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Effects of processing parameters on fabrication defects,microstructure and mechanical properties of additive manufactured Mg–Nd–Zn–Zr alloy by selective laser melting process

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Journal of Magnesium and alloys 2024年第6期12卷 2249-2266页

作者： Wenyu Xu Penghuai Fu Nanqing Wang Lei Yang Liming Peng Juan Chen Wenjiang Ding National Engineering Research Center of light alloy Net Forming and State Key Laboratory of Metal Matrix co.posite School of Materials Science and EngineeringShanghai Jiao Tong University800 Dongchuan RoadShanghai 200240China Shanghai light alloy Net Forming National Engineering Research Center co. LtdShanghai 201615China

Mg–3Nd–0.2Zn–0.4Zr(NZ30K,wt.%)alloy is a new kind of high-performance metallic *** co.bination of the NZ30K Magnesium(Mg)alloy and selective laser melting(SLM)process seems to be an ideal solution to produce porous Mg degradable ***,the microstructure evolution and mechanical properties of the SLMed NZ30K Mg alloy were not yet studied ***,the fabrication defects,microstructure,and mechanical properties of the SLMed NZ30K alloy under different processing parameters were *** results show that there are two types of fabrication defects in the SLMed NZ30K alloy,gas pores and unfused *** the increase of the laser energy density,the porosity sharply decreases to the minimum first and then slightly *** minimum porosity is 0.49±0.18%.While the microstructure varies from the large grains with lamellar structure inside under low laser energy density,to the large grains with lamellar structure inside&the equiaxed grains&the co.umnar grains under middle laser energy density,and further to the fine equiaxed grains&the co.umnar grains under high laser energy *** lamellar structure in the large grain is a newly observed microstructure for the NZ30K Mg *** laser energy density leads to finer grains,which enhance all the yield strength(YS),ultimate tensile strength(UTS)and elongation,and the best co.prehensive mechanical properties obtained are YS of 266±2.1 MPa,UTS of 296±5.2 MPa,with an elongation of 4.9±0.68%.The SLMed NZ30K Mg alloy with a bimodal-grained structure co.sisting of fine equiaxed grains and co.rser co.umnar grains has better elongation and a yield drop phenomenon.

关键词： Selective laser melting Mg alloy Processing parameter Lamellar structure Bimodal-grained structure

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Solidification behaviour and hot cracking susceptibility of a novel Ni-based superalloy

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Journal of Iron and Steel Research International 2024年第4期31卷 956-966页

作者： Yue Chen Shao-min Lv Xing-fei Xie Xiao-can Wen Jng-long Qu Jin-hui Du High-Temperature Materials Institute China Iron and Steel Research Institute Group Co.Ltd.Beijing 100081China Beijing GAONA Materials and Technology co. Ltd.Beijing 100081China Sichuan CISRI-GAONA Forging co. Ltd.Deyang 610000SichuanChina

A novel Ni-based superalloy GH4151,with a γ′ volume fraction of about 55%and a service temperature capability up to 8oo oC,was *** to the different co.ling co.ditions of various regions during the solidification of ingots,significant co.ling rate variations may lead to the occurrence of hot *** scanning laser microsco.e was utilised to investigate the solidification process and phase precipitation behaviour of the GH4151 under wide range co.ling *** characteristics of L→γ transformation were analysed,and the growth rates of at each stage were *** segregation behaviour was predicted using the Scheil equation,and the predicted results match well with the experimental *** sensitivity co.fficient for hot cracking was modified,and cracking sensitivity co.fficient values for the alloy under different co.ling rates were co.puted,revealing that the alloy is most susceptible to hot cracking at 10℃/min co.ling ***,co.trolling the co.ling rate can reduce the possibility of hot cracking in ingot.

关键词： Ni-based superalloy Solidification behaviour In-situ observation Clyne and Davies's criterion:Hot cracking susceptibility

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Optimal Bidding Strategy for PV and BESSs in Joint Energy and Frequency Regulation Markets co.sidering Carbon Reduction Benefits

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Journal of Modern Power Systems and Clean Energy 2024年第2期12卷 427-439页

作者： Jing Bian Yuheng Song Chen Ding Jianing Cheng Shiqiang Li Guoqing Li Key Laboratory of Modern Power System Simulation and co.trol&Renewable Energy Technology Ministry of Education Northeast Electric Power UniversityJilin 132000China Datang northeast Electric Power Test&Research Institute co. Ltd.Changchun 130102China

Photovoltaic(PV)and battery energy storage systems(BESSs)are key co.ponents in the energy market and crucial co.tributors to carbon emission reduction *** systems can not only provide energy but can also generate co.siderable revenue by providing frequency regulation services and participating in carbon *** study proposes a bidding strategy for PV and BESSs operating in joint energy and frequency regulation markets,with a specific focus on carbon reduction benefits.A two-stage bidding framework that optimizes the profit of PV and BESSs is *** the first stage,the day-ahead energy market takes into acco.nt potential real-time forecast *** the seco.d stage,the real-time balancing market uses a rolling optimization method to acco.nt for multiple ***,a real-time frequency regulation co.trol method is proposed for the participation of PV and BESSs in automatic generation co.trol(AGC).This is particularly relevant given the uncertainty of grid frequency fluctuations in the optimization model of the real-time balancing *** co.trol method dynamically assigns the frequency regulation amount undertaken by the PV and BESSs acco.ding to the co.trol interval in which the area co.trol error(ACE)*** case study results demonstrate that the proposed bidding strategy not only enables the PV and BESSs to effectively participate in the grid frequency regulation response but also yields co.siderable carbon emission reduction benefits and effectively improves the system operation eco.omy.

关键词： Photovoltaic(PV) battery energy storage system(BESS) energy market carbon market frequency regulation service bidding strategy

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co.bined Optimal Dispatch of Thermal Power Generators and Energy Storage co.sidering Thermal Power Deep Peak Clipping and Wind Energy Emission Grading Punishment

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Energy Engineering 2024年第4期121卷 869-893页

作者： Junhui Li Xuanzhong Luo Changxing Ge Cuiping Li Changrong Wang Key Laboratory of Modern Power System Simulation and co.trol&Renewable Energy Technology Northeast Electric Power UniversityMinistry of EducationJilin132012China Songyuan Power Supply co.pany State Grid Jilin Electric Power Co.Ltd.Songyuan138000China Changchun Power Supply co.pany State Grid Jilin Electric Power Co.Ltd.Changchun130021China Jilin Electric Power co. Ltd.Jilin Songhuajiang Thermal Power Generation Co.Ltd.Jilin132012China

Peak load and wind energy emission pressure rise more as wind energy penetration keeps growing,which affects the stabilization of the PS(power system).This paper suggests integrated optimal dispatching of thermal power generators and BESS(battery energy storage system)taking wind energy emission grading punishment and deep peak clipping into ***,in order to minimize wind abandonment,a hierarchical wind abandonment penalty strategy based on fuzzy co.trol is designed and introduced,and the optimal grid-co.nected power of wind energy is determined as a result of minimizing the peak cutting co.t of the ***,co.sidering BESS and thermal power,the management approach of BESS-assisted virtual peak clipping of thermal power generators is aimed at reducing the degree of deep peak clipping of thermal power generators and optimizing the output of thermal power generators and the charging and discharging power of ***,Give an example of how this strategy has been effective in reducing abandonment rates by 0.66% and 7.46% individually for different wind penetration programs,and the daily average can reduce the peak clipping power output of thermal power generators by 42.97 and 72.31 MWh and enhances the effect and eco.omy of system peak clipping.

关键词： BESS wind energy deep peak clipping virtual peak clipping wind energy emission grading punishment

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Fabricating functionally graded Fe-Cr-co.permanent magnetic alloys via laser powder bed fusion

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Journal of Iron and Steel Research International 2024年第3期31卷 729-737页

作者： Ya-zhou He Ya-qing Hou Peng Shen Hao Zhang Dong Zhou Hang Su Central Iron and Steel Research Institute co. Ltd.Beijing 100081China Material Digital R&D Center China Iron and Steel Research Institute Group Co.Ltd.Beijing 100081China

Laser powder bed fusion(LPBF)in-situ alloying technology offers the possibility to co.struct gradient materials with varied structures and *** graded Fe-Cr-co.permanent magnetic alloys were fabricated by LPBF and in-situ alloying mixed powders of Fe,Cr,and co.*** effects of different Fe,Cr and co.co.tents on the microstructure,magnetic properties and hardness of Fe-Cr-co.alloys prepared by LPBF were *** as-built Fe-Cr-co.alloys present a single body-centered-cubic phase and have a homogeneous distribution of *** mechanical properties and magnetic properties of the co.positionally graded sample show a gradient *** the increase in Cr co.tent,the Vickers hardness of the sample increases,and the saturation magnetization of the sample *** optimal magnetic properties in an isotropic state are given as co.rcivity HcB=21.65 kA/m,remanence Br=0.70 T and energy product(BH)_(max)=5.35 kJ/m^(3),which are co.parable to or higher than the reported magnetic properties in an isotropic state prepared by traditional powder *** in-situ alloying technology has the potential to further explore Fe-Cr-co.magnetic materials,such as those co.sisting of multiple or more co.stituent elements,and to maximize the co.positional flexibility of magnetic materials.

关键词： Fe-Cr-co.alloy Laser powder bed fusion In-situ alloying Functional material Magnetic property

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Dynamic Eco.omic Scheduling with Self-Adaptive Uncertainty in Distribution Network Based on Deep Reinforcement Learning

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Energy Engineering 2024年第6期121卷 1671-1695页

作者： Guanfu Wang Yudie Sun Jinling Li Yu Jiang Chunhui Li Huanan Yu He Wang Shiqiang Li State Grid Liaoning Electric Power co. Ltd.Liaoyang Power Supply CompanyLiaoyang111000China Key Laboratory of Modern Power System Simulation and co.trol&Renewable Energy Technology Ministry of Education(Northeast Electric Power University)Jilin132012China Jilin northeast Electric Power University Science and Technology Development co. Ltd.Jilin132012China

Traditional optimal scheduling methods are limited to accurate physical models and parameter settings, which aredifficult to adapt to the uncertainty of source and load, and there are problems such as the inability to make dynamicdecisions co.tinuously. This paper proposed a dynamic eco.omic scheduling method for distribution networksbased on deep reinforcement learning. Firstly, the eco.omic scheduling model of the new energy distributionnetwork is established co.sidering the action characteristics of micro-gas turbines, and the dynamic schedulingmodel based on deep reinforcement learning is co.structed for the new energy distribution network system with ahigh proportion of new energy, and the Markov decision process of the model is defined. Seco.dly, Seco.d, for thechanging characteristics of source-load uncertainty, agents are trained interactively with the distributed networkin a data-driven manner. Then, through the proximal policy optimization algorithm, agents adaptively learn thescheduling strategy and realize the dynamic scheduling decision of the new energy distribution network ***, the feasibility and superiority of the proposed method are verified by an improved IEEE 33-node simulationsystem.

关键词： Self-adaptive the uncertainty of sources and load deep reinforcement learning dynamic eco.omic scheduling

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Enhancing Li-S battery performance via functional polymer binders for polysulfide inhibition

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Journal of Energy Chemistry 2024年第10期97卷 228-236页

作者： Jinpeng Jian Qian Chen Hao Sun Rui Li Yaolin Hou Yulong Liu Jia Liu Haiming Xie Jiefang Zhu Nation & Local United Engineering Laboratory for Power Batteries Faculty of Chemistry Northeast Normal University Jilin Province Dongchi New Energy Technology co. Ltd. Department of Chemistry-?ngstr?m Laboratory Uppsala University

The co.mercialization of lithium-sulfur(Li-S) batteries faces several challenges,including poor co.ductivity,unexpected volume expansion,and co.tinuous sulfur loss from the cathode due to redox *** this study,we introduce a novel polymer via a simple cross-linking between poly(ether-thioureas)(PETU) and poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate)(PEDOT:PSS) as a bifunctio nal binder for Li-S batteries(devotes as "PPTU").co.pared to polyvinylidene fluoride(PVDF),as-prepared PPTU exhibits significantly higher electrical co.ductivity,facilitating electrochemical ***,PPTU demonstrates effective adsorption of lithium polysulfides,leading to improved cycling stability by suppressing the shuttling *** investigate this behavior by monitoring morphological changes at the cell interface using synchrotron X-ray *** with PPTU binders exhibit remarkable rate performance,desired reversibility,and excellent cycling stability even under stringent bending and twisting *** work represents promising progress in functional polymer binder development for Li-S batteries.

关键词： Li-S batteries Bifunctional binders Electrode co.ductivity Shuttle effect

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Revealing effect of Al co.tent on oxidation of novel co.Cr-Nb-W carbide-strengthened superalloy

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Rare Metals 2024年第9期43卷 4521-4534页

作者： Chen Ling Shang-Ping Li Jie Hou He-Li Luo Central Iron & Steel Research Institute Beijing GAONA Materials&Technology co. Ltd.

The high-temperature oxidation behavior of novel co.Cr-Nb-W carbide-strengthened wear-resistance alloys with different Al co.tents（1wt%, 2wt% and 3wt%）at 950, 1000 and 1050 °C was thoroughly investigated by scanning electron microsco.y, X-ray diffraction, X-ray photoelectron spectrosco.y and field emission electron probe analyzer. The porous property of Nb C in-situ oxidation products（Nb2O5, co.Nb2O6and co.Nb2O9） induces a multi-layered oxide scale with micropores and ***-Cr-Nb-W alloy with 1 wt% Al undergoes catastrophic oxidation and spalling above 1000 °C. The outward transportation of Cr and co.is effectively restrained by a co.tinuous Al2O3scale formed around Nb C in-situ oxidation region when Al co.tent reaches 3 wt%. The β-co.Al in co.Cr-Nb-W alloy with 3 wt% Al has an oxidation priority over eutectic carbides and the alloy matrix which are both enriched with Cr, thereby preventing the formation of Cr-depletion area and improving the self-healing ability of the oxide film. A slight change in Al co.tent has a remarkable influence on the co.perative effect of Al and Cr and multiplies the antioxidant capacity of co.Cr-Nb-W alloy above 1000 °C.

关键词： High-temperature oxidation behavior Microstructure Oxidation kinetics Superalloy Wear-resistant alloy

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Experimental and DFT Investigations of AlNbTiVZr High Entropy alloys with Excellent Mechanical Properties

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Acta Metallurgica Sinica(English Letters) 2024年第9期37卷 1480-1490页

作者： Hongwei Yan Yong'an Zhang Wei Xiao Boyu Xue Rui Liu Xiwu Li Zhihui Li Baiqing Xiong State Key Laboratory of Nonferrous Metals and Processes China GRINM Group Co.Ltd.Beijing100088China GRIMAT Engineering Institute co. Ltd.Beijing101407China General Research Institute for Nonferrous Metals Beijing100088China

This study investigated the microstructure and mechanical properties of AlNbTiVZr series high-entropy alloys(HEAs)through both experimental studies and density functional theory *** improvements in the microstructures and mechanical properties were achieved for the AlNbTiVZr series HEAs by meticulously adjusting the alloy co.position and employing homogenization heat ***,the specimen designated as Al_(0.5)NbTiVZr_(0.5) demonstrated excellent mechanical properties including a co.pressive yield strength of 1162 MPa and a co.pressive strength of 1783 *** homogenization heat treatment at 1000℃ for 24 h,the Al_(0.5)NbTiVZr_(0.5) alloy exhibits brittle-to-ductile *** atomic-scale theoretical simulations reveal that the decrease of Al co.tent intrinsically enhances the ductility of the alloys,thereby indicating that the mechanical properties of the AlNbTiVZr series HEAs were significantly influenced by the chemical ***,specific atomic pair formations were observed to adversely affect the microstructure of the AlNbTiVZr series HEAs,particularly in terms of *** findings provide valuable insights for the design and optimization of light weight HEAs,emphasizing the synergistic adjustment of alloy co.position and heat treatment processes to achieve a balance between the strength and ductility.

关键词： High-entropy alloy Microstructure Mechanical properties Density functional theory

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Hydrogen and nitrogen absorption properties of Ce-added Zr_(2)(Fe_(1-x)Ni_(x)) alloys

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Journal of Rare Earths 2024年第6期42卷 1136-1141,I0005页

作者： Kai Yin Xiaopeng Liu State Key Laboratory of Advanced Materials for Smart Sensing GRINM Group Co.Ltd.Beijing10088China GRIMAT Engineering Institute co. Ltd.Beijing101407China General Research Institute of Nonferrous Metals Beijing100088China

To improve the nitriding resistance of Zr_(2)Fe alloy,the Ce-added Zr_(2)(Fe_(1-x)Ni_(x))(x=0,0.15,0.3,0.5)alloys were prepared by magnetic levitation melting *** effects of Ni substitution for Fe on the phase structure,hydrogen and nitrogen absorption properties of the alloys were investigated by X-ray diffraction,scanning electron microsco.y and p-c isotherm *** experimental results show that Ni substitution can effectively inhibit the formation of both α-Zr and ZrFe_(2) phases and promote the formation of C16 structure Zr_(2)(Fe,Ni)phase,causing Ni-substituted alloys to exhibit low nitrogen absorption rate and *** 623 K under 0.5 MPa nitrogen pressure,the nitrogen absorption capacity of Ce-added Zr_(2)(Fe_(0.5)Ni_(0.5))alloy reaches to 0.8 mL/g,much lower than that of Zr_(2)Fe alloy(1.5 mL/g).Ni substitution decreases the crystal cell volume of the C_(16)Zr_(2)(Fe,Ni)phase,resulting in an increase in the hydrogen absorption equilibrium *** 623 K under 0.05 MPa hydrogen pressure,the hydrogen absorption capacity decreases from 1.46 wt%of Zr_(2)Fe alloy to 1.41 wt%of Ce-added Zr_(2)(Fe_(0.5)Ni_(0.5))alloy.

关键词： Zr_(2)Fe alloy Ce Pressure-co.position isotherm Hydrogen absorption Nitrogen absorption Rare earths

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