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Mechanistic insight into the synergy between nickel single atoms and nanoparticles on N-doped carbon for electroreduction of CO2

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Journal of Energy Chemistry 2025年第1期100卷 327-336页

作者： Mingdong Sun Wenwen Guan Cailing Chen Chao Wu Xiaoling Liu Biao Meng Tao Chen Yu Han Jun Wang Shibo Xi Yu Zhou State Key Laboratory of Materials-Oriented Chemical Engineering College of Chemical Engineering Nanjing Tech University Advanced Membranes and Porous Materials Center Physical Sciences and Engineering Division King Abdullah University of Science and Technology Institute of Sustainability for Chemicals Energy and Environment A*STAR (Agency for Science Technology and Research) College of Materials Science and Engineering Sichuan University

The synergy of single atoms （SAs） and nanoparticles （NPs） has demonstrated great potential in promoting the electrocatalytic carbon dioxide reduction reaction （CO2RR）;however,the rationalization of the SAs/NPs proportion remains one challenge for the catalyst ***,a Ni2+-loaded porous poly（ionic liquids）(PIL) precursor synthesized through the free radical self-polymerization of the ionic liquid monomer,1-allyl-3-vinylimidazolium chloride,was pyrolyzed to prepare the Ni,N co-doped carbon materials,in which the proportion of Ni SAs and NPs could be facilely modulated by controlling the annealing *** catalyst Ni-NC-1000 with a moderate proportion of Ni SAs and NPs exhibited high efficiency in the electrocatalytic conversion of CO2into *** Ni K-edge X-ray absorption near-edge structure （XANES） spectra and theoretical calculations were conducted to gain insight into the synergy of Ni SAs and *** charge transfer from Ni NPs to the surrounding carbon layer and then to the Ni SAs resulted in the electron-enriched Ni SAs active *** the electroreduction of CO2,the coexistence of Ni SAs and NPs strengthened the CO2activation and the affinity towards the key intermediate of*COOH,lowering the free energy for the potential-determining*CO2→*COOH step,and therefore promoted the catalysis efficiency.

关键词： Single atom catalyst Synergy effect Carbon catalyst Electrocatalysis

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Transport mechanism in chemically reactive hybrid nanofluid flow containing gyrotactic micro-organisms over a curved oscillatory surface

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Applied Mathematics and Mechanics(English Edition) 2025年第1期46卷 177-192页

作者： M.NAVEED M.IMRAN T.ASGHAR Z.ABBAS Department of Mathematics Division of Science and TechnologyUniversity of Education Department of Mathematics The Islamia University of Bahawalpur

This paper examines the transport analysis, including both heat transfer and mass transfer, in hybrid nanofluid flow containing gyrotactic microorganisms towards a curved oscillatory surface. The influence of magnetic fields is also inspected in terms of their physical characteristics. To depict the phenomena of transport, modified versions of both Fick's and Fourier's laws are used. Additionally, the characteristics of both heterogeneous and homogeneous chemical reactions are also incorporated. Utilizing a curvilinear coordinate system, the flow problem is formulated as partial differential equations(PDEs)for momentum, concentration, microorganism field, and energy. An analytical solution to the obtained flow equations is achieved utilizing the homotopy analysis method(HAM).The effects of significant flow parameters on the pressure and microorganism fields, velocity, oscillation velocity, concentration, and temperature distributions are shown via graphs. Furthermore, the variations in skin friction, mass transfer rate, heat transfer rate, and local motile number due to different involved parameters are presented in tables and are analyzed in detail. Graphical results indicate that the curves of velocity and temperature fields are enhanced as the values of the solid volume fraction variables *** is also verified that the concentration rate field decreases as the values of the homogeneous reaction strength parameter and the radius of curvature parameter increase, and it increases with the Schmidt number and the heterogeneous reaction strength *** outcomes show a favorable response of the motile number to advanced values of the Peclet number, the Schmidt number, the microorganism difference parameter, and the bio-convective Lewis number.

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Ferroelectric materials for vibrational energy harvesting

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Science China(Technological Sciences) 2016年第7期59卷 1012-1022页

作者： SONG JunDong WANG Jin division of Energy and environment in Graduate School at Shenzhen Tsinghua University

Energy harvesting is an appealing technology that makes use of the ambient energy which is otherwise wasted. Piezoelectric materials directly convert the elastic energy to the electric energy, and thus have a great advantage in scavenging vibrational energy for simplicity in device structure with relatively high power density. This paper provides an overview on the research of piezoelectric materials in energy harvesting in recent decades, from basics of piezoelectricity and working principle of energy harvesting with piezoelectric materials, to the progress of development of high-performance piezoelectrics including ceramics, single crystals and polymers, then to experimental attempts on the device fabrication and optimization, finally to perspective applications of piezoelectric energy harvesting(PEH). The criteria for selection of materials for PEH applications are introduced. Not only the figure of merit but also maximum allowable stress of materials are taken into account in the evaluation of their potential in achieving high energy density and output power density. The influence of the device configuration on the performance is also acknowledged and discussed. The magnitude and distribution of induced stress in the piezoelectric unit upon excitation by the vibration source play an important role in determining the output power density and can be tuned via proper design of device configuration without changing its resonant frequency. Approaches to address the issue of frequency match accompanying with the resonant mode are illustrated with literature examples. Usage of PEH devices can be extended to a variety of vibration sources in everyday life as well as in nature. Some appealing applications of PEH, such as in implantable and wearable devices, are reviewed.

关键词： energy harvesting ferroelectric materials piezoelectricity figure of merit applications

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Transfer of CrylAc and Cry2Ab proteins from genetically engineered Bt cotton to herbivores and predators

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Insect Science 2018年第5期25卷 823-832页

作者： Michael Meissle Jorg Romeis Agroscope Research division Agroecology and environment Zurich Switzerland

With the cukivation of Bt cotton, the produced insecticidal Cry proteins are ingested by herbivores and potentially transferred along the food chain to natural enemies, such as predators. In laboratory experiments with Bollgard II cotton, concentrations of CrylAc and Cry2Ab were measured in Lepidoptera larvae （Spodoptera littoralis, Hello- this virescens）, plant bugs （Euschistus heros）, aphids （Aphis gossypii）, whiteflies （Bemisia tabaci）, thrips （ Thrips tabaci, Frankliniella occidentalis）, and spider mites （Tetranychus urticae）. Tritrophic experiments were conducted with caterpillars ofS. littoralis as prey and larvae of ladybird beetles （Harmonia axyridis, Adalia bipunctata） and lacewings （Chrysop- erla carnea） as predators. Immunological measurements （ELISA） indicated that herbivores feeding on Bt cotton contained 5%-50% of the Bt protein concentrations in leaves except whiteflies and aphids, which contained no or only traces of Bt protein, and spider mites, which contained 7 times more Cry 1Ac than leaves. Similarly, predators contained 1%-30% of the Cry protein concentration in prey. For the nontarget risk assessment, this indicates that Bt protein concentrations decrease considerably from one trophic level to the next in the food web, except for spider mites that contain Bt protein concentrations higher than those measured in the leaves. Exposure of phloem sucking hemipterans is negligible.

关键词： arthropod food web Bacillus thuringiensis Bt cotton Cry protein ELISA transgenic plants

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Geometrical and Geotechnical Characteristics of Landslides in Korea under Various Geological Conditions

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Journal of Mountain Science 2015年第5期12卷 1267-1280页

作者： Kyeong-Su KIM Young-Suk SONG Geologic environment division Korea Institute of Geoscience and Mineral Resources

The goal of this study is to determine the geometrical and geotechnical characteristics of landslides under various geological conditions using detailed field surveys, laboratory soil tests and precipitation records. Three study areas are selected to consider different rocks, including gneiss in Jangheung, granite in Sangju and sedimentary rocks in Pohang, South Korea. Many landslides have occurred in these three areas during the rainy *** records indicate that landslides occurring in the gneiss area of Jangheung and granite area of Sangju may be influenced by the hourly rainfall intensity rather than cumulative ***, landslides occurring in the sedimentary rock area of Pohang may be influenced by hourly rainfall intensity and cumulative rainfall. To investigate the factors that influence these types of landslides, a detailed landslide survey was performed and a series of laboratory soil tests were *** to the detailed field survey, most landslides occurred on the flanks of mountain slopes, and the slope inclination where they occurred mostly ranged from 26 to 30 degrees, regardless of the geological conditions. The landslide in the gneiss area of Jangheung is larger than the landslides in the granite area of Sangju and sedimentary rock area of ***, the landslide in the sedimentary rock area is shorter and shallower than the landslides in the gneiss and granite areas. Thus, the shape and size of the landslide are clearly related to the geological conditions. According to the integrated soil property and landslide occurrence analyses results, the average dry unit weight of the soils from the landslide sites is smaller than that of the soils obtained from the nonlandslide site. The average coefficient of permeability of soils obtained from the landslide sites is greater than that of soils obtained from the non-landslide sites with the same geology. These results indicate that the soils from the landslide site

关键词： Landslides Geological condition Geometrical characteristics Precipitation Soilproperties South Korea

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Treatment of tunnel wash waters-experiments with organic sorbent materials. PartⅡ: Removal of toxic metals

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Journal of environmental Sciences 2008年第8期20卷 1042-1045页

作者： PARUCH Adam M ROSETH Roger Bioforsk-the Norwegian Institute for Agricultural and environmental Research Soil and Environment Division

In the first part of the article, the column and the bag experiments concerning removal of polycyclic aromatic hydrocarbons (PAHs) and nonpolar oil (NPO) from tunnel wash waters using organic sorbent materials have been described. This part presents the results of removal of toxic metals. The metals of concern (Al, As, Cd, Cr, Cu, Fe, Pb, Mo, Ni, and Zn) were selected based on the priority toxicant pollutants defined in surface water quality criteria. Concentrations of these metals in the collected effluent...

关键词： electrostatic filters reduction level sorbents tunnel toxic metals treatment efficiency wash water

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Creation of passivated Nb/N p-n co-doped ZnO nanoparticles and their enhanced photocatalytic performance under visible light illumination

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Journal of Materials Science & Technology 2019年第4期35卷 610-614页

作者： Shuang Gao Weiyi Yang Jun Xiao Bo Li Qi Li division of Energy and environment Graduate School at ShenzhenTsinghua University environment Functional Materials division Shenyang National Laboratory for Materials ScienceInstitute of Metal ResearchChinese Academy of Sciences

Passivated niobium/nitrogen(Nb-N) p-n co-doped zinc oxide nanoparticles were created by a simple precipitation process with in-situ self-formed NaCl "cage" to confine the nanoparticle growth followed by the heat treatment in a flow of ammonia gas. Enhanced optical absorbance into the visible light region was observed in the Nb/N co-doped ZnO nanoparticle photocatalyst due to the Nb/N co-doping *** demonstrated a largely enhanced photocatalytic performance in the disinfection of Escherichia coli bacteria under visible light illumination, which could be attributed to the passivated co-doping of NbN to suppress the photogenerated charge carrier recombination on dopants. This robust approach for passivated p-n co-doping may also be applied to other material systems for a wide range of technical applications.

关键词： Zinc oxide Nanoparticles Passivated Nb/N p-n Co-doping Photocatalyst Visible light

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Kinetics of Al Evaporation from Liquid U-Al Alloys in Vacuum Induction Melting

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Journal of Materials Science & Technology 2015年第4期31卷 423-426页

作者： Y.J.Duan B.Chen Y.C.Ma K.Liu Materials for Special environment division Institute of Metal ResearchChinese Academy of Sciences

A research on kinetics of Al evaporation from liquid U—Al alloys was made in a vacuum induction melting（VIM） furnace at 1673—1843 *** evaporation rate of Al was found to be first order with respect to Al content in the *** overall mass transfer coefficient of Al was determined and it was found that the evaporation rate of Al increased with increasing *** apparent activation energy of Al evaporation at 1673-1843 K was 171.5 kJ *** value of mass transfer coefficient of Al in the liquid phase was estimated to be 3.77 × 10-6,7.41×10-6,and 9.40 × 10-6m s-1at 1673,1753,and 1843 K,***,rate determining steps were discussed and it was concluded that the evaporation rate of Al is mainly controlled by liquid phase mass transfer.

关键词： Al evaporation Kinetics Liquid U-Al alloys Mass tr

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Laser processed micro-supercapacitors based on carbon nanotubes/manganese dioxide nanosheets composite with excellent electrochemical performance and aesthetic property

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Chinese Chemical Letters 2018年第4期29卷 592-595页

作者： Lu Shi Yang Wang Peichao Zou Xuanyu Wang Dang Wu Ronghe Wang Cheng Yang division of Energy and environment Graduate School at Shenzhen Tsinghua University

Micro-supercapacitors with excellent electrochemical performance and aesthetic property are realized using the carbon nanotubes/manganese dioxide nanosheets（CNTs/δ-MnO2） composite as *** CNTs/d-MnO2 nanocomposite is excellently compatible with the slurry dispensing process for electrode fabrication, and thus is conducive for preparing thick electrode films, which exhibits a specific capacitance of 257 F/g with an electrode thickness of 13μm. By involving laser-scribing technique, the electrode film can be patterned with a high resolution and fabricated into a planar micro-supercapacitor,showing the maximum energy density of 6.83 mWh/cm^3 at the power density of 154.3 mW/cm^3, and maintained a value of 2.71 mWh/cm^3 at the maximum power density of 2557.5 mW/cm^3. Considering the versatility of the laser-scribing technical platform, the micro-supercapacitors fabricated in this way exhibit excellent aesthetic property and can cater to various miniaturized wearable electronic applications. This technology opens up opportunities for facile and scalable fabrication of high performance energy devices with shape diversity and a meaning of art.

关键词： Micro-supercapacitors MnO2 Slurry dispensing Laser Aesthetic property

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Genotoxicity of drinking water treated with different disinfectants and effects of disinfection conditions detected by umu-test

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Journal of environmental Sciences 2017年第6期29卷 36-44页

作者： Xuebiao Nie Wenjun Liu Liping Zhang Qing Liu division of Drinking Water Safety School of EnvironmentTsinghua UniversityBeijing 100084China

The genotoxieity of drinking water treated with 6 disinfection methods and the effects of disinfection conditions were investigated using the urea-test The pretreatment procedure of samples for the urea-test was optimized for drinking water analysis. The results of the urea-test were in good correlation with those of the Ames-test The genotoxicity and production of haloacetic acids （HAAs） were the highest for chlorinated samples. UV ＋ chloramination is the safest disinfection method from the aspects of genotoxicity, HAA production and inactivation effects. For chloramination, the effects of the mass ratio of C12 to N of chloramine on genotoxicity were also studied. The changes of genotoxicity were different from those of HAA production, which implied that HAA production cannot represent the genotoxic potential of water. The genotoxicity per chlorine decay of chlorination and chloramination had similar trends, indicating that the reaction of organic matters and chlorine made a great contribution to the genotoxicity. The results of this study are of engineering significance for optimizing the operation of waterworks.

关键词： CenotoxicityDrinking waterChlorineUVDisinfectionumu-test

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