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Synthesis of boron nitride nanorod and its performance as a metalfree catalyst for oxidative desulfurization of diesel fuel

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Chinese Journal of Chemical Engineering 2024年第4期68卷 120-132页

作者： Tanaz Ghanadi Gholamreza Moradi Alimorad Rashidi Catalyst research center Faculty of Chemical and Petroleum EngineeringRazi UniversityKermanshahIran Nanotechnology research center Research Institute of Petroleum Industry(RIPI)TehranIran

In order to reduce the sulfur compounds in diesel fuel,boron nitride(BN)has been used as a novel metal efree catalyst in the present research.This nanocatalyst was synthesized via template-free approach followed by heating treatment at 900℃in nitrogen atmosphere that the characteristics of the sample were identified by the X-ray diffraction,Fourier-transform infrared spectroscopy,Raman spectroscopy,field emission scanning electron microscopy,transmission electron microscopy,atomic force microscopy,and N2 adsorptionedesorption isotherms.The results of structural and morphological analysis represented that BN has been successfully synthesized.The efficacy of the main operating parameters on the process was studied by using response surface methodology based on the BoxeBehnken design method.The prepared catalyst showed high efficiency in oxidative desulfurization of diesel fuel with initial sulfur content of 8040 mg·kg^(-1)S.From statistical analysis,a significant quadratic model was obtained to predict the sulfur removal as a function of efficient parameters.The maximum efficiency of 72.4%was achieved under optimized conditions at oxidant/sulfur molar ratio of 10.2,temperature of 71℃,reaction time of 113 min,and catalyst dosage of 0.36 g.Also,the reusability of the BN was studied,and the result showed little reduction in activity of the catalyst after 10 times regeneration.Moreover,a plausible mechanism was proposed for oxidation of sulfur compounds on the surface of the catalyst.The present study shows that BN materials can be selected as promising metal-free catalysts for desulfurization process.

关键词： Desulfurization Boron nitride(BN)nanostructure Experimental design BoxeBehnken

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Effects of synthesis parameters on the performance of crosslinked Co-polymers with clays for conformance control

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petroleum research 2024年第1期9卷 98-108页

作者： A.A.Roslan N.A.A.Aziz N.F.A.Deraman I.Dzulkarnain petroleum Engineering Department Centre of Research Enhanced Oil Recovery(COREOR)Universiti Teknologi PETRONASSeri IskandarPerakMalaysia Chemical Engineering Department Centre of Research Enhanced Oil Recovery(COREOR)Universiti Teknologi PETRONASSeri IskandarPerakMalaysia

Conformance control or water shut-off is a technique used to improve oil recovery.During conformance control,polymers block high permeability water areas and redistribute water drive toward unswept oil zones.In this study,co-polymers(denoted ATP-PGV/AM-co-AMPS)were synthesized using acrylamide(AM)and 2-acrylamide-2-methylpropane sulfonic acid(AMPS)as the monomers,polyethylene glycol(PEG)-200 and methylenebisacrylamide(MBA)as the crosslinkers,attapulgite(ATP)and bentonite(PGV)as the clay types,and ammonium persulfate(APS)as the initiator,in addition to paraffin oil and surfactants.Samples were synthesized using inverse emulsion polymerization with different concentrations of monomers,crosslinkers,and clays,and they were characterized using Fourier-transform infrared(FTIR)spectroscopy and scanning electron microscopy(SEM)with energy dispersive X-ray spectroscopy(EDX).FTIR spectra of the samples confirmed the existence of sulfonate and hydroxyl groups,which are important for polymer swelling.SEM-EDX images indicated that the morphology and elemental composition were different before and after swelling,confirming the occurrence of swelling.Moreover,samples were placed in sodium chloride solution(20,000 ppm)for 7 days to evaluate swelling at both room temperature and 90°C.Thermogravimetric analysis(TGA)and differential scanning calorimetry(DSC)were used to determine the thermal characteristics of the microparticles.Finally,rheological measurements were used to assess the deformation and rheological behavior of the hydrogels.The results showed that after 1 day,good swelling without loss of mechanical strength was achieved with the composite synthesized using 10%AM,15%AMPS,6%PGV,and 10%ATP.

关键词： Polymer Clay Water shut-off Conformance Swelling

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research on a TOPSIS energy efficiency evaluation system for crude oil gathering and transportation systems based on a GA-BP neural network

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petroleum Science 2024年第1期21卷 621-640页

作者： Xue-Qiang Zhang Qing-Lin Cheng Wei Sun Yi Zhao Zhi-Min Li Key Lab of Ministry of Education for Enhancing the Oil and Gas recovery Ratio Northeast Petroleum UniversityDaqing163318HeilongjiangChina China petroleum Pipeline Material and Equipment Co. LtdLangfang065000HebeiChina research Institute of petroleum Engineering and Technology Sinopec Northwest Oilfield CompanyUrumqi830011XinjiangChina

As the main link of ground engineering,crude oil gathering and transportation systems require huge energy consumption and complex structures.It is necessary to establish an energy efficiency evaluation system for crude oil gathering and transportation systems and identify the energy efficiency gaps.In this paper,the energy efficiency evaluation system of the crude oil gathering and transportation system in an oilfield in western China is established.Combined with the big data analysis method,the GA-BP neural network is used to establish the energy efficiency index prediction model for crude oil gathering and transportation systems.The comprehensive energy consumption,gas consumption,power consumption,energy utilization rate,heat utilization rate,and power utilization rate of crude oil gathering and transportation systems are predicted.Considering the efficiency and unit consumption index of the crude oil gathering and transportation system,the energy efficiency evaluation system of the crude oil gathering and transportation system is established based on a game theory combined weighting method and TOPSIS evaluation method,and the subjective weight is determined by the triangular fuzzy analytic hierarchy process.The entropy weight method determines the objective weight,and the combined weight of game theory combines subjectivity with objectivity to comprehensively evaluate the comprehensive energy efficiency of crude oil gathering and transportation systems and their subsystems.Finally,the weak links in energy utilization are identified,and energy conservation and consumption reduction are improved.The above research provides technical support for the green,efficient and intelligent development of crude oil gathering and transportation systems.

关键词： Crude oil gathering and transportation system GA-BP neural network Energy efficiency evaluation TOPSIS evaluation method Energy saving and consumption reduction

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Implications of electrode modifications in aqueous organic redox flow batteries

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Journal of Energy Chemistry 2024年第8期95卷 499-510页

作者： Zahid Manzoor Bhat Mohammad Furquan Muhammad Aurang Zeb Gul Sial Umair Alam Atif Saeed Alzahrani Mohammad Qamar Interdisciplinary research center for Hydrogen Technologies and Carbon Management(IRC-HTCM) King Fahd University of Petroleum & Minerals(KFUPM) Department of Materials Science and Engineering King Fahd University of Petroleum and Minerals Interdisciplinary research center for Sustainable Energy Systems(IRC-SES) King Fahd University of Petroleum and Minerals

Aqueous organic redox flow batteries(RFBs) exhibit favorable characteristics, such as tunability, multielectron transfer capability, and stability of the redox active molecules utilized as anolytes and catholytes, making them very viable contenders for large-scale grid storage applications. Considerable attention has been paid on the development of efficient redox-active molecules and their performance optimization through chemical substitutions at various places on the backbone as part of the pursuit for high-performance RFBs. Despite the fact that electrodes are vital to optimal performance, they have not garnered significant attention. Limited research has been conducted on the effects of electrode modifications to improve the performance of RFBs. The primary emphasis has been given on the impact of electrode engineering to augment the efficiency of aqueous organic RFBs. An overview of electron transfer at the electrode–electrolyte interface is provided. The implications of electrode modification on the performance of redox flow batteries, with a particular focus on the anodic and cathodic half-cells separately, are then discussed. In each section, significant discrepancies surrounding the effects of electrode engineering are thoroughly examined and discussed. Finally, we have presented a comprehensive assessment along with our perspectives on the future trajectory.

关键词： Electrode modification Organic redox molecules Outer sphere and inner sphere Redox flow batteries

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Proppant transport in rough fracture networks using supercritical CO2

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petroleum Science 2024年第3期21卷 1852-1864页

作者： Yong Zheng Meng-Meng Zhou Ergun Kuru Bin Wang Jun Ni Bing Yang Ke Hu Hai Huang Hai-Zhu Wang School of petroleum Engineering Xi'an Shiyou University Shaanxi Key Laboratory of Carbon Dioxide Sequestration and Enhanced Oil recovery State Key Laboratory of petroleum Resources and Engineering China University of Petroleum (Beijing) School of Mining and petroleum Engineering University of Alberta Shaanxi Yanchang petroleum (Group) Co. Ltd.

Proppant transport within fractures is one of the most critical tasks in oil, gas and geothermal reservoir stimulation, as it largely determines the ultimate performance of the operating well. Proppant transport in rough fracture networks is still a relatively new area of research and the associated transport mechanisms are still unclear. In this study, representative parameters of rough fracture surfaces formed by supercritical CO2fracturing were used to generate a rough fracture network model based on a spectral synthesis method. Computational fluid dynamics（CFD） coupled with the discrete element method（DEM） was used to study proppant transport in this rough fracture network. To reveal the turning transport mechanism of proppants into branching fractures at the intersections of rough fracture networks, a comparison was made with the behavior within smooth fracture networks, and the effect of key pumping parameters on the proppant placement in a secondary fracture was analyzed. The results show that the transport behavior of proppant in rough fracture networks is very different from that of the one in the smooth fracture networks. The turning transport mechanisms of proppant into secondary fractures in rough fracture networks are gravity-driven sliding, high velocity fluid suspension, and fracture structure induction. Under the same injection conditions, supercritical CO2with high flow Reynolds number still has a weaker ability to transport proppant into secondary fractures than water. Thickening of the supercritical CO2needs to be increased beyond a certain value to have a significant effect on proppant carrying, and under the temperature and pressure conditions of this paper, it needs to be increased more than 20 times（about 0.94 m Pa s）. Increasing the injection velocity and decreasing the proppant concentration facilitates the entry of proppant into the branching fractures, which in turn results in a larger stimulated reservoir volume. The results help to understand the proppant transport and placement proce

关键词： Reservoir stimulation CCUS Rough fracture network Supercritical CO 2 Proppant transport

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Linearized waveform inversion for vertical transversely isotropic elastic media:Methodology and multi-parameter crosstalk analysis

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petroleum Science 2024年第1期21卷 252-271页

作者： Ke Chen Lu Liu Li-Nan Xu Fei Hu Yuan Yang Jia-Hui Zuo Le-Le Zhang Yang Zhao National Key Laboratory of petroleum Resources and Engineering Unconventional Petroleum Research InstituteChina University of Petroleum(Beijing)Beijing102249China Aramco Beijing research center Aramco AsiaBeijing100102China University of Lausanne LausanneCH-1015Switzerland Bureau of Geophysical Prospecting China National Petroleum CorporationZhuozhou 072750HebeiChina

Seismic migration and inversion are closely related techniques to portray subsurface images and identify hydrocarbon reservoirs.Seismic migration aims at obtaining structural images of subsurface geologic discontinuities.More specifically,seismic migration estimates the reflectivity function(stacked average reflectivity or pre-stack angle-dependent reflectivity)from seismic reflection data.On the other hand,seismic inversion quantitatively estimates the intrinsic rock properties of subsurface formulations.Such seismic inversion methods are applicable to detect hydrocarbon reservoirs that may exhibit lateral variations in the inverted parameters.Although there exist many differences,pre-stack seismic migration is similar with the first iteration of the general linearized seismic inversion.Usually,seismic migration and inversion techniques assume an acoustic or isotropic elastic medium.Unconventional reservoirs such as shale and tight sand formation have notable anisotropic property.We present a linearized waveform inversion(LWI)scheme for weakly anisotropic elastic media with vertical transversely isotropic(VTI)symmetry.It is based on two-way anisotropic elastic wave equation and simultaneously inverts for the localized perturbations(ΔVp_(0)/Vp_(0)/Vs_(0)/Vs_(0)/,Δ∈,Δδ)from the long-wavelength reference model.Our proposed VTI-elastic LWI is an iterative method that requires a forward and an adjoint operator acting on vectors in each iteration.We derive the forward Born approximation operator by perturbation theory and adjoint operator via adjoint-state method.The inversion has improved the quality of the images and reduces the multi-parameter crosstalk comparing with the adjoint-based images.We have observed that the multi-parameter crosstalk problem is more prominent in the inversion images for Thomsen anisotropy parameters.Especially,the Thomsen parameter is the most difficult to resolve.We also analyze the multi-parameter crosstalk using scattering radiation patterns.The linearized waveform inversion for VTI-el

关键词： Elastic Anisotropy Least-squares imaging Waveform inversion Computational geophysics

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Metagenomic insights into microorganisms and antibiotic resistance genes of waste antibiotic fermentation residues along production,storage and treatment processes

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Journal of Environmental Sciences 2024年第2期136卷 45-55页

作者： Ziming Han Xiao Luan Haodi Feng Yanqin Deng Min Yang Yu Zhang State Key Laboratory of Environmental Aquatic Chemistry Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China National Engineering research center of Industrial Wastewater Detoxication and Resource recovery Beijing 100085China Wuhan Agricultural Inspection center Wuhan 430016China University of Chinese Academy of Sciences Beijing 100049China

Antibiotic fermentation residue(AFR)is nutrient-rich solid waste generated from fermentative antibiotic production process.It is demonstrated that AFR contains high-concentration of remaining antibiotics,and thus may promote antibiotic resistance development in receiving environment or feeding farmed animals.However,the dominate microorganisms and antibiotic resistance genes(ARGs)in AFRs have not been adequately explored,hampering understanding on the potential antibiotic resistance risk development caused by AFRs.Herein,seven kinds of representative AFRs along their production,storage,and treatment processes were collected,and multiple methods including amplicon sequencing,metagenomic sequencing,and bioinformatic approaches were adopted to explore the biological characteristics of AFRs.As expected,antibiotic fermentation producer was found as the predominant species in raw AFRs,which were collected at the outlet of fermentation tanks.However,except for producer species,more environment-derived species persisted in stored AFRs,which were temporarily stored at a semi-open space.Lactobacillus genus,classified as Firmicutes phylum and Bacilli class,became predominant bacterial taxa in stored AFRs,which might attribute to its tolerance to high concentration of antibiotics.Results from metagenomic sequencing together with assembly and binning approaches showed that these newly-colonizing species(e.g.,Lactobacillus genus)tended to carry ARGs conferring resistance to the remaining antibiotic.However,after thermal treatment,remaining antibiotic could be efficiently removed from AFRs,and microorganisms together with DNA could be strongly destroyed.In sum,the main risk from the AFRs was the remaining antibiotic,while environment-derived bacteria which tolerate extreme environment,survived in ARFs with high content antibiotics,and may carry ARGs.Thus,hydrothermal or other harmless treatment technologies are recommended to remove antibiotic content and inactivate bacteria before recycling of AFRs in pharmaceutical industry.

关键词： Pharmaceutical manufacturing Antibiotic mycelia residue Antibiotic resistance bacteria Thermal treatment Solid waste

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A reweighted damped singular spectrum analysis method for robust seismic noise suppression

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petroleum Science 2024年第3期21卷 1671-1682页

作者： Wei-Lin Huang Yan-Xin Zhou Yang Zhou Wei-Jie Liu Ji-Dong Li State Key Laboratory of petroleum Resources and Engineering China University of Petroleum (Beijing) SINOPEC petroleum Exploration and Production research Institute SINOPEC Geophysical research Institute

(Multichannel) Singular spectrum analysis is considered as one of the most effective methods for seismic incoherent noise suppression. It utilizes the low-rank feature of seismic signal and regards the noise suppression as a low-rank reconstruction problem. However, in some cases the seismic geophones receive some erratic disturbances and the amplitudes are dramatically larger than other receivers. The presence of this kind of noise, called erratic noise, makes singular spectrum analysis(SSA) reconstruction unstable and has undesirable effects on the final results. We robustify the low-rank reconstruction of seismic data by a reweighted damped SSA(RD-SSA) method. It incorporates the damped SSA, an improved version of SSA, into a reweighted framework. The damping operator is used to weaken the artificial disturbance introduced by the low-rank projection of both erratic and random noise. The central idea of the RD-SSA method is to iteratively approximate the observed data with the quadratic norm for the first iteration and the Tukeys bisquare norm for the rest iterations. The RD-SSA method can suppress seismic incoherent noise and keep the reconstruction process robust to the erratic disturbance. The feasibility of RD-SSA is validated via both synthetic and field data examples.

关键词： Singular spectrum analysis Damping operator Seismic erratic noise Seismic signal processing Robust low-rank reconstruction

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Combined Promoting Effects of Specific Organic Functional Groups and Alumina Surface Characteristics for the Design of a Highly Efficient NiMo/Al_(2)O_(3) Hydrodesulfurization Catalyst

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China petroleum Processing & Petrochemical Technology 2024年第1期26卷 1-11页

作者： Li Huifeng Li Mingfeng Zhang Le Wang Wei Nie Hong National Energy R&D center of petroleum Refining Technology SINOPEC Research Institute of Petroleum Processing Co.Ltd.Beijing 100083China

To prepare a highly efficient NiMo/Al_(2)O_(3) hydrodesulfurization catalyst,the combined effects of specific organic functional groups and alumina surface characteristics were investigated.First,the correlation between the surface characteristics of four different alumina and the existing Mo species states was established.It was found that the Mo equilibrium adsorption capacity can be used as a specific descriptor to quantitatively evaluate the changes in surface characteristics of different alumina.A lower Mo equilibrium adsorption capacity for alumina means weaker metal-support interaction and the loaded Mo species are easier to transform into MoS2.However,the Mo-O-Al bonds still exist at the metal-support interface.The introduction of cationic surfactant hecadecyl trimethyl ammonium bromide(CTAB)can further improve Mo species dispersion through electrostatic attraction with Mo anions and interaction of its alkyl chain with the alumina surface;meanwhile,the introduction of ethylenediamine tetraacetic acid(EDTA)can complex with Ni ions to enhance the Ni-promoting effect on Mo.Therefore,the NiMo catalyst designed using alumina with lower Mo equilibrium adsorption capacity and the simultaneous addition of EDTA and CTAB exhibits the highest hydrodesulfurization activity for 4,6-dimethyl dibenzothiophene because of its proper metal-support interaction and more well-dispersed Ni-Mo-S active phases.

关键词： alumina Mo equilibrium adsorption capacity organic functional groups metal-support interaction hydrodesulfurization

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A New Heat Transfer Model for Multi-Gradient Drilling with Hollow Sphere Injection

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Fluid Dynamics & Materials Processing 2024年第3期20卷 537-546页

作者： Jiangshuai Wang Chuchu Cai Pan Fu Jun Li Hongwei Yang Song Deng School of petroleum and Natural Gas Engineering Changzhou UniversityChangzhouChina CNPC research Institute of Engineering Technology Co. Ltd.BeijingChina National Engineering research center for Oil&Gas Drilling and Completion Technology BeijingChina College of petroleum Engineering China University of Petroleum(Beijing)BeijingChina College of petroleum Karamay CampusChina University of Petroleum(Beijing)BeijingChina

Multi-gradient drilling is a new offshore drilling method.The accurate calculation of the related wellbore temperature is of great significance for the prediction of the gas hydrate formation area and the precise control of the wellbore pressure.In this study,a new heat transfer model is proposed by which the variable mass flow is properly taken into account.Using this model,the effects of the main factors influencing the wellbore temperature are analyzed.The results indicate that at the position where the separation injection device is installed,the temperature increase of the fluid in the drill pipe is mitigated due to the inflow/outflow of hollow spheres,and the temperature drop of the fluid in the annulus also decreases.In addition,a lower separation efficiency of the device,a shallower installation depth and a smaller circulating displacement tend to increase the temperature near the bottom of the annulus,thereby helping to reduce the hydrate generation area and playing a positive role in the prevention and control of hydrates in deepwater drilling.

关键词： Multi-gradient drilling wellbore temperature hydrate separate injection device variable mass

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