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Journal of Energy Chemistry 2025年第1期100卷 621-627页

作者： Fei Lv Longjie Liu Jiazhe Wu Pengfei Wang Lixia Pan Dengwei Jing Yubin Chen International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University

Combining water electrolysis and rechargeable battery technologies into a single system holds great promise for the co-production of hydrogen （H2） and ***,the design and development of such systems is still in its ***,an integrated hydrogen-oxygen （O2）-electricity co-production system featuring a bipolar membrane-assisted decoupled electrolyzer and a Na-Zn ion battery was established with sodium nickelhexacyanoferrate （NaNiHCF） and Zn2+/Zn as dual redox *** decoupled electrolyzer enables to produce H2and O2in different time and space with almost 100%Faradaic efficiency at 100 mA ***,the charged NaNiHCF and Zn electrodes after the electrolysis processes formed a Na-Zn ion battery,which can generate electricity with an average cell voltage of 1.75 V at 10 m A *** connecting Si photovoltaics with the modular electrochemical device,a well-matched solar driven system was built to convert the intermittent solar energy into hydrogen and electric energy with a solar to hydrogen-electricity efficiency of 16.7%,demonstrating the flexible storage and conversion of renewables.

关键词： Hydrogen Electricity Decoupled water electrolyzer Na-Zn ion battery Solar energy

Electrochemical conversion of methane to bridge the gap in the artificial carbon cycle

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Journal of Energy Chemistry 2025年第1期100卷 286-308页

作者： Yuhao Peng Yuefeng Song Ihar Razanau Juanxiu Xiao Wei Xiao Di Hu Guoxiong Wang College of Chemistry and Molecular Sciences Hubei Key Laboratory of Electrochemical Power Sources Wuhan University State key laboratory of Catalysis Dalian National Laboratory for Clean Energy iChEM (Collaborative Innovation Center of Chemistry for Energy Materials) Dalian Institute of Chemical Physics Chinese Academy of Sciences laboratory of Physical-Chemical Technologies SSPA Scientific and Practical Materials Research Centre of NAS of Belarus State key laboratory of Marine Resources Utilization in South China Sea Collaborative Innovation Center of Marine Science and Technology School of Marine Science and Engineering Hainan University Department of Chemical and Environmental Engineering University of Nottingham Ningbo China

Methane, an abundant one-carbon（C1） resource, is extensively used in the industrial production of vital fuels and value-added chemicals. However, current industrial methane conversion technologies are energy-and carbon-intensive, mainly due to the high activation energy required to break the inert C–H bond, low selectivity, and problematic side reactions, including CO2emissions and coke deposition. Electrochemical conversion of methane（ECM） using intermittent renewable energy offers an attractive solution, due to its modular reactor design and operational flexibility across a broad spectrum of temperatures and pressures. This review emphasizes conversion pathways of methane in various reaction systems, highlighting the significance and advantages of ECM in facilitating a sustainable artificial carbon cycle. This work provides a comprehensive overview of conventional methane activation mechanisms and delineates the complete pathways of methane conversion in electrolysis contexts. Based on surface/interface chemistry, this work systematically analyzes proposed reaction pathways and corresponding strategies to enhance ECM efficiency towards various target products, including syngas, hydrocarbons, oxygenates, and advanced carbon materials. The discussion also encompasses opportunities and challenges for the ECM process, including insights into ECM pathways, rational electrocatalyst design, establishment of benchmarking protocols, electrolyte engineering, enhancement of CH4conversion rates, and minimization of CO2emission.

关键词： Methane Electrochemical conversion Reaction mechanism Catalyst design Electrode Electrocatalysis

16.48% Efficient solution-processed CIGS solar cells with crystal growth and defects engineering enabled by Ag doping strategy

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Journal of Energy Chemistry 2025年第1期100卷 59-65页

作者： Mengyu Xu Shaocong Yan Ting Liang Jia Jia Shengjie Yuan Dongxing Kou Zhengji Zhou Wenhui Zhou Yafang Qi Yuena Meng Litao Han Sixin Wu key laboratory for Special Functional Materials of MOE National & Local Joint Engineering Research Centre for High-efficiency Display and Lighting Technology School of Nanoscience and Materials Engineering Henan University

Solution-processed Cu（In,Ga）Se2（CIGS） solar cells suffer from serious carrier recombination and power conversion efficiency（PCE） loss because of the poor film properties and easy formation of ***, we propose Ag&Se co-selenization strategy to enhance the crystallization and passivate harmful defects of the CIGS films. The formation of Ag-Se phase during the selenization process enables the formation of large grains and suppresses the deep level defects. It is found that Ag doping can enlarge the depletion region width, lower the Urbach energy and prolong the carrier lifetime. As a result, a champion solution-processed CIGS solar cell presents a high efficiency of 16.48% with the highly improved opencircuit voltage（VOC） of 662 m V and fill factor（FF） of 75.8%. This work provides an efficient strategy to prepare high quality solution-processed CIGS films for high-performance CIGS solar cells.

关键词： CIGS solar cells Solution-processed method Ag doping Crystal growth Defects engineering

Research of inverse mathematical model to high-speed trains

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Journal of Central South University 2014年第1期21卷 428-438页

作者：朱涛肖守讷马卫华阳光武 traction power national key laboratory Southwest Jiaotong University

Operation safety and stability of the train mainly depend on the interaction between the wheel and *** of wheel/rail contact force is important for vehicle control systems that aim to enhance vehicle stability and passenger *** wheel/rail contact forces of high-speed train are very difficult to measure directly,a new estimation process for wheel/rail contact forces was introduced in this *** on the state space equation,dynamic programming methods and the Bellman principle of optimality,the main theoretical derivation of the inversion mathematical model was *** new method overcomes the weakness of large fluctuations which exist in current inverse ***-speed vehicle was chosen as the research object,accelerations of axle box as input conditions,10 degrees of freedom vertical vibration model and 17 degrees of freedom lateral vibration model were established,*** 250 km/h,the vertical and lateral wheel/rail forces were *** the time domain and frequency domain,the comparison of the results between inverse and SIMPACK models were *** results show that the inverse mathematical model has high precision for inversing the wheel/rail contact forces of an operation high-speed vehicle.

关键词： load inversion high-speed vehicle wheel/rail contact force derailment index

Advancements and Challenges in Organic–Inorganic Composite Solid Electrolytes for All‑Solid‑State Lithium Batteries

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Nano-Micro Letters 2025年第1期17卷 46-97页

作者： Xueyan Zhang Shichao Cheng Chuankai Fu Geping Yin Liguang Wang Yongmin Wu Hua Huo State key laboratory of Space power‑Sources School of Chemistry and Chemical EngineeringHarbin Institute of TechnologyHarbin 150001People’s Republic of China College of Chemical and Biological Engineering Zhejiang UniversityHangzhou 310058People’s Republic of China State key laboratory of Space power-Sources 2965 Dongchuan RoadMinhang DistrictShanghai 200240People’s Republic of China

To address the limitations of contemporary lithium-ion batteries,particularly their low energy density and safety concerns,all-solid-state lithium batteries equipped with solid-state electrolytes have been identified as an up-and-coming *** the various SEs,organic–inorganic composite solid electrolytes(OICSEs)that combine the advantages of both polymer and inorganic materials demonstrate promising potential for large-scale ***,OICSEs still face many challenges in practical applications,such as low ionic conductivity and poor interfacial stability,which severely limit their *** review provides a comprehensive overview of recent research advancements in ***,the influence of inorganic fillers on the main functional parameters of OICSEs,including ionic conductivity,Li+transfer number,mechanical strength,electrochemical stability,electronic conductivity,and thermal stability are systematically *** lithium-ion conduction mechanism of OICSE is thoroughly analyzed and concluded from the microscopic ***,the classic inorganic filler types,including both inert and active fillers,are categorized with special emphasis on the relationship between inorganic filler structure design and the electrochemical performance of ***,the advanced characterization techniques relevant to OICSEs are summarized,and the challenges and perspectives on the future development of OICSEs are also highlighted for constructing superior ASSLBs.

关键词： Composite solid electrolytes Inorganic filler Interfacial stability Li-ion conduction mechanism Characterization techniques

Wheel/rail dynamic interaction due to excitation of rail corrugation in high-speed railway

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Science China(Technological Sciences) 2015年第2期58卷 226-235页

作者： WANG Kai Yun LIU Peng Fei ZHAI Wan Ming HUANG Chao CHEN Zai Gang GAO JianMin State key laboratory of traction power Southwest Jiaotong University

Characteristics of wheel-rail dynamic interaction due to the rail corrugation in a high-speed railway are analyzed based on the theory of vehicle-track coupled dynamics in this *** of the corrugation wavelength and depth on the wheel-rail dynamic performance are *** results show that,under the excitation of a measured rail corrugation,the wheel-rail dynamic interaction of high-speed railway is enhanced obviously,and the high-frequency dynamic force between wheel and rail is generated,which has an obvious impact on the vibrations of the wheelset and rail,and little effect on the vibration of the frame and *** the corrugation wavelength is shorter than the sensitive wavelength,the wheel-rail vertical force will increase with the growth of the corrugation wavelength,otherwise,it will ***,the wheel-rail vertical force keeps increasing with the growth of corrugation ***,if the corrugation wavelength is shorter than the sensitive wavelength,the wheel-rail vertical force will increase with the decrease of the running speed,otherwise,it will *** is also found that the critical wavelength of corrugation increases with the growth of the corrugation depth and the running speed,and the critical depth of corrugation is nonlinearly related to the sensitive wavelength.

关键词： dynamic interaction rail corrugation high-speed railway critical wavelength critical depth sensitive wavelength

Numerical Analysis of Rolling-sliding Contact with the Frictional Heat in Rail

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Chinese Journal of Mechanical Engineering 2014年第1期27卷 41-49页

作者： LI Wei WEN Zefeng JIN Xuesong WU Lei State key laboratory of traction power Southwest Jiaotong University

Thermal damage caused by frictional heat of rolling-sliding contact is one of the most important failure forms of wheel and rail. Many studies of wheel-rail frictional heating have been devoted to the temperature field, but few literatures focus on wheel-rail thermal stress caused by frictional heating. However, the wheel-rail creepage is one of important influencing factors of the thermal stress In this paper, a thermo-mechanical coupling model of wheel-rail rolling-sliding contact is developed using thermo-elasto-plastic finite element method. The effect of the wheel-rail elastic creepage on the distribution of heat flux is investigated using the numerical model in which the temperature-dependent material properties are taken into consideration. The moving wheel-rail contact force and the frictional heating are used to simulate the wheel rolling on the rail. The effect of the creepage on the temperature rise, thermal strain, residual stress and residual strain under wheel-rail sliding-rolling contact are investigated. The investigation results show that the thermally affected zone exists mainly in a very thin layer of material near the rail contact surface during the rolling-sliding contact. Both the temperature and thermal strain of rail increase with increasing creepage. The residual stresses induced by the frictional heat in the surface layer of rail appear to be tensile. When the creepage is large, the frictional heat has a significant influence on the residual stresses and residual strains of rail. This paper develops a thermo-meehanical coupling model of wheel-rail rolling-sliding contact, and the obtained results can help to understand the mechanism of wheel/rail frictional thermal fatigue.

关键词： wheel-rail rolling-sliding contact frictional heating creepage residual stress/strain,thermo-elasto-plastic finite element method

Effect of Train Carbody's Parameters on Vertical Bending Stiffness Performance

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Chinese Journal of Mechanical Engineering 2016年第6期29卷 1120-1127页

作者： YANG Guangwu WANG Changke XIANG Futeng XIAO Shoune State key laboratory of traction power Southwest Jiaotong University

Finite element analysis（FEA） and modal test are main methods to give the first-order vertical bending vibration frequency of train carbody at present, but they are inefficiency and waste plenty of time. Based on Timoshenko beam theory, the bending deformation, moment of inertia and shear deformation are considered. Carbody is divided into some parts with the same length, and it＇s stiffness is calculated with series principle, it＇s cross section area, moment of inertia and shear shape coefficient is equivalent by segment length, and the fimal corrected first-order vertical bending vibration frequency analytical formula is deduced. There are 6 simple carbodies and 1 real carbody as examples to test the formula, all analysis frequencies are very close to their FEA frequencies, and especially for the real carbody, the error between analysis and experiment frequency is 0.75%. Based on the analytic formula, sensitivity analysis of the real carbody＇s design parameters is done, and some main parameters are found. The series principle of carbody stiffness is introduced into Timoshenko beam theory to deduce a formula, which can estimate the first-order vertical bending vibration frequency of carbody quickly without traditional FEA method and provide a reference to design engineers.

关键词： train carbody vertical bending vibration frequency analysis formula sensitivity analysis

Safety threshold of high-speed railway pier settlement based on train-track-bridge dynamic interaction

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Science China(Technological Sciences) 2015年第2期58卷 202-210页

作者： CHEN Zhao Wei ZHAI Wan Ming CAI Cheng Biao SUN Yu State key laboratory of traction power Southwest Jiaotong University

This paper presents a method to determine the safety threshold of bridge pier settlement in high-speed *** analytical expression of the mapping relationship between the pier settlement and the rail deformation is derived theoretically for the double block ballastless track-bridge *** adopting the superposition of the track random irregularity and the rail deformation caused by the pier settlement as the excitation inputs,the variations of vehicle dynamics indices with pier settlement are comparatively ***,the safety threshold of the bridge pier settlement is obtained according to the limit of vehicle running safety and ride comfort indices of the high-speed *** show that the dynamics indices of different trains have different sensitivities to the pier settlement,and the train CRH2C is the most sensitive one among all the types of Chinese high-speed *** passing through the bridges in common span with pier settlement at the speed of 250–350 km/h,the trains suffer the low-frequency excitations,and the vertical acceleration of car body is most sensitive to the pier settlement of all the dynamics *** the car body vertical acceleration just exceeds the allowable limit,the critical settlement value is 23.4 mm,which is much bigger than the pier differential settlement limit in the current code for Chinese high-speed railways.

关键词： high-speed railway pier settlement safety threshold dynamic characteristics train-track-bridge dynamic interaction

Effect of RANS Turbulence Model on Aerodynamic Behavior of Trains in Crosswind

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Chinese Journal of Mechanical Engineering 2019年第5期32卷 145-156页

作者： Tian Li Deng Qin Jiye Zhang State key laboratory of traction power Southwest Jiaotong University

The numerical simulation based on Reynolds time-averaged equation is one of the approved methods to evaluate the aerodynamic performance of trains in ***,there are several turbulence models,trains may present different aerodynamic performances in crosswind using different turbulence *** order to select the most suitable turbulence model,the inter-city express 2(ICE2)model is chosen as a research object,6 different turbulence models are used to simulate the flow characteristics,surface pressure and aerodynamic forces of the train in crosswind,respectively.6 turbulence models are the standard k-ε,Renormalization Group(RNG)k-ε,Realizable k-ε,Shear Stress Transport(SST)k-ω,standard k-ωand Spalart-Allmaras(SPA),*** numerical results and the wind tunnel experimental data are *** results show that the most accurate model for predicting the surface pressure of the train is SST k-ω,followed by Realizable k-ε.Compared with the experimental result,the error of the side force coefficient obtained by SST k-ωand Realizable k-εturbulence model is less than 1%.The most accurate prediction for the lift force coefficient is achieved by SST k-ω,followed by RNG k-ε.By comparing 6 different turbulence models,the SST k-ωmodel is most suitable for the numerical simulation of the aerodynamic behavior of trains in crosswind.

关键词： Turbulence model Crosswind High speed train Numerical simulation Aerodynamic