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A synergetic strategy of NIR-Ⅱ squaraine dyes with ultrahigh photothermal conversion efficiency for photothermal therapy

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Science China Chemistry 2024年第2期67卷 612-621页

作者： Yigang Wang Guomin Xia Junhui Wang Mingda Wang Weihan Guo Manman Tan Leilei Si Yang Yang Hua Wang Hongming Wang Institute for Advanced Study and School of Chemistry and Chemical Engineering Nanchang UniversityNanchang330031China State Key Laboratory of Molecular Reaction dynamics and dynamics research center for Energy and Environmental Materials Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian116023China The Second Affiliated Hospital of Nanchang University Nanchang330031China

Recent research on photothermal therapy(PTT) has sparked significant interest in the development of new organic photothermal agents(PTAs),ranging from single-molecule to aggregated ***,controlling aggregation pathways for PTAs with ultrahigh photothermal conversion efficiency(PCE) remains a major ***,a two-pronged approach utilizing “Haggregation” and “intramolecular motion” was employed to enhance the PCE of an acceptor-substituted squaraine dye(NSQs).The C2vmolecular symmetry of the NSQs,which possess a ground state dipole moment(μg),promotes H-dimeric aggregates through dipole-dipole *** triphenylethylene or diphenylamine groups were added to this H-dimeric *** was done to enhance intramolecular motions for heat generation and also to extend conjugation,which redshifted the optical absorption and balanced the blue-shift induced by *** this technique,an organic PTA with NIR-II absorption was developed,and its nanoparticle achieved a remarkable PCE of 86.3% under 1,064 nm laser *** transient absorption spectroscopy and quantum mechanical calculations demonstrated the accelerated internal conversion process in NIR-II PTAs for rapid heat *** NSQs nanoparticles exhibit superior photothermal therapeutic properties for in vivo photoacoustic imaging-guided PTT,demonstrating the potential of bottom-up design to enable synergistic engineering strategies towards efficient phototheranostic agents.

关键词： squaraine dyes second near-infrared window H-aggregation intramolecular motion photothermal therapy

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Achieving Seconds-to-Hours Duration-Tunable Organic Long Persistent Luminescence from Carbon Dots-Based Exciplex Systems by Energy Gaps Regulation

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Chinese Journal of Chemistry 2024年第12期42卷 1407-1417页

作者： Yixuan Xu Kai Jiang Linger Feng Xinyuan Tong Zuxu Zhou Fengshi Li Yi Zhang Jiaren Du Hengwei Lin International Joint research center for photo-responsive Molecules and Materials School of Chemical and Material EngineeringJiangnan UniversityWuxiJiangsu214122China State Key Laboratory of Food Science and Resources Jiangnan UniversityWuxiJiangsu 214122China

Comprehensive Summary Duration-tunable afterglow materials have garnered considerable attention in various ***,carbon dots(CDs)-based long persistent luminescence(LPL)composites with a tunable duration in an ultrawide range of seconds-to-hours levels were designed and prepared for the first *** contrast to the established CD-based afterglow materials,we reported that CD-based composites exhibit LPL in the form of exciplexes and long-lived charge-separated states,enabling the LPL to be prolonged from several seconds to over one hour,exceeding the typical regulation range(limited to 1 min).Further studies revealed that the relationship between the excited and charge-transfer states of CDs plays a pivotal role in activating the LPL and regulating its ***,these composites exhibited high photoluminescence(PL)quantum yields of up to 60.63%,and their LPL was robust under ambient conditions,even in aqueous *** robust and superior LPL performance endows these composites with a strong competitive advantage in dynamic display systems,such as tags for time-resolved data encryption and displays of the remaining time of *** study offers an approach to preparing CDs-based LPL composites with tunable durations and may provide new insights for the development of rare-earth-free LPL materials.

关键词： Carbon dots Composites Charge separation Exciplex Persistent luminescence

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The dual-action mechanism of Arabidopsis cryptochromes

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Journal of Integrative Plant Biology 2024年第5期66卷 883-896页

作者： Gao-Ping Qu Bochen Jiang Chentao Lin Basic Forestry and Plant Proteomics research center Fujian Agriculture and Forestry UniversityFuzhou 350002China Department of Chemistry Department of Biochemistry and Molecular BiologyInstitute for Biophysical DynamicsThe University of ChicagoChicagoIL 60637USA

photoreceptor cryptochromes (CRYs) mediate blue-light regulation of plant growth and development. It has been reported that Arabidopsis CRY1and CRY2 function by physically interacting with at least 84 proteins, including transcription factors or co-factors, chromatin regulators, splicing factors, messenger RNA methyltransferases, DNA repair proteins, E3 ubiquitin ligases, protein kinases and so on. Of these 84 proteins, 47 have been reported to exhibit altered binding affinity to CRYs in response to blue light, and 41 have been shown to exhibit condensation to CRY photobodies. The blue light-regulated composition or condensation of CRY complexes results in changes of gene expression and developmental programs. In this mini-review, we analyzed recent studies of the photoregulatory mechanisms of Arabidopsis CRY complexes and proposed the dual mechanisms of action, including the “Lock-and-Key” and the “Liquid-Liquid Phase Separation (LLPS)” mechanisms. The dual CRY action mechanisms explain, at least partially, the structural diversity of CRY-interacting proteins and the functional diversity of the CRY photoreceptors.

关键词： Arabidopsis blue light cryptochrome CRY1 CRY2 phaseseparation

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1.6-μm single-frequency erbium-doped fiber laser based on two cascaded subrings

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Chinese Optics Letters 2024年第4期22卷 77-82页

作者：翟雅琦文瀚陈浩伟陆宝乐白晋涛 State Key Laboratory of Energy photon-Technology in Western China International Collaborative Center on Photoelectric Technology and Nano Functional MaterialsInstitute of Photonics&Photon-TechnologyNorthwest UniversityXi’an 710127China Shaanxi Engineering Technology research center for Solid State Lasers and Application Shaanxi Provincial Key Laboratory of Photo-electronic TechnologyNorthwest UniversityXi’an 710127China

We demonstrate a stable narrow linewidth single-frequency erbium-doped fiber laser(EDFL)operating at 1.6μm.A Fabry–Perot fiber Bragg grating and two cascaded subrings are incorporated in the main ring cavity to achieve singlefrequency *** experimentally measured optical signal-to-noise ratio is greater than 73 ***,the linewidth of the EDFL is measured to be about 480 Hz by the self-built short-delayed self-heterodyne interferometry *** laser shows superior stability,with no mode-hopping during the 60-min observation *** proposed EDFL provides a new experimental idea for realizing a single-frequency fiber laser in the L-band.

关键词： erbium-doped fiber laser two cascaded subrings single frequency

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钙钛矿纳米晶固体中普遍存在的、显著的激子转移（英文）

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Science China Materials 2024年第9期67卷 2818-2827页

作者：罗余庆党志亚孟令晨陈泽龙黎梓豪路通通饶小斌赵书苑孙祺高平奇 School of Materials Shenzhen Campus of Sun Yat-sen University State Key Laboratory of Optoelectronic Materials and Technologies Sun Yat-sen University State Key Laboratory of Molecular Reaction dynamics and the Dynamic research center for Energy and Environmental Materials Dalian Institute of Chemical PhysicsChinese Academy of Sciences

钙钛矿纳米晶(PNC)固体是很有前景的光电应用材料.最近的研究表明,PNC固体中的激子扩散通过交替的激子跳跃(EH)和光子循环(PR)而实现.PNC固体中尺寸分布引起的能量不均一性是普遍存在的,目前尚不清楚该因素对激子扩散的影响.在这里,我... 详细信息

钙钛矿纳米晶(PNC)固体是很有前景的光电应用材料.最近的研究表明,PNC固体中的激子扩散通过交替的激子跳跃(EH)和光子循环(PR)而实现.PNC固体中尺寸分布引起的能量不均一性是普遍存在的,目前尚不清楚该因素对激子扩散的影响.在这里,我们通过透射模式的多波段稳态和瞬态光致发光(PL)光谱学测试,研究了尺寸呈高斯分布(边长约为11.2±6.8 nm)的CsPbBr3 NC固体中的激子扩散.我们的研究结果表明,激子沿着能量降低的方向在不同能量位点之间进行转移,这一过程支配着PNC固体的激子扩散,低温PL分析结果进一步证实了这一点.更为详细的研究揭示出,受体分布与吸收系数共同决定了EH和PR在不同能量位点之间的激子转移中所做的贡献.因此,在不同厚度的PNC固体中,激子扩散机制有所不同:高能位点向较低能位点的EH和PR效率高,主导着几百纳米薄膜中的激子转移;在数微米的厚膜中,从中等能量位点向低能位点的、主要通过PR而进行的激子转移也变得明显起来.这些发现不仅使我们进一步理解了受体分布在PNC固体的激子扩散过程中所起的关键作用,也为基于PNC固体的光电应用提供了重要基础和指导.我们的工作还利用常规的测试手段来深入研究激子扩散过程,有利于揭示以往的表面PL成像方法所隐藏了的关于材料内部激子扩散的信息.

关键词： photoluminescence spectroscopy exciton diffusion exciton transfer perovskite nanocrystals photon recycling exciton hopping reabsorption

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Experimental Investigation of the Operating Characteristics of a Pulsating Heat Pipe with Ultra-Pure Water and Micro Encapsulated Phase Change Material Suspension

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Journal of Thermal Science 2024年第2期33卷 457-468页

作者： SHI Weixiu SU Xiaoyang CHEN Hongdi PAN Lisheng Beijing Engineering research center of Sustainable Energy and Buildings Beijing University of Civil Engineering and ArchitectureBeijing100044China School of Environment and Energy Engineering Beijing University of Civil Engineering and ArchitectureBeijing100044China State Key Laboratory of High Temperature Gas dynamics Institute of MechanicsChinese Academy of SciencesBeijing100190China

The specific heat capacity of working fluid is an important influence factor on heat transfer characteristic of the pulsating heat pipe(PHP).Due to the relatively large specific heat capacity of micro encapsulated phase change material(MEPCM) suspension,a heat transfer performance experimental facility of the PHP was *** heat transfer characteristic with MEPCM suspension of different mass concentrations(0.5% and 1.0%) and ultra-pure water were compared *** was found that when the PHP uses MEPCM suspension as its working fluid,operating stability is impoverished under lower heating power and the operating stability is better under higher heating *** the inclination angle of 90°,the temperature at heating side decreases compared to ultra-pure water and the temperature at heating side decreases with the raising of MEPCM suspension mass *** heat transfer characteristic of the PHP is positively correlated with the inclination angle and the 90° is *** unfavorable effect of the inclination angle decreases with heating power *** the inclination angle is 90°,the PHP with MEPCM suspension at 1.0% of mass concentration has the lowest thermal transfer resistance and followed by ultra-pure water and MEPCM suspension at 0.5% of mass concentration has the highest thermal transfer *** the inclination angles are 60° and30°,the effect of gravity on the flow direction is reduced to 86.6% and 50% of that on the inclination angle of 90°,respectively,and the promoting effect of gravity on the working fluid is further weakened as the inclination angle further *** to the high viscosity of MEPCM suspension,the PHP with ultra-pure water has the lowest heat transfer *** the inclination angles is 60°,the thermal resistance with MEPCM suspension at0.5% of the mass concentration is lower than that at 1.0% at the heating power below 230 *** thermal resistance of MEPCM suspension tends to be simila

关键词： pulsating heat pipe(PHP) micro encapsulated phase change material(MEPCM) heat transfer characteristic inclination angle

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Biomimetic MXene membranes with negatively thermo-responsive switchable 2D nanochannels for graded molecular sieving

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Green Energy & Environment 2024年第6期9卷 1058-1067页

作者： Yi Wang Yangyang Wang Chang Liu Dongjian Shi Weifu Dong Baoliang Peng Liangliang Dong Mingqing Chen The Key Laboratory of Synthetic and Biological Colloids Ministry of EducationSchool of Chemical and Material EngineeringJiangnan UniversityWuxiJiangsu214122China International research center for photo-responsive Molecules and Materials Jiangnan UniversityWuxiJiangsu214122China research Institute of Petroleum Exploration&Development(RIPED) PetroChina/Key Laboratory of Oilfield ChemistryCNPCBeijing100083China

Negatively thermo-responsive 2D membranes,which mimic the stomatal opening/closing of plants,have drawn substantial interest for tunable molecular separation ***,these membranes are still restricted significantly on account of low water permeability and poor dynamic tunability of 2D nanochannels under temperature ***,we present a biomimetic negatively thermo-responsive MXene membrane by covalently grafting poly(N-isopropylacrylamide)(PNIPAm)onto MXene *** uniformly grafted PNIPAm polymer chains can enlarge the interlayer spacings for increasing water permeability while also allowing more tunability of 2D nanochannels for enhancing the capability of gradually separating multiple molecules of different *** expected,the constructed membrane exhibits ultrahigh water permeance of 95.6 L m^(-2) h^(-1) bar^(-1) at 25℃,which is eight-fold higher than the state-of-the-art negatively thermoresponsive 2D ***,the highly temperature-tunable 2D nanochannels enable the constructed membrane to perform excellent graded molecular sieving for dye-and antibiotic-based ternary *** strategy provides new perspectives in engineering smart 2D membrane and expands the scope of temperature-responsive membranes,showing promising applications in micro/nanofluidics and molecular separation.

关键词： Thermo-responsive 2D membrane MXene nanosheets PNIPAm Temperature-tunable 2D nanochannels Graded molecular sieving

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Effect of coil and chamber structure on plasma radial uniformity in radio frequency inductively coupled plasma

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Plasma Science and Technology 2024年第7期26卷 58-66页

作者：赵洋周晓华高升荣宋莎莎赵玉真 Shaanxi International Joint research center for Applied Technology of Controllable Neutron Source Xijing UniversityXi’an 710123People’s Republic of China Technological Institute of Materials&Energy Science(TIMES) Xi’an Key Laboratory of Advanced Photo-electronics Materials and Energy Conversion DeviceSchool of Electronic InformationXijing UniversityXi’an 710123People’s Republic of China

Enhancing plasma uniformity can be achieved by modifying coil and chamber structures in radio frequency inductively coupled plasma(ICP)to meet the demand for large-area and uniformly distributed plasma in industrial *** study utilized a two-dimensional self-consistent fluid model to investigate how different coil configurations and chamber aspect ratios affect the radial uniformity of plasma in radio frequency *** findings indicate that optimizing the radial spacing of the coil enhances plasma uniformity but with a reduction in electron ***,optimizing the coil within the ICP reactor,using the interior point method in the Interior Point Optimizer significantly enhances plasma uniformity,elevating it from 56%to 96%within the range of the model ***,when the chamber aspect ratio k changes from 2.8 to 4.7,the plasma distribution changes from a center-high to a saddleshaped ***,the plasma uniformity becomes ***,adjusting process parameters,such as increasing source power and gas pressure,can enhance plasma *** findings contribute to optimizing the etching process by improving plasma radial uniformity.

关键词： inductively coupled plasma fluid simulation optimized coil chamber aspect ratio plasma uniformity

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A modified stochastic model for LS+AR hybrid method and its application in polar motion short-term prediction

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Geodesy and Geodynamics 2024年第1期15卷 100-105页

作者： Fei Ye Yunbin Yuan State Key Laboratory of Geodesy and Earth's dynamics Innovation Academy for Precision Measurement Science and TechnologyChinese Academy of SciencesWuhan 430077China BeiDou High-precision Satellite Navigation and Location Service Hunan Engineering research center Hunan Institute of Geomatics Sciences and TechnologyChangsha 410007China Hunan Continuously Operating Reference Stations(HNCORS)Data center Hunan Institute of Geomatics Sciences and TechnologyChangsha 410007China

Short-term(up to 30 days)predictions of Earth Rotation Parameters(ERPs)such as Polar Motion(PM:PMX and PMY)play an essential role in real-time applications related to high-precision reference frame ***,least squares(LS)+auto-regressive(AR)hybrid method is one of the main techniques of PM ***,the weighted LS+AR hybrid method performs well for PM short-term ***,the corresponding covariance information of LS fitting residuals deserves further exploration in the AR *** this study,we have derived a modified stochastic model for the LS+AR hybrid method,namely the weighted LS+weighted AR hybrid *** using the PM data products of IERS EOP 14 C04,the numerical results indicate that for PM short-term forecasting,the proposed weighted LS+weighted AR hybrid method shows an advantage over both the LS+AR hybrid method and the weighted LS+AR hybrid *** to the mean absolute errors(MAEs)of PMX/PMY sho rt-term prediction of the LS+AR hybrid method and the weighted LS+AR hybrid method,the weighted LS+weighted AR hybrid method shows average improvements of 6.61%/12.08%and 0.24%/11.65%,***,for the slopes of the linear regression lines fitted to the errors of each method,the growth of the prediction error of the proposed method is slower than that of the other two methods.

关键词： Stochastic model LS+AR Short-term prediction The earth rotation parameter(ERP) Observation model

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Influence of syngas components and ash particles on the radiative heat transfer in a radiant syngas cooler

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Chinese Journal of Chemical Engineering 2024年第4期68卷 203-215页

作者： Chen Han Youmin Situ Huaxing Zhu Jianliang Xu Zhenghua Dai Guangsuo Yu Haifeng Liu National Energy Coal Gasification Technology research and Development center East China University of Science and TechnologyShanghai 200237China Shanghai Engineering research center of Coal Gasification East China University of Science and TechnologyShanghai 200237China

Radiant syngas cooler(RSC)is widely used as a waste heat recovery equipment in industrial *** this work,an RSC with radiation screens is established and the impact of gaseous radiative property models,gas components,and ash particles on heat transfer is investigated by the numerical simulation *** the syngas components and the pressure environment of the RSC,a modified weighted-sum-of-gray-gases model was *** modified model shows high accuracy in *** computational fluid dynamics simulation,the calculated steam production is only 0.63%in error with the industrial *** with Smith's model,the temperature decay along the axial direction calculated by the modified model is *** components are of great significance to heat recovery capacity,especially when the absorbing gas fraction is less than 10%.After considering the influence of particles,the outlet temperature and the proportion of radiative heat transfer are less affected,but the difference in steam output reaches 2.7 t·h^(-1).The particle deposition on the wall greatly reduces the heat recovery performance of an RSC.

关键词： Radiant syngas cooler Weighted-sum-of-gray-gases model Numerical simulation Particle radiation

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