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High adsorption selectivity of activated carbon and carbon molecular sieve boosting CO_(2)/N_(2) and CH_(4)/N_(2) separation

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Chinese Journal of Chemical engineering 2024年第3期67卷 282-297页

作者： Siang Chen Wenling Wu Zhaoyang Niu Deqi Kong Wenbin Li Zhongli Tang Donghui Zhang The research center of Chemical engineering School of Chemical Engineering and TechnologyTianjin UniversityTianjin 300072China

Flue gas and coal bed methane are two important sources of greenhouse *** swing adsorption process has a wide range of application in the field of gas separation,and the selection of adsorbent is *** this regard,in order to assess the better adsorbent for separating CO_(2) from flue gas and CH_(4) from coal bed methane,adsorption isotherms of CO_(2),CH_(4) and N_(2) on activated carbon and carbon molecular sieve are measured at 303.15,318.15 and 333.15 K,and up to 250 *** experimental data fit better with Langmuir 2 compared to Langmuir 3 and Langmuir-Freundlich models,and Clausius-Clapeyron equation was used to calculate the isosteric *** the order of the adsorbed amount and the adsorption heat on the two adsorbents are CO_(2)>CH_(4)>N_(2).The adsorption kinetics are calculated by the pseudo-first kinetic model,and the order of adsorption rates on activated carbon is N_(2)-CH_(4)>CO_(2),while on carbon molecular sieve,it is CO_(2)-N_(2)>CH_(4).It is shown that relative molecular mass and adsorption heat are the primary effect on kinetics for activated carbon,while kinetic diameter is the main resistance factor for carbon molecular ***,the adsorption selectivity of CH_(4)/N_(2) and CO_(2)/N_(2) were estimated with the ideal adsorption solution theory,and carbon molecular sieve performed best at 318.15 K for both CO_(2) and CH_(4) *** study suggested that activated carbon is a better choice for separating flue gas and carbon molecular sieve can be a strong candidate for separating coal bed methane.

关键词： Activated carbon Carbon molecular sieve Adsorbent evaluation Adsorption equilibrium and kinetics Heat of adsorption Selectivity

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Constructing the Impossible Differential of Type-II GFN with Boolean Function and Its application to WARP

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Chinese Journal of Electronics 2024年第1期33卷 80-89页

作者： Jiali SHI Guoqiang LIU Chao LI College of Liberal Arts and Sciences National University of Defense Technology Hunan engineering research center of Commercial Cryptography Theory and Technology Innovation State Key Laboratory of Information Security Institute of Information Engineering

Type-Ⅱ generalized Feist el network(GFN) has attracted a lot of attention for its simplicity and high *** differential attack is one of the powerful cryptanalytic approaches for word-oriented block ciphers such as Feistel-like *** deduce the impossible differential of Type-Ⅱ GFN by analyzing the Boolean function in the middle *** main idea is to investigate the expression with the variable representing the plaintext(ciphertext) difference words for the internal state *** adopting the miss-in-the-middle approach,we can construct the impossible differential of Type-Ⅱ *** an illustration,we apply this approach to WARP,a lightweight 128-bit block cipher with a 128-bit key which was presented by Banik et *** SAC *** structure of WARP is a 32-branch Type-Ⅱ ***,we find two 21-round truncated impossible differentials and implement a 32-round key recovery attack on *** the 32-round key recovery attack on WARP,some observations are used to mount an effective *** the advantage of the early abort technique,the data,time,and memory complexities are 2125.69chosen plaintexts,2126.6832-round encryptions,and 2100-bit,*** the best of our knowledge,this is the best attack on WARP in the single-key scenario.

关键词： Ciphers Boolean functions Parallel processing Complexity theory

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The Caching and Pricing Strategy for Information-Centric Networking with Advertisers’Participation

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China Communications 2024年第3期21卷 283-295页

作者： Zheng Quan Yan Wenliang Wu Rong Tan Xiaobin Yang Jian Yuan Liu Xu Zhenghuan Laboratory for Future Networks Department of AutomationUniversity of Science and Technology of ChinaHefei 230026China Institute of Artificial Intelligence Hefei Comprehensive National Science CenterHefei 230088China Institute of Advanced Technology University of Science and Technology of ChinaHefei 230088China Suzhou Nuclear Power research Institute Suzhou 215004China national engineering Laboratory for Public Safety Risk Perception and Control by big data(NEL-PSRPC) China Academy of Electronics and Information Technology of CETCBeijing 100041China

As users’access to the network has evolved into the acquisition of mass contents instead of IP addresses,the IP network architecture based on end-to-end communication cannot meet users’***,the Information-Centric Networking(ICN)came into *** a technical point of view,ICN is a promising future network *** and customizing a reasonable pricing mechanism plays a positive role in promoting the deployment of *** current research on ICN pricing mechanism is focused on paid ***,we study an ICN pricing model for free content,which uses game theory based on Nash equilibrium to *** this work,advertisers are considered,and an advertiser model is established to describe the economic interaction between advertisers and ICN *** solution can formulate the best pricing strategy for all ICN entities and maximize the benefits of each *** extensive analysis and numerical results show that the proposed pricing framework is significantly better than existing solutions when it comes to free content.

关键词： advertisers cache free content Information-Centric Networking pricing strategy

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Landslide susceptibility mapping(LSM)based on different boosting and hyperparameter optimization algorithms:A case of Wanzhou District,China

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Journal of Rock Mechanics and Geotechnical engineering 2024年第8期16卷 3221-3232页

作者： Deliang Sun Jing Wang Haijia Wen YueKai Ding Changlin Mi Key Laboratory of GIS application research Chongqing Normal UniversityChongqing 401331China Key Laboratory of New Technology for Construction of Cities in Mountain Area Ministry of EducationChongqing UniversityChongqing 400045China national Joint engineering research center of Geohazards Prevention in the Reservoir Areas Chongqing UniversityChongqing 400045China School of Civil engineering Chongqing UniversityChongqing 400045China Natural Resources Development Service center of Linyi Linyi 276000China

Boosting algorithms have been widely utilized in the development of landslide susceptibility mapping(LSM)***,these algorithms possess distinct computational strategies and hyperparameters,making it challenging to propose an ideal LSM *** investigate the impact of different boosting algorithms and hyperparameter optimization algorithms on LSM,this study constructed a geospatial database comprising 12 conditioning factors,such as elevation,stratum,and annual average *** XGBoost(XGB),LightGBM(LGBM),and CatBoost(CB)algorithms were employed to construct the LSM ***,the Bayesian optimization(BO),particle swarm optimization(PSO),and Hyperband optimization(HO)algorithms were applied to optimizing the LSM *** boosting algorithms exhibited varying performances,with CB demonstrating the highest precision,followed by LGBM,and XGB showing poorer ***,the hyperparameter optimization algorithms displayed different performances,with HO outperforming PSO and BO showing poorer *** HO-CB model achieved the highest precision,boasting an accuracy of 0.764,an F1-score of 0.777,an area under the curve(AUC)value of 0.837 for the training set,and an AUC value of 0.863 for the test *** model was interpreted using SHapley Additive exPlanations(SHAP),revealing that slope,curvature,topographic wetness index(TWI),degree of relief,and elevation significantly influenced landslides in the study *** study offers a scientific reference for LSM and disaster prevention *** study examines the utilization of various boosting algorithms and hyperparameter optimization algorithms in Wanzhou *** proposes the HO-CB-SHAP framework as an effective approach to accurately forecast landslide disasters and interpret LSM ***,limitations exist concerning the generalizability of the model and the data processing,which require further exploration in subsequent studies.

关键词： Landslide susceptibility Hyperparameter optimization Boosting algorithms SHapley additive exPlanations(SHAP)

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Summer Atmospheric Water Cycle under the Transition Influence of the Westerly and Summer Monsoon over the Yarlung Zangbo River Basin in the Southern Tibetan Plateau

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Advances in Atmospheric Sciences 2024年第5期41卷 830-846页

作者： Qianhui MA Chunyan ZHANG Donghai WANG Zihao PANG School of Atmospheric Sciences Sun Yat-sen UniversityGuangdong Province Key Laboratory for Climate Change and Natural Disaster StudiesKey Laboratory of Tropical Atmosphere-Ocean SystemMinistry of EducationZhuhai 519082China Southern Marine Science and engineering Guangdong Laboratory(Zhuhai) Zhuhai 519082China Guangdong Meteorological data center Guangdong Meteorological ServiceGuangzhou 510080China national Observation and research Station of Coastal ecological Environments in Macao Macao Environmental Research InstituteMacao University of Science and TechnologyMacao SAR 999078China national Meteorological Information center China Meteorological AdministrationBeijing 100081China

This study compares the summer atmospheric water cycle,including moisture sources and consumption,in the upstream,midstream,and downstream regions of the Yarlung Zangbo River Basin in the southern Tibetan *** evolutions of moisture properties under the influence of the westerly and summer southerly monsoon are examined using 5-yr multi-source measurements and ERA5 reanalysis *** that moisture consumption in this study is associated with clouds,precipitation,and diabatic *** to the midstream and downstream regions,the upstream region has less moisture,clouds,and precipitation,where the moisture is brought by the *** early August,the vertical wet advection over this region becomes enhanced and generates more high clouds and *** midstream region has moisture carried by the westerly in June and by the southerly monsoon from July to *** higher vertical wet advection maximum here forms more high clouds,with a precipitation peak in early *** downstream region is mainly affected by the southerly-driven wet *** rich moisture and strong vertical wet advection here produce the most clouds and precipitation among the three regions,with a precipitation peak in late *** height of the maximum moisture condensation is different between the midstream region(325 hPa)and the other two regions(375 hPa),due to the higher upward motion maximum in the midstream *** diabatic heating structures show that stratiform clouds dominate the upstream region,stratiform clouds and deep convection co-exist in the midstream region,and deep convection systems characterize the downstream region.

关键词： Yarlung Zangbo River Basin atmospheric water cycle constrained variational analysis moisture source and consumption

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Detection and analysis of landslide geomorphology based on UAV vertical photogrammetry

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Journal of Mountain Science 2024年第4期21卷 1190-1214页

作者： BI Rui GAN Shu YUAN Xiping LI Kun LI Raobo LUO Weidong CHEN Cheng GAO Sha HU Lin ZHU Zhifu School of Land and Resources engineering Kunming University of Science and TechnologyKunming 650093China Plication engineering research center of Spatial Information Surveying and Mapping Technology in Plateau and Mountainous Areas Set by Universities in Yunnan Province Kunming 650093China West Yunnan University of Applied Sciences Key Laboratory of Mountain Real Scene Point Cloud Data Processing and Application for Universities in Yunnan ProvinceDali 671006China

High-resolution landslide images are required for detailed geomorphological analysis in complex topographic environment with steep and vertical landslide *** study proposed a vertical route planning method for unmanned aerial vehicles(UAVs),which could achieve rapid image collection based on strictly calculated route *** effectiveness of this method was verified using a DJI Mavic 2 Pro,obtaining high-resolution landslide images within the Dongchuan debris flow gully,in the Xiaojiang River Basin,Dongchuan District,Yunnan,China.A three-dimensional(3D)model was constructed by the structure-from-motion and multi-view stereo(SfM-MVS).Micro-geomorphic features were analyzed through visual interpretation,geographic information system(GIS),spatial analysis,and mathematical statistics *** results demonstrated that the proposed method could obtain comprehensive vertical information on landslides while improving measurement *** 3D model was constructed using the vertically oriented flight route to achieve centimeter-level accuracy(horizontal accuracy better than 6 cm,elevation accuracy better than 3 cm,and relative accuracy better than 3.5 cm).The UAV technology could further help understand the micro internal spatial and structural characteristics of landslides,facilitating intuitive acquisition of surface *** slope of landslide clusters ranged from 36°to 72°,with the majority of the slope facing east and *** elevation levels were relatively consistent while middle to lower elevation levels gradually decreased from left to right with significant variations in lower elevation *** the rainy season,surface runoff was abundant,and steep topography exacerbated changes in surface *** route method is suitable for unmanned aerial vehicle(UAV)landslide surveys in complex mountainous *** geomorphological analysis methods used will provide references for identifying and describing topographic

关键词： UAV Landslide Vertical route SfM-MVS Topographic features

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analysis of the effect of the 2021 Semeru eruption on water vapor content and atmospheric particles using GNSS and remote sensing

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Geodesy and Geodynamics 2024年第1期15卷 33-41页

作者： Mokhamad Nur Cahyadi Arizal Bawasir Syachrul Arief Amien Widodo Meifal Rusli Deni Kusumawardani Yessi Rahmawati Ana Martina Putra Maulida Hilda Lestiana Department of Geomatics engineering Institut Teknologi Sepuluh NopemberSurabaya 60111Indonesia research center of Marine and Earth Science-Technology Directorate of Research and Community ServiceInstitut Teknologi Sepuluh NopemberSurabaya 60111Indonesia Geospatial Education and Training Division Geospatial Information Agency(BIG)Cibinong 16911Indonesia Department of Geophysics engineering Institut Teknologi Sepuluh NopemberSurabaya 60111Indonesia Department of Mechanical engineering Andalas UniversityPadang City 25175Indonesia Department of Economics Airlangga UniversitySurabaya 60286Indonesia research center for Geological Resources National Research and Innovation AgencyJakarta 10340Indonesia

Mount Semeru,an active volcano in East Java,Indonesia,erupted on December 4,2021,following extreme rainfall that caused an avalanche of hot pyroclastic flows and *** tropospheric conditions and dominant particle components in the atmosphere can be monitored using Global Navigation Satellite System(GNSS)technology and remote sensing *** signal propagation delay in Precise Point Positioning(PPP)processing can be used to determine Zenith Tropospheric Delay(ZTD)and Precipitable Water Vapor(PWV)variables so that atmospheric conditions can be *** addition,by using remote sensing satellite data,it is possible to obtain rainfall data with high temporal resolution as well as the dominant particle and gas content values during *** the eruption period,the high value of PWV was dominated by the high intensity of precipitation during the rainy *** rainfall before the eruption caused activity inside the mountain to increase,which occurred in avalanche type *** from that,the atmosphere around Semeru was also dominated by SO_(2)content,which spreaded for tens of ***_(2)content began to be detected significantly by remote sensing sensors on December 7,*** this study,deformation and atmospheric monitoring were also carried out using low-cost GNSS at the Semeru Monitoring Station on September 9-15,*** results of the ZTD and ZWD values show the dominance of the wet component,which is directly proportional to rainfall activity in this period.

关键词： Semeru GNSS Water vapor Rainfall SO_(2)

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Fabrication of corrosion inhibiting microcapsules functional coating and their high-efficiency corrosion resistance

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Rare Metals 2024年第2期43卷 842-848页

作者： Hao-Ran Yun Lu Lu Xue-Long Hao Xing-Xiang Zhang School of Material Science and engineering Tiangong UniversityTianjin300387China national center of analysis and Testing for Nonferrous Metals and Electronic Materials General Research Institute for Nonferrous MetalsBeijing100088China Guobiao(Beijing)Testing&Certification Co. Ltd.Beijing101407China

Benzotriazole(BTA)was loaded into calcium carbonate microsphere shell by self-assembly method and a new type of high-efficiency corrosion inhibiting microcapsules(CIMs)were fabricated,which were added and dispersed into epoxy resin coating to obtain a new corrosion resistance functional *** corrosion inhibition effect of benzotriazole on aluminum alloy matrix was verified by polarization curve *** effectiveness of the CIMs and their loading capacity on inhibitor were evaluated by scanning electron microscope,laser confocal Raman spectroscopy together with thermogravimetric analysis.

关键词： corrosion coating resistance

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An overview and experimental analysis of WO3/TiO2 composite with enhanced electrochromic properties for smart windows application

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Tungsten 2024年第4期6卷 732-747页

作者： Ayesha Khan Mayur A.Gaikwad Jin Hyeok Kim Anamika Kadam The Institute of Science Dr.Homi Bhabha State University Optoelectronics Convergence research center and Department of Materials Science and engineering Chonnam National University

Internationally,standards for electrochromic（EC） requirements in smart window applications have been established,with ongoing global initiatives aimed at elevating them to highly advanced *** paper covers a comprehensive investigation of the structural,optical,morphological,and electrochemical properties of WO3/TiO2composite ***,an experimental analysis of WO3/TiO2was envisaged by a two-step ***,WO3thin films were hydrothermally deposited onto indium-doped tin oxide-coated glass substrates using an aqueous solution of Na2WO4·2H2O at a pH value of ***,a layer of TiO2was electrodeposited onto the WO3thin films.X-ray diffraction analysis confirmed the successful formation of WO3/TiO2composite films,with the WO3phase exhibiting a hexagonal tunnel *** electron microscopy revealed the formation of porous nanorods（NRs） of WO3,uniformly coated with TiO2,resulting in a porous morphology of the WO./*** EC performance of the WO3/TiO2films was thoroughly assessed through cyclic voltammetry and chronoamperometry measurements over a potential window ranging from-2.0 to+1.2 V（versus Ag/AgCl） in a 0.5 mol·L-1LiClO4-PC *** WO3/TiO2composite films exhibited cathodic electrochromism,characterized by a reversible color change from dark blue to *** improved EC performance in comparison to pure WO3films is attributed to enhanced double ion/electron insertion and extraction ***,the WO3/TiO2composite films demonstrated excellent optical modulation properties,with a significant modulation at 633 nm（46.87%）.The coloration efficiency reached a high value of 193.25 cm2·C-1,indicating their potential for practical EC ***,the WO3/TiO2composite films displayed exceptional EC stability,with no significant degradation observed over 2500 cyclic voltammetry *** superior EC performance can be attributed to the synergistic effect between the hexagonal WO3NRs

关键词： Electrochromism Smart window Stability WO3/TiO2

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Phenology of different types of vegetation and their response to climate change in the Qilian Mountains,China

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Journal of Mountain Science 2024年第2期21卷 511-525页

作者： ZHAO Kaixin LI Xuemei ZHANG Zhengrong LIU Xinyu Faculty of Geomatics Lanzhou Jiaotong UniversityLanzhou 730070China national-Local Joint engineering research center of Technologies and applications for national Geographic State Monitoring Lanzhou 730070China Gansu Provincial engineering Laboratory for national Geographic State Monitoring Lanzhou 730070China

The Qilian Mountains(QM)possess a delicate vegetation ecosystem,amplifying the evident response of vegetation phenology to climate *** relationship between changes in vegetation growth and climate remains *** this end,we used MODIS NDVI data to extract the phenological parameters of the vegetation including meadow(MDW),grassland(GSD),and alpine vegetation(ALV))in the QM from 2002 to ***,we employed path analysis to reveal the direct and indirect impacts of seasonal climate change on vegetation ***,we decomposed the vegetation phenology in a time series using the trigonometric seasonality,Box-Cox transformation,ARMA errors,and Trend Seasonal components model(TBATS).The findings showed a distinct pattern in the vegetation phenology of the QM,characterized by a progressive shift towards an earlier start of the growing season(SOS),a delayed end of the growing season(EOS),and an extended length of the growing season(LOS).The growth cycle of MDW,GSD,and ALV in the QM species is clearly *** SOS for MDW and GSD occurred earlier,mainly between late April and August,while the SOS for ALVs occurred between mid-May and mid-August,a one-month delay compared to the other *** EOS in MDW and GSD were concentrated between late August and April and early September and early January,*** phenology exhibits distinct responses to seasonal temperature and precipitation *** advancement and delay of SOS were mainly influenced by the direct effect of spring temperatures and precipitation,which affected 19.59%and 22.17%of the study area,*** advancement and delay of EOS were mainly influenced by the direct effect of fall temperatures and precipitation,which affected 30.18%and 21.17%of the area,*** the contrary,the direct effects of temperature and precipitation in summer and winter on vegetation phenology seem less noticeable and were mainly influenced by indirect *** indirec

关键词： Vegetation phenology Time series decomposition Path analysis Climate change

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