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Optimization of both coercivity and knee-point magnetic field of Sm2Co17-type magnets via solid solution process

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Journal of rare earths 2020年第11期38卷 1224-1230,I0003页

作者： Shuai Wang Yikun Fang Kuikui Song Xiaoyu Zhu Lei Wang Wei Sun Wei Pan Minggang Zhu Wei Li Division of functional materials research Central Iron and Steel Research InstituteBeijing 100081China national engineering research Center for Magnetic materials Beijing 102600China

It is confirmed that phase homogenization is very important for improving the magnetic properties of 2:17-type Sm-Co sintered magnets,In this work,the influence of solid solution process on microstructure and magnetic properties of the Sm(CobalFe0.233Cu0.073Zr0.024)7.6 sintered magnets was systematically *** the solid-solution treating duration(tS)increasing from 0 to 4 h,intrinsic coercivity(Hcj)increases from 12.83 to 36.54 kOe,magnetic field at knee-point(Hknee)increases from2.76 to 19.14 kOe,and the maximum energy product increases from 19.79 to 29.48 *** electron probe microanalyzer results reveal that there mainly exist gray and dark regions besides"white"rare earth-rich phase,and the conte nt of Sm,Fe and Cu elements for the two kinds of regions changes a lot for the specimens,Furthermore,with tS increasing up to 4 h,the elements content deviation between the gray and dark regions becomes small gradually from 3.94 at%to 0.27 at%,7.66 at%to 0.21 at%and 7.27 at%to 0.16 at%for Sm,Fe and Cu elements,***,transmission electron microscopy results show that the distribution of cell size is much more concentrated for aged specimens when tS is 4 *** is also found that the Cu concentration at cell boundaries for the 4 h solid-solution treatment case shows relatively higher values and greater concentration gradient(1.94 at%/nm).It is verified that sufficient solution treatment duration is prerequisite to form these homogeneous microstructural features,which are the key points for obtaining both high Hcj and Hknee.

关键词： Sm-Co magnets Solid solution process Coercivity Microstructure Cell size rare earths

Large magnetocaloric effect and magnetoresistance in ErNi single crystal

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Journal of materials Science & Technology 2021年第27期86卷 56-63页

作者： Xuanwei Zhao Xianming Zheng Xiaohua Luo Fei Gaod Hai Zeng Guang Yu Sajjad Ur Rehman Changcai Chen Shengcan Ma Weijun Ren Zhenchen Zhong Jiangxi Key Laboratory for rare earth Magnetic materials and Devices College of Rare earthsJiangxi University of Science and TechnologyGanzhou 341000People’s Republic of China Ganzhou Key Laboratory for rare earth Magnetic functional materials and Physics College of Rare earthsJiangxi University of Science and TechnologyGanzhou 341000People’s Republic of China School of materials Science and engineering Faculty of Materials Metallurgy and ChemistryJiangxi University of Science and TechnologyGanzhou 341000People’s Republic of China Shenyang national Laboratory for materials Science Institute of Metal ResearchChinese Academy of SciencesShenyang 110016People’s Republic of China Key Laboratory of Electromagnetic Processing of materials Northeastern UniversityShenyang110819People’s Republic of China

The magnetic properties,magnetocaloric effect and magnetoresistance in Er Ni single crystal have been investigated in *** decreasing temperature,Er Ni single crystal undergoes two successive magnetic transitions:a paramagnetic to ferromagnetic transition at T_(C)=11 K and a spin-reorientation transition at TS_(R)=5 ***,a sharp field-induced metamagnetic transition is observed below the T_(C)along the a *** Ni single crystal possesses a giant magnetocaloric effect around T_(C).The maximum magnetic entropy change is-36.1 J(kg K)^(-1)along the a axis under the field change of 0-50 k *** particular,the rotating magnetocaloric effect in Er Ni single crystal reaches its maximum under a relatively low field,and the maximum rotating entropy change with a value of 9.3 J(kg K)^(-1)is obtained by rotating the applied field from the[011]to[100]directions under 13 k *** results suggest that Er Ni could be a promising candidate for magnetic refrigeration working at liquid-helium temperature ***,a complicated transport behavior is uncovered in Er Ni single crystal,which is attributed to the complex magnetic states and magnetic polaronic *** positive and negative magnetoresistance are observed.A considerable large magnetoresistance with the value of-34.5%is acquired at 8 K under50 k Oe when the field is along the[100]direction.

关键词： rare-earth transition-metal intermetallics Magnetic refrigeration Magnetocaloric effect Magnetocrystalline anisotropy Magnetoresistance

Zr-doped titanium lithium ion sieve and EP-granulated composite:Superb adsorption and recycling performance

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Particuology 2022年第10期20卷 100-110页

作者： Suyu Zhou Xiaojing Guo Xi Yan Yan Chen Wanzhong Lang The Education Ministry Key Laboratory of Resource Chemistry Shanghai Key Laboratory of Rare Earth Functional MaterialsDepartment of Chemistry and Chemical EngineeringShanghai Normal UniversityShanghai 200234China

Lithium ion sieve(LIS)has attracted great attention due to its high adsorption selectivity towards Li+.Herein,a new type of Zr-doped Ti-LIS(HZrTO)was synthesized by a simple calcination *** adsorption capacity increased from 56.3 mgg-1(before doping)to 93.2 mgg-1 after doping in LiOH solution(lithium 1.8gL-1).The adsorption isotherm and adsorption kinetics of HZrTO accord with the Langmuir isotherm and the pseudo-second-order kinetic equation,*** experiments showed that HZrTO has good stability and *** addition,HZrTO was granulated via epoxy resin(E-12),and the obtained granular adsorbent showed good adsorption capacity,excellent stability and high selectivity towards Li+.

关键词： Lithium ion sieve Lithium titanium oxide Zr-doped Granulation

Polarization engineering in porous organic polymers for charge separation efficiency and its applications in photocatalytic aerobic oxidations

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Science China Chemistry 2024年第3期67卷 1000-1007页

作者： Kun Wu Pei-Wen Cheng Xin-Yi Liu Ji Zheng Xiao-Wei Zhu Mo Xie Puxin Weng Weigang Lu Dan Li College of Chemistry and materials Science Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and ApplicationsJinan UniversityGuangzhou 510632China Guangdong rare earth Photofunctional materials engineering Technology research Center School of Chemistry and EnvironmentJiaying UniversityMeizhou 514015China

Photocatalytic aerobic oxidation reactions are largely governed by the efficiency of charge separation and subsequent reactive oxygen species(ROS) generation. Herein, we report a polarization engineering strategy to promote the charge separation and ROS generation efficiency by substituting the benzene unit with furan/thiophene in porous organic polymers(POPs). Benefiting from the extent of local polarization, the thiophene-containing POP(JNU-218) exhibits the best photocatalytic performance in aerobic oxidation reactions, with a yield much higher than those for the furan-containing POP(JNU-217) and the benzenecontaining POP(JNU-216). Experimental studies and theoretical calculations reveal that the increase of local polarization can indeed reduce the exciton binding energy, and therefore facilitate the separation of electron-hole pairs. This work demonstrates a viable strategy to tune charge separation and ROS generation efficiency by modulating the dipole moments of the building blocks in porous polymeric organic semiconductors.

关键词： porous organic polymer local polarization photocatalytic aerobic oxidation charge separation reactive oxygen species exciton binding energy

Leveraging crystal symmetry for thermoelectric performance optimization in cubic GeSe

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rare Metals 2024年第10期43卷 5332-5345页

作者： Yu-Geng Li Yong-Qiang Liu Mo-Ran Wang Wen-Qing Yao Xiao-Huan Luo Tu Lyu Wei-Qin Ao Chao-Hua Zhang Fu-Sheng Liu Li-Peng Hu College of materials Science and engineering Institute of Deep Earth Sciences and Green EnergyShenzhen Key Laboratory of Special Functional MaterialsGuangdong Provincial Key Laboratory of Deep Earth Sciences and Geothermal Energy Exploitation and UtilizationGuangdong Research Center for Interfacial Engineering of Functional MaterialsShenzhen UniversityShenzhen 518060China

In thermoelectrics,the manipulation of crystal symmetry is instrumental in optimizing the electrical and thermal transport *** this context,the present study explored the largely overlooked high-symmetry cubic GeSe,which presented larger band degeneracy than its widely studied medium-symmetry rhombohedral *** have successfully stabilized cubic Ge Se a ambient conditions through co-alloying with AgSnTe_(2)and *** incorporation of AgSnTe_(2)initiates the transition of GeSe from a low-symmetry orthorhombic to a mediumsymmetry rhombohedral phase,culminating in a highsymmetry cubic structure,underpinned by variation in chemical bonding *** this,the persistence of Ag_(2)Te precipitates impedes the total elimination of the residual orthorhombic phase due to the disparate chemical bonding mechanism between Ag_(2)Te and *** Bi into the rhombohedral-dominated(GeSe)_(0.7)(AgSnTe_(2))_(0.3)matrix leads to the dissolution of Ag_(2)Te precipitates,elimination of the residual orthorhombic phase,and the subsequent stabilization of the exclusive cubic *** to its orthorhombic counterpart,the cubic GeSe exhibits diminished bandgap and Ge vacancy formation energy,amplified band degeneracy,reduced sound velocity,intensified lattice anharmonicity and multiple phonon scattering centres engendering elevated carrier concentration and density-ofstates effective mass,alongside restrained lattice therma ***,a peak zT of 0.46 at 573 K is attained for cubic(Ge_(0.7)Bi_(0.3)Se)_(0.7)(AgSnTe_(2))_(0.3),signifying a ninefold increase relative to the initial orthorhombic Ge *** results illuminate the critical role of crystal symmetry manipulation in advancing the thermoelectric performance.

关键词： Thermoelectric GeSe Crystal symmetry High-entropy alloying Band degeneracy

Stable all-solid-state Li-Te battery with Li_(3)TbBr_(6) superionic conductor

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Nano research 2023年第7期16卷 9344-9351页

作者： Zhichao Zeng Xiaomeng Shi Mingzi Sun Hongtu Zhang Wei Luo Yunhui Huang Bolong Huang Yaping Du Chun-Hua Yan Tianjin Key Lab for rare earth materials and Applications Center for Rare Earth and Inorganic Functional MaterialsHaihe Laboratory of Sustainable Chemical TransformationsSmart Sensing Interdisciplinary Science CenterSchool of Materials Science and EngineeringNational Institute for Advanced MaterialsNankai UniversityTianjin 300350China Department of Applied Biology and Chemical Technology The Hong Kong Polytechnic UniversityHung HomKowloonHong Kong 999077China Institute of New Energy for Vehicles School of Materials Science and EngineeringTongji UniversityShanghai 201804China Beijing national Laboratory for Molecular Sciences State Key Laboratory of Rare Earth MaterialsChemistry and ApplicationsPKU-HKU Joint Laboratory in Rare Earth Materials and Bioinorganic ChemistryCollege of Chemistry and Molecular EngineeringPeking UniversityBeijing 100871China College of Chemistry and Chemical engineering Lanzhou UniversityLanzhou 730000China

rare-earth(RE)halide solid electrolytes(HSEs)have been an emerging research area due to their good electrochemical and mechanical properties for all-solid-state lithium batteries(ASSBs).However,only very limited types of HSEs have been reported with high *** this work,tens of grams of RE-HSE Li_(3)TbBr_(6)(LTbB)was synthesized by a vacuum evaporationassisted *** as-prepared LTbB displays a high ionic conductivity of 1.7 mS·cm^(-1),a wide electrochemical window,and good ***,the assembled solid lithium-tellurium(Li-Te)battery based on the LTbB HSE exhibits excellent cycling stability up to 600 cycles,which is superior to most previous *** processes and the chemicals during the discharge/charge of Li-Te batteries have been studied by various in situ and ex situ *** calculations have demonstrated the dominant conductivity contributions of the direct[octahedral]-[octahedral]([Oct]-[Oct])pathway for Li ion migrations in the *** Tb sites guarantee efficient electron transfer while the Li 2s orbitals are not affected during migration,leading to a low activation ***,this successful fabrication and application of LTbB have offered a highly competitive solution for solid electrolytes in ASSBs,indicating the great potential of RE-based HSEs in energy devices.

关键词： rare-earth halide solid electrolytes all-solid-state lithium batteries superionic conductor Li-Te solid battery

Coordination-reduction leaching process of ion-adsorption type rare earth ore with ascorbic acid

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Journal of rare earths 2023年第8期41卷 1225-1233,I0004页

作者： Jinfa Chen Jiang Qiu Li Huang Xin Chen Ying Yang Yanfei Xiao Faculty of materials metallurgy and Chemistry Jiangxi University of Science and TechnologyGanzhou 341000China Ganzhou engineering Technology research Center of Green metallurgy and Process Intensification Ganzhou 341000China Key Laboratory of Ionic rare earth Resources and Environment Ministry of Natural ResourcesGanzhou 341000China Key Laboratory of Testing and Tracing of rare earth Products for State Market Regulation Ganzhou 341000China

The magnesium sulfate(MgSO_(4))-ascorbic acid(Vc)compound leaching technique can extract rare earth elements(REEs)existing in ion-exchangeable phase and colloidal phase from ion-adso rption type rare earth ore through the synergy effect of coordination and reduction,but its reaction process and mechanism remain *** this paper,the coordination-reduction leaching mechanism was analyzed from the perspectives of leaching thermodynamics and kinetics,which provide theoretical guidance for the compound leaching *** the case of neodymium,about 45%of dissolved neodymium will exist as the complex species of NdVc_(()3(aq))in Nd-Vc-sulfate *** on this,it is deduced that the Gibbs free energy of the leaching reaction of ion-exchangeable phase REEs will change to a more negative value through the coordination of REEs cations and Vc anions in the MgSO_(4)leaching *** addition,the E_(h)-pH diagrams of Ce-SO_(4)^(2-)-H_(2)O and Fe-SO_(4)^(2-)-H_(2)O together with the dissolution experiments confirm that the added Vc initiates the leaching process of colloidal phase REEs through reduction-dissolution *** the study of leaching kinetics,the leaching of REEs is controlled by diffusion and chemical reaction in the co mpound leaching system since colloidal phase REEs are ***,the addition of Vc can shift the leaching equilibrium to a more favorable state and accelerate leaching *** rare earth leaching efficiency of ion-exchangeable phase and colloidal phase can be effectively improved by increasing the reaction temperature,the conce ntrations of leaching agent and Vc,and the leaching agent acidity.

关键词： Ion-adsorption type rare earth ore Ascorbic acid Coordination Reduction Leaching Mechanism

High Colloidal Stable Carbon Dots Armored Liquid Metal Nano-Droplets for Versatile 3D/4D Printing Through Digital Light Processing(DLP)

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Energy & Environmental materials 2024年第3期7卷 432-438页

作者： Linan Wang Junle Zhang Xi Zhang Ge Shi Yanjie He Zhe Cui Xiaomeng Zhang Peng Fu Minying Liu Xiaoguang Qiao Xinchang Pang Henan Joint International research Laboratory of Living Polymerizations and functional Nanomaterials Henan Key Laboratory of Advanced Nylon Materials and ApplicationSchool of Materials Science and EngineeringZhengzhou UniversityZhengzhou 450001China College of materials engineering Henan International Joint Laboratory of Rare Earth Composite MaterialsHenan Engineering Technology Research Center for Fiber Preparation and ModificationHenan University of EngineeringZhengzhou 451191China

Liquid metal(LM)and liquid metal alloys(LMs)possess unique physicochemical features,which have become emerging and functionalized materials that are attractive applicants in various ***,uniform LM nanodroplets armored by carbon dots(LMD@CDs)were prepared and exhibited high colloidal stability in various solvents,as well as *** optimization,LMD@CDs can be applied as functional additives for the 3D/4D printing of hydrogel and cross-linked resin through digital light processing(DLP).The light absorption of LMD@CDs not only improved the printing accuracy,but also led to the cross-linking density differential during the post-curing *** on the cross-linking density differential of soft hydrogel and photothermal performance of the LM,the 3D printed objects can exhibit stimulus responses to both water and laser ***,the CDs shell and LM core of LMD@CDs provide the printed objects interesting photoluminescence and electric conductivity capabilities,*** deduce this versatile 3D/4D printing system would provide a new platform for the preparation of multi-functional and stimuli-responsive advance materials.

关键词： 4D printing carbon dots liquid metal nanodroplets

Fe_(2)O_(3)/TiO_(2)/reduced graphene oxide-driven recycled visible-photocatalytic Fenton reactions to mineralize organic pollutants in a wide pH range

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Journal of Environmental Sciences 2023年第12期134卷 11-20页

作者： Ru Zheng Dehong Yang Yao Chen Zhenfeng Bian Hexing Li Ministry of Education Key Laboratory of Resource Chemistry and Shanghai Key Laboratory of rare earth functional materials Shanghai Normal UniversityShanghai 200234China

Photocatalytic Fenton reactions combined the advantages from both photocatalysis and Fenton reaction in mineralizing organic pollutants. The key problems are the efficiency and recycling stability. Herein, we reported a novel Fe_(2)O_(3)/TiO_(2)/reduced graphene oxide(FTG) nanocomposite synthesized by a facile solvothermal method. The TiO_(2)in FTG degraded organic pollutants and mineralized intermediates via photocatalysis under visible light irradiation, which could also promote Fenton reaction by accelerating Fe^(3+)-Fe^(2+)recycle. Meanwhile, the Fe_(2)O_(3)rapidly degraded organic pollutants via Fenton reactions, which also promoted photocatalysis by enhancing visible light absorbance and diminishing photoelectronhole recombination. The high distribution of TiO_(2)and Fe_(2)O_(3)on rGO, together with their strong interaction resulted in enhanced synergetic cooperation between photocatalysis and Fenton reactions, leading to the high mineralization efficiency of organic pollutants. More importantly, it could also inhibit the leaching of Fe species, leading to the long lifetime of FTG during photocatalytic Fenton reactions in a wide pH range from 3.4 to 9.2.

关键词： Fe_(2)O_(3)/TiO_(2)/rGO nanocomposite(FTG) Visible-photocatalytic Fenton reactions Synergetic effect Pollutant mineralization Strong durability in a wide pH range