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Recent Research Progress of Paper-Based Supercapacitors Based on Cellulose

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Energy & Environmental Materials 2024年第3期7卷 349-377页

作者： Chuanyin Xiong Tianxu Wang Jing Han zhao Zhang Yonghao Ni College of Bioresources Chemical & Materials engineering Shaanxi University of Science and Technology School of Materials Science and engineering Tianjin Polytechnic University Department of Chemical and Biomedical engineering The University of Maine University of new Brunswick Limerick Pulp & Paper Ctr

In recent years,paper-based functional materials have received extensive attention in the field of energy storage due to their advantages of rich and adjustable porous network structure and good *** an important energy storage device,paper-based supercapacitors have important application prospects in many fields and have also received extensive attention from researchers in recent *** present,researchers have modified and regulated paper-based materials by different means such as structural design and material composition to enhance their electrochemical storage *** development of paper-based supercapacitors provides an important direction for the development of green and sustainable ***,it is of great significance to summarize the relevant work of paper-based supercapacitors for their rapid development and *** this review,the recent research progress of paper-based supercapacitors based on cellulose was summarized in terms of various cellulose-based composites,preparation skills,and electrochemical ***,some opinions on the problems in the development of this field and the future development trend were *** is hoped that this review can provide valuable references and ideas for the rapid development of paperbased energy storage devices.

关键词： cellulose electrochemical performance flexibility paper-based supercapacitor porous

Enhancement of–OH content on mechanical properties of antiperovskite solid electrolytes

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Nano Research 2024年第7期17卷 6139-6146页

作者： Zunqiu Xiao Huaying Wang Ningyuan Cai Yutong Li Kejia Xiang Wei Wei Tao Ye Zhongtai Zhang Shitong Wang Zilong Tang State Key Lab of new Ceramics and Fine Processing School of Materials Science and EngineeringTsinghua UniversityBeijing 100084China College of new Energy Advanced Chemical Engineering and Energy Materials Research CenterChina University of Petroleum(East China)Qingdao 266580China Department of Nuclear Science and engineering Massachusetts Institute of TechnologyCambridgeMA 02139USA

All-solid-state batteries,renowned for their enhanced safety and high energy density,have garnered broad *** solid electrolytes are highly anticipated for their balanced ***,their high Young’s modulus and inadaptability to volume change during cycling lead to poor contact and eventual battery *** this work,Young’s modulus of Li_(1+x)(OH)_(x)Cl samples is lowered to a level comparable to that of sulfide by regulating the–OH *** the–OH content increases,Young’s modulus of Li_(1+x)(OH)_(x)Cl samples decreases *** may be due to the local aggregation of–OH groups,forming cavities similar to LiOH structure,which reduces the bonding of the *** the premise of high Li-ion conductivity and electrochemical stability,the lowered Young’s modulus improves the contact between the solid electrolyte and the electrodes,forming a strong and stable interfacial layer,thereby improving interfacial and cycling *** symmetrical lithium metal cell shows excellent cycle performance of 600 h,and the assembled LiFePO_(4)|Li_(2.4)(OH)1.4Cl|Li cell shows significantly enhanced cycling endurance with 80%capacity retention after 150 *** work not only emphasizes the crucial importance of Young’s modulus in improving interface issues but also offers innovative approaches to advance the mechanical properties of solid electrolytes.

关键词： mechanical properties -OH content anti-perovskite solid electrolytes Li-ion batteries

Effect of cooling media on bead geometry,microstructure,and mechanical properties of wire arc additive manufactured IN718 alloy

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Advances in Manufacturing 2024年第1期12卷 124-149页

作者： Parveen Kumar Satish Kumar Sharma Ratnesh Kumar Raj Singh Department of Mechanical engineering Thapar Institute of Engineering and TechnologyPatialaPunjab147004India

This work aims to present and explore thermal management techniques for the wire arc additive manufacturing(WAAM)of IN718 *** heat can be mitigated via air or water *** this study,the material was deposited under four different heat-input conditions with air or water *** air cooling,the layer is deposited in a normal atmospheric air environment,whereas with water cooling,the material is deposited inside a water tank by varying the water *** validate the air and water cooling thermal management techniques,IN718 single-pass and multilayer linear walls were deposited using the bidirectional gas metal arc welding based WAAM setup under four different heat input *** the deposition of single layers,the temperature profiles were recorded,and the geometric and microstructural features were *** multilayer wall structures,the mechanical properties(hardness,tensile strength,and elongation)were determined and assessed using the corresponding microstructural features explored through scanning electron microscopy(SEM),energy dispersive spectroscopy(EDS),and electron backscatter diffraction(EBSD)*** microstructure observed through SEM analysis in the building direction was found to be nonhomogenous compared with that in the deposition ***,water cooling was found to govern bead characteristics,such as wall width and *** grain size and anisotropy of the mechanical properties also decreased in the water-cooled ***,water cooling is an economical and efficient method to mitigate excessive heat accumulation in WAAM-deposited IN718.

关键词： Air cooling Water cooling IN718 Bead characteristics Microstructure Electron backscatter diffraction(EBSD)

Cooperative composites anchored with single atom Pb and carbon confined PbO nanoparticles for superior lead-carbon batteries

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Journal of Energy Chemistry 2024年第10期97卷 486-497页

作者： Puqiang He Yi Yang Hui Huang Jing Huang Hongbiao Wang Yapeng He Zhongcheng Guo Faculty of Metallurgical and Energy engineering Kunming University of Science and Technology Metallurgical Electrode Material engineering technology Research Center of Yunnan Province Kunming Hendera technology Co.LTD.

The mitigation of sulphation and parasitic hydrogen evolution is considered as prominent research emphasis for the development of lead-carbon batteries（LCBs） in large-scale energy storage ***,cooperative Pb-C composites consisting of single atom Pb and carbon-encapsulated PbO nanoparticles were prepared by freeze-drying technique and pyrolytic reduction to address above *** innovative use of Pb2+to cross-link sodium alginate enabled a uniform distribution of Pb in the composites,generating Pb-C-PbO three-phase *** analysis and theoretical calculations revealed the synergistic interactions between single-atom Pb and PbO nanoparticles in suppressing parasitic hydrogen evolution and promoting the adsorption of Pb *** presence of monatomic Pb and PbO enhanced the affinity of the composites for the negative active materials and facilitated the transformation of the active materials from bulk into spherical shapes to enhance the specific surface area,thereby counteracting *** the coordinated integration of various functionalities offered by Pb@C-x,the cycle life of the battery at HRPSoC reaches 7025 cycles,which is two times for LCB with pure carbon ***,the discharge capacity increased from 3.52 to 3.79 *** study provides substantial insights into the construction of Pb-C composites for LCBs to inhibit negative sulphation and hydrogen evolution.

关键词： Hydrogen evolution Lead carbon composites Lead-carbon battery Negative sulphation Single-atom

Development of design charts to predict the dynamic response of pile supported machine foundations

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Frontiers of Structural and Civil engineering 2024年第4期18卷 663-679页

作者： Deepthi SUDHI Sanjit BISWAS Bappaditya MANNA Department of Civil engineering National Institute TechnologyWarangal 506004India Department of Civil engineering Indian Institute of TechnologyDelhi 110016India

This paper proposes design charts for estimating imperative input parameters for continuum approach analysis of the nonlinear dynamic response of *** and analytical studies using continuum approach have been conducted on single and 2×2 grouped piles under coupled and vertical modes of vibration,for different dynamic forces and pile *** these design charts are derived from model piles,the charts have been validated for prototype pile foundations using scaling *** experimental responses of model piles are scaled up and these responses exhibit good agreement with analytical *** study also extends to estimation of the errors in computing frequency–amplitude responses with an increase in pile *** is found that,with an increase in pile length,the errors also *** effectiveness of the proposed design charts is also checked with data based on different field setups given in existing literature,and these charts are found to be ***,the developed design charts can be beneficial in estimating the input parameters for continuum approach analysis for determining the nonlinear responses of pile supported machine foundations.

关键词： pile foundation vertical vibration coupled vibration continuum approach soil-pile separation boundary zone parameters

The Mechanism of Cube Texture Formation in Ni-7 at%W Substrate

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Journal of Wuhan University of technology(Materials Science) 2024年第5期39卷 1260-1269页

作者： ZHAO Congcong SUO Hongli JI Yaotang GAO Mangmang MA Lin LIU Min School of Materials Science and engineering Beijing University of TechnologyBeijing 100124China College of Materials and new Energy Ningxia UniversityYinchuan 750021China

In order to obtain the sharp cube texture,a new process,the intermediate annealing rolling technique,has been introduced to prepare the Ni7W *** this paper,a cubic texture content up to 98.5%within 10°of the standard cubic orientation is obtained in the final substrate and the influence of this improved rolling technique on the cube texture formation has been *** results show that the increased cube texture in the Ni7W substrate is caused by the optimized deformation texture and the increased nucleated fraction of the cube grains.

关键词： cube texture coated conductor deformation texture recrystallization

A new type of lipophilic hydrophobic self-repairing cellulose insulating paper developed with ST-110/FAS/PTFE ternary system as coating substrate

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High Voltage 2024年第2期9卷 474-483页

作者： Zhenglin Zeng Jinshan Qin Zuhao Wang Weimin Tan Chao Tang College of engineering and technology Southwest UniversityChongqingChina International R&D Center for new Technologies of Smart Grid and Equipment ChongqingChina

The moisture generated by the ageing of the oil-paper insulating system can easily lead to the deterioration of the performance of the insulating *** order to alleviate the impact of moisture on the performance of the insulating paper,we developed a kind of lipophilic hydrophobic self-repairing cellulose insulating paper(new insulating paper)based on the ternary system of polytetrafluoroethylene,fluorocarbon surfactant and fluorinated alkyl silane,and accelerated thermal ageing test for 45 days at 130°C was carried *** experimental results show that the new insulating paper with excellent lipophilic property can realise hydrophobic self-repairing through heat treatment after physical *** tensile strength and elongation at break of the new insulating paper increased by 5%–8%and 6.25%–27%respectively compared with the original cellulose insulating *** the end of ageing,the relative dielectric constant and dielectric loss factor of new insulating paper are 10.4%and 9.9%lower than that of the original cel-lulose insulating paper,while the breakdown voltage is 6.8%*** acid and moisture content produced during the ageing process of the insulating oil impregnated with new insulating paper are also less,indicating that the coating can delay the ageing of the insulating paper.

关键词： coating moisture cellulose

Urea-induced interfacial engineering enabling highly reversible aqueous zinc-ion battery

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Rare Metals 2024年第4期43卷 1599-1609页

作者： Bin-Rui Xu Quan-An Li Yong Liu Guang-Bin Wang Zi-He Zhang Feng-Zhang Ren School of Material Science and engineering Henan University of Science and TechnologyLuoyang471023China School of Information engineering Henan University of Science and TechnologyLuoyang471023China Longmen Laboratory Luoyang471023China Provincial and Ministerial Co-Construction of Collaborative Innovation Center for Non-Ferrous Metal new Materials and Advanced Processing technology Luoyang471023China

Aqueous zinc-ion batteries(AZIBs)have been regarded as prospective rechargeable energy storage devices because of the high theoretical capacity and low redox potential of Zn ***,the uncontrollable formation of dendrites and the water-induced side reactions at the Zn/electrolyte interface,and the poor reversibility under a high current density(>2 mA·cm^(-2))and large area capacity(>2 mAh·cm^(-2))still limit the practical applications of ***,a strategy that can overcome these difficulties is urgently ***,we introduce an environmentally friendly and low-cost additive,namely urea,to the electrolyte of AZIBs to induce uniform Zn deposition and suppress the side *** of the adsorption behavior,electrochemical characterization,and observations of the morphology revealed the interfacial modification induced by urea on the Zn/electrolyte interface,demonstrating its huge potential in ***,the long-term cycling stability(over2100 h)of a Zn/Zn symmetric cell under a high current density of 5 mA·cm^(-2)and a capacity of 5 mAh·cm^(-2)was achieved with a 1 mol·L^(-1)ZnSO_(4)electrolyte with the urea ***,the assembled Zn/NH_4V_4O_(10)full cell with urea exhibited excellent cycling performance and an outstanding average Coulombic efficiency of 99.98%.These results indicate that this is a low-cost and effective additive strategy for realizing highly reversible AZIBs.

关键词： Zn anode Urea additive Interface engineering Dendrite growth Side reaction

Heterostructure:application of absorption-catalytic center in lithium-sulfur batteries

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Rare Metals 2024年第4期43卷 1461-1487页

作者： Fei Wang Chun-Man Yang Yong-Qi Wang Dan You Wen-Hao Yang Rong-Wei Huang Ji-Yue Hou Qian Wang Ying-Jie Zhang Ying Wang Yue-Jing Zeng Yi-Yong Zhang Xue Li National Local Joint engineering Research Center for Lithium-Ion Batteries and Materials Preparation technology Key Laboratory of Advanced Batteries Materials of Yunnan ProvinceFaculty of Metallurgical and Energy EngineeringKunming University of Science and TechnologyKunming650093China College of Electrical Information engineering Panzhihua UniversityPanzhihua617000China State Key Laboratory of Physical Chemistry of Solid Surfaces Collaborative Innovation Centre of Chemistry for Energy MaterialsState-Province Joint Engineering Laboratory of Power Source Technology for New Energy VehicleEngineering Research Center of Electrochemical TechnologyMinistry of EducationCollege of Chemistry and Chemical EngineeringXiamen UniversityXiamen361005China

Due to the high theoretical specific capacity(1675 mAh·g^(-1)),low cost,and high safety of the sulfur cathodes,they are expected to be one of the most promising rivals for a new generation of energy storage ***,the shuttle effect,low conductivity of sulfur and its discharge products,volume expansion,and other factors hinder the commercialization of lithium-sulfur batteries(LSBs).The development of sulfur-fixing materials and the design of multifunctional materials to enhance the electrochemical performance of LSBs have been the main research priorities in recent *** of the advantages of high conductivity,built-in electric field,and good synergism,more and more researchers have employed heterostructure into sulfur-fixing materials to enhance the catalytic and absorption ability for *** this review,the principle of heterostructure and the mechanism of enhancing the performance of lithium-sulfur batteries are *** applications of heterostructure in cathode and interlayer of LSBs in the latest years are ***,the cutting-edge troubles and possibilities of heterostructures in LSBs are briefly presented.

关键词： Lithium-sulfur batteries(LSBs) Heterostructure Built-in electric field Catalytic Absorption