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Multi boron-doping effects in hard carbon toward enhanced sodium ion storage

Journal of energy Chemistry 2025年第1期100卷 730-738页

作者： Peng Zheng Wang Zhou Ying Mo Biao Zheng Miaomiao Han Qin Zhong Wenwen Yang Peng Gao Lezhi Yang Jilei Liu College of Materials Science and Engineering Hunan Joint International Laboratory of Advanced Materials and Technology for Clean Energy Hunan Province Key Laboratory for Advanced Carbon Materials and Applied Technology Hunan University Greater Bay Area Institute for Innovation Hunan University Changsha Research Institute of Mining & Metallurgy Co. LTD.

Hard carbon （HC） has been considered as promising anode material for sodium-ion batteries （SIBs）.The optimization of hard carbon’s microstructure and solid electrolyte interface （SEI） property are demonstrated effective in enhancing the Na+storage capability,however,a one-step regulation strategy to achieve simultaneous multi-scale structures optimization is highly ***,we have systematically investigated the effects of boron doping on hard carbon’s microstructure and interface chemistry.A variety of structure characterizations show that appropriate amount of boron doping can increase the size of closed pores via rearrangement of carbon layers with improved graphitization degree,which provides more Na+storage ***-situ Fourier transform infrared spectroscopy/electrochemical impedance spectroscopy （FTIR/EIS） and X-ray photoelectron spectroscopy （XPS） analysis demonstrate the presence of more BC3and less B–C–O structures that result in enhanced ion diffusion kinetics and the formation of inorganic rich and robust SEI,which leads to facilitated charge transfer and excellent rate *** a result,the hard carbon anode with optimized boron doping content exhibits enhanced rate and cycling *** general,this work unravels the critical role of boron doping in optimizing the pore structure,interface chemistry and diffusion kinetics of hard carbon,which enables rational design of sodium-ion battery anode with enhanced Na+storage performance.

关键词： X ray photoelectron spectroscopy

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SensFL:Privacy-Preserving Vertical Federated Learning with Sensitive Regularization

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Computer Modeling in Engineering & Sciences 2025年第1期142卷 385-404页

作者： Chongzhen Zhang Zhichen Liu Xiangrui Xu Fuqiang Hu Jiao Dai Baigen Cai Wei Wang School of Automation and Intelligence Beijing Jiaotong UniversityBeijing100044China Shuohuang Railway Development Co. Ltd.National Energy GroupCangzhou062350China Beijing Key Laboratory of Security and Privacy in Intelligent Transportation School of Computer Science and TechnologyBeijing Jiaotong UniversityBeijing100044China

In the realm of Intelligent Railway Transportation Systems,effective multi-party collaboration is crucial due to concerns over privacy and data *** Federated Learning(VFL)has emerged as a promising approach to facilitate such collaboration,allowing diverse entities to collectively enhance machine learning models without the need to share sensitive training ***,existing works have highlighted VFL’s susceptibility to privacy inference attacks,where an honest but curious server could potentially reconstruct a client’s raw data from embeddings uploaded by the *** vulnerability poses a significant threat to VFL-based intelligent railway transportation *** this paper,we introduce SensFL,a novel privacy-enhancing method to against privacy inference attacks in ***,SensFL integrates regularization of the sensitivity of embeddings to the original data into the model training process,effectively limiting the information contained in shared *** reducing the sensitivity of embeddings to the original data,SensFL can effectively resist reverse privacy attacks and prevent the reconstruction of the original data from the *** experiments were conducted on four distinct datasets and three different models to demonstrate the efficacy of *** results show that SensFL can effectively mitigate privacy inference attacks while maintaining the accuracy of the primary learning *** results underscore SensFL’s potential to advance privacy protection technologies within VFL-based intelligent railway systems,addressing critical security concerns in collaborative learning environments.

关键词： Vertical federated learning privacy defenses

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Features of seismic hazard in large dam projects and strong motion monitoring of large dams

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Frontiers of Structural and Civil Engineering 2010年第1期4卷 56-64页

作者： Martin WIELAND Chairman ICOLD Committee on Seismic Aspects of Dam DesignPoyry Energy Ltd.Zurich CH-8037Switzerland

Earthquakes can affect large dam projects in many different ***,design engineers are focussing on ground shaking and neglect the other *** May 12,2008 Wenchuan earthquake has damaged 1803 dams and reservoirs,and 403 hydropower plants with an installed capacity of *** these dams were the 132-m-high Shapai RCC arch dam and the 156-m-high Zipingpu concrete face rockfill *** recently completed dams are dam types which,up to now,have not experienced strong ground *** widespread mass movements have caused substantial damage to dams and surface powerhouses in *** different features of earthquake hazard are presented,i.e.,ground shaking,faulting and mass *** is proposed to prepare project-specific safety plans for all dams,which consist of a matrix where the possible hazards and the corresponding countermeasures are *** earthquake behaviors of the Sefid Rud,Zipingpu and Shapai dams,which,in the past,have experienced strong ground shaking from nearby earthquakes,are ***,the need for strong motion instrumentation of large dams is *** is proposed that major dams with large damage potential,dams located in areas of high seismicity,and dams showing signs of abnormal behavior be equipped with strong motion instruments.

关键词： seismic hazard arch dam concrete face rockfill dam strong motion instrumentation reservoirtriggered seismicity Wenchuan earthquake

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Preparation of Co/S co-doped carbon catalysts for excellent methylene blue degradation

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International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 169-181页

作者： Haixu Li Haobo He Tiannan Jiang Yunfei Du Zhichen Wu Liang Xu Xinjie Wang Xiaoguang Liu Wanhua Yu Wendong Xue School of Materials Science and Engineering University of Science and Technology BeijingBeijing 100083China Beijing Jinyu Tongda Refractory Technologies Co. Ltd.Beijing 100085China

S and Co co-doped carbon catalysts were prepared via pyrolysis of MOF-71 and thiourea mixtures at 800℃at a mass ratio of MOF-71 to thiourea of 1:0.1 to effectively activate peroxymonosulfate(PMS)for methylene blue(MB)*** effects of two different mixing routes were identified on the MB degradation ***,the catalyst obtained by the alcohol solvent evaporation(MOF-AEP)mixing route could degrade 95.60%MB(50 mg/L)within 4 min(degradation rate:K=0.78 min^(-1)),which was faster than that derived from the direct grinding method(MOF-DGP,80.97%,K=0.39 min^(-1)).X-ray photoelectron spectroscopy revealed that the Co-S content of MOF-AEP(43.39at%)was less than that of MOF-DGP(54.73at%),and the proportion of C-S-C in MOF-AEP(13.56at%)was higher than that of MOF-DGP(10.67at%).Density functional theory calculations revealed that the adsorption energy of Co for PMS was -2.94 eV when sulfur was doped as C-S-C on the carbon skeleton,which was higher than that when sulfur was doped next to cobalt in the form of Co-S bond(-2.86 eV).Thus,the C-S-C sites might provide more contributions to activate PMS compared with ***,the degradation parameters,including pH and MOF-AEP dosage,were ***,radical quenching experiments and electron paramagnetic resonance(EPR)measurements revealed that ^(1)O_(2)might be the primary catalytic species,whereas·O~(2-)might be the secondary one in degrading MB.

关键词： advanced oxidation process alcohol solvent evaporation hydrogen bond S and Co co-doped carbon catalysts wastewater remediation

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Long-term dam safety monitoring of Punt dal Gall arch dam in Switzerland

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Frontiers of Structural and Civil Engineering 2012年第1期6卷 76-83页

作者： M.WIELAND G.F.KIRCHEN poyry energy ltd. Hardturmstrasse 161Zurich CH-8037Switzerland Engadiner Kraftwerke AG Zernez CH-7530Switzerland

The 130m high Punt dal Gall dam is located at the Swiss-Italian border in the South-eastern part of Switzerland and was completed in *** dam is founded on highly folded and partially crushed dolomite and limestone formations.A grout curtain with an area of 120,000m^(2) was provided for controlling *** the monitoring of the dam deformations five inverted pendulums were installed in the dam and three in the rock foundation of the right abutment outside of the *** a seasonal water level fluctuation in the reservoir of about 60 m the maximum amplitude of the radial displacement is 25 mm,which includes both the effects of the water load and temperature *** a comprehensive geodetic network was established,57 joint meters were installed and cracks in the crest gallery are monitored by crack *** are also thermometers,piczometers and *** at the left and fight banks of the dam are monitored and chemical analyses of the seepage water and springs are performed *** dam is equipped with strong motion instruments and several near-field earthquakes have been recorded in the *** paper describes the long-term safety monitoring of this 42 years old arch dam.A short description of the Swiss practice in dam safety monitoring and emergency planning is also given.

关键词： dam safety concept arch dam dam instrumentation dam safety monitoring

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Study on the hydrogen absorption properties of a YGdTbDyHo rare-earth high-entropy alloy

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International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 127-135页

作者： Tongyue Li Ziliang Xie Wenjiao Zhou Huan Tong Dawen Yang Anjia Zhang Yuan Wu Xiping Song State Key Laboratory for Advanced Metals and Materials University of Science and Technology BeijingBeijing 100083China Whole Win(Beijing)Materials Sci.&Tech.Co. Ltd.Beijing 100083China

This study investigated the microstructure and hydrogen absorption properties of a rare-earth high-entropy alloy(HEA),*** indicated that the YGdTbDyHo alloy had a microstructure of equiaxed grains,with the alloy elements distributed *** hydrogen absorption,the phase structure of the HEA changed from a solid solution with an hexagonal-close-packed(HCP)structure to a high-entropy hydride with an faced-centered-cubic(FCC)structure without any secondary phase *** alloy demonstrated a maximum hydrogen storage capacity of 2.33 H/M(hydrogen atom/metal atom)at 723 K,with an enthalpy change(ΔH)of-141.09 kJ·mol^(-1)and an entropy change(ΔS)of-119.14 J·mol^(-1)·K^(-1).The kinetic mechanism of hydrogen absorption was hydride nucleation and growth,with an apparent activation energy(E_(a))of 20.90 kJ·mol^(-1).Without any activation,the YGdTbDyHo alloy could absorb hydrogen quickly(180 s at 923 K)with nearly no incubation period *** reason for the obtained value of 2.33 H/M was that the hydrogen atoms occupied both tetrahedral and octahedral *** results demonstrate the potential application of HEAs as a high-capacity hydrogen storage material with a large H/M ratio,which can be used in the deuterium storage field.

关键词： rare-earth high-entropy alloy hydrogen absorption capacity pressure–composition–temperature curves kinetics

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小型水坝的地震安全(英文)

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岩土工程学报 2008年第11期30卷 1679-1682页

作者： Martin Wieland Chairman ICOLD Committee on Seismic Aspects of Dam DesignPoyry Energy Ltd.Hardturmstrasse 161ZurichSwitzerland

大多数用于灌溉和供水的坝为高度小于 15 m 的土坝,并称之为乡村坝。国际大坝委员会所辖大坝的坝高都在15 m 以上,这些小型水坝并不在委员会管辖范围之内。通常,乡村坝由地方社区或水坝工程建设经验不足的组织资助修建起来的,印度尤其... 详细信息

大多数用于灌溉和供水的坝为高度小于 15 m 的土坝,并称之为乡村坝。国际大坝委员会所辖大坝的坝高都在15 m 以上,这些小型水坝并不在委员会管辖范围之内。通常,乡村坝由地方社区或水坝工程建设经验不足的组织资助修建起来的,印度尤其如此。例如 1 月 26 日发生在印度古茶拉底省的 Bhuj 地震,波及到 240 座水坝。显然这些坝的质量远比不上水电站大坝的质量,然而小型水坝的事故将会影响到整个大坝行业的前景,所以这些乡村水坝也应该满足基本的设计与安全准则,以免对整个大坝行业造成负面影响。

关键词：水坝安全小型水坝土石坝地震破坏

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Development of aluminum-doped ZnO films for a-Si:H/μc-Si:H solar cell applications

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Journal of Semiconductors 2013年第6期34卷 32-37页

作者：雷志芳陈光羽谷士斌代玲玲杨荣孟原郭铁李立伟 ENN Solar energy Co. Ltd.

This study deals with the optimization of direct current（DC） sputtered aluminum-doped zinc oxide （AZO） thin films and their incorporation into a-Si：H/μc-Si：H tandem junction thin film solar cells aiming for high conversion *** and optical properties of AZO films,***,carrier density,resistivity, and transmittance,were comprehensively characterized and analyzed by varying sputtering deposition conditions, including chamber pressure,substrate temperature,and sputtering *** correlations between sputtering processes and AZO thin film properties were first ***,the AZO films were textured by diluted hydrochloric acid wet *** optimization of deposition and texturing processes,AZO films yield excellent electrical and optical properties with a high transmittance above 81%over the 380-1100 nm wavelength range,lowsheet resistance of 11Ω/□and high haze ratio of 41.3%.In preliminary experiments,the AZO films were applied to a-Si：H/μc-Si：H tandem thin film solar cells as front contact electrodes,resulting in an initial conversion efficiency of 12.5%with good current matching between subcells.

关键词： aluminum-doped zinc oxide magnetron sputtering tandem silicon thin film solar cell

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Constructing Donor–Acceptor‑Linked COFs Electrolytes to Regulate Electron Density and Accelerate the Li^(+)Migration in Quasi‑Solid‑State Battery

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Nano-Micro Letters 2025年第1期17卷 456-471页

作者： Genfu Zhao Hang Ma Conghui Zhang Yongxin Yang Shuyuan Yu Haiye Zhu Yongjiang Sun Hong Guo School of Materials and energy International Joint Research Center for Advanced Energy Materials of Yunnan ProvinceYunnan UniversityKunming 650091People’s Republic of China Yunnan Yuntianhua Co. LtdR&D CenterKunming 650228People’s Republic of China Southwest United Graduate School Kunming 650091People’s Republic of China

Regulation the electronic density of solid-state electrolyte by donor–acceptor(D–A)system can achieve highly-selective Li^(+)transportation and conduction in solid-state Li metal *** study reports a high-performance solid-state electrolyte thorough D–A-linked covalent organic frameworks(COFs)based on intramolecular charge transfer *** other reported COFbased solid-state electrolyte,the developed concept with D–A-linked COFs not only achieves electronic modulation to promote highly-selective Li^(+)migration and inhibit Li dendrite,but also offers a crucial opportunity to understand the role of electronic density in solid-state Li metal *** introduced strong electronegativity F-based ligand in COF electrolyte results in highlyselective Li^(+)(transference number 0.83),high ionic conductivity(6.7×10^(-4)S cm^(−1)),excellent cyclic ability(1000 h)in Li metal symmetric cell and high-capacity retention in Li/LiFePO_(4)cell(90.8%for 300 cycles at 5C)than substituted C-and N-based *** is ascribed to outstanding D–A interaction between donor porphyrin and acceptor F atoms,which effectively expedites electron transferring from porphyrin to F-based ligand and enhances Li^(+)***,we anticipate that this work creates insight into the strategy for accelerating Li^(+)conduction in high-performance solid-state Li metal batteries through D–A system.

关键词： Electronic modulation engineering Donor-acceptor-linked covalent organic frameworks Quasi-solid-state Li metal battery

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La2Zr2O7 and MgO co-doped composite Li-Garnet solid electrolyte

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Journal of energy Chemistry 2020年第1期29卷 132-136,I0005页

作者： Jiu Lin Linbin Wu Zhen Huang Xiaoxiong Xu Jiheng Liu Zhejiang Funlithium New energy Technology Co. Ltd.

Various solid electrolytes,such as sulfides(10^-3-10^-2 S cm^-1)and oxides(10^-4–10^-3 S cm^-1)are explored and developed to solve the safety problems in commercial Li-ion batteries using liquid flammable *** Li anod... 详细信息

关键词： Li-Garnet Li7La3Zr2O12 Composite electrolyte High conductivity La2Zr2O7 MgO

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