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Corrosion Behavior of Pre-oxidized GH4169 Alloy with Solid NaCI Deposited in a Wet Oxygen Flow at 600 ℃

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Acta Metallurgica Sinica(English Letters) 2024年第7期37卷 1249-1264页

作者： Weidong Zhang Yu Cui Li Liu Wenquan Wang Wenzheng Chen Rui Li Fuhui Wang Shenyang National Laboratory for materials Science Northeastern UniversityShenyang110819China Shi-Changxu innovation Center for Advanced materials Institute of Metal ResearchChinese Academy of SciencesShenyang110016China

The corrosion behavior of the pre-oxidized GH4169 alloy was studied after 20 h of exposure under a solid NaCl deposit film in a wet O_(2) environment at 600℃ by mass-gain measurements,X-ray diffraction,scanning electron microscopy,transmission electron microscopy *** results indicate that the pre-oxidized GH4169 alloy undergoes serious corrosion in the corrosive *** preformed Cr_(2)O_(3) layer is gradually destroyed by deposit NaCl,and the inner Nb2O5 layer beneath the complete outer Cr_(2)O_(3) layer also reacts with NaCl to form NaNbO_(3).The electrochemical test results testified the existence of electrochemical reactions during this corrosion *** corrosion behavior of pre-oxidized GH4169 under a solid NaCl deposit film in a wet O_(2) environment at 600℃has been discussed in detail.

关键词： Pre-oxidation Solid NaCl Wet O2 Electrochemical corrosion

Electron-distribution control via Pt/NC and MoC/NC dual junction:Boosted hydrogen electro-oxidation and theoretical study

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Journal of Energy Chemistry 2024年第1期88卷 513-520,I0011页

作者： Feng Zhou Xiaofeng Ke Yihuang Chen Mei Zhao Yun Yang Youqing Dong Chao Zou Xi’an Chen Huile Jin Lijie Zhang Shun Wang Key Laboratory of Carbon materials of Zhejiang Province College of Chemistry and Materials EngineeringWenzhou UniversityWenzhou 325000ZhejiangChina Zhejiang Engineering Research Center for Electrochemical Energy materials and Devices Institute of New Materials&Industry TechnologyWenzhou UniversityWenzhou 325000ZhejiangChina

The scarcity,high cost and susceptibility to CO of Platinum severely restrict its application in alkaline hydrogen oxidation reaction(HOR).Hybridizing Pt with other transition metals provides an effective strategy to modulate its catalytic HOR performance,but at the cost of mass activity due to the coverage of modifiers on Pt ***,we constructed dual junctions'Pt/nitrogen-doped carbon(Pt/NC)andδ-MoC/NC to modify electronic structure of Pt via interfacial electron transfer to acquire Pt-MoC@NC catalyst with electron-deficient Pt nanoparticles,simultaneously endowing it with high mass activity and durability of alkaline ***,the unique structure of Pt-MoC@NC endows Pt with a high COtolerance at 1,000 ppm CO/H_(2),a quality that commercial Pt-C catalyst *** theoretical calculations not only confirm the diffusion of electrons from Pt/NC to Mo C/NC could occur,but also demonstrate the negative shift of Pt d-band center for the optimized binding energies of*H,*OH and CO.

关键词： Hydrogen oxidation reaction Dual junctions CO-tolerance Platinum

Lightweight foam-like nitrogen-doped carbon nanotube complex achieving highly efficient electromagnetic wave absorption

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Journal of materials Science & Technology 2024年第1期168卷 114-123页

作者： Zongcheng Li Jin Liang Zhiheng Wei Xin Cao Jiahui Shan Chunwei Li Xiaoyi Chen Dong Zhou Ruizhe Xing Chunjia Luo Jie Kong MOE Key Lab of materials Physics and Chemistry in Extraordinary Conditions Shaanxi Key Laboratory of Macromolecular Science and TechnologySchool of Chemistry and Chemical EngineeringNorthwestern Polytechnical UniversityXi’an 710072China Key laboratory of Flexible Electronics of Zhejiang Province Ningbo Institute of Northwestern Polytechnical UniversityNingbo 315103China Polymer materials and Engineering Department School of Materials Science and EngineeringChang’an UniversityXi’an 710064China

With the increased electromagnetic wave(EMW)threat to military and human health,the develop-ment of EMW-absorbing materials is ***-organic framework derivatives containing magnetic nanoparticles and a carbon matrix are potential candidates for designing efficient EMW-absorbing ***,a zeolitic imidazolate framework-67(ZIF-67)-embedded three-dimensional melamine foam is pyrolyzed to afford carbon foam-based nitrogen-doped carbon nanotube composites,named 3D foam-like CoO/Co/*** CoO/Co particles are confined in the dielectric carbon nanotube *** carbon nanotubes provide considerable conductive loss,while CoO/Co magnetic particles are con-ducive to providing magnetic loss and adjusting impedance ***,the numerous defect structures introduced by heteroatomic doping(nitrogen)cause dipole polarization and simultaneously adjust impedance ***,the unique porous nanotube structure promotes multiple re-flections and scattering of EMWs,further optimizing impedance ***/Co/N-CNTs composites exhibit a minimum reflection loss of−52.3 dB at a matching thickness of 2.0 mm,while the correspond-ing effective absorption bandwidth is 5.28 GHz at a matching thickness of 2.2 *** study reports a novel approach to fabricating a lightweight high-performance EMW-absorbing material.

关键词： Lightweight porous carbon materials Carbon nanotubes CoO/Co magnetic particles Electromagnetic synergistic effect Impedance matching

Boosting oxygen reduction in acidic media through integration of Pt-Co alloy effect and strong interaction with carbon defects

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Nano Research 2024年第9期17卷 7900-7908页

作者： Nannan Ji Haoyun Sheng Shilong Liu Yangyuan Zhang Hongfei Sun Lingzhi Wei Ziqi Tian Peng Jiang Qianwang Chen Jianwei Su institutes of Physical Science and Information Technology Key Laboratory of Structure and Functional Regulation of Hybrid MaterialsAnhui UniversityHefei 230601China ningbo institute of materials Technology and Engineering Chinese Academy of SciencesNingbo 315201China Hefei National Laboratory for Physical Science at Microscale Department of Materials Science&EngineeringUniversity of Science and Technology of ChinaHefei 230026China International Collaborative Laboratory of 2D materials for Optoelectronics Science and Technology of Ministry of Education Institute of Microscale OptoelectronicsShenzhen UniversityShenzhen 518060China

Optimization of Pt atom utilization efficiency is critical for the development of proton-exchange-membrane fuel *** we aim to develop an efficient oxygen reduction reaction(ORR)catalyst with a low Pt content through the concurrent modification of Pt-Co alloy catalysts and carbon *** the present study,ultrafine Pt-Co alloy nanoparticles are successfully synthesized and stabilized by topological carbon defects via adopting the ammonia thermal *** the low Pt loading,the obtained catalyst exhibits an impressive half-wave potential of 0.926 V versus the reversible hydrogen electrode in 0.1 M HClO_(4)***,the durability testing using the timed-current method demonstrates a tiny loss of only 3.6%after 12 *** experimental results and theoretical calculations demonstrate that topological carbon defects significantly enhance the charge transfer processes at the alloy/carbon interface,contributing to the strong electronic metal-support interactions between the Pt-Co alloy nanoparticles and topological carbon *** interactions,along with the alloy effect,play a crucial role in promoting the ORR performance in acidic media.

关键词： electrocatalysis oxygen reduction reaction Pt-Co alloy electronic interaction topological carbon defects

Coercivity mechanism of high-performance anisotropic heterostructure SmCo5 magnets

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Journal of Rare Earths 2024年第10期42卷 1882-1888页

作者： Yuan Teng Yuqing Li Weiqiang Liu Xiaochang Xu Zhanjia Wang Jianjun Yang Dongtao Zhang Hongguo Zhang Qingmei Lu Qiong Wu Weixing Xia Ming Yue Faculty of materials and Manufacturing Key Laboratory of Advanced Functional MaterialsMinistry of Education of ChinaBeijing University of Technology School of Mechanical and Electrical Engineering Henan Institute of Science and Technology School of Mechanical Engineering Anyang Institute of Technology Key Laboratory of Magnetic materials and Devices Ningbo Institute of Material Technology and EngineeringChinese Academy of Sciences

Due to its large magnetocrystalline anisotropy field and high Curie temperature,SmCo-based magnets are irreplaceable in high-temperature applications,The hot-deformed SmCo-based magnets are especially attractive for their excellent corrosion resistance,making them more suitable for harsh ***,it is still challenging for hot-deformed SmCo-based magnets to obtain high magnetization and high coercivity ***,it is necessary to analyze the relationship between its microstructure and magnetic properties and explore its magnetic hardening mechanism to guide the further improvement of magnetic *** this paper,the anisotropic heterostructure SmCo5magnet was prepared by combining large height-reduction and introducing a nano-grained Smrich *** c-axis texture,（BH）m of 16.1 MGOe,and Hciof 9.6 kOe were obtained via the heterostructure with SmCo5micron-grain and Sm-rich nano-scale *** magnetic domain observation and technical magnetization analysis demonstrate that the coe rcivity mechanism is dominated by *** results also show that the smooth and Sm-rich precipitated grain boundary provides weak pinning *** provides a reference for the development of high-pe rformance nanocrystalline SmCo5magnets.

关键词： Permanent magnet Heterostructure Rare earths Coercivity mechanism Hot-deformed SmCo magnet

Martensite decomposition under thermal-mechanical coupling conditions to fabricate an ultrafine-grained Ti6Al4Mo4Zr1W0.2Si alloy

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Journal of materials Science & Technology 2024年第1期168卷 157-168页

作者： Taoyu Zhou Jiuxu Yang Nan Li Hao Sun Bohua Zhang Zibo Zhao Qingjiang Wang Shi-changxu innovation Center for Advanced materials Institute of Metal ResearchChinese Academy of SciencesShenyang 110016China School of materials Science and Engineering University of Science and Technology of ChinaShenyang 110016China

The fabrication of ultrafine-grained microstructures(grain size below 1μm)in titanium alloys is beneficial for improving their mechanical properties at room temperature and medium tempera-tures(400-550°C).However,a long-standing challenge involves the low-cost manufacturing of bulk ultrafine-grained titanium *** this work,we developed a facile strategy through martensite de-composition at thermal-mechanical coupling conditions,to fabricate an equiaxed microstructure in a Ti6Al4Mo4Zr1W0.2Si model alloy with an averageαgrain size of 315±62 *** formation of the ultrafine-grained microstructure was because the lattice strain stored in the martensitic initial mi-crostructure enhanced the nucleation rate of dynamic recrystallization,meanwhile,the pinning role of martensite decomposition productsβand(Ti,Zr)_(5)Si_(3)phases suppressed grain coarsening at high *** to conventional(α+β)alloys,the tensile strength of this alloy improved by 20%-30%at both room temperature and 550°C,without decreasing its *** situ SEM observations revealed that the ultrafine-grained microstructure would not only suppress dislocation motions but also contribute to the homogenous deformation in the matrix of the material,therefore,it resulted in higher mechanical *** research results may be of great significance to the development of next-generation aviation titanium alloys.

关键词： Ultrafine-grained Titanium alloy In situ observation Deformation mechanism Thermostability

Phase-stable wide-bandgap perovskites enabled by suppressed ion migration

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Journal of Energy Chemistry 2024年第9期96卷 120-128页

作者： Zhiyu Gao Yu Zhu Jingwei Zhu Cong Chen Zongjin Yi Yi Luo Yuliang Xu Kai Wu Tianshu Ma Fangfang Cao Zijun Chen Fang Yao Juncheng Wang Wenwu Wang Chuanxiao Xiao Hao Huang Hongxiang Li Qianqian Lin Pei Cheng Changlei Wang Xia Hao Guanggen Zeng Dewei Zhao College of materials Science and Engineering&institute of New Energy and Low-Carbon Technology&Engineering Research Center of Alternative Energy materials and Devices Ministry of EducationSichuan UniversityChengdu 610065SichuanChina School of Optoelectronic Science and Engineering&Collaborative innovation Center of Suzhou Nano Science and Technology Key Lab of Advanced Optical Manufacturing Technologies of Jiangsu Province&Key Lab of Modern Optical Technologies of Education Ministry of ChinaSoochow UniversitySuzhou 215006JiangsuChina ningbo institute of materials Technology and Engineering Chinese Academy of SciencesNingbo 315201ZhejiangChina ningbo New materials Testing and Evaluation Center Co.Ltd Ningbo 315201ZhejiangChina State Key Laboratory of Featured Metal materials and Life-cycle Safety for Composite Structure&School of Resources Environment and MaterialsGuangxi UniversityNanning 530004GuangxiChina Key Lab of Artificial Micro-and Nano-Structures of Ministry of Education of China School of Physics and TechnologyWuhan UniversityWuhan 430072HubeiChina College of Polymer Science and Engineering State Key Laboratory of Polymer Materials EngineeringSichuan UniversityChengdu 610065SichuanChina

Wide-bandgap(>1.7 eV)perovskites suffer from severe light-induced phase segregation due to high bromine content,causing irreversible damage to devices ***,the strategies of suppressing photoinduced phase segregation and related mechanisms have not been fully ***,we report a new passivation agent 4-aminotetrahydrothiopyran hydrochloride(4-ATpHCl)with multifunctional groups for the interface treatment of a 1.77-eV wide-bandgap perovskite film.4-ATpH^(+)impeded halogen ion migration by anchoring on the perovskite surface,leading to the inhibition of phase segregation and thus the passivation of defects,which is ascribed to the interaction of 4-ATpH^(+)with perovskite and the formation of low-dimensional ***,the champion device achieved an efficiency of 19.32%with an open-circuit voltage(V_(OC))of 1.314 V and a fill factor of 83.32%.Moreover,4-ATpHCl modified device exhibited significant improved stability as compared with control *** target device maintained 80%of its initial efficiency after 519 h of maximum power output(MPP)tracking under 1 sun illumination,however,the control device showed a rapid decrease in efficiency after 267 ***,an efficiency of 27.38%of the champion 4-terminal all-perovskite tandem solar cell was achieved by mechanically stacking this wide-bandgap top subcell with a 1.25-eV low-bandgap perovskite bottom subcell.

关键词： Wide-bandgap perovskite Phase segregation lon migration Interface post-treatment All-perovskite tandems

Effect of bipolar-plates design on corrosion,mass and heat transfer in proton-exchange membrane fuel cells and water electrolyzers:A review

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International Journal of Minerals,Metallurgy and materials 2024年第7期31卷 1599-1616页

作者： Jiuhong Zhang Xiejing Luo Yingyu Ding Luqi Chang Chaofang Dong Key Laboratory for Corrosion and Protection(MOE) Institute for Advanced Materials and TechnologyUniversity of Science and Technology BeijingBeijing 100083China Beijing Advanced innovation Center for materials Genome Engineering Beijing 100083China

Attaining a decarbonized and sustainable energy system,which is the core solution to global energy issues,is accessible through the development of hydrogen ***-exchange membrane water electrolyzers(PEMWEs)are promising devices for hydrogen production,given their high efficiency,rapid responsiveness,and *** plates account for a relatively high percentage of the total cost and weight compared with other components of ***,optimization of their design may accelerate the promotion of *** paper reviews the advances in materials and flow-field design for bipolar ***,the working conditions of proton-exchange membrane fuel cells(PEMFCs)and PEMWEs are compared,including reaction direction,operating temperature,pressure,input/output,and ***,the current research status of bipolar-plate substrates and surface coatings is summarized,and some typical channel-rib flow fields and porous flow fields are ***,the effects of materials on mass and heat transfer and the possibility of reducing corrosion by improving the flow field structure are ***,this review discusses the potential directions of the development of bipolar-plate design,including material fabrication,flow-field geometry optimization using threedimensional printing,and surface-coating composition optimization based on computational materials science.

关键词： bipolar-plates flow design mass and heat transfer corrosion water electrolyzers fuel cells

High-Speed Rubbing Behavior of Abrasive Coating Coated on Titanium Alloy Blade Tips

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Acta Metallurgica Sinica(English Letters) 2024年第4期37卷 749-762页

作者： Wenshuang Gu Shuai Yang Shiyi Zhang Zhiliang Pei Weihai Xue Deli Duan Jun Gong Chao Sun Shi-Changxu innovation Center for Advanced materials Institute of Metal ResearchChinese Academy of SciencesShenyang110016China School of materials Science and Engineering University of Science and Technology of ChinaShenyang110016China

In aero-engines, abrasive coatings are typically utilized to protect the blade tip from excessive wear caused by the harder abradable sealing coating and thereby improve the sealing performance of engines. Therefore, a Ni/cBN abrasive coating was prepared on titanium alloy using electrodeposition. The high-speed rubbing tests with a linear velocity of 350 m/s and different incursion rates were performed to investigate the effect of the Ni/cBN abrasive coating on the wear behavior against NiCrAl/diatomite seal coating. Results showed that melting wear and adhesive transfer occurred on the bare blades, causing the bare blade to suffer excessive wear. While the Ni/cBN abrasive coating exhibited superior wear resistance and cutting performance. The cBN grits pullout, the abrasion of Ni matrix and transfer of seal coating to the cBN grits were the main wear mechanism of the Ni/cBN abrasive coating. Additionally, it was found that the relationship between the incursion rate and high-speed rubbing behavior is quite different for the bare blade and Ni/cBN coating. The reason for the difference in wear behavior of bare blade and Ni/cBN coating at different incursion rates was discussed in detail.

关键词： Gas turbine sealing Abrasive coating High-speed rubbing Material transfer Abradable coating