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Multi boron-doping effects in hard carbon toward enhanced sodium ion storage

Journal of Energy Chemistry 2025年第1期100卷 730-738页

作者： Peng Zheng Wang Zhou Ying Mo Biao Zheng Miaomiao Han Qin Zhong Wenwen Yang Peng Gao Lezhi Yang Jilei Liu College of Materials Science and Engineering Hunan Joint International Laboratory of Advanced Materials and Technology for Clean Energy Hunan Province Key Laboratory for Advanced Carbon Materials and Applied Technology Hunan University Greater Bay Area Institute for Innovation Hunan University Changsha Research Institute of Mining & metallurgy Co. LTD.

Hard carbon （HC） has been considered as promising anode material for sodium-ion batteries （SIBs）.The optimization of hard carbon’s microstructure and solid electrolyte interface （SEI） property are demonstrated effective in enhancing the Na+storage capability,however,a one-step regulation strategy to achieve simultaneous multi-scale structures optimization is highly ***,we have systematically investigated the effects of boron doping on hard carbon’s microstructure and interface chemistry.A variety of structure characterizations show that appropriate amount of boron doping can increase the size of closed pores via rearrangement of carbon layers with improved graphitization degree,which provides more Na+storage ***-situ Fourier transform infrared spectroscopy/electrochemical impedance spectroscopy （FTIR/EIS） and X-ray photoelectron spectroscopy （XPS） analysis demonstrate the presence of more BC3and less B–C–O structures that result in enhanced ion diffusion kinetics and the formation of inorganic rich and robust SEI,which leads to facilitated charge transfer and excellent rate *** a result,the hard carbon anode with optimized boron doping content exhibits enhanced rate and cycling *** general,this work unravels the critical role of boron doping in optimizing the pore structure,interface chemistry and diffusion kinetics of hard carbon,which enables rational design of sodium-ion battery anode with enhanced Na+storage performance.

关键词： X ray photoelectron spectroscopy

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Wetting behavior of CaO-Al_(2)O_(3)-based mold flux with various BaO and MgO contents on the steel substrate

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international Journal of Minerals,metallurgy and Materials 2022年第6期29卷 1179-1185页

作者： Lejun Zhou Hao Luo Wanlin Wang Houfa Wu Erzhuo Gao You Zhou Daoyuan Huang School of metallurgy and Environment Central South UniversityChangsha 410083China national center for international cooperation of clean metallurgy Changsha 410083China

The Interfacial phenomena in mold have a great impact on the smooth operation of continuous casting process and the quality of the casting *** this paper,the wetting behavior of CaO-Al_(2)O_(3)-based mold flux with different BaO and MgO contents was *** results showed that the contact angle between molten flux and interstitial free(IF)steel substrate increased from 62.4°to 74.5°with the increase of BaO content from 3 wt%to 7 wt%,while it decreased from 62.4°to 51.3°with the increase of MgO content from 3 wt%to 7 wt%.The interfacial tension also increased from 1630.3 to 1740.8 mN/m when the BaO content increased,but it reduced from 1630.3 to 1539.7 mN/m with the addition of *** changes of contact angle and interfacial tension were mainly due to the fact that the bridging oxygen(O^(0)) at the interface was broken into non-bridging oxygen(O^(-)) and free oxygen(O_(2-)) by ***,more O^(-) and O_(2-) connected into O^(0) when BaO was added,since the charge compensation effect of BaO was so stronger that it offset the effect of providing O_(2-).

关键词： mold flux wetting contact angle interfacial tension melt structure continuous casting

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Effect of Al_(2)O_(3)/Na_(2)O ratio and MnO on high-temperature properties of mold flux for casting peritectic steel

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Journal of Iron and Steel Research international 2022年第1期29卷 53-60页

作者： Le-jun Zhou Hao Luo Wan-lin Wang Xiong Yan Hou-fa Wu School of metallurgy and Environment Central South UniversityChangsha 410083HunanChina national center for international cooperation of clean metallurgy Changsha 410083HunanChina

The influences of Al_(2)O_(3)/Na_(2)O ratio and MnO content on high-temperature properties,such as melting,crystallization,heat transfer,and viscosity of mold flux for casting peritectic steel,have been *** results show that the melting temperatures of mold flux decrease,whereas the ratio of crystalline layers increases with the decrease in Al_(2)O_(3)/Na_(2)O ratio and increase in MnO *** average response temperatures of the three mold fluxes decrease from 566,525,to 512℃,respectively,which indicates that the heat transfer controlling ability of mold flux is promoted due to the increase in crystallization ability and addition of transition metal oxide ***,the viscosity-temperature curves suggest that the viscosity at 1300℃ decreases,but the break temperature increases with the reduction in Al_(2)O_(3)/Na_(2)O and addition of MnO.

关键词： Mold flux Peritectic steel Melting Crystallization Heat transfer Viscosity

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Effect of AI_(2)O_(3)and MgO on crystallization and structure of Ca0-Si0_(2)-B_(2)0_(3)-based fluorine-free mold flux

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Journal of Iron and Steel Research international 2021年第5期28卷 552-562页

作者： Jun-yu Chen Wan-lin Wang Le-jun Zhou Zi-hang Pan School of metallurgy and Environment Central South UniversityChangsha 410083HunanChina national center for international cooperation of clean metallurgy Changsha 41(K)83HunanChina

The crytallization behavior and melt structure of the CaO-Si0^(2-)B20_(3)-based fluorine-free mold fux were *** results show that the crytallization of the mold fux was first inhibited and then promoted with the increase in Al_(2)0_(3) content from 4 to 12 wt.%.However,it was enhanced by MgO in the range of 2-10 wt.%.The results of Fourier transform infrared spectroscopy and Raman spectroscopy showed that Al_(2)0_(3) worked as a network former in the mold flux melt when its content was in the range of 4-8 wt.%,whereas it worked as the network breaker to provide 0^(2-)when its content was in the range of 8-12 wt.%.In addition,the combined efects from the charge compensation by Mg^(2+)and the network broken by 0^(2-)led to the increase in some typicalT-O-T(AI-O-A1,B-O-B,etc.,)and simpler structural units(Q^(2)(Si),B_^(O-)in the[B0_(2)0^(-)],.etc.)when the MgO content was in the range of 2-6 wt.%.The continuous increase in 0^(2-)provided by the addition of MgO from 6 to 10 wt.%further depolymerized the network of the melt and fnally caused fast crystallizationo.

关键词： Crystallization Single hot thermocouple technique Melt structure Fluorine-free mold flux

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Depression mechanism of sulfite ions on sphalerite and Pb^(2+)activated sphalerite in the flotation separation of galena from sphalerite

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international Journal of Minerals,metallurgy and Materials 2025年第2期32卷 335-345页

作者： Feng Zhang Chenyang Zhang Linlin Wu Wei Sun Hongliang Zhang Jianhua Chen Yong Pei Songjiang Li Engineering Research center of Ministry of Education for Carbon Emission Reduction in Metal Resource Exploitation and Utilization Hunan International Joint Research Center for Efficient and Clean Utilization of Critical Metal Mineral ResourcesSchool of Minerals Processing and BioengineeringCentral South UniversityChangsha 410083China State Key Laboratory of Mineral Processing Beijing General Research Institute of Mining&MetallurgyBeijing 100160China Hunan Provincial Key Laboratory of Micro&Nano Materials Interfaces Science College of Chemistry and Chemical EngineeringCentral South UniversityChangsha 410083China School of Resources Environment and MaterialsGuangxi UniversityNanning 530004China Department of Chemistry Xiangtan UniversityXiangtan 411105China China Railway Resource Group Co.Ltd Beijing 102300China

The depression mechanism of sulfite ions on sphalerite and Pb^(2+)activated sphalerite in the flotation separation of galena from sphalerite still lacked in-depth ***,the depression mechanism of sulfite ions on sphalerite and Pb^(2+)activated sphalerite in the flotation separation of galena from sphalerite was further systematically investigated with experiments and density functional theory(DFT)*** X-ray photoelectric spectroscopy(XPS)results,DFT calculation results,and frontier molecular orbital analysis indicated that sulfite ions were difficult to be adsorbed on sphalerite surface,suggesting that sulfite ions achieved depression effects on sphalerite through other non-adsorption ***,the oxygen content in the surface of sphalerite treated with sulfite ions in creased,which enhanced the hydrophilicity of the sphalerite and further increased the difference in hydrophilicity between sphalerite and ***,sulfite ions were chelated with lead ions to form PbSO_(3)in *** hydrophilic PbSO_(3)was more easily adsorbed on sphalerite than *** interaction between sulfite ions and lead ions could effectively inhibit the activation of *** addition the UV spectrum showed that after adding sulfite ions,the peak of perxanthate in the sphalerite treated xanthate solution was significantly stronger than that in the galena with xanthate solution,indicating that xanthate interacted more readily with sulfite ions and oxygen mo lecules within the sphalerite system,leading to the formation of ***,sulfite ions hardly depressed the flotation of ga lena and could promote the flotation of galena to some *** study deepened the understanding of the depression mechanism o sulfite ions on sphalerite and Pb^(2+)activated sphalerite.

关键词： sphalerite galena sulfite ion density functional theory depression mechanism

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Preparation of FeCoNi medium entropy alloy from Fe^(3+)-Co^(2+)-Ni^(2+)solution system

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international Journal of Minerals,metallurgy and Materials 2025年第1期32卷 92-101页

作者： Zongyou Cheng Qing Zhao Mengjie Tao Jijun Du Xingxi Huang Chengjun Liu Key Laboratory for Ecological metallurgy of Multimetallic Mineral(Ministry of Education) Northeastern UniversityShenyang 110819China School of metallurgy Northeastern UniversityShenyang 110819China Engineering Research center of Frontier Technologies for Low-carbon Steelmaking(Ministry of Education) Shenyang 110819China

In recent years,medium entropy alloys have become a research hotspot due to their excellent physical and chemical *** controlling reasonable elemental composition and processing parameters,the medium entropy alloys can exhibit similar properties to high entropy alloys and have lower *** this paper,a FeCoNi medium entropy alloy precursor was prepared via sol-gel and coprecipitation methods,respectively,and FeCoNi medium entropy alloys were prepared by carbothermal and hydrogen *** phases and magnetic properties of FeCoNi medium entropy alloy were *** showed that FeCoNi medium entropy alloy was produced by carbothermal and hydrogen reduction at 1500℃.Some carbon was detected in the FeCoNi medium entropy alloy prepared by carbothermal *** alloy prepared by hydrogen reduction was uniform and showed a relatively high ***,the hydrogen reduction product exhibited better saturation magnetization and lower coercivity.

关键词： medium entropy alloy sol-gel co-precipitation carbothermal hydrogen reduction

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A simple route for preparation of TRIP-assisted Si-Mn steel with excellent performance using direct strip casting

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international Journal of Minerals,metallurgy and Materials 2024年第10期31卷 2173-2181页

作者： Hui Xu Lejun Zhou Wanlin Wang Yang Yi School of metallurgy and Environment Central South UniversityChangsha 410083China national center for international Research of clean metallurgy Central South UniversityChangsha 410083China

The complex producing procedures and high energy-consuming limit the large-scale production and application of advanced high-strength steels(AHSSs).In this study,the direct strip casting(DSC)technology with unique sub-rapid solidification characteristics and cost advantages was applied to the production of low-alloy Si-Mn steel with the help of quenching&partitioning(Q&P)concept to address these *** this method with the conventional compact strip production(CSP)process,the initial microstructure formed under different solidification conditions and the influence of heat treatment processes on the final mechanical properties were *** results show that the initial structure of the DSC sample is a dual-phase structure composed of fine lath martensite and bainite,while the initial structure of the CSP sample consists of pearlite and *** volume fraction and carbon content of retained austenite(RA)in DSC samples are usually higher than those in CSP samples after the same Q&P *** samples typically demonstrate better comprehensive mechanical properties than the CSP *** DSC sample partitioned at 300℃ for 300 s(DSC-Pt300)achieves the best comprehensive mechanical properties,with yield strength(YS)of 1282 MPa,ultimate tensile strength(UTS)of 1501 MPa,total elongation(TE)of 21.5%,and product of strength and elongation(PSE)as high as 32.3 GPa·%.These results indicate that the excellent mechanical properties in low-alloy Si-Mn steel can be obtained through a simple process(DSC-Q&P),which also demonstrates the superiority of DSC technology in manufacturing AHSSs.

关键词： direct strip casting sub-rapid solidification quenching and partitioning TRIP-assisted AHSSs microstructure

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Kinetics of austenite growth and bainite transformation during reheating and cooling treatments of high strength microalloyed steel produced by sub-rapid solidification

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international Journal of Minerals,metallurgy and Materials 2023年第2期30卷 354-364页

作者： Wanlin Wang Lankun Wang Peisheng Lyu School of metallurgy and Environment Central South UniversityChangsha 410083China national center for international Research of clean metallurgy Central South UniversityChangsha 410083China

First,strip cast samples of high strength microalloyed steel with sub-rapid solidification characteristics were prepared by simulated strip casting ***,the isothermal growth of austenite grain during the reheating treatment of strip casts was observed in situ through confocal laser scanning microscope(CLSM).The results indicated that the time exponent of grains growth suddenly rise when the isothermal temperature higher than 1000℃.And the activation energy for austenite grain growth were calculated to be 538.0 kJ/mol in the high temperature region(above 1000℃)and 693.2 kJ/mol in the low temperature region(below 1000℃),***,the kinetics model of austenite isothermal growth was established,which can predict the austenite grain size during isothermal hold very ***,high density of second phase particles with small size was found during the isothermal hold at the low temperature region,leading to the refinement of austenite *** isothermal hold at different temperature for 1800 s,the bainite transformation in microalloyed steel strip was also observed in situ during the continuous cooling *** growth rates of bainite plates with different nucleation positions and different prior austenite grain size(PAGS)were *** was indicated that the growth rate of the bainite plate is not only related to the nucleation position but also to the PAGS.

关键词： microalloyed steel strip casting precipitation austenite growth bainite transformation

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Effect of Al2O3/SiO2 and CaO/Al2O3 ratios on wettability and structure of CaO-SiO2-Al2O3-based mold flux system

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Journal of Iron and Steel Research international 2019年第4期26卷 355-364页

作者： Wan-lin Wang Er-zhuo Gao Le-jun Zhou Lei Zhang Huan Li School of metallurgy and Environment Central South UniversityChangsha 410083HunanChina national center for international Research of clean metallurgy Central South UniversityChangsha 410083HunanChina

The effect of Al2O3/SiO2 and CaO/Al2O3 ratios on the molten structure of CaO-SiO2-Al2O3-based mold flux system was analyzed by Fourier transform infrared spectroscopy,Raman spectroscopy,and X-ray photoelectron ***,the variation in the wettability between the mold flux system and an interstitial free(IF)steel substrate was investigated using the sessile drop *** results indicate that the contact angle and interfacial tension between the molten slag and solid steel increase slightly with the increase in the Al2O3/SiO2 ratio,while they decrease with the increase in the CaO/Al2O3 *** network structure for the designed mold flux system changes gradually from silicate to aluminosilicate and aluminate with the increase in the Al2O3/SiO2 ratio,and the network is simplified with the increase in the CaO/Al2O3 ***,combining the results of sessile drop method and melt structure analyses,it suggests that the variation in interfacial properties of mold flux/IF steel substrate is mainly caused by the change in melt structure,especially the variation in free oxygen ions(O^2-)and non-bridged oxygen(O^-)at the interface.

关键词： Wettability Melt structure Interfacial tension Sessile drop method Mold flux system

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Effect of electropulsing treatment on solidification behavior of spring steels in a continuous casting mold simulator

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Journal of Iron and Steel Research international 2020年第6期27卷 656-664页

作者： Wan-lin Wang Guo-min Ying Jie Zeng Hai-hui Zhang School of metallurgy and Environment Central South UniversityChangsha 410083HunanChina national center for international Research of clean metallurgy Central South UniversityChangsha 410083HunanChina

An electropulsing-assisted mold simulator technique was developed to investigate the effects of a pulsed electric voltage on the quality of spring steels during continuous casting by analyzing the mold flux film,shell surface profile,shell micro-structure and inclusion *** results revealed significantly increased crystallization fraction of the mold flux film from 61.2%to 75.3%and finer crystalline phase morphology in the case of electropulsing *** surface of the initially solidified shell could be effectively healed,resulting in smoother shell surface profiles with higher pulsed voltage from 0 to ***,an increase in the pulsed voltage from 0 to 30V resulted in finer dendritic structures during solidification with decreasing secondary dendrite arm spacing from the values of 17.6-32.2 to 9.7-15.0μm in the direction of shell side toward melt *** addition,an area scan analysis of inclusions in the as-cast spring steel samples showed that the number of MnS inclusions in the size range of 2.0-4.0μm gradually decreased from 836 to 114 and the number of Al2O3 inclusions in the same size range decreased from 144 to 39,as the voltage increased from 0 to 30V.

关键词： Electropulsing treatment Mold flux film Shell surface proifle Inclusion distribution Shell microstructure

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