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International Journal of Mining Science and technology 2024年第3期34卷 339-349页

作者： Qi Wang Shuo Xu Bei Jiang Chong Zhang Zhe Sun Jingxuan Liu Cailin Jiao State Key laboratory for Tunnel engineering China University of Mining&Technology-BeijingBeijing 100083China Research Center of Geotechnical and Structural engineering Shandong UniversityJinan 250061China

In underground engineering with complex conditions,the bolt(cable)anchorage support system is in an environment where static and dynamic stresses coexist,under the action of geological conditions such as high stresses and strong disturbances and construction conditions such as the application of high *** is essential to study the support components performance under dynamic-static coupling *** on this,a multi-functional anchorage support dynamic-static coupling performance test system(MAC system)is developed,which can achieve 7 types of testing functions,including single component performance,anchored net performance,anchored rock performance and so *** bolt and cable mechanical tests are conducted by MAC system under different prestress *** results showed that compared to the non-prestress condition,the impact resistance performance of prestressed bolts(cables)is significantly *** the prestress range of 50–160 k N,the maximum reduction rate of impact energy resisted by different types of bolts is 53.9%–61.5%compared to non-prestress *** the prestress range of 150–300 k N,the impact energy resisted by high-strength cable is reduced by76.8%–84.6%compared to non-prestress *** MAC system achieves dynamic-static coupling performance test,which provide an effective means for the design of anchorage support system.

关键词： Anchorage support system Development of test system Dynamic-static coupling test Combined stress

Strain engineering of Pt-based electrocatalysts for oxygen reaction reduction

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Frontiers in Energy 2024年第2期18卷 241-262页

作者： Zeyu WANG Yanru LIU Shun CHEN Yun ZHENG Xiaogang FU Yan ZHANG Wanglei WANG State Key laboratory of Solidification Processing Atomic Control and Catalysis Engineering LaboratorySchool of Materials Science and EngineeringNorthwestern Polytechnical UniversityXi’an 710072China State Key laboratory of Oral and Maxillofacial Reconstruction and Regeneration National Clinical Research Center for Oral DiseasesShaanxi Key Laboratory of StomatologyDepartment of Dental MaterialsSchool of StomatologyThe Fourth Military Medical UniversityXi’an 710032China Institute of New Energy Materials and engineering School of Materials Science and EngineeringFuzhou UniversityFuzhou 350108China Key laboratory of Marine Chemistry Theory and technology(Ministry of Education) College of Chemistry and Chemical EngineeringOcean University of ChinaQingdao 266100China

Proton exchange membrane fuel cells(PEMFCs)are playing irreplaceable roles in the construction of the future sustainable energy ***,the insufficient performance of platinum(Pt)-based electrocatalysts for oxygen reduction reaction(ORR)hinders the overall efficiency of *** the surface strain of catalysts is considered an effective way to tune their electronic structures and therefore optimize catalytic *** this paper,insights into strain engineering for improving Pt-based catalysts toward ORR are elaborated in ***,recent advances in understanding the strain effects on ORR catalysts are comprehensively ***,strain engineering methodologies for adjusting Ptbased catalysts are comprehensively ***,further information on the various challenges and potential prospects for strain modulation of Pt-based catalysts is provided.

关键词： strain engineering Pt-based catalysts oxygen reduction reaction(ORR) catalytic performance proton exchange membrane fuel cells(PEMFCs)

Cycling performance of layered oxide cathode materials for sodium-ion batteries

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International Journal of Minerals,Metallurgy and Materials 2024年第7期31卷 1720-1744页

作者： Jinpin Wu Junhang Tian Xueyi Sun Weidong Zhuang School of Metallurgical and Ecological engineering University of Science and Technology BeijingBeijing 100083China State Key laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing 100083China Beijing Key laboratory for Green Recovery and Extraction of Rare and Precious Metals University of Science and Technology BeijingBeijing 100083China

Layered oxide is a promising cathode material for sodium-ion batteries because of its high-capacity,high operating voltage,and simple *** performance is an important criterion for evaluating the application prospects of ***,facing challenges,including phase transitions,ambient stability,side reactions,and irreversible anionic oxygen activity,the cycling performance of layered oxide cathode materials still cannot meet the application ***,this review proposes several strategies to address these ***,bulk doping is introduced from three aspects:cationic single doping,anionic single doping,and multi-ion ***,homogeneous surface coating and concentration gradient modification are *** addition,methods such as mixed structure design,particle engineering,high-entropy material construction,and integrated modification are ***,a summary and outlook provide a new horizon for developing and modifying layered oxide cathode materials.

关键词： sodium-ion battery layered oxide materials cycling performance bulking doping surface coating concentration gradient mixed structure high-entropy

From tunnel boring machine to tunnel boring robot: perspectives on intelligent shield machine and its smart operation

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Journal of Zhejiang University-Science A(Applied Physics & engineering) 2024年第5期25卷 357-381页

作者： Yakun ZHANG Guofang GONG Huayong YANG Jianbin LI Liujie JING State Key laboratory of Fluid Power and Mechatronic Systems Zhejiang UniversityHangzhou 310058China China railway engineering Equipment Group Co. Lid.Zhengzhou 450016China Maha Fluid Power Research Center Purdue UniversityWest LafayetteIN 47905USA

Advances in intelligent shield machines reflect an evolving trend from traditional tunnel boring machines(TBMs)to tunnel boring robots(TBRs).This shift aims to address the challenges encountered by the conventional shield machine industry arising from construction environment and manual *** study presents a systematic review of intelligent shield machine technology,with a particular emphasis on its smart ***,the definition,meaning,contents,and development modes of intelligent shield machines are *** development status of the intelligent shield machine and its smart operation are then *** analyzing the operation process of the shield machine,an autonomous operation framework considering both stand-alone and fleet levels is *** and recommendations are given for achieving autonomous *** study offers insights into the essence and developmental framework of intelligent shield machines to propel the advancement of this technology.

关键词： Intelligent shield machine Tunnel boring machine(TBM) Tunnel boring robot(TBR) Self-driving Autonomous control Shield machine

Recent advances of high-entropy electrocatalysts for water electrolysis by electrodeposition technology:a short review

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Rare Metals 2024年第6期43卷 2371-2390页

作者： Han-Ming Zhang Shao-Fei Zhang Li-Hao Zuo Jia-Kang Li Jun-Xia Guo Peng Wang Jin-Feng Sun Lei Dai Hebei Key laboratory of Flexible Functional Materials School of Materials Science and EngineeringHebei University of Science and TechnologyShijiazhuang 050018China Department of Chemistry National University of SingaporeSingapore117543Singapore

Hydrogen is considered as the promising energy carrier to substitute traditional fossil fuel,due to its cleanliness,renewability and high energy *** electrolysis is a simple and eonvenient technology for hydrogen *** efficiency of water electrolysis for hydrogen production is limited by the electrocatalytic performances on hydrogen evolution reaction(HER)and oxygen evolution reaction(OER).The exorbitant Pt-and Ir-/Ru-based electrocatalysts as optimal HER and OER electrocatalysts,respectively,restrict water electrolysis ***,non-precious metal-based high-entropy electrocatalysts have exhibited excellent electrocatalytic activities and long-term stabilities for water electrolysis,as promising precious cataly st ***,the construction of the high-entropy electroc atalysts is vital to water electrolysis *** technology is an efficient method for the preparation of high-entropy electrocatalysts due to its simple,fast,energy-saving and environmental-friendly ***-component co-precipitation facilely occurs during the electroredox in electrodeposition ***-entropy alloys,oxides,(oxy)hydroxides,phosphides and phosphorus sulfide oxides have been successfully prepared by galvanostatic,potentiostatic electrodeposition,cyclic voltammetry,pulse,nanodroplet-mediated and cathodic plasma electrodeposition ***,introduction of the development of high-entropy electrocatalysts synthesized by electrodeposition technology is significant to researchers and *** and outlooks are also concluded to boost the industrial application of electrodeposition in water electrolysis and other energy conversion areas.

关键词： high-entropy electrocatalysts Electrodeposition technology Water electrolysis Multi-component co-precipitation Excellent electrocatalytic performances

A post-modification strategy to precisely construct dual-atom sites for oxygen reduction electrocatalysis

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Journal of Energy Chemistry 2024年第3期90卷 511-517,I0012页

作者： Juan Wang Xinyan Liu Chang-Xin Zhao Yun-Wei Song Jia-Ning Liu Xi-Yao Li Chen-Xi Bi Xin Wan Jianglan Shui Hong-Jie Peng Bo-Quan Li Jia-Qi Huang School of Materials Science and engineering Beijing Institute of TechnologyBeijing 100081China Advanced Research Institute of Multidisciplinary Science Beijing Institute of TechnologyBeijing 100081China Beijing Key laboratory of Green Chemical Reaction engineering and technology Department of Chemical EngineeringTsinghua UniversityBeijing 100084China Institute of Fundamental and Frontier Sciences University of Electronic Science and Technology of ChinaChengdu 611731SichuanChina School of Materials Science and engineering Beihang UniversityBeijing 100191China

Dual-atom catalysts(DACs) afford promising potential for oxygen reduction electrocatalysis due to their high atomic efficiency and high intrinsic ***,precise construction of dual-atom sites remains a *** this work,a post-modification strategy is proposed to precisely fabricate DACs for oxygen reduction ***,a secondary metal precursor is introduced to the primary single-atom sites to introduce direct metal-metal interaction,which ensures the formation of desired atom pair structure during the subsequent pyrolysis process and allows for successful construction of *** as-prepared FeCo-NC DAC exhibits superior oxygen reduction electrocatalytic activity with a half-wave potential of 0,91 V *** hydrogen ***-air batteries equipped with the FeCo-NC DAC demonstrate higher peak power density than those with the Pt/C *** importantly,this post-modification strategy is demonstrated universal to achieve a variety of dual-atom *** work presents an effective synthesis methodology for precise construction of catalytic materials and propels their applications in energy-related devices.

关键词： Dual-atom catalysts Electrocatalysis Oxygen reduction reaction Post-modification Zinc–air batteries

Tortuosity regulation of two-dimensional nanofluidic films for water evaporation-induced electricity generation

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Nano Research 2024年第7期17卷 6192-6202页

作者： Zhihang Liu Chao Liu Anqi Ni Kunpeng Mao Long Chen Liang Xue Jingwen Sun Xin Wang Pan Xiong Junwu Zhu Key laboratory for Soft Chemistry and Functional Materials of Ministry Education School of Chemistry and Chemical EngineeringNanjing University of Science and TechnologyNanjing 210094China

Water evaporation-induced electricity generation is a promising technology for renewable energy ***,the output power of some reported two-dimensional(2D)nanofluidic films is still restricted by the relatively weak water–solid interactions within the tortuous *** further enhance the comprehension and utilization of water–solid interactions,it is of utmost importance to conduct an in-depth investigation and propose a regulatory concept encompassing ion ***,we propose tortuosity regulation of 2D nanofluidic titanium oxide(Ti_(0.8)7O_(2))films to optimize the ion transport within the interlayer nanochannel for enhanced efficiency in water evaporation-induced electricity generation for the first *** significance of tortuosity in ion transport is elucidated by designing three 2D nanofluidic films with different *** analysis and in situ Raman measurement demonstrate that low tortuosity can facilitate the formation of efficient pathways for hydrated proton transport and promote water–solid ***,devices fabricated with the optimized 2D nanofluidic films exhibited a significantly enhanced output power density of approximately 204.01μW·cm^(−2),far exceeding those prepared by the high-tortuosity 2D nanofluidic *** work highlights the significance of the construction of low tortuosity channels for 2D nanofluidic films with excellent performance.

关键词： water evaporation-induced electricity generation tortuosity ion transport two-dimensional nanofluidic films

Effect of dry-wet cycles on dynamic properties and microstructures of sandstone:Experiments and modelling

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International Journal of Mining Science and technology 2024年第5期34卷 655-679页

作者： Hai Pu Qingyu Yi Andrey P.Jivkov Zhengfu Bian Weiqiang Chen Jiangyu Wu State Key laboratory of Intelligent construction and Healthy Operation and Maintenance of Deep Earth engineering China University of Mining and TechnologyXuzhou 221116China Key laboratory of Xinjiang Coal Resources Green Mining Ministry of EducationXinjiang Institute of EngineeringUrumqi 830023China Department of Solids and Structures School of EngineeringUniversity of ManchesterManchester M139PLUK School of Environment Science and Spatial Informatics China University of Mining and TechnologyXuzhou 221116China Department of Civil and Environmental engineering Rice UniversityHouston 77005USA State Key laboratory of high Performance Civil engineering Materials Jiangsu Research Institute of Building Science Co.Ltd.Nanjing 210008China Department of Materials University of OxfordOxford OX13PHUK

Underground pumped storage power plant(UPSP)is an innovative concept for space recycling of abandoned *** realization requires better understanding of the dynamic performance and durability of reservoir *** paper conducted ultrasonic detection,split Hopkinson pressure bar(SHPB)impact,mercury intrusion porosimetry(MIP),and backscatter electron observation(BSE)tests to investigate the dynamical behaviour and microstructure of sandstone with cyclical dry-wet damage.A coupling FEM-DEM model was constructed for reappearing mesoscopic structure *** results show that dry-wet cycles decrease the dynamic compressive strength(DCS)with a maximum reduction of 39.40%,the elastic limit strength is reduced from 41.75 to 25.62 *** sieved fragments obtain the highest crack growth rate during the 23rd dry-wet cycle with a predictable life of 25 cycles for each rock *** pore fractal features of the macropores and micro-meso pores show great differences between the early and late cycles,which verifies the computational statistics analysis of particle *** numerical results show that the failure patterns are governed by the strain in pre-peak stage and the shear cracks are *** dry-wet cycles reduce the energy transfer efficiency and lead to the discretization of force chain and crack fields.

关键词： Underground pumped storage power plant Dry-wet cycles Split Hopkinson pressure bar Macro and micro properties FEM-DEM coupling model Damage characterization

Promising interlayer sensitization strategy for the construction of high-performance blue hyperfluorescence OLEDs

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Light(Science & Applications) 2024年第7期13卷 1372-1382页

作者： Jianghui Wang Peng Zou Letian Chen Zhentao Bai Hao Liu Wen-Cheng Chen Yanping Huo Ben Zhong Tang Zujin Zhao State Key laboratory of Luminescent Materials and Devices Guangdong Provincial Key Laboratory of Luminescence from Molecular AggregatesSouth China University of TechnologyGuangzhou 510640China. School of Chemical engineering and Light Industry Guangdong University of TechnologyGuangzhou 510006China. School of Science and engineering Shenzhen Institute of Aggregate Science and TechnologyThe Chinese University of Hong KongShenzhenGuangdong 518172China

Multi-resonance thermally activated delayed fluorescence(MR-TADF)materials are promising candidates for organic light-emitting diodes(OLEDs)with narrow electroluminescence(EL)*** researches focus on fabricating hyperfluorescence OLEDs to improve EL efficiencies of MR-TADF emitters by co-doping them with TADF sensitizers in a single host ***,in many cases,the polarity of the single host could be not suitable for both blue MRTADF emitters and blue TADF sensitizers,resulting in broadened EL spectra in high-polar hosts or decreased EL efficiencies in low-polar ***,we wish to report an efficient sensitization strategy for blue MR-TADF emitters by constructing an interlayer-sensitizing configuration,in which the blue TADF sensitizers and blue MR-TADF emitters are separated into two closely aligned host layers with high polarity and low polarity,*** on this strategy,efficient blue hyperfluorescence OLEDs are realized and verified by employing various TADF sensitizers and different MR-TADF emitters,furnishing outstanding external quantum efficiencies of up to 38.8%and narrow EL *** results validate the feasibility and universality of this interlayer sensitization strategy,which provides an effective alternative to high-performance blue hyperfluorescence OLEDs.

关键词： OLEDs interlayer sensitization

The Roadmap of 2D Materials and Devices Toward Chips

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Nano-Micro Letters 2024年第6期16卷 343-438页

作者： Anhan Liu Xiaowei Zhang Ziyu Liu Yuning Li Xueyang Peng Xin Li Yue Qin Chen Hu Yanqing Qiu Han Jiang Yang Wang Yifan Li Jun Tang Jun Liu Hao Guo Tao Deng Songang Peng He Tian Tian‑Ling Ren School of Integrated Circuits and Beijing national Research Center for Information Science and technology(BNRist) Tsinghua UniversityBeijing 100049People’s Republic of China School of Microelectronics Fudan UniversityShanghai 200433People’s Republic of China State Key laboratory of Dynamic Measurement technology Shanxi Province Key Laboratory of Quantum Sensing and Precision MeasurementNorth University of ChinaTaiyuan 030051People’s Republic of China high‑Frequency high‑Voltage Device and Integrated Circuits R&D Center Institute of MicroelectronicsChinese Academy of SciencesBeijing 100029People’s Republic of China School of Electronic and Information engineering Beijing Jiaotong UniversityBeijing 100044People’s Republic of China School of Integrated Circuits University of Chinese Academy of SciencesBeijing 100049People’s Republic of China IMECAS-HKUST-Joint laboratory of Microelectronics Beijing 100029People’s Republic of China

Due to the constraints imposed by physical effects and performance degra certain limitations in sustaining the advancement of Moore’s ***-dimensional(2D)materials have emerged as highly promising candidates for the post-Moore era,offering significant potential in domains such as integrated circuits and next-generation ***,in this review,the progress of 2D semiconductors in process engineering and various electronic applications are summarized.A careful introduction of material synthesis,transistor engineering focused on device configuration,dielectric engineering,contact engineering,and material integration are given *** 2D transistors for certain electronic applications including digital and analog circuits,heterogeneous integration chips,and sensing circuits are ***,several promising applications(artificial intelligence chips and quantum chips)based on specific mechanism devices are ***,the challenges for 2D materials encountered in achieving circuit-level or system-level applications are analyzed,and potential development pathways or roadmaps are further speculated and outlooked.

关键词： Two-dimensional materials Roadmap Integrated circuits Post-Moore era