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Tannins from Acacia mangium Bark as Natural Dyes for Textiles:Characteristics and Applications

Journal of Renewable Materials 2024年第9期12卷 1625-1637页

作者： Maya Ismayati Nissa Nurfajrin Solihat Fifi Melinda Setiawati Wasrin Syafii Yuki Tobimatsu Deni Zulfiana research Center for Biomass and Bioproducts Research Organization for Life Sciences and EnvironmentNational Research and Innovation Agency(BRIN)Jl.Raya Bogor KM 46CibinongBogor16911Indonesia Department of Forest Product Technology Faculty of ForestryIPB UniversityBogor16680Indonesia research Institute for Sustainable Humanosphere Kyoto UniversityUjiKyoto611-0011Japan research Center for applied Microbiology Research Organization for Life Sciences and EnvironmentNational Research and Innovation Agency(BRIN)Jl.Raya Bogor KM 46CibinongBogor16911Indonesia

Tannins are capable of producing natural dyes with antioxidant and antibacterial propertis,while synthetic dyes are commonly used in the textile industry,causing environmental issues like water *** research aims to utilize waste tannins as natural dyes as an alternative to synthetic *** study examined the effect of the extraction method on tannin properties such as phenolic content,antioxidants,and antibacterial *** addition,Pyrolysis Gas Chromatography‒Mass Spectrometry(Py-GCMS)analysis was used to identify the effect of extraction temperature on the chemical elucidation of *** effect of tannin concentration was evaluated against four bacteria that are usually found on human skin:Staphylococcus epidermidis,Bacillus subtilis,Propionibacterium acnes,and Staphylococcus *** temperature significantly influences the chemical composition of tannin,which leads to different antioxidant *** maximum antibacterial properties of tannin were obtained at 90℃with the inhibition zone in the range of 0.9–1.0 mm against four bacteria,tannin yield of 26.59%,Gallic Acid Equivalents or total phenolic content(GAE)of 40.30 mg/g,and Radical Scavenging Activity or antioxidant activity(RSA)of 89.88%.Moreover,the concentration of tannin was significantly linear with its antibacterial *** was successfully applied to the textile by using alum as a mordanting agent to create an antibacterial *** textile’s bacterial structure damage was analyzed under Field Emission Scanning Electron Microscopy(FESEM).After 50 washings,tannin-textiles with alum-modified properties remained stable compared to those without alum,with *** and *** being the most vulnerable bacteria,as confirmed by FESEM ***,tannin is a feasible alternative to harmful and nondegradable synthetic dyes and antibacterial agents.

关键词： Acacia mangium tannin antibacterial antioxidant different temperature extraction dyes

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Flow Injection Analysis Technique for Online Preconcentration of Lead Ions in Airborne Particulate Matter Using Imprinted Polymer as the Sorbent

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Journal of Analysis and Testing 2024年第2期8卷 180-190页

作者： Muhammad Bachri Amran Novita Ambarsari Muhammad Ali Zulfikar Asri Indrawati Rusnadi Rusnadi Saipul Hamdi Analytical Chemistry Division Faculty of Mathematics and Natural SciencesInstitut Teknologi BandungBandung 40132Indonesia research Center for Climate and Atmosphere National Research and Innovation AgencyBandung 40135Indonesia

This work reported a simple and sensitive flow injection analysis(FIA)technique coupled with a Flame Atomic Absorption Spectrophotometer(FAAS)for online preconcentration of lead(Ⅱ)ions in the airborne particulate matter samples(PM_(2.5))using ion-imprinted polymers as adsorbent packed in minicolumn.A bulk polymerization method was chosen to synthesize the polymer based on a ternary complex of lead ions with 4-2-pyridilazo resorcinol and 4-vinyl pyridine with methacrylic acid as a functional *** optimum pH for sorption was 6,and other variables for the FIA system were optimized,including breakthrough volume,eluent concentration,and eluent *** optimum conditions were reached with a breakthrough volume of 4.45 mL,calculated as a dynamic retention capacity of 5.20 mg/g of Pb(II)40 mg/L,with a 1.5 mL/min flow *** eluent used for the FIA system was 0.5 mL HNO_(3)of 3 mol/***,precision,and limits of detection of the FIA system were determined before being applied to preconcentration and analysis of lead ions in PM_(2.5)*** precision of the method was determined to be 3.09%by calculating the coefficients of the *** of the method in the concentration range of 50-1000μg/L gave a coefficient correlation of 0.9925,showing a good response,and the limit of detection of the system was 5.11μg/L,better than that of the FAAS *** of the FIA system were evaluated and showed good results with an enrichment factor of more than 20 times higher and a concentration efficiency of 11.65 min^(-1)with a consumptive index of 4.5 *** and analysis of the PM_(2.5)samples in Bandung City showed the concentrations of Pb(II)were 26.67μg/L and 33.3μg/L with the accuracy of the method for each sample of104.75%and 107.86%.

关键词： Flow injection analysis Lead(II)ions Imprinted polymer Particulate matter

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Three dimensional velocity model and its tectonic implications at China Seismic Experimental Site,eastern margin of the Tibetan Plateau

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Science China Earth Sciences 2024年第7期67卷 2268-2290页

作者： Jianping WU Yan CAI Wei WANG Weilai WANG Changzai WANG Lihua FANG Yaning LIU Jing LIU Institute of Geophysics China Earthquake AdministrationBeijing 100081China Beijing Baijiatuan Earth Science national Observation and research Station Beijing 1095China Beijing Earthquake agency Beijing 100080China

The China Seismic Experimental Site(CSES)is located at the intersection of the Tibetan Plateau,South China Block,and Indian Plate and has complex geological settings and intense crustal deformation,making it one of the most seismically active areas in Chinese mainland.A high-resolution,three-dimensional(3D)crust-mantle velocity structure is crucial for understanding seismotectonic environments,lithospheric deformation mechanisms,and deep dynamic *** first constructed a high-vertical-resolution 3D initial velocity model using the joint inversion of receiver functions and surface waves and then obtained a 3D P-and S-wave velocity model(CSES-VM1.0)with the highest lateral resolution of 0.25°for the CSES using double-difference *** to the limitations of the Sn observation data,the resolution of the S-wave velocity model in the lower crust and upper mantle was reduced,making it closer to the initial model provided by joint inversion.A comparison with explosive-source seismic data showed that the synthetic P-wave first-arrival travel times of the new model were closer to the observations than those of the previous velocity *** velocity cross-sections across the source areas of the 2022 Lushan MS6.1 and Ludian MS6.8 earthquakes reveal that the former earthquake occurred near a weak contact zone between the Tibetan Plateau and Sichuan Basin,and the rupture of the latter earthquake occurred in a granitic area,with the northern end blocked by rigid high-velocity bodies.A clear high-velocity anomaly zone is distributed along the western margin of the Yangtze Block,revealing the spatial distribution of Neoproterozoic intermediate-basic *** high-velocity zone significantly controls the morphology of fault zones and influences the rupture processes of major *** northeast-southwest and north-south trending high-velocity anomalies were found near Panzhihua,potentially related to Neoproterozoic and Middle-Late Permian intermediate

关键词： Eastern Tibetan Plateau China Seismic Experimental Site Yangtze Block Velocity model Double-difference tomography

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Strengthening-softening transition and maximum strength in Schwarz nanocrystals

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Nano Materials Science 2024年第3期6卷 320-328页

作者： Hanzheng Xing Jiaxi Jiang Yujia Wang Yongpan Zeng Xiaoyan Li Center for Advanced Mechanics and Materials Applied Mechanics LaboratoryDepartment of Engineering MechanicsTsinghua UniversityBeijing100084China Institute of High Performance Computing(IHPC) Agency for ScienceTechnology and Research(A*STAR)Singapore138632Singapore

Recently,a Schwarz crystal structure with curved grain boundaries(GBs)constrained by twin-boundary(TB)networks was discovered in nanocrystalline Cu through experiments and atomistic *** Cu with nanosized Schwarz crystals exhibited high strength and excellent thermal ***,the grainsize effect and associated deformation mechanisms of Schwarz nanocrystals remain ***,we performed large-scale atomistic simulations to investigate the deformation behaviors and grain-size effect of nanocrystalline Cu with Schwarz *** simulations showed that similar to regular nanocrystals,Schwarz nanocrystals exhibit a strengthening-softening transition with decreasing grain *** critical grain size in Schwarz nanocrystals is smaller than that in regular nanocrystals,leading to a maximum strength higher than that of regular *** simulations revealed that the softening in Schwarz nanocrystals mainly originates from TB migration(or detwinning)and annihilation of GBs,rather than GB-mediated processes(including GB migration,sliding and diffusion)dominating the softening in regular *** analyses of simulation data further showed that compared with those in regular nanocrystals,the GB-mediated processes in Schwarz nanocrystals are suppressed,which is related to the low volume fraction of amorphous-like GBs and constraints of TB *** smaller critical grain size arises from the suppression of GB-mediated processes.

关键词： Schwarz nanocrystal Curved grain boundary Atomistic simulation Grain size effect Maximum strength

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SOLVING OPTIMIZATION PROBLEMS OVER THE STIEFEL MANIFOLD BY SMOOTH EXACT PENALTY FUNCTIONS

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Journal of Computational Mathematics 2024年第5期42卷 1246-1276页

作者： Nachuan Xiao Xin Liu The Institute of Operations research and Analytics National University of SingaporeSingapore State Key Laboratory of scientific and Engineering Computing Academy of Mathematics and Systems ScienceChinese Academy of Sciencesand University of Chinese Academy of SciencesChina

In this paper,we present a novel penalty model called ExPen for optimization over the Stiefel *** from existing penalty functions for orthogonality constraints,ExPen adopts a smooth penalty function without using any first-order derivative of the objective *** show that all the first-order stationary points of ExPen with a sufficiently large penalty parameter are either feasible,namely,are the first-order stationary points of the original optimization problem,or far from the Stiefel ***,the original problem and ExPen share the same second-order stationary ***,the exact gradient and Hessian of ExPen are easy to *** a consequence,abundant algorithm resources in unconstrained optimization can be applied straightforwardly to solve ExPen.

关键词： Orthogonality constraint Stiefel manifold Penalty function

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Stereoselective recognition of morphine enantiomers by μ-opioid receptor

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national Science Review 2024年第3期11卷 183-191页

作者： Yibo Wang Van A.Ngo Xiaohui Wang Laboratory of Chemical Biology Changchun Institute of Applied ChemistryChinese Academy of Sciences Advanced Computing for Life Sciences and Engineering Group Science Engagement Section National Center for Computational Sciences Oak Ridge National Lab School of applied Chemistry and Engineering University of Science and Technology of China Beijing national Laboratory for Molecular Sciences

Stereospecific recognition of chiral molecules plays a crucial role in biological systems. The μ-opioid receptor（MOR） exhibits binding affinity towards（-）-morphine, a well-established gold standard in pain management, while it shows minimal binding affinity for the（+）-morphine enantiomer, resulting in a lack of analgesic activity. Understanding how MOR stereoselectively recognizes morphine enantiomers has remained a puzzle in neuroscience and pharmacology for over half-a-century due to the lack of direct observation techniques. To unravel this mystery, we constructed the binding and unbinding processes of morphine enantiomers with MOR via molecular dynamics simulations to investigate the thermodynamics and kinetics governing MOR's stereoselective recognition of morphine enantiomers. Our findings reveal that the binding of（-）-morphine stabilizes MOR in its activated state, exhibiting a deep energy well and a prolonged residence time. In contrast,（+）-morphine fails to sustain the activation state of ***, the results suggest that specific residues, namely D1142.50and D1473.32, are deprotonated in the active state of MOR bound to（-）-morphine. This work highlights that the selectivity in molecular recognition goes beyond binding affinities, extending into the realm of residence time.

关键词： stereoselective recognition thermodynamics and kinetics residence time morphine enantiomers μ-opioid receptor

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Artificial enhancement of sturgeon stock in freshwater reservoirs:A case study on sterlet Acipenser ruthenus of the Kama reservoir

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Aquaculture and Fisheries 2024年第2期9卷 287-294页

作者： Pavel B.Mikheev Semyon N.Kazarinov Alla G.Melnikova Stanislav V.Ponosov Nikolai G.Petrenko Andrei I.Nikiforov Alexey Yu Puzik Olga N.Elchenkova Perm State national research University Perm614990Russia Khabarovsk Branch of the Federal State Budget scientific Institution“Russian Federal research Institute of Fisheries and Oceanography”“KhabarovskNIRO” Khabarovsk680038Russia Perm Branch of the Federal State Budget scientific Institution“Russian Federal research Institute of Fisheries and Oceanography”“PermNIRO” Perm614991Russia Federal State Budget scientific Institution“Russian Federal research Institute of Fisheries and Oceanography”“VNIRO” Moscow117454Russia Moscow State Institute of International Relations(University)of the Ministry for Foreign Affairs of Russia“MGIMO” Moscow117454Russia Department of State Control Supervision and Protection of Aquatic Biological Resources for Perm KraiMiddle-Volga Regional Office of the Federal Fishery AgencyPerm614990Russia

The paper presents the results of the sterlet sturgeon Acipenser ruthenus reintroduction into the Kama Reservoir(Perm Krai,Russia)by sterlet fry from hatcheries into the reservoir since *** effectiveness of hatchery releases was evaluated by monitoring gillnet sampling *** results showed that the species was reported throughout entire Kama Reservoir,which contrasts with 1988-1994 data,when the species was registered only at the upper part of the reservoir near the Kama River *** highest number and biomass values of catch per unit effort(CPUE)of the sterlet were found in submerged river channels-the deepest habitats with flow conditions which are close to the ecological requirements of the *** distribution of the sterlet within the channel biotopes of the reservoir is defined by reduced *** biggest individuals and the widest size range of the sterlet were typical for the upper area of the reservoir and Chusovskoy Bay,which have the greatest *** smallest sizes were typical for fish from catches near the dam of the reservoir,which is consistent with the published data on the distribution of sterlet in reservoir *** presented results may indicate the artificial formation of the sterlet stock in the Kama Reservoir maintained by hatchery *** revealed distribution of the sterlet in the reservoir determines the direction of further research on natural reproduction and thus formation of an artificially formed ***,future studies are required to assess the possibility of hybridization of the sterlet of artificial origin with natural populations of the species,since the low genetic diversity of the sterlet released into the Kama Reservoir which can lead to irreversible loss of genetic individuality of the natural stocks of the species in the catchment of upper course of the Kama River.

关键词： Sterlet Acipenser ruthenus Kama reservoir Hatchery releases CPUE Artificial stock formation

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Seismic and geological evidence of hidden faults in the Yinpan Reservoir area based on a dense seismic array

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Science China Earth Sciences 2024年第7期67卷 2401-2407页

作者： Guangyao YIN Huai ZHANG Liwen GONG Q ipeng BAI Yicun GUO Bing ZHANG Yaolin SHI Key Laboratoryof Earth System Numerical Modeling and Application(Chinese Academyof Sciences) College of Earth and Planetary SciencesUniversity of Chinese Academy of SciencesBeijing 100049China Key Laboratory of Computational Geodynamics Chinese Academy of SciencesBeijing 100049China Southern Marine Science and Engineering Guangdong Laboratory(Zhuhai) Zhuhai 519080China Beijing Yanshan Critical Zone national Field scientific Observation and research Station Beijing 101408China Chongqing Earthquake agency Chongqing 401147 China Institute of Earthquake Forecasting China Earthquake AdministrationBeijing 100036China Hangzhou applied Acoustics research Institute Hangzhou 311100China State Key Laboratory of Geodesy and Earths Dynamics Innovation Academy for Precision Measurement Science and TechnologyCASWuhan 430077China

*** November 23,2017,an M_(S)5.0 earthquake occurred in Wulong,Chongqing,China,resulting in tens of casualties and considerable economic ***,the epicenter of this earthquake was located in the transition zone from the... 详细信息

关键词： earthquake southeast seismic

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Nutritional Characterization of Traditional Foods Based on Millet, Sorghum and Cowpea from the North-Central Region of Burkina Faso

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Food and Nutrition Sciences 2024年第8期15卷 681-694页

作者： Rasmata Dabo Fatoumata Hama-Ba Serge Samandoulgou Aly Savadogo Food Technology Department Institute for Research in Applied Sciences and Technologies National Center for Scientific and Technological Research Ouagadougou Burkina Faso Laboratory of Biochemistry and applied Immunology Training and Research Unit in Life and Earth Sciences Joseph Ki-Zerbo University Ouagadougou Burkina Faso

The food and nutrition situation in Burkina Faso, like most developing countries in sub-Saharan Africa, is marked by growing food vulnerability. The majority of local dishes are being abandoned in favor of a minority of imported cereal dishes and other ultra-processed foods. This minority of cereal foods is blamed for stunted growth in children, while ultra-processed foods are linked to chronic diseases such as hypertension, certain types of diabetes and cancer. Knowledge of the nutritional value of local foods is needed to determine their nutritional quality. The aim of this study was to determine the nutritional values of local dishes based on millet, sorghum and cowpea in the Centre-North region. The methodology consisted of making an inventory of millet-, sorghum- and cowpea-based dishes using focus groups made up of women and men from three age groups comprising young people, adults and the elderly in the communes of Lebda and Boussouma. The dishes were reproduced, and standard biochemical methods were used for nutritional characterization. A total of 34 dishes were inventoried, including 16 millet/sorghum-based dishes, 8 cowpea-based dishes and 10 dishes composed of millet/sorghum and cowpea or leaves. The mean protein, carbohydrate, ash and iron contents per 100 g DM of the three types of dishes were significantly different (p ≤ 0.05), ranging respectively from 13.61 to 22.63 g, 70.76 to 80.88 g, 1.87 to 5.96 g and 7.67 to 12.06 mg. Those for lipid, energy and zinc were not significantly different, ranging from 5.51 to 6.56 g, from 427 to 433 Kcal and from 2.98 to 3.32 mg respectively. Cowpea-based and mixed dishes cover the nutritional requirements for protein, carbohydrates, iron, zinc and energy recommended for children and adults. The consumption of mixed dishes and cowpea-based dishes could be promoted by nutritional policy to reduce stunting and recommended to obese, hypertensive and diabetic people as part of their diet.

关键词： Cereals Legumes Food Nutritional Burkina Faso

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Eco-toxicity and health risk assessment of polycyclic aromatic hydrocarbons in surface sediments of Burullus Lake in Egypt

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China Geology 2024年第3期7卷 460-468页

作者： Hanan E Osman Mohamed H E El-Morsy Hazem T Abd El-Hamid Department of Biology Faculty of Applied ScienceUmm Al-Qura UniversityMecca 24382Saudi Arabia Deanship of scientific research Umm Al-Qura UniversityMakkah 24372Saudi Arabia national Institute of Oceanography and Fisheries(NIOF) Cairo 11865Egypt Botany and Microbiology Department Faculty of ScienceAl-Azhar UniversityCairo 11651Egypt

Polycyclic aromatic hydrocarbons(PAHs)are ubiquitous environmental contaminants of growing concern due to their potential ecological and human health *** study presents a comprehensive assessment of PAHs contamination in the surface sediments of Burullus Lake,a vital and second largest delta lake in *** aim was to evaluate the eco-toxicity and potential health risks associated with the presence of these *** seven sediment samples were collected from various drains in the southern part of Burullus *** extraction method was employed to extract PAHs(16PAHs)from the sediment ***,target compounds were located using *** results showed that samples contained PAHs levels ranging from 0.038×10^(-6)to 0.459×10^(-6),which is considered heavily polluted by the European standard for PAHs ***,there was no apparent source of PAHs in the ElKhashah drain or the Brinbal Canal,as HPLC found none of the *** most prevalent compound in sediment samples along the study area was *** diagnostic indices in the present study indicated that the hydrocarbons in the region originated from pyrolytic and man-made sources along the drains of Burullus *** principal component analysis(PCA)and diagnostic ratios revealed that coal combustion and pyrolytic sources were responsible for the PAHs contamination in the surface *** non-carcinogenic risk(HI),which is the product of the HQs for the adult and child populations,respectively,was *** values under 1,therefore,demonstrated that they had no carcinogenic effects on human *** and MEQs in the sediments of Burullus Lake do not have a cancer-causing impact on *** the safety of nearby wildlife,aquatic life,and people,all activities that raise petroleum hydrocarbon levels in Burullus Lake must be adequately regulated and *** to the ecological risk assessment,there is little chance that PAHs will be found

关键词： Polycyclic aromatic hydrocarbons Diagnostic indices Toxicity Delta lake sediment Burullus Lake Human health risk Aquatic ecosystem HPLC Coal combustion

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