Chongqing Innovation Center Beijing Institute of TechnologyChongqingChina College of New Energy Xi′an Shiyou UniversityXi′anChina Institute for Carbon Neutralization College of Chemistry and Materials EngineeringWenzhou UniversityWenzhouChina Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education) Nankai UniversityTianjinChina

The commercialization of silicon-based anodes is affected by their low initial Coulombic efficiency(ICE)and capacity decay,which are attributed to the formation of an unstable solid electrolyte interface(SEI)***,a feasible and cost-effective prelithiation method under a localized highconcentration electrolyte system(LHCE)for the silicon-silica/graphite(Si-SiO_(2)/C@G)anode is designed for stabilizing the SEI layer and enhancing the *** thin SiO_(2)/C layers with-NH2 groups covered on nano-Si surfaces are demonstrated to be beneficial to the prelithiation process by density functional theory calculations and electrochemical *** SEI formed under LHCE is proven to be rich in ionic conductivity,inorganic substances,and flexible organic ***,faster Li+transportation across the SEI further enhances the prelithiation effect and the rate performance of Si-SiO_(2)/C@G *** also leads to uniform decomposition and high stability of the SEI with abundant organic *** a result,the prepared anode shows a high reversible specific capacity of 937.5 mAh g^(-1)after 400 cycles at a current density of 1 *** 811‖Li-SSGLHCE full cell achieves a high-capacity retention of 126.15 mAh g^(-1)at 1 C over 750 cycles with 84.82%ICE,indicating the great value of this strategy for Si-based anodes in large-scale applications.

关键词： localized high-concentration electrolytes prelithiation SEI layer silicon anode