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Nano Research 2024年第7期17卷 5856-5862页

作者： Xingyu Liu Xue Yang Han Sun Zekai Yang Haijun Chen Tianjin Key Laboratory of Optoelectronic thin film Devices and Technology College of Electronic Information and Optical EngineeringNankai UniversityTianjin 300350China

Ammonia has garnered recognition as a zero-carbon fuel due to its high-density hydrogen storage capacity and its convenience for storage and *** address the challenges associated with the direct usage of ammonia,the development of NH_(3)-to-H_(2)conversion technologies has emerged as a promising and effective ***,we present for the first time that crystallized Sm_(2)O_(3−x)electrodes demonstrate high and stable electrocatalytic activities,including N_(2)evolution rate and Faradaic efficiency,for ammonia electrolysis in a non-aqueous *** was observed that Sm^(2+)ions in samarium oxide play an indispensable role in the ammonia electrooxidation reaction on the ***,the mechanism of ammonia electrooxidation has also been elucidated,laying the foundation for a better understanding of the relationship between local structure and electrochemical properties in order to facilitate research on Pt-free electrocatalysts for the electrolysis of ammonia into H_(2).

关键词： NH_(3)-to-N_(2)conversion ammonia electrooxidation reaction ammonia electrolysis non-aqueous electrolyte samarium oxide

A novel silver-doped nickel oxide hole-selective contact for crystalline silicon heterojunction solar cells

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Frontiers of Chemical Science and Engineering 2024年第2期18卷 93-101页

作者： Junfeng Zhao Xudong Yang Zhongqing Zhang Shengpeng Xie Fangfang Liu Anjun Han Zhengxin Liu Yun Sun Wei Liu Key Laboratory of Photoelectronic thin film Devices and Technology of Tianjin Engineering Research Center of Thin Film Photoelectronic TechnologyInstitute of Photoelectronic Thin Film Devices and Technology of Nankai University(Ministry of Education)Tianjin 300350China Shanghai Institute of Microsystem and Information Technology Chinese Academy of SciencesShanghai 201800China

Based on its band alignment,p-type nickel oxide(NiO_(x))is an excellent candidate material for hole transport layers in crystalline silicon heterojunction solar cells,as it has a smallΔEV and largeΔEC with crystalline ***,to overcome the poor hole selectivity of stoichiometric NiO_(x) due to its low carrier concentration and conductivity,silver-doped nickel oxide(NiO_(x):Ag)hole transport layers with high carrier concentrations were prepared by co-sputtering high-purity silver sheets and pure NiO_(x) *** improved electrical conductivity of NiO_(x) was attributed to the holes generated by the Ag^(+)substituents for Ni^(2+),and moreover,the introduction of Ag^(+)also increased the amount of Ni^(3+)present,both of which increased the carrier concentration in NiO_(x).Ag^(+)doping also reduced the c-Si/NiO_(x) contact resistivity and improved the hole-selective contact with NiO_(x).Furthermore,the problems of particle clusters and interfacial defects on the surfaces of NiO_(x):Ag films were solved by UV-ozone oxidation and high-temperature annealing,which facilitated separation and transport of carriers at the c-Si/NiO_(x) *** constructed c-Si/NiO_(x):Ag solar cell exhibited an increase in open-circuit voltage from 490 to 596 mV and achieved a conversion efficiency of 14.4%.

关键词： band alignment nickel oxide hole transport layer silver-doped nickel oxide UV-ozone

Promoted monolithic perovskite/organic tandem solar cells through elaborate manipulation of light transmission and carrier tunneling in interconnect junction

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Science China Chemistry 2024年第9期67卷 3131-3139页

作者： Rongbo Wang Jiawei Zhang Juntao Zhao Ya Wang Yi Ding Ying Zhao Xiaodan Zhang Guofu Hou Institute of Photoelectronic thin film Devices and Technology Renewable Energy Conversion and Storage CenterSolar Energy Conversion CenterNankai UniversityTianjin 300350China Key Laboratory of Photoelectronic thin film Devices and Technology of Tianjin Tianjin 300350China Engineering Research center of thin film Photoelectronic Technology of Ministry of Education Tianjin 300350China State Key Laboratory of Photovoltaic Materials and Solar Cells Tianjin 300350China

Monolithic perovskite/organic tandem solar cells(TSCs)have emerged as promising thin film solar *** is recognized that interconnect junction plays a pivotal role in tandem ***,wide bandgap Cs_(0.25)FA_(0.75)Pb(I_(0.6)Br_(0.4))_(3)perovskite top-cell and narrow bandgap PM6:Y6:PC_(61)BM ternary organic bottom-cell were integrated in this study with several kinds of thin metal interconnect layers,which provides feasibility to elaborately manipulate light transmission and carrier tunneling process in interconnect *** is confirmed that,in comparison with Au,employing an Ag interconnect layer elevates integrated transmittance of light in longer wavelength regions,mainly because of the alleviated screening effect with a lower free electron concentration,which offers sufficient light harvest for the ***,established energy barriers with moderate height afford convenient extraction and recombination for both holes and ***,the performance of TSCs is promoted ***,an innovative Ag/Au double interconnect layer is proposed accordingly,which can preserve exceptional conductivity and light transmission and further reduce barrier height,especially for hole tunneling,by optimizing the band alignment between the interconnect layer and ***,the monolithic perovskite/organic TSC with a striking efficiency of 23.26% is *** a word,this study can pave a general approach toward high-performance TSCs integration.

关键词： tandem solar cells band alignment perovskite organic solar cells interconnect junction

Co-electrolysis of ethylene glycol and carbon dioxide for formate synthesis

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Science China Chemistry 2024年第5期67卷 1539-1544页

作者： Dongfeng Du Fusong Kang Shiru Yang Bin Shao Jingshan Luo Institute of Photoelectronic thin film Devices and Technology State Key Laboratory of Photovoltaic Materials and CellsKey Laboratory of Photoelectronic Thin Film Devices and Technology of TianjinMinistry of Education Engineering Research Center of Thin Film Photoelectronic TechnologyNankai UniversityTianjin 300350China Haihe Laboratory of Sustainable Chemical Transformations Tianjin 300192China Frontiers Science center for New Organic Matter Nankai UniversityTianjin 300071China College of Electronic Information and optical Engineering Tianjin Key Laboratory of Optoelectronic Sensor and Sensing Network TechnologyNankai UniversityTianjin 300350China

Co-electrolysis of waste plastics and carbon dioxide(CO_(2)) into value-added chemicals or fuels is a promising pathway for a sustainable society, but efficient and selective conversion remains a challenge. Herein, a gold-mediated nickel hydroxide(Au/Ni(OH)_(2)) is developed to oxidize waste plastic-derived ethylene glycol(EG) into formate. In-situ electrochemical experiments and theoretical results reveal that the introduction of Au favors the redox properties and EG adsorption behavior of Ni(OH)_(2). The Au/Ni(OH)_(2) catalyst shows an excellent formate selectivity of >90% at high current densities of above 100 m A cm^(-2). When coupled with sputtered bismuth(Bi) cathode for CO_(2) reduction, a high formate Faradic efficiency(FE) of 188.2% at 200 m A cm^(-2)and a good formate productivity of 7.33 mmol m^(-2)s^(-1)at 10 A are obtained in a flow cell and a zero-gap membrane electrode assembly(MEA) cell, respectively. This work demonstrates a promising strategy to convert waste plastics and CO_(2) into valuable products.

关键词： waste plastic upcycling ethylene glycol oxidation carbon dioxide reduction electrocatalysis formate synthesis

Elucidating the structure-activity relationship of Cu-Ag bimetallic catalysts for electrochemical CO_(2) reduction

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Journal of Energy Chemistry 2024年第6期93卷 345-351,I0009页

作者： Qining Huang Lili Wan Qingxuan Ren Jingshan Luo Institute of Photoelectronic thin film Devices and Technology State Key Laboratory of Photovoltaic Materials and CellsKey Laboratory of Photoelectronic Thin Film Devices and Technology of TianjinMinistry of Education Engineering Research Center of Thin Film Photoelectronic TechnologyNankai UniversityTianjin 300350China Frontiers Science center for New Organic Matter Nankai UniversityTianjin 300071China Haihe Laboratory of Sustainable Chemical Transformations Tianjin 300192China

Developing bimetallic catalysts is an effective strategy for enhancing the activity and selectivity of electrochemical CO_(2) reduction reactions,where understanding the structure-activity relationship is essential for catalyst ***,we prepared two Cu-Ag bimetallic catalysts with Ag nanoparticles attached to the top or the bottom of Cu *** tested in a flow cell,the Cu-Ag catalyst with Ag nanoparticles on the bottom achieved a faradaic efficiency of 54%for ethylene production,much higher than the catalyst with Ag nanoparticles on the *** catalysts were further studied in the H-cell and zero-gap MEA *** was found that placing the two metals in the intensified reaction zone is crucial to triggering the tandem reaction of bimetallic *** work elucidates the structure-activity relationship of bimetallic catalysts for CO_(2) reduction and demonstrates the importance of considering both catalyst structures and cell characteristics to achieve high activity and selectivity.

关键词： Electrochemical CO_(2)reduction Bimetallic catalyst Cu-Ag Structure-activity relationship

A neuromorphic device mimicking synaptic plasticity under different body fluid K^(+) homeostasis for artificial reflex path construction and pattern recognition

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Fundamental Research 2024年第2期4卷 353-361页

作者： Lu Yang Yao Ni Chengpeng Jiang Lu Liu Song Zhang Jiaqi Liu Lin Sun Wentao Xu Institute of Photoelectronic thin film Devices and Technology Key Laboratory of Optoelectronic Thin Film Devices and Technology of TianjinEngineering Research Center of Thin Film Photoelectronic TechnologyMinistry of EducationNankai UniversityTianjin 300350China Shenzhen Research Institute of Nankai University Shenzhen 518000China

The ionic environment of body fluids influences nervous functions for maintaining homeostasis in organisms and ensures normal perceptual abilities and reflex *** reflex activities,such as limb movements,are closely associated with potassium ions(K+).In this study,we developed artificial synaptic devices based on ion concentration-adjustable gels for emulating various synaptic plasticities under different K+concentrations in body *** addition to performing essential synaptic functions,potential applications in information processing and associative learning using short-and long-term plasticity realized using ion concentration-adjustable gels are *** synaptic devices can be used for constructing an artificial neural pathway that controls artificial muscle reflex activities and can be used for image pattern *** tests show a strong relationship with ion *** devices could be applied to neuromorphic robots and human-machine interfaces.

关键词： Nervous regulation Artificial synaptic device Ion gel Ion homeostasis Artificial reflex pathway

Polyethylene imine functionalized porous carbon framework for selective nitrogen dioxide sensing with smartphone communication

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Chinese Chemical Letters 2024年第9期35卷 432-436页

作者： Xiaxia Xing Xiaoyu Chen Zhenxu Li Xinhua Zhao Yingying Tian Xiaoyan Lang Dachi Yang Tianjin Key Laboratory of Optoelectronic Sensor and Sensing Network Technology Engineering Research Center of Thin Film Optoelectronics TechnologyMinistry of Education and Department of ElectronicsCollege of Electronic Information and Optical EngineeringNankai UniversityTianjin 300350China

Highly selective and remotely communicable nitrogen dioxide(NO_(2))sensing may contribute to future Internet of things in environmental ***,room-temperature NO_(2)sensing materials such as carbon materials is still less than satisfactory due to their insensitive interaction with target ***,polyethylene imine functionalized three-dimensional(3D)carbon framework(PEI/C framework)has been developed for enhanced selective NO_(2)sensing,via combined template synthesis and subsequent ***,the 3D PEI/C framework is observed porous shape with irregular ***,the response of C framework to NO_(2)increases while those of interfering gases decrease after being functionalized with ***,the sensor prototypes show a 100 ppb-concentration detection limit at room ***,such excellent NO_(2)sensing is attributed to the large specific surface ratio of porous 3D PEI/C framework,in which PEI serves as an active layer for target NO_(2),while a passivated one for interfering ***,such PEI/C framework sensor prototype is simulated for NO_(2)sensing device and communicated with a smartphone,showing great potential in future intelligent environmental monitoring.

关键词： PEI/C framework Nitrogen dioxide sensing Enhanced selectivity Smartphone communication Practical monitoring simulation

Textured Perovskite/Silicon Tandem Solar Cells Achieving Over 30% Efficiency Promoted by 4-Fluorobenzylamine Hydroiodide

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Nano-Micro Letters 2024年第9期16卷 557-570页

作者： Jingjing Liu Biao Shi Qiaojing Xu Yucheng Li Yuxiang Li Pengfei Liu Zetong SunLi Xuejiao Wang Cong Sun Wei Han Diannan Li Sanlong Wang Dekun Zhang Guangwu Li Xiaona Du Ying Zhao Xiaodan Zhang Renewable Energy Conversion and Storage center Solar Energy Conversion CenterInstitute of Photoelectronic Thin Film Devices and TechnologyNankai UniversityTianjin 300350People’s Republic of China Key Laboratory of Photoelectronic thin film Devices and Technology of Tianjin Tianjin 300350People’s Republic of China Haihe Laboratory of Sustainable Chemical Transformations Tianjin 300192People’s Republic of China Engineering Research center of thin film Photoelectronic Technology of Ministry of Education Tianjin 300350People’s Republic of China Collaborative Innovation center of Chemical Science and Engineering(Tianjin) Tianjin 300072People’s Republic of China center of Single‑Molecule Sciences Institute of Modern OpticsTianjin Key Laboratory of Micro‑Scale Optical Information Science and TechnologyCollege of Electronic Information and Optical EngineeringNankai University38 Tongyan RoadJinnan DistrictTianjin 300350People’s Republic of China Shenzhen Research Institute of Nankai University 16Th FloorYantian Science and Technology BuildingHaishan StreetYantian DistrictShenzhen 518083People’s Republic of China

Monolithic textured perovskite/silicon tandem solar cells(TSCs)are expected to achieve maximum light capture at the lowest cost,potentially exhibiting the best power conversion ***,it is challenging to fabricate high-quality perovskite films and preferred crystal orientation on commercially textured silicon substrates with micrometersize ***,we introduced a bulky organic molecule(4-fluorobenzylamine hydroiodide(F-PMAI))as a perovskite *** is found that F-PMAI can retard the crystallization process of perovskite film through hydrogen bond interaction between F^(−)and FA^(+)and reduce(111)facet surface energy due to enhanced adsorption energy of F-PMAI on the(111)***,the bulky molecular is extruded to the bottom and top of perovskite film after crystal growth,which can passivate interface defects through strong interaction between F-PMA+and undercoordinated Pb^(2+)/I^(−).As a result,the additive facilitates the formation of large perovskite grains and(111)preferred orientation with a reduced trap-state density,thereby promoting charge carrier transportation,and enhancing device performance and *** perovskite/silicon TSCs achieved a champion efficiency of 30.05%based on a silicon thin film tunneling *** addition,the devices exhibit excellent longterm thermal and light stability without *** work provides an effective strategy for achieving efficient and stable TSCs.

关键词： Perovskite crystallization (111)preferred orientation Defect passivation Perovskite/silicon tandem solar cells

A new study on formation mechanism of ordered porous anodized metal oxides

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Rare Metals 2024年第10期43卷 5410-5418页

作者： Xi-Di Sun Xin Guo Jia-Han Zhang Jing Wu Yi Shi Hui-Yuan Sun Cao-Feng Pan Li-Jia Pan Collaborative Innovation center of Advanced Microstructures School of Electronic Science and EngineeringNanjing University College of Physics and Hebei Advanced thin film Laboratory Hebei Normal University Institute of Atomic Manufacturing Beihang University

The preparation of ordered porous metal oxide films by anodic oxidation is an efficient and simple preparation ***,there has been no unified explanation about the formation mechanism of the porous structure for many *** this paper,the relationship between the crystal structure of metals and the morphology of ordered porous metal oxide films is *** influence of the crystal structures of different metals on the optimal morphology of porous films is discussed.

关键词： Anodic oxidation

Two-dimensional precise figuring of 500 mm-long X-ray mirror using one-dimensional ion beam system

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Advances in Manufacturing 2024年第1期12卷 177-184页

作者： Qiu-Shi Huang Han-Dan Huang Qiao-Yu Wu Jun Yu Zhong Zhang Zhan-Shan Wang MOE Key Laboratory of Advanced Micro-Structured Materials Institute of Precision Optical Engineering(IPOE)School of Physics Science and EngineeringTongji UniversityShanghai200092People’s Republic of China Shanghai Professional Technical Service Platform for Full-Spectrum and High-Performance optical thin film Devices and Applications Tongji UniversityShanghai200092People’s Republic of China Shanghai Frontiers Science center of Digital Optics Tongji UniversityShanghai200092People’s Republic of China

In this study,a new method was developed to realize two-dimensional(2D)figure correction of grazing-incidence X-ray mirrors using a one-dimensional(1D)ion-beam figuring system.A mask of holes was specifically designed to generate removal functions at different widths and extend the figuring capability over a wide ***,a long mirror could be *** this method,the surface height root-mean-square(RMS)error of the center area of 484 mm×16 mm was reduced from 11.49 nm to 2.01 nm,and the 1D meridional RMS error reached 1.0 *** proposed method exhibits high precision and cost effectiveness for production of long X-ray mirrors.

关键词： Long-size mirrors Ion beam figuring Two-dimensional figure correction Mask