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Bioinspired smart dual-layer hydrogels system with synchronous solar and thermal radiation modulation for energy-saving all-season temperature regulation

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Journal of Energy Chemistry 2025年第2期101卷 175-190页

作者： Meng-Chen Huang Chao-Hua Xue Zhongxue Bai Jun Cheng Yong-Gang Wu Chao-Qun Ma Li Wan Long Xie Hui-Di Wang Bing-Ying Liu Xiao-Jing Guo College of Bioresources Chemical and Materials Engineering Shaanxi University of Science & Technology School of Manufacture Science and Engineering Key Laboratory of Testing Technology for Manufacturing Process Ministry of Education Southwest University of Science and Technology School of Life Science and Engineering Southwest University of Science and Technology northwest institute for nonferrous metal research Shaanxi Key Laboratory of Biomedical Metal Materials

All-season thermal management with zero energy consumption and emissions is more crucial to global decarbonization over traditional energy-intensive cooling/heating ***,the static single thermal management for cooling or heating fails to self-regulate the temperature in dynamic seasonal temperature ***,inspired by the dual-temperature regulation function of the fur color changes on the backs and abdomens of penguins,a smart thermal management composite hydrogel(PNA@H-PM Gel) system was subtly created though an "on-demand" dual-layer structure design *** PNA@H-PM Gel system features synchronous solar and thermal radiation modulation as well as tunable phase transition temperatures to meet the variable seasonal thermal requirements and energy-saving demands via self-adaptive radiative cooling and solar heating ***,this system demonstrates superb modulations of both the solar reflectance(ΔR=0.74) and thermal emissivity(ΔE=0.52) in response to ambient temperature changes,highlighting efficient temperature regulation with average radiative cooling and solar heating effects of 9.6℃ in summer and 6.1℃ in winter,***,compared to standard building baselines,the PNA@H-PM Gel presents a more substantial energy-saving cooling/heating potentials for energy-efficient buildings across various regions and *** novel solution,inspired by penguins in the real world,will offer a fresh approach for producing intelligent,energy-saving thermal management materials,and serve for temperature regulation under dynamic climate conditions and even throughout all seasons.

关键词： Energy-saving Radiative cooling Self-adaptive thermal management Spectral modulation Thermochromic hydrogel

Effects of Cerium-Rich Rare Earth and Al-Ti-B Composite Addition on Microstructure and Mechanical Properties of Al-Mg-Si Alloys

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稀有金属材料与工程 2025年第1期54卷 50-61页

作者： Chong Yufan Du Zhaoxin Gong Tianhao Sun Baoan Pan Zheru Qi Lele Xie Chengcheng Cheng Jun School of Materials Science and Engineering Inner Mongolia University of TechnologyHohhot 010051China institute of Physics Chinese Academy of SciencesBeijing 100190China northwest institute for nonferrous metal research Xi'an 710016China

Modification of 6061 aluminum alloy was conducted through composite addition of cerium-rich rare earths and *** show that the composite addition of Al-Ti-B and Ce/La element at a specific ratio notably promotes the refinement of the alloy's *** and La elements are combined with Si and other elements to form rare earth phases,improving the morphology and distribution of precipitates and mitigating the adverse effects ofβ-Fe phases on the microstructure and mechanical properties of ***,excessive rare earth content poses challenges;it not only leads to a decrease in Mg-Si strengthening phase by binding with Si but also promotes the formation of larger or numerous rare earth phases that may act as initiation points for cracks,thereby impeding the improvement of the structure and performance of *** composite addition of cerium-rich rare earths and Al-Ti-B not only preserves the strength of the alloy but also significantly enhances the plasticity of the 6061 as-cast *** a composite addition ratio of Al-Ti-B:RE=2:1,the newly developed 6061-RE aluminum alloy exhibits increased average elongation by 50%and 45%in its as-cast and homogenized states,respectively,compared to the baseline 6061 alloy,facilitating subsequent deformation *** solution treatment at 540℃for 1 h and aging at 180℃for 5 h,the average ultimate tensile strength and yield strength of 6061-RE alloys reach 313.2 and 283.1 MPa,increased by 12.3%and 14.5%compared with those of the original alloy,respectively,and the average elongation is improved by 41%.

关键词： rare earth alloy Al-Mg-Si alloy cerium-rich rare earth mechanical property microstructure

A machine learning method approach for designing novel high strength and plasticity metastable β titanium alloys

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Progress in Natural Science:Materials International 2025年第01期 156-165页

作者： Zhiduo Liu Haoyu Zhang Shuai Zhang Jun Cheng Yixuan He Ge Zhou Jiawei Liu Suping Song Lijia Chen School of Materials Science and Engineering Shenyang University of Technology Shenyang Key Laboratory of Advanced Structural Materials and Applications Shenyang University of Technology northwest institute for nonferrous metal research Shaanxi Key Laboratory of Biomedical Metal Materials State Key Laboratory of Solidification Processing Northwestern Polytechnical University Ansteel Group Automation Co. Ltd

In order to improve efficiency and reduce costs, four machine learning models were established for the design of metastable β titanium alloys, including the Adaboost model, the LightGBM model, the Voting model, and the Stacking model. The accuracy of these models was evaluated, and all models exhibited excellent accuracy for tensile strength, yield strength, and elongation. The values of R-squared coefficients（R2） all greater than *** them, the LightGBM model showed the highest accuracy, with relatively smallest values of mean absolute error（MAE） and root mean square error（RMSE） and relatively largest value of R2. To further verify the accuracy of the model, a metastable β titanium alloy Ti-5.5Cr-5Al-4Mo-3Nb-2Zr was designed by the LightGBM model. The predicted values of the alloy's tensile strength, yield strength, and elongation under three heat treatment processes were in high agreement with the experimental values. The alloy exhibited optimal strength-plasticity matching after undergoing a solution treatment at 850°C for 0.5 h, followed by aging at 650°C for 8 h, with a tensile strength of 1317 MPa, an elongation of 11.17 %, and a strength-plasticity product of 14.711 GPa·%.

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Molecular dynamics simulation:The key to reveal the enrichment mechanisms of helium

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Science China Earth Sciences 2025年第2期68卷 643-645页

作者： Wenhui LIU Department of Geology Northwest UniversityXi’an 710069China Petroleum Exploration and Production research institute SINOPECBeijing 102206China

In recent years,helium and its enrichment mechanisms have been the frontier and attractive research in the field of geological resources(Liu et al.,2024).In the earliest geosciences,noble gases and their isotopes,including helium,were used as tracers for geochronology and geological processes due to their chemical inertness and *** attention has been paid to the isotope composition in geological bodies.

关键词： attractive frontier gases

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Limit of structure refinement for 7075 aluminum alloy at elevated temperature by hot deformation

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中国有色金属学会会刊：英文版 2003年第3期13卷 645-648页

作者：张小明张廷杰马光来田锋李中奎周廉 northwest institute for nonferrous metal research

Performance of commercial alloys can be improved greatly by severe plastic deformation, which refines grain of metals to several micrometer or sub micrometer order. During severe plastic deformation, the final size of grain structure depends on the following factors: strain rate, total strain, deformation temperature and so on. Under a certain condition, structure cannot be infinitely refined, which means that the size of grain has a limit with the increase of total strain. Under conventional hot deformation temperature, the grain size of 7075 aluminum alloy can be refined to 12 μm, and it will not become smaller with the increase of total strain, that is to say, the limit of grain refinement is about 1 μm.

关键词：铝合金热变形精炼高温结构塑性成形

Flow behavior and dynamic softening mechanism of Pt−10Ir precious alloy

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Transactions of nonferrous metals Society of China 2025年第1期35卷 225-242页

作者： Xin-pei ZHANG Jun-jie HE Lin PI Quan FU Wen-yan ZHOU Jun CHENG Sheng-wen BAI Xuan ZHOU Yi LIU Yong MAO Materials Genome institute School of Materials and EnergyYunnan UniversityKunming 650091China Kunming Precious Materials&Technology Co. Ltd.Yunnan Precious Metals Laboratory Co.Ltd.Sino-Platinum Metals Co.Ltd.Kunming 650106China Kunming institute of Precious metals Kunming 650106China State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum metals Sino-Platinum Metals Co.Ltd.Kunming 650106China Shaanxi Key Laboratory of Biomedical metal Materials Northwest Institute for Non-ferrous Metal ResearchXi’an 710016China College of Materials Science and Engineering Chongqing UniversityChongqing 400044China

The hot deformation behavior of Pt−10Ir alloy was studied under a wide range of deformation *** a low deformation temperature(950−1150℃),the softening mechanism is primarily dynamic *** addition,dynamic recrystallization by progressive lattice rotation near grain boundaries(DRX by LRGBs)and microshear bands assisted dynamic recrystallization(MSBs assisted DRX)coordinate the ***,it is difficult for the dynamic softening to offset the stain hardening due to a limited amount of DRXed *** a high deformation temperature(1250−1350℃),three main DRX mechanisms associated with strain rates occur:DRX by LRGBs,DRX by a homogeneous increase in misorientation(HIM)and geometric DRX(GDRX).With increasing strain,DRX by LRGBs is enhanced gradually under high strain rates;the“pinch-off”effect is enhanced at low strain rates,which was conducive to the formation of a uniform and fine microstructure.

关键词： platinum alloy hot deformation microstructure evolution dynamic recovery dynamic recrystallization

Transition of Y_2BaCuO_5 Phase in Powder Melting Processed YBa_2Cu_3O_(7-x) Superconductors

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Journal of Wuhan University of Technology(Materials Science) 2011年第4期26卷 620-623页

作者：冯建情 northwest institute for nonferrous metal research

The morphology and the formation of Y2BaCuO5 phase in powder melting processed YBa2Cu3O7-x superconductors were investigated. The experimental results show the heat treatment can not change the shape of Y2BaCuO5 particles in powder melting processed samples. The formation of round Y2BaCuO5 phase is due to relative content of each constitution of precursor powders in powder melting process. For powder melting process, the excessive liquid phase is eliminated, which restrains the preferred growth of Y2BaCuO5 particles.

关键词： morphology powder melting process YBa2Cu3O7-x scanning electron microscopy

Quick-homogeneous Corrosion of Ti-2A1-2.5Zr Alloy in High-temperature and High-pressure Water Steam

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Journal of Materials Science & Technology 2001年第1期17卷 43-44页

作者： Lin YANG Zhentao YU Ju DENG northwest institute for nonferrous metal research Xi’an 710016China

The corrosion behavior of Ti-2A1-2.5Zr alloy with 5 alloy contents and 5 surface states were studied in water steam at 400℃, 10.3 MPa for 72 h. The weight-increments of all samples are under 4 mg/dm2, better than Zr and Zr-alloy. or-Ti is oxidized into anatase-type TiO2 preferentially. The corrosion resistance is improved by adding Al element or pre-oxidizing treatment, the latter is more effective relatively.

关键词： corrosion resistance corrosion behavior surface states Al element

Fabrication of multilayer Nb_2O_5 nanoporous film by anodization of niobium foils

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Rare metals 2015年第2期34卷 77-80页

作者： Guang-Zhong Li Hui-Ping Tang Wen-Yan Zhang Gang Li Lan-Lan Yu Ya-Ning Li State Key Laboratory of Porous metal Materials Northwest Institute for Nonferrous Metal Research

Multilayer Nb2O5 nanoporous films were successfully synthesized on Nb surfaces by the control anodization process in ethylene glycol containing 4 vol% HF and 2 vol% H2O2 electrolyte. The nanoporous films are characterized in detail by field-emission scanning electron microscopy（FESEM）, transmission electron microscopy（TEM）, and X-ray diffraction（XRD）. The Nb_2O_5 nanoporous films have a multilayer morphology with the side wall thickness of ～5 nm, irregular pores with a diameter of ～25 nm, and a length of up to 7.39 lm, depending on the anodization time. A mechanism for the multilayer Nb2O5 nanoporous formation was also discussed. These nanoporous materials can be very useful in the fields of solar cells, gas sensors, catalysts, optical filters, and capacitors.

关键词： Anodization Multilayer Nanoporous film Growth mechanism