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Bifunctional bridging capping layer enables 24.5% efficiency of perovskite solar cells with polymer-based hole transport materials

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Science China Chemistry 2025年第1期 350-359页

作者： Can Zhu Yiyang Wang Lei Meng Beibei Qiu Jing Li Shucheng Qin Ke Hu Xin Jiang Wenbin Lai Minchao Liu Zhe Liu Chenxing Lu Jinyuan Zhang Yongfang Li Beijing national laboratory for Molecular Sciences CAS Key Laboratory of Organic Solids Institute of Chemistry Chinese Academy of Sciences School of Chemical Science University of Chinese Academy of Sciences key laboratory of Solid State Optoelectronic Devices of Zhejiang Province College of Physics and Electronic Information Engineering Zhejiang Normal University key laboratory of Photochemical Conversion and Optoelectronic Materials Technical Institute of Physics and ChemistryChinese Academy of Sciences laboratory of Advanced Optoelectronic Materials College of Chemistry Chemical Engineering and Materials ScienceSoochow University

Developing a bridge capping layer between perovskite and hole transport layer materials（HTMs） in the n-i-p perovskite solar cells（pero-SCs） is an effective approach to modify the morphology of HTMs and passivate the perovskite ***, we select the quinoxaline-based bifunctional passivation agent, quinoxalin-6-yl-methylamine hydrochloride（Qx MACl）,as the bridging layer, and a D-A copolymer PBQ12 containing the same quinoxaline unit as an HTM for the n-i-p pero-SCs. Due to the π-π stacking among the common quinoxaline units in the bridge layer and HTM, Qx MACl induces the π-π stacking of the PBQ12 film and improves the film morphology of HTMs with better conductivity. Additionally, Qx MACl can effectively passivate the perovskite surface, and PBQ12 possesses appropriate energy levels and high hole mobility. The pero-SCs based on FAPbI3with PBQ12/Qx MACl treatment showed a higher power conversion efficiency（PCE） of 24.05% and outstanding stability, maintaining 95.4% and 92.1% of its initial PCE after 750 h of storage and after over 800 h of thermal annealing at 85 °C, respectively. To further enhance the PCE of the PBQ12/Qx MACl-based devices, we developed a non-metal ion dopant for the PBQ12 HTM. Through trace doping of PBQ12 HTM by the non-metal ion dopant, the PCE of the PBQ12/Qx MACl-based devices reached 25.24%（the calibrated PCE of 24.55% by the national Institute of Metrology, China）.

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Modifying metabolic and immune hallmarks of cancer by a copper complex

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Science China Chemistry 2025年

作者： Chengyan Chu Yunhua Zhang Chengyuan Qian Xiuzhi Yang Yicun Shang Zijian Guo Xiaoyong Wang State key laboratory of Pharmaceutical Biotechnology School of Life Sciences Nanjing University State key laboratory of Coordination Chemistry School of Chemistry and Chemical Engineering Nanjing University

Metabolic adaptation of cancer cells is a key tactic for maintaining their tumorigenicity and viability in the tumor immune microenvironment （TIME）.Concurrent modulation on the metabolic pathway and immune system could change the living condition of cancer cells and potentiate the efficacy of anticancer drugs.A copper complex （DDCu） was designed to influence the energy metabolism of cancer cells and reshape the *** restrained the production and transportation of lactate by inhibiting the expression of lactate dehydrogenase and monocarboxylate transporter 4,thereby altering the metabolic pathway of cancer cells and improving the acidic tumor ***,DDCu was reduced to Cu+by cellular glutathione to react with lipoylated proteins of the tricarboxylic acid cycle and destabilize the Fe–S cluster proteins,leading to the aggregation of dihydrolipoamide S-acetyltransferase and cuproptosis in cancer ***,DDCu promoted the polarization of macrophages from the M2 to M1 phenotype,activated CD4+and CD8+T cells,and reversed the *** a result,DDCu inhibited the tumor growth through a synergy between metabolic regulation and immunomodulation.

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Numerical Investigation on the Heat Transfer Characteristics of Supercritical Water in a Non-Uniformly Heated Tube for a Supercritical CFB Boiler

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Journal of Thermal Science 2023年第5期32卷 1807-1818页

作者： DU Xiaocheng SONG Yuanyuan XIANG Yuxuan ZHOU Yanjun WANG Aoyu YANG Dong State key laboratory of multiphase flow in power engineering Xi'an Jiaotong UniversityXi'an 710049China

In this paper,a numerical model was built by ANSYS FLUENT to investigate the heat transfer performances of supercritical water in a circumferential non-uniformly heated vertical *** Shear Stress Transport(SST)k-ωmodel was adopted for describing *** operating parameters are chosen according to a 660 MW ultra-supercritical CFB *** heat transfer performances under different operating parameters,such as boiler load,flow direction and heat flux distribution are *** temperature and heat flux on inner wall varies along the circumference and show symmetric *** overall heat transfer performances at each cross section are better than the local heat transfer performance of midpoint of heating *** direction has a great influence on heat transfer performance;it changes the radial distribution of axial velocity and then affects the turbulence ***,upward flow condition shows a better heat transfer *** heat flux improves both the overall and local heat transfer *** the heat flux area is not conducive to the overall heat transfer,but does not affect the local heat transfer at the midpoint of heating ***,a new correlation is fitted based on the simulated results of supercritical water heat transfer with circumferential non-uniform heat flux distributions.

关键词： supercritical CFB boiler circumferential non-uniform heat flux numerical simulation heat transfer correlation

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A Review on Thermal Design of Liquid Droplet Radiator System

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Journal of Thermal Science 2021年第2期30卷 394-417页

作者： CHONG Daotong ZHU Maoguo ZHAO Quanbin CHEN Weixiong YAN Junjie State key laboratory of multiphase flow in power engineering Xi'an Jiaotong UniversityXi'an 710049China

Liquid Droplet Radiator (LDR) system is regarded as a quite promising waste heat rejection system for aerospace engineering.A comprehensive review on the state-of-the-art of LDR system was carried *** thermal design considerations of crucial components such as working fluid,droplet generator and collector,intermediate heat exchanger,circulating pump and return pipe were *** state-of-the-art of existing mathematical models of radiation and evaporation characteristics of droplet layer from literatures were ***,thermal designs of three LDR systems were *** weight and required planform area between the rectangular and triangular LDR systems were respectively compared and the evaporation models for calculating the mass loss were *** on the review,some prospective studies of LDR system were put forward in this paper.

关键词： Liquid Droplet Radiator(LDR)system thermal design considerations radiative heat transfer evaporation loss

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Physical Layer Security Scheme With AoI-Awareness for Industrial IoT Based on Covert Communications

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IEEE/CAA Journal of Automatica Sinica 2025年第1期 276-278页

作者： Yaping Li Zhi-Xin Liu Jia-Wei Su Ya-Zhou Yuan the key laboratory of Industrial Computer Control engineering of Hebei Province Yanshan University

Dear Editor,Industrial Internet of things(IIoT) is a typical application of cyberphysical system(CPS). In the IIoT, wireless communication is an inevitable trend to replace the deployment-limited wired transmission for cases with large-scale and mobile devices. However, wireless communication gives rise to critical issues related to physical security, such as malicious detections and attacks [1].

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Discrete particle simulation of mixed sand transport

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Particuology 2012年第2期10卷 221-228页

作者： Fengjiun Xiao Lieiin Guo Debiao Li Yueshe Wang State key laboratory of multiphase flow in power engineering Xi'an Jiaotong UniversityXi'an 710049China

An Eulerian/Lagrangian numerical simulation is performed on mixed sand transport. Volume averaged Navier-Stokes equations are solved to calculate gas motion, and particle motion is calculated using Newton＇s equation, involving a hard sphere model to describe particle-to-particle and particle-to-wall collisions. The influence of wall characteristics, size distribution of sand particles and boundary layer depth on vertical distribution of sand mass flux and particle mean horizontal velocity is analyzed, suggesting that all these three factors affect sand transport at different levels. In all cases, for small size groups, sand mass flux first increases with height and then decreases while for large size groups, it decreases exponen- tially with height and for middle size groups the behavior is in-between. The mean horizontal velocity for all size groups well fits experimental data, that is, increasing logarithmically with height in the middle height region. Wall characteristics greatly affects particle to wall collision and makes the fiat bed similar to a Gobi surface and the rough bed similar to a sandy surface. Particle size distribution largely affects the sand mass flux and the highest heights they can reach especially for larger particles.

关键词： Mixed sand transportHard sphere modelSand mass fluxParticle horizontal mean velocity

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Effect of temperature on Lu’an bituminous char structure evolution in pyrolysis and combustion

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Frontiers in Energy 2021年第1期15卷 14-25页

作者： Yandi ZHANG Yinhe LIU Xiaoli DUAN Yao ZHOU Xiaoqian LIU Shijin XU State key laboratory of multiphase flow in power engineering Xi'an Jiaotong UniversityXi'an 710049China

In the process of pyrolysis and combustion of coal particles, coal structure evolution will be affected by the ash behavior, which will further affect the char reactivity, especially in the ash melting temperature zone. Lu’an bituminous char and ash samples were prepared at the N_(2) and air atmospheres respectively across ash melting temperature. A scanning electron microscope (SEM) was used to observe the morphology of char and ash. The specific surface area (SSA) analyzer and thermogravimetric analyzer were respectively adopted to obtain the pore structure characteristics of the coal chars and combustion parameters. Besides, an X-ray diffractometer (XRD) was applied to investigate the graphitization degree of coal chars prepared at different pyrolysis temperatures. The SEM results indicated that the number density and physical dimension of ash spheres exuded from the char particles both gradually increased with the increasing temperature, thus the coalescence of ash spheres could be observed obviously above 1100℃. Some flocculent materials appeared on the surface of the char particles at 1300℃, and it could be speculated that β-Si_(3)N_(4) was generated in the pyrolysis process under N_(2). The SSA of the chars decreased with the increasing pyrolysis temperature. Inside the char particles, the micropore area and its proportion in the SSA also declined as the pyrolysis temperature increased. Furthermore, the constantly increasing pyrolysis temperature also caused the reactivity of char decrease, which is consistent with the results obtained by XRD. The higher combustion temperature resulted in the lower porosity and more fragments of the ash.

关键词： bituminous char pyrolysis ash structure evolution reactivity

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Measurement,Modelling and Analysis of Residence Time Distribution Characteristics in a Continuous Hydrothermal Reactor

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Journal of Thermal Science 2024年第4期33卷 1301-1311页

作者： LI Yi ZHAI Binjiang WANG Junying WANG Weizuo JIN Hui State key laboratory of multiphase flow in power engineering Xi’an Jiaotong UniversityXi’an710049China

Understanding the residence time distribution(RTD)of a continuous hydrothermal reactor is of great significance to improve product quality and reaction *** this work,an on-line measurement system is attached to a continuous reactor to investigate the characteristics of *** approach that can accurately fit and describe the experimental measured RTD curve by finding characteristic values is proposed for analysis and *** RTD curves of three experiment groups are measured and the characteristic values are *** show that increasing total flow rate and extending effective reactor length have inverse effect on average residence time,but they both cause the reactor to approach a plug flow reactor and improve the materials *** branch flow rate fraction has no significant effect on RTD characteristics in the scope of the present work except the weak negative correlation with the average residence ***,the natural convection stirring effect can also increase the average residence time,especially when the forced flow is *** analysis reveals that it is necessary to consider the matching of natural convection,forced flow and reactor size to control RTD when designing the hydrothermal reactor and working conditions.

关键词： continuous reactor residence time distribution modelling

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Effects of physical properties of supercritical water on coarse graining of particle cluster

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Particuology 2023年第11期82卷 166-178页

作者： Xiaoyu Li Huibo Wang Yi Li Hui Jin State key laboratory of multiphase flow in power engineering Xi'an Jiaotong UniversityXi'an710049China

The coarse graining of particle cluster is of great significance to the study of a fluidized bed. The effects of variations in the physical properties of supercritical water on the coarse graining of particle cluster are investigated in this work. The drag coefficient distributions of the particle cluster are not influenced by the physical properties. However, the physical properties have effects on the values of drag coefficient. The effects of physical properties are weaker in the case of large particle concentrations. Furthermore, the physical properties lead to that the effect of particle cluster wake on the drag of downstream particles being significantly different from that of constant property flow. The variation trend of drag of coarse graining particle is consistent with that of isolated particle. The physical properties lead to significant differences in the values of drag. In this paper, the dominance of the effects of physical properties in a variety of cases is confirmed. Finally, a physical properties effect model is developed accordingly.

关键词： Supercritical water Variations in physical properties Fluidized bed Coarse grain method Particle drag

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Effects of physical properties of supercritical water on heat transfer characteristics of single particle within a particle cluster Author links open overlay panel

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Particuology 2024年第8期91卷 291-302页

作者： Xiaoyu Li Bowei Zhang Huibo Wang Hui Jin State key laboratory of multiphase flow in power engineering Xi'an Jiaotong UniversityXi'an710049China

The complex physical properties of supercritical water(SCW)make the heat transfer characteristics of particles within a particle cluster *** heat transfer characteristics of single particle within a particle cluster in SCW,influenced by surrounding particles,have not been effectively *** numerical simulations were conducted to investigate the heat transfer characteristics of particle clusters in SCW under different *** results were compared and analyzed with those from constant property *** was found that Reynolds number(Re)and the void fraction of particle cluster have no special effects on the variation trends of Nusselt number(Nu)for the focused ***,the particle temperature had a significant effect on the variation trends of *** effect of Re on the heat transfer rate exponent(η)of the focused particle can be divided into two zones:a significant effect zone and a non-significant effect *** effect of void fraction onηin the non-significant effect zone was *** the non-significant effect zone,ηdecreased with the increasing particle *** the significant effect zone,the variation trends ofηbecame more *** fundamental reason for this series of phenomena is the changes in distribution of physical properties.A model forηwas developed for the non-significant effect *** model can filter out the effects of Re and certain particle cluster spatial configurations,and it demonstrates good predictive performance.

关键词： Supercritical water Particle cluster Heat transfer characteristics Heat transfer rate exponent Physical properties correction

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