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Enhancing hydrogen evolution and oxidation kinetics through oxygen insertion into nickel lattice

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Journal of Energy Chemistry 2024年第8期95卷 529-539,I0012页

作者： Wanli Liang Xiyu Gong Jinchang Xu Zixuan Dan Fanyan Xie Hulei Yu Hao-Fan Wang Yanshuo Jin Hongjuan Wang Yonghai Cao Hui Meng Hao Yu School of Chemistry and Chemical Engineering South China University of TechnologyGuangzhou 510641GuangdongChina Siyuan Laboratory Guangzhou Key Laboratory of Vacuum Coating Technologies and New Energy MaterialsGuangdong Provincial Engineering Technology Research Center of Vacuum Coating Technologies and New Energy MaterialsGuangdong Provincial Key Laboratory of Optical Fiber Sensing and CommunicationsDepartment of PhysicsJinan UniversityGuangzhou 510632GuangdongChina GBA Branch of Aerospace Information Research Institute Chinese Academy of SciencesGuangzhou 510700GuangdongChina Instrumental Analysis&Research center Sun Yat-sen UniversityGuangzhou 510275GuangdongChina School of Materials Science and Engineering South China University of TechnologyGuangzhou 510641GuangdongChina

Nickel-based materials,including metallic Ni and Ni oxide,have been widely studied in the exploration of non-precious-metal hydrogen electrocatalysts,but neither pure Ni nor NiO is ideal for the hydrogen evolution reaction(HER)and hydrogen oxidation reaction(HOR).In this paper,an oxygen insertion strategy was applied on nickel to regulate its hydrogen electrocatalytic performance,and the oxygen-inserted nickel catalyst was successfully obtained with the assistance of tungsten dioxide support(denoted as O-Ni/WO_(2)).The partial insertion of oxygen in Ni maintains the face-centered cubic arrangement of Ni atoms,simultaneously expanding the lattice and increasing the lattice ***,the adsorption strength of^(*)H and^(*)OH on Ni is optimized,thus resulting in superior electrocatalytic performance of0-Ni/WO_(2)in alkaline HER/*** Tafel slope of O-Ni/WO_(2)@NF for HER is 56 mV dec^(-1),and the kinetic current density of O-Ni/WO_(2)for HOR reaches 4.85 mA cm^(-2),which is ahead of most currently reported *** proposed strategy of inserting an appropriate amount of anions into the metal lattice could provide more possibilities for the design of high-performance catalysts.

关键词： Hydrogen evolution Hydrogen oxidation Nickel Oxygen insertion Adsorption free energy

Black Phosphorus for Photonic Integrated Circuits

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Research 2024年第2期2023卷 339-353页

作者： Mingxin Zhang Lele Yang Xiaoxuan Wu Junjia Wang National Research center for optical Sensors/communications Integrated Networks School of Electronic Science and EngineeringSoutheast University2 SipailouNanjing 210096China

Black phosphorus gives several advantages and complementarities over other two-dimensional *** has drawn extensive interest owing to its relatively high carrier mobility,wide tunable bandgap,and in-plane anisotropy in recent *** manuscript briefly reviews the structure and physical properties of black phosphorus and targets on black phosphorus for photonic integrated *** of the applications are discussed including photodetection,optical modulation,light emission,and polarization *** recent progresses,associated challenges,and future potentials are covered.

关键词： polarization tunable phosphorus

Dynamic tunable LWIR achromatic metalens comprising all-As_(2)Se_(3) microstructures

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Chinese Optics Letters 2024年第6期22卷 191-195页

作者： Zhihao He Bingxia Wang Zhiang Qian Kongsi Zhou Xiang Shen Yungui Ma Laboratory of Infrared Materials and Devices The Research Institute of Advanced TechnologiesKey Laboratory of Photoelectric Detection Materials and Devices of Zhejiang ProvinceNingbo UniversityNingbo 315211China State Key Laboratory of Modern optical Instrumentation Centre for Optical and Electromagnetic ResearchCollege of Optical Science and EngineeringInternational Research Center for Advanced PhotonicsZhejiang UniversityHangzhou 310058China

In the field of long-wave infrared(LWIR) thermal imaging, vital for applications such as military surveillance and medical diagnostics, metalenses show immense potential for compact, lightweight, and low-power optical systems. However, to date, the development of LWIR broadband achromatic metalenses with dynamic tunable focus, which are suitable for both coaxial and off-axis applications, remains a large unexplored area. Herein, we have developed an extensive database of broadband achromatic all-As2Se3microstructure units for the LWIR range. Utilizing this database with the particle swarm optimization (PSO) algorithm, we have designed and demonstrated LWIR broadband achromatic metalenses capable of coaxial and off-axis focusing with three dynamic tunable states. This research may have potential applications for the design of compact, high-performance optical devices, including those with extreme depth-of-field and wide-angle imaging capabilities.

关键词： achromatic metalens long-wave infrared dynamic tunable focus

Physical Layer Encryption of OFDM-PON Based on Quantum Noise Stream Cipher with Polar Code

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China Communications 2024年第3期21卷 174-188页

作者： Xu Yinbo Gao Mingyi Zhu Huaqing Chen Bowen Xiang Lian Shen Gangxiang Jiangsu Engineering Research center of Novel optical Fiber Technology and Communication Network Suzhou Key Laboratory of Advanced Optical Communication Network Technologythe School of Electronic and Information EngineeringSoochow UniversityNo.1 Shizi StreetSuzhou 215006China

Orthogonal frequency division multiplexing passive optical network(OFDM-PON) has superior anti-dispersion property to operate in the C-band of fiber for increased optical power budget. However,the downlink broadcast exposes the physical layer vulnerable to the threat of illegal eavesdropping. Quantum noise stream cipher(QNSC) is a classic physical layer encryption method and well compatible with the OFDM-PON. Meanwhile, it is indispensable to exploit forward error correction(FEC) to control errors in data transmission. However, when QNSC and FEC are jointly coded, the redundant information becomes heavier and thus the code rate of the transmitted signal will be largely reduced. In this work, we propose a physical layer encryption scheme based on polar-code-assisted QNSC. In order to improve the code rate and security of the transmitted signal, we exploit chaotic sequences to yield the redundant bits and utilize the redundant information of the polar code to generate the higher-order encrypted signal in the QNSC scheme with the operation of the *** experimentally demonstrate the encrypted 16/64-QAM, 16/256-QAM, 16/1024-QAM, 16/4096-QAM QNSC signals transmitted over 30-km standard single mode fiber. For the transmitted 16/4096-QAM QNSC signal, compared with the conventional QNSC method, the proposed method increases the code rate from 0.1 to 0.32 with enhanced security.

关键词： physical layer encryption polar code quantum noise stream cipher

Self-confocal NIR-II fluorescence microscopy for multifunctional in vivo imaging

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Journal of Innovative optical Health Sciences 2024年第1期17卷 105-119页

作者： Jing Zhou Tianxiang Wu Runze Chen Liang Zhu Hequn Zhang Yifei Li Liying Chen Jun Qian State Key Laboratory of Modern optical Instrumentations Centre for Optical and Electromagnetic ResearchCollege of Optical Science and EngineeringInternational Research Center for Advanced PhotonicsZhejiang UniversityHangzhou 310058P.R.China Dr.Li Dak Sum&Yip Yio Chin center for Stem Cell and Regenerative Medicine Zhejiang UniversityHangzhou 310058P.R.China College of Biomedical Engineering and Instrument Science Interdisciplinary Institute of Neuroscience and Technology(ZIINT)Zhejiang UniversityHangzhou 310027P.R.China

Fluorescence imaging in the second near-infrared window(NIR-II,900–1880 nm)with less scattering background in biological tissues has been combined with the confocal microscopic system for achieving deep in vivo imaging with high spatial ***,the traditional NIR-IIfluorescence confocal microscope with separate excitation focus and detection pinhole makes it possess low confocal e±ciency,as well as di±cultly to *** types of upgraded NIR-IIfluorescence confocal microscopes,sharing the same pinhole by excitation and emission focus,leading to higher confocal e±ciency,are built in this *** type is-ber-pinhole-based confocal microscope applicable to CW laser *** is constructed forfluorescence intensity imaging with large depth,high stabilization and low cost,which could replace multiphotonfluorescence microscopy in some applications(e.g.,cerebrovascular and hepatocellular imaging).The other type is air-pinhole-based confocal microscope applicable to femtosecond(fs)laser *** can be employed not only for NIR-IIfluorescence intensity imaging,but also for multi-channelfluorescence lifetime imaging to recognize different structures with similarfluorescence ***,it can be facilely combined with multiphotonfluorescence microscopy.A single fs pulsed laser is utilized to achieve up-conversion(visible multiphotonfluorescence)and down-conversion(NIR-II one-photonfluorescence)excitation simultaneously,extending imaging spectral channels,and thus facilitates multi-structure and multi-functional observation.

关键词： Self-confocal fiber-pinhole air-pinhole multi-channe fluorescence lifetime imaging multi-color imaging

Diverse atomic structure configurations of metal-doped transition metal dichalcogenides for enhancing hydrogen evolution

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Nano Research 2024年第5期17卷 3586-3602页

作者： Longlu Wang Yuxin Zhang Chen Gu Haoxuan Yu Yanling Zhuang Zechao Zhuang College of Electronic and optical Engineering and College of Flexible Electronics(Future Technology) Jiangsu Province Engineering Research Center for Fabrication and Application of Special Optical Fiber Materials and DevicesNanjing University of Posts and TelecommunicationsNanjing 210023China Department of Chemical Engineering Columbia UniversityNew YorkNY 10027USA

Doping foreign metal atoms into the substrate of transition metal dichalcogenides(TMDs)enables the formation of diverse atomic structure configurations,including isolated atoms,chains,and ***,it is very important to reasonably control the atomic structure and determine the structure-activity relationship between the atomic configurations and the hydrogen evolution reaction(HER)*** numerous studies have indicated that doping can yield diverse atomic structure configurations,there remains an incomplete understanding of the relationship between atomic configurations within the lattice of TMDs and their ***,diverse atomic structure configurations of adsorptive doping,substitutional doping,and TMDs alloys are *** structure-activity relationship between different atomic configurations and HER performance can be determined by micro-nanostructure devices and density functional theory(DFT)*** diverse atomic structure configurations are of great significance for activating the inert basal plane of TMDs and improving the catalytic activity of ***,we have summarized the current challenges and future opportunities,offering new perspectives for the design of highly active and stable metal-doped TMDs catalysts.

关键词： transition metal dichalcogenides(TMDs) dopant effect diverse atomic structure configurations hydrogen evolution reaction(HER)

High performance and stable pure-blue quasi-2D perovskite light-emitting diodes by multifunctional zwitterionic passivation engineering

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Advanced Photonics 2024年第2期6卷 32-40页

作者： Chao Shen Shuyan Fang Jibin Zhang Xiangfei Liang Chenhui Su Jian Qing Wanzhu Cai Yunhan Luo Renqiang Yang Lintao Hou Jinan University College of Physics and Optical Engineering Guangdong Provincial Engineering Technology Research Center of Vacuum Coating Technologies and New Energy Materials Guangzhou Key Laboratory of Vacuum Coating Technologies and New Energy Materials Jinan University College of Physics and Optical Engineering Guangdong Provincial Key Laboratory of Optical Fiber Sensing and Communications Zhengzhou University School of Physics and Microelectronics Key Laboratory of Materials Physics of Ministry of Education Jinan University Key Laboratory of Optoelectronic Information and Sensing Technologies of Guangdong Higher Education Institutes Jianghan University School of Optoelectronic Materials and Technology Key Laboratory of Optoelectronic Chemical Materials and Devices of Ministry of Education

Despite the rapid advances of red and green perovskite light-emitting diodes（Pe LEDs）, achieving high brightness with high external quantum efficiency（EQE） remains a challenge for the pure-blue Pe LEDs,which greatly hinders their practical applications, such as white-light illumination and in optical communication as a high-speed and low-loss light source. Herein, we report a high-performance pure-blue Pe LED based on mixed-halide quasi-2D perovskites incorporated with a zwitterionic molecule of 3-（benzyldimethylammonio）propanesulfonate（3-BAS）. Experimental and density functional theory analysis reveals that 3-BAS can simultaneously eliminate non-radiative recombination loss, suppress halide migration, and regulate phase distribution for smoothing energy transfer in the mixed-halide quasi-2D perovskites, leading to the final perovskites with high photoluminescence quantum yield and robust spectrum stability. Thus, the highperformance pure-blue Pe LED with a recorded brightness with 1806 cd m;-2;and a relative higher EQE of 9.25% is achieved, which is successfully demonstrated in a visible light communication system for voice signal transmission. We pave the way for achieving highly efficient pure-blue Pe LEDs with great application potential in future optical communication networks.

关键词： pure-blue PeLEDs quasi-2D perovskite zwitterionic additive visible light communication

An isolated symmetrical 2T2R cell enabling high precision and high density for RRAM-based in-memory computing

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Science China(Information Sciences) 2024年第5期67卷 287-294页

作者： Yaotian LING Zongwei WANG Yuhang YANG Lin BAO Shengyu BAO Qishen WANG Yimao CAI Ru HUANG School of Integrated Circuits Beijing Advanced Innovation Center for Integrated Circuits Peking University State Key Laboratory of Information Photonics and optical Communications Beijing University of Posts and Telecommunications

In-memory computing(IMC), leveraging emerging memories, holds significant promise in overcoming memory limitations and improving energy efficiency. However, the prevailing IMC array structure based on serially connected transistors and memory cells(1T1R/2T2R), along with the signed weight mapping scheme, can lead to asymmetrical weight sensing issues(AWS) due to electrical asymmetry within the1T1R/2T2R structure, particularly in highly scaled cells where the transistor's resistance becomes significant. In this paper, we propose and fabricate an electrically symmetric memory cell based on a physically isolated 2T2R structure for IMC. This design aims to enhance the precision and density of RRAM-based IMC arrays. The 2T2R cells are manufactured using the back-end-of-line(BEOL) process of a commercial40 nm technology platform. The feasibility of this design is verified through measured and simulated results,showcasing its capability to address the issue of AWS. Compared to conventional 2T2R cells, this design achieves a considerably smaller transistor footprint without compromising accuracy, while also improving integration density by 42.2%. These innovative memory cell advancements have the potential to further advance high-energy-efficient IMC technology.

关键词： RRAM 2T2R multi-level storage weight asymmetry in-memory computing

Structure and defect dual-engineering of cobalt oxides for lowtemperature Zn-air batteries

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Nano Research 2024年第5期17卷 4108-4117页

作者： Hang Lei Zhuowen Huangfu Liangjun Chen Xuelin Yang Zilong Wang Wenjie Mai Hubei Provincial Collaborative Innovation center for New Energy Microgrid College of Electrical Engineering&New EnergyChina Three Gorges UniversityYichang 443002China Siyuan Laboratory Guangdong Provincial Engineering Technology Research Center of Vacuum Coating Technologies and New Energy MaterialsDepartment of PhysicsJinan UniversityGuangzhou 510632China

The exploration of bifunctional electrocatalysts with high catalytic activity and long-term durability for low-temperature Zn-air batteries(ZABs)is an ongoing ***,quintet-shelled hollow spheres,P-doped multi-layer Co_(3)O_(4)(PM-Co_(3)O_(4)),with enriched oxygen vacancies are prepared by thermally induced mass relocation and a simple phosphating *** advanced characterizations reveal P anion-induced effects on internal electronic structure and local coordination *** finite element method elucidates that the complex multi-layer spherical nanostructure is conducive to the transport and diffusion of OH-and O_(2).Benefiting from its unique structural features and abundant oxygen vacancies,the well-designed PM-Co_(3)O_(4) presents small reversible oxygen overpotential for catalyzing oxygen reduction/evolution ***,the fabricated low-temperature ZABs based on PM-Co_(3)O_(4) as air-cathode exhibit high power density(20.8 mW·cm^(-2))and long-term stability(over 600 cycles)at the ultra-low temperature of-40℃,outperforming state-of-art Pt/C+IrO_(2)-based ***,the dynamic evolution mechanism of cobalt oxide catalysts during ZAB operation is *** work provides a guideline to design efficient electrocatalysts with regulated electronic configurations and exquisite nano-/microstructures for ZABs under extreme working conditions.

关键词： Zn-air batteries electrocatalysts low temperature hollow spheres oxygen vacancies