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Preparation of co/S co-doped carbon catalysts for excellent methylene blue degradation

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International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 169-181页

作者： Haixu Li Haobo He Tiannan Jiang Yunfei Du Zhichen Wu Liang Xu Xinjie Wang Xiaoguang Liu Wanhua Yu Wendong Xue School of Materials Science and Engineering University of Science and Technology BeijingBeijing 100083China Beijing Jinyu Tongda Refractory Technologies co. Ltd.Beijing 100085China

S and co co-doped carbon catalysts were prepared via pyrolysis of MOF-71 and thiourea mixtures at 800℃at a mass ratio of MOF-71 to thiourea of 1:0.1 to effectively activate peroxymonosulfate(PMS)for methylene blue(MB)*** effects of two different mixing routes were identified on the MB degradation ***,the catalyst obtained by the alcohol solvent evaporation(MOF-AEP)mixing route could degrade 95.60%MB(50 mg/L)within 4 min(degradation rate:K=0.78 min^(-1)),which was faster than that derived from the direct grinding method(MOF-DGP,80.97%,K=0.39 min^(-1)).X-ray photoelectron spectroscopy revealed that the co-S content of MOF-AEP(43.39at%)was less than that of MOF-DGP(54.73at%),and the proportion of C-S-C in MOF-AEP(13.56at%)was higher than that of MOF-DGP(10.67at%).Density functional theory calculations revealed that the adsorption energy of co for PMS was -2.94 eV when sulfur was doped as C-S-C on the carbon skeleton,which was higher than that when sulfur was doped next to cobalt in the form of co-S bond(-2.86 eV).Thus,the C-S-C sites might provide more contributions to activate PMS compared with ***,the degradation parameters,including pH and MOF-AEP dosage,were ***,radical quenching experiments and electron paramagnetic resonance(EPR)measurements revealed that ^(1)O_(2)might be the primary catalytic species,whereas·O~(2-)might be the secondary one in degrading MB.

关键词： advanced oxidation process alcohol solvent evaporation hydrogen bond S and co co-doped carbon catalysts wastewater remediation

SensFL:Privacy-Preserving Vertical Federated Learning with Sensitive Regularization

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computer Modeling in Engineering & Sciences 2025年第1期142卷 385-404页

作者： Chongzhen Zhang Zhichen Liu Xiangrui Xu Fuqiang Hu Jiao Dai Baigen Cai Wei Wang School of Automation and Intelligence Beijing Jiaotong UniversityBeijing100044China Shuohuang Railway Development co. Ltd.National Energy GroupCangzhou062350China Beijing Key Laboratory of Security and Privacy in Intelligent Transportation School of Computer Science and TechnologyBeijing Jiaotong UniversityBeijing100044China

In the realm of Intelligent Railway Transportation Systems,effective multi-party collaboration is crucial due to concerns over privacy and data *** Federated Learning(VFL)has emerged as a promising approach to facilitate such collaboration,allowing diverse entities to collectively enhance machine learning models without the need to share sensitive training ***,existing works have highlighted VFL’s susceptibility to privacy inference attacks,where an honest but curious server could potentially reconstruct a client’s raw data from embeddings uploaded by the *** vulnerability poses a significant threat to VFL-based intelligent railway transportation *** this paper,we introduce SensFL,a novel privacy-enhancing method to against privacy inference attacks in ***,SensFL integrates regularization of the sensitivity of embeddings to the original data into the model training process,effectively limiting the information contained in shared *** reducing the sensitivity of embeddings to the original data,SensFL can effectively resist reverse privacy attacks and prevent the reconstruction of the original data from the *** experiments were conducted on four distinct datasets and three different models to demonstrate the efficacy of *** results show that SensFL can effectively mitigate privacy inference attacks while maintaining the accuracy of the primary learning *** results underscore SensFL’s potential to advance privacy protection technologies within VFL-based intelligent railway systems,addressing critical security concerns in collaborative learning environments.

关键词： Vertical federated learning privacy defenses

Dynamic evolution of co species and morphological reconstruction on co-n-C during the nitrate reduction reaction in neutral solution

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nano Research 2025年第1期18卷 164-172页

作者： Yuanlin Fu Xiaoting Yang Ya Yu Kang Zhou Xiaoyang Ye Aoxiang Zhang Xiaojiao Hou Bingbing Chen Fuqiang Fan Yuhang Li Yu Fu Department of Chemistry College of SciencesNortheastern UniversityShenyang 110819China Department of Physical Education Shen Yang Institute of Science and TechnologyShenyang 110167China Sungrow Power Supply co. Ltd.Hefei 230088China

The electrochemical nitrate reduction reaction(enO_(3)^(-)RR)is considered an effective approach for converting nitrate-containing wastewater to *** adsorption and activation of nO_(3)^(-)is the critical step for many materials and the high energy barrier inhibits the continuation of the reduction *** co nanoparticles encapsulated in the carbon layer we prepared spontaneously react with nO_(3)^(-)and the resulting co^(2+)is then reduced by electroreduction to co^(0),which circulates *** resulted in overcoming the energy input required for nO_(3)^(-)adsorption and conversion,thereby increasing the catalytic *** the same time,the morphology of the catalyst reconstructed from a dodecahedron to an interwoven nanosheet structure and the increased surface area also gives it better *** obtained co(OH)_(2)@co-n-C has an excellent enO_(3)^(-)RR of 2774.7μg·h^(-1)·cm^(-2)with a Faraday efficiency of 81.4%in neutral *** the same time,the material-modified electrode can run stably for more than 100 *** work provides a new idea for the design of co-based catalysts for enO_(3)^(-)RR.

关键词： electrochemical nitrate reduction reaction co-based catalyst dynamic evolution of co species morphological reconstruction

Effect of alloying on high temperature fatigue performance of ZL114A(Al-7Si) alloy

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中国有色金属学会会刊：英文版 2012年第S3期22卷 661-667页

作者： DOnG Xu-gang ZHOU Jie JIA Yao-jun LIU Bin college of Materials Science and Engineering Chongqing University Baoji Petpoleum steel pipe co. Ltd.

The effect of Cu,Fe and ni on high-temperature mechanical performance and fatigue properties of ZL114A alloy was studied through high temperature fatigue test and *** results show that the three elements have a detrimental influence on high temperature cyclic fatigue *** the contents (mass fraction) of Fe,Cu and ni in ZL114A alloy are 0.28%,1.53% and 0.16%,respectively,the high temperature tensile strength and cyclic fatigue of ZL114A alloy are improved from 194 MPa and 40.2 MPa to 236 MPa and 48.2 MPa by *** main reason that high temperature tensile strength and cyclic fatigue of ZL114A alloy are improved significantly is that the three elements greatly improve the proportion of Cu/Mg in ZL114A alloy and nickel content.

关键词： aluminum alloys alloying high temperature fatigue fracture

Study on the hydrogen absorption properties of a YGdTbDyHo rare-earth high-entropy alloy

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International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 127-135页

作者： Tongyue Li Ziliang Xie Wenjiao Zhou Huan Tong Dawen Yang Anjia Zhang Yuan Wu Xiping Song State Key Laboratory for Advanced Metals and Materials University of Science and Technology BeijingBeijing 100083China Whole Win(Beijing)Materials Sci.&Tech.co. Ltd.Beijing 100083China

This study investigated the microstructure and hydrogen absorption properties of a rare-earth high-entropy alloy(HEA),*** indicated that the YGdTbDyHo alloy had a microstructure of equiaxed grains,with the alloy elements distributed *** hydrogen absorption,the phase structure of the HEA changed from a solid solution with an hexagonal-close-packed(HCP)structure to a high-entropy hydride with an faced-centered-cubic(FCC)structure without any secondary phase *** alloy demonstrated a maximum hydrogen storage capacity of 2.33 H/M(hydrogen atom/metal atom)at 723 K,with an enthalpy change(ΔH)of-141.09 kJ·mol^(-1)and an entropy change(ΔS)of-119.14 J·mol^(-1)·K^(-1).The kinetic mechanism of hydrogen absorption was hydride nucleation and growth,with an apparent activation energy(E_(a))of 20.90 kJ·mol^(-1).Without any activation,the YGdTbDyHo alloy could absorb hydrogen quickly(180 s at 923 K)with nearly no incubation period *** reason for the obtained value of 2.33 H/M was that the hydrogen atoms occupied both tetrahedral and octahedral *** results demonstrate the potential application of HEAs as a high-capacity hydrogen storage material with a large H/M ratio,which can be used in the deuterium storage field.

关键词： rare-earth high-entropy alloy hydrogen absorption capacity pressure–composition–temperature curves kinetics

Study on intelligent control technology for forming steel pipe of pipeline with Jco process

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Science china(Technological Sciences) 2011年第10期54卷 2754-2759页

作者： ZHAO Jun LI Jian QU XiaoYang WAnG Gang SUn HongLei MA Rui college of Mechanical Engineering Yanshan University Qinhuangdao 066004 China Julong steel pipe co. ltd. Qinhuangdao 062658 China

Based on plastic bending engineering theory and machine vision technology, the intelligent control technology for forming steel pipe with Jco process is presented in this paper. By ‘twice pre-bending method’ in the first forming step, the springback law can be obtained. With the springback law and the target angle, the exact punch displacement which determines the formed angle in each bending step is predicted. In the succedent forming steps, the bending process is carried out with the exact punch displacement by real-time revising the springback law. And the angle error in each forming step is calculated by comparing the actual formed angle with the target angle. By conducting compensation for the last angle error in the next forming step, each precise bending process step is realized. A system of intelligent control technology for forming the steel pipe was developed. A calibration method is proposed to calculate the exterior parameters of the CCD camera, in which the equilateral triangle is em-ployed as the calibrating board and only one image needs to be captured. A mathematical model, which converts the angle in the image into the actual formed angle, is derived. The experimental results showed that the ellipticity of the formed pipes was less than 1.5% and the high-quality pipes can be manufactured without the worker's operating experience by employing the in-telligent control technology.

关键词： steel pipe of pipeline intelligent control technology calibration Jco process ellipticity

Depression mechanism of sulfite ions on sphalerite and Pb^(2+)activated sphalerite in the flotation separation of galena from sphalerite

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International Journal of Minerals,Metallurgy and Materials 2025年第2期32卷 335-345页

作者： Feng Zhang Chenyang Zhang Linlin Wu Wei Sun Hongliang Zhang Jianhua Chen Yong Pei Songjiang Li Engineering Research Center of Ministry of Education for Carbon Emission Reduction in Metal Resource Exploitation and Utilization Hunan International Joint Research Center for Efficient and Clean Utilization of Critical Metal Mineral ResourcesSchool of Minerals Processing and BioengineeringCentral South UniversityChangsha 410083China State Key Laboratory of Mineral Processing Beijing General Research Institute of Mining&MetallurgyBeijing 100160China Hunan Provincial Key Laboratory of Micro&nano Materials Interfaces Science College of Chemistry and Chemical EngineeringCentral South UniversityChangsha 410083China School of Resources Environment and MaterialsGuangxi UniversityNanning 530004China Department of Chemistry Xiangtan UniversityXiangtan 411105China china Railway Resource Group co.ltd Beijing 102300China

The depression mechanism of sulfite ions on sphalerite and Pb^(2+)activated sphalerite in the flotation separation of galena from sphalerite still lacked in-depth ***,the depression mechanism of sulfite ions on sphalerite and Pb^(2+)activated sphalerite in the flotation separation of galena from sphalerite was further systematically investigated with experiments and density functional theory(DFT)*** X-ray photoelectric spectroscopy(XPS)results,DFT calculation results,and frontier molecular orbital analysis indicated that sulfite ions were difficult to be adsorbed on sphalerite surface,suggesting that sulfite ions achieved depression effects on sphalerite through other non-adsorption ***,the oxygen content in the surface of sphalerite treated with sulfite ions in creased,which enhanced the hydrophilicity of the sphalerite and further increased the difference in hydrophilicity between sphalerite and ***,sulfite ions were chelated with lead ions to form PbSO_(3)in *** hydrophilic PbSO_(3)was more easily adsorbed on sphalerite than *** interaction between sulfite ions and lead ions could effectively inhibit the activation of *** addition the UV spectrum showed that after adding sulfite ions,the peak of perxanthate in the sphalerite treated xanthate solution was significantly stronger than that in the galena with xanthate solution,indicating that xanthate interacted more readily with sulfite ions and oxygen mo lecules within the sphalerite system,leading to the formation of ***,sulfite ions hardly depressed the flotation of ga lena and could promote the flotation of galena to some *** study deepened the understanding of the depression mechanism o sulfite ions on sphalerite and Pb^(2+)activated sphalerite.

关键词： sphalerite galena sulfite ion density functional theory depression mechanism

CFD Investigation of Diffusion Law and Harmful Boundary of Buried natural Gas pipeline in the Mountainous Environment

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Energy Engineering 2024年第8期121卷 2143-2165页

作者： Liqiong Chen Kui Zhao Kai Zhang Duo Xv Hongxvan Hu Guoguang Ma Wenwen Zhan School of petroleum Engineering Southwest Petroleum UniversityChengdu610000China national pipe network Group Southwest pipeline co. Ltd.Chengdu610000China national pipeline Research Center conveyance pipe Institute Baoji Petroleum Steel Pipe Co.Ltd.Baoji721000China

The leakage gas from a buried natural gas pipelines has the great potential to cause economic losses and environmental pollution owing to the complexity of the mountainous *** this study,computational fluid dynamics(CFD)method was applied to investigate the diffusion law and hazard range of buried natural gas pipeline leakage in mountainous *** on cloud chart,concentration at the monitoring site and hazard range of lower explosion limit(LEL)and upper explosion limit(UEL),the influences of leakage hole direction and shape,soil property,burial depth,obstacle type on the diffusion law and hazard range are *** show that the leakage gas is not radially diffused until it reaches the ground,and the velocity of gas diffusion to the ground and the hazard range decrease as the angle between the leaking direction and the buoyancy direction *** and square leak holes have a faster diffusion rate and a wider hazard range than *** diffusion rate of leakage gas in soil rises as soil granularity and porosity *** time of leakage gas diffusion to the ground increases significantly with the increase of burial depth,and the hazard range reduces as burial depth ***-type obstacles will alter the diffusion path of the leakage gas and accelerate the expansion of the hazard distance,while trench-type obstacles will cause the natural gas to accumulate in the trench and form a high concentration region slowing the expansion of the surface gas concentration.

关键词： Mountainous environment buried pipeline leakage and diffusion hazard range numerical simulation

Moment Redistribution Effect of the continuous Glass Fiber Reinforced Polymer-concrete composite Slabs Based on Static Loading Experiment

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Structural Durability & Health Monitoring 2025年第1期19卷 105-123页

作者： Zhao-Jun Zhang Wen-Wei Wang Jing-Shui Zhen Bo-Cheng Li De-Cheng Cai Yang-Yang Du Hui Huang Offshore Oil Engineering co.ltd. Tianjin300461China Department of Bridge Engineering School of TransportationSoutheast UniversityNanjing211189China

This study aimed to investigate the moment redistribution in continuous glass fiber reinforced polymer(GFRP)-concrete composite slabs caused by concrete cracking and steel bar yielding in the negative bending moment *** experimental bending moment redistribution test was conducted on continuous GFRP-concrete composite slabs,and a calculation method based on the conjugate beam method was *** composite slabs were formed by combining GFRP profiles with a concrete layer and supported on steel beams to create two-span continuous composite slab *** methods,epoxy resin bonding,and stud connection,were used to connect the composite slabs with the steel *** experimental findings showed that the specimen connected with epoxy resin exhibited two moments redistribution phenomena during the loading process:concrete cracking and steel bar yielding at the internal *** contrast,the composite slab connected with steel beams by studs exhibited only one-moment redistribution phenomenon throughout the loading *** the concrete at the internal support cracked,the bending moment decreased in the internal support section and increased in the midspan *** the steel bars yielded,the bending moment further decreased in the internal support section and increased in the mid-span *** GFRP profiles do not experience cracking,there was no significant decrease in the bending moment of the mid-span *** test specimens experienced compressive failure of concrete at the mid-span *** results showed good agreement between the calculated and experimental values of bending moments in the mid-span section and internal support *** proposed model can effectively predict the moment redistribution behavior of continuous GFRP-concrete composite slabs.

关键词： Moment redistribution GFRP-concrete composite slabs bending moment experimental study analysis model