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Flow and geochemical modeling of drainage from Tomitaka mine,Miyazaki,Japan

Journal of Environmental Sciences 2015年第10期27卷 130-143页

作者： Kohei Yamaguchi Shingo Tomiyama Hideya Metugi Hiroyuki Ii Akira Ueda mitsubishi materials corporation 1-297 KitabukuroOmiyaSaitama 330-0835Japan mitsubishi materials Techno corporation 1-14-16 KudankitaChiyoda-kuTokyo 102-8205Japan Faculty of Systems Engineering Wakayama University Japan Oil Gas and Metals National Corporation Graduate School Division of Science and Engineering University of Toyama

The chemistry and flow of water in the abandoned Tomitaka mine of Miyazaki, western Japan were investigated. This mine is located in a non-ferrous metal deposit and acid mine drainage issues from it. The study was undertaken to estimate the quantities of mine drainage that needs to be treated in order to avoid acidification of local rivers, taking into account seasonal variations in rainfall. Numerical models aimed to reproduce observed water levels and fluxes and chemical variations of groundwater and mine drainage. Rock–water interactions that may explain the observed variations in water chemistry are proposed. The results show that：（1） rain water infiltrates into the deeper bedrock through a highly permeable zone formed largely by stopes that are partially filled with spoil from excavations（ore minerals and host rocks）;（2） the water becomes acidic（p H from 3 to 4） as dissolved oxygen oxidizes pyrite;（3） along the flow path through the rocks, the redox potential of the water becomes reducing, such that pyrite becomes stable and p H of the mine drainage becomes neutral; and（4） upon leaving the mine, the drainage becomes acidic again due to oxidation of pyrite in the rocks. The present numerical model with considering of the geochemical characteristics can simulate the main variations in groundwater flow and water levels in and around the Tomitaka mine, and apply to the future treatment of the mine drainage.

关键词： Mine drainage Hydrogen isotope Oxygen isotope Rock–water interaction Water movement

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An Approximate High Gain Observer for Speed-sensorless Estimation of Induction Motors

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IEEE/CAA Journal of Automatica Sinica 2019年第1期6卷 53-63页

作者： Yebin Wang Lei Zhou Scott A.Bortoff Akira Satake Shinichi Furutani IEEE mitsubishi Electric Research Laboratories the Department of Mechanical Engineering Massachusetts Institute of Technology the Advanced Technology R&D Center Mitsubishi Electric Corporation

Rotor speed estimation for induction motors is a key problem in speed-sensorless motor drives. This paper performs nonlinear high gain observer design based on the full-order model of the induction motor. Such an effort appears nontrivial due to the fact that the full-model at best admits locally a non-triangular observable form(NTOF), and its analytical representation in the NTOF can not be obtained. This paper proposes an approximate high gain estimation algorithm, which enjoys a constructive design, ease of tuning, and improved speed estimation and tracking performance. Experiments demonstrate the effectiveness of the proposed algorithm.

关键词： Induction motor industrial applications nonlinear state estimation speed-sensorless motor drive

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Effect of surface treatment for aluminum foils on discharge properties of lithium-ion battery

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Transactions of Nonferrous Metals Society of China 2014年第7期24卷 2314-2319页

作者： Shigeki NAKANISHI Takashi SUZUKI Qi CUI Jun AKIKUSA Kenzo NAKAMURA Products Research and Development Department Mitsubishi Aluminum Co. Ltd. Central Research Institute Electronic Components Department Mitsubishi Materials Corporation

Aluminum foils having thicknesses of 10-20 μm are commonly employed as current collectors for cathode electrodes in Li-ion batteries. The effects of the surface morphology of the foil on battery performance were investigated by using a foil with roughened surface by chemical etching and a plain foil with smooth surface on both sides. For high-conductivity LiCoO2 active materials with large particle size, there are no significant differences in battery performance between the two types of foils. But for low-conductivity LiFePO4 active materials with small particle size, high-rate discharge properties are significantly different. The possibility shows that optimizing both the surface morphology of the aluminum foil and particle size of active material leads to improvement of the battery performance.

关键词： lithium-ion battery battery performance surface treatment conductivity plain foil roughened foil

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Formation mechanism of extension fractures induced by excavation of a gallery in soft sedimentary rock,Horonobe area,Northern Japan

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Geoscience Frontiers 2013年第1期4卷 105-111页

作者： Tetsuya Tokiwa Kimikazu Tsusaka Makoto Matsubara Taiki Ishikawa Daisuke Ogawa Horonobe Underground Research Unit Japan Atomic Energy AgencyHokkaido 098-3224Japan Geoscience Research Laboratory Kanagawa 242-0014Japan mitsubishi materials Techno corporation Tokyo 102-8205Japan

This paper focuses on the formation mechanism of fractures induced by excavation of a gallery in soft sedimentary rocks in the Horonobe area of Japan. Detailed fracture mapping of the gallery indicates that the fractures consist of both pre-existing shear fractures and excavation damaged zone （EDZ） fractures. EDZ fractures correspond to weak planes associated with bedding planes or transgranular cracks. The EDZ fractures terminate against pre-existing shear fractures. Therefore, even for excavations in soft sedimentary rocks, formation of the EDZ fractures are controlled by pre-existing fractures and earlier weak planes.

关键词： Fracture Excavation damaged zone (EDZ)Weak plane Soft rock Excavation

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FTY720,Sphingosine 1-Phosphate Receptor Modulator,Ameliorates Experimental Autoimmune Encephalomyelitis by Inhibition of T Cell Infiltration

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Cellular & Molecular Immunology 2005年第6期2卷 439-448页

作者： Hirotoshi Kataoka Kunio Sugaharal Kyoko Shimano Koji Teshima Mamoru Koyama Atsyshi Fukunari Kenji Chiba Research Laboratory Ⅲ(Immunology) Pharmaceutical Research UnitResearch and Development DivisionMitsubishi Pharma CorporationYokohamaJapan Research Laboratory 1(CNS) Pharmaceutical Research UnitResearch and Development DivisionMitsubishi Pharma CorporationYokohamaJapan Discovery Technology Laboratory Ⅰ Pharmaceutical Research UnitResearch and Development DivisionMitsubishi Pharma CorporationYokohamaJapan Research Laboratory Ⅲ(Immunology) Pharmaceutical Research UnitResearch and Development DivisionMitsubishi Pharma Corporation1000 Kamoshida-choAoba-kuYokohama 227-0033.Japan.

FTY720, a sphingosine 1-phosphate receptor modulator, induces a marked decrease in the number of peripheral blood lymphocytes and exerts immunomodulating activity in various experimental allograft and autoimmune disease models. In this study, we evaluated the effect of FTY720 and its active metabolite, （S）-enantiomer of FTY720-phosphate [（S）-FTY720-P] on experimental autoimmune encephalomyelitis （EAE） in rats and mice. Prophylactic administration of FTY720 at 0.1 to 1 mg/kg almost completely prevented the development of EAE, and therapeutic treatment with FTY720 significantly inhibited the progression of EAE and EAE-associated histological change in the spinal cords of LEW rats induced by immunization with myelin basic protein. Consistent with rat EAE, the development of proteolipid protein-induced EAE in SJL/J mice was almost completely prevented and infiltration of CD4^＋ T cells into spinal cord was decreased by prophylactic treatment with FTY720 and （S）-FTY720-P. When FTY720 or （S）-FTY720-P was given after establishment of EAE in SJL/J mice, the relapse of EAE was markedly inhibited as compared with interferon-β, and the area of demyelination and the infiltration of CD4^＋ T cells were decreased in spinal cords of EAE mice. Similar therapeutic effect by FTY720 was obtained in myelin oligodendrocyte glycoprotein-induced EAE in C57BL/6 mice. These results indicate that FTY720 exhibits not only a prophylactic but also a therapeutic effect on EAE in rats and mice, and that the effect of FTY720 on EAE appears to be due to a reduction of the infiltration of myelin antigen-specific CD4^＋ T cells into the inflammation site. Cellular ＆ Molecular Immunology. 2005;2（6）：439-448.

关键词： FTY720 S1P receptor modulator lymphopenia EAE T cell infiltration

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Moisture Detection of SF_6 Gas Instruments by Solid Electrolyte

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稀有金属材料与工程 2006年第A3期35卷 353-356页

作者： Eiichi Nagao Tadao Minagawa Chieko Nishida Mitsuhito Kamei mitsubishi Electric corporation 8-1-1Tsukaguchi-HonmachiAmagasakiHyogo661-8661Japan

Humidity measurement in a very low moisture atmosphere was studied by using solid electrolyte film coated with porous electrodes,considering its application to the moisture monitoring of SF_6 gas-insulated high voltage instruments such as gas-insulated switchgear (GIS) and gas circuit breakers (GCBs).Compared to the AC impedance values measured in an ambient atmosphere where the moisture atmosphere is far higher than that in these instruments,considerably large impedance values were obtained in a very low moisture *** impedance was systematically measured in accordance with the conditions of these instruments whose moisture contents were less than 1 000×10^(-6).A good correlation was obtained between the impedance values and the moisture *** frequency characteristics of the impedance were analyzed based on a conventional equivalent circuit where a number of CR circuits were connected in *** the dielectric relaxation of each circuit,it was found that the frequency characteristics of the impedance can be explained by the equivalent circuit. Two semicircles were clearly obtained in the Cole-Cole impedance plot which are thought to reflect the impedance characteristics of the film and the *** AC impedance can be a good indicator of the moisture content of SF_6 gas-insulated high voltage instruments.

关键词： humidity moisture solid electrolyte impedance ion conductivity

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Applications of quantum computing for investigations of electronic transitions in phenylsulfonyl-carbazole TADF emitters

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npj Computational materials 2021年第1期7卷 619-627页

作者： Qi Gao Gavin O.Jones Mario Motta Michihiko Sugawara Hiroshi CWatanabe Takao Kobayashi Eriko Watanabe Yu-ya Ohnishi Hajime Nakamura Naoki Yamamoto mitsubishi Chemical corporation Science&Innovation CenterYokohamaJapan Quantum Computing Center Keio UniversityYokohamaJapan IBM Quantum IBM Research-AlmadenSan JoseCAUSA materials Informatics Initiative Yokkaichi Research CenterJSR CorporationYokkaichiMieJapan IBM Research-Tokyo TokyoJapan Department of Applied Physics and Physico-Informatics Keio UniversityYokohamaJapan

A quantum chemistry study of the first singlet(S_(1))and triplet(T_(1))excited states of phenylsulfonyl-carbazole compounds,proposed as useful thermally activated delayed fluorescence(TADF)emitters for organic light emitting diode(OLED)applications,was performed with the quantum Equation-Of-Motion Variational Quantum Eigensolver(qEOM-VQE)and Variational Quantum Deflation(VQD)algorithms on quantum simulators and *** quantum simulations were performed with double zeta quality basis sets on an active space comprising the highest occupied and lowest unoccupied molecular orbitals(HOMO,LUMO)of the TADF *** differences in energy separations between S_(1) and T_(1)(ΔEST)predicted by calculations on quantum simulators were found to be in excellent agreement with experimental *** of 17 and 88 mHa with respect to exact energies were found for excited states by using the qEOM-VQE and VQD algorithms,respectively,to perform simulations on quantum devices without error *** utilizing state tomography to purify the quantum states and correct energy values,the large errors found for unmitigated results could be improved to differences of,at most,4 mHa with respect to exact ***,excellent agreement could be found between values ofΔEST predicted by quantum simulations and those found in experiments.

关键词： quantum excited occupied

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A tree-shaped motion strategy for robustly executing robotic assembly tasks

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Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2010年第12期11卷 986-991页

作者： Yusuke BOTA Hajime MIZUYAMA Akio NODA Tatsuya NAGATANI Ken-ichi TANAKA Department of Mechanical Engineering and Science Kyoto University Yoshida-Honmachi Advanced Technology R&D Center Mitsubishi Electric Corporation 8-1-1Tsukaguchi-Honmachi

An assembly robot needs to be capable of executing an assembly task robustly under various *** attain this goal,we use a task sequence tree model originally proposed for manual *** model regards an assembly task under uncertainties as a transformation of the contact state *** concept may contain several contact states with probabilities but these are transformed through a series of task elements into the contact state concept having only the goal state at the *** transformed contact state concept can be classified according to the terminal condition of each task ***,the whole assembly task can be designed as a tree-shaped contingent strategy called a task sequence *** paper proposes a systematic approach for reconfiguring a task sequence tree model for application to a robotic assembly *** addition,by taking a 2D peg-in-hole insertion task to be performed by a robot equipped with a force sensor as an example,we confirm that the proposed approach can provide a robust motion strategy for the task and that the robot can actually execute the task robustly under bounded uncertainty according to the strategy.

关键词： Active compliant motion Contact states Motion strategy Robotic assembly Task sequence tree

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PRODUCTION OF HIGH QUALITYLUBRICATING BASE OIL

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石油学报（石油加工） 2001年第1期17卷 77-80页

作者： Hajime OKAZAKI MichiakiADACHI Jin ichiIGARASHI Central Technical Research Laboratory Nippon mitsubishi Oil corporation 日本 2 3 1 0 81

Bench studies were conducted on a hydrocracking (HDC) catalyst produced by Nippon mitsubishi Oil Corp (NMOC) and its affiliate company, Nippon mitsubishi Petroleum Refining Co (NMPRC). NMOC and NMPRC operate their hydrocracker both in fuel oil production mode and in lubricating oil production mode. In the latter, high viscosity index lubricating oil called VHDC is produced. By applying the VHDC and efficient friction modifier technology, NMOC has developed super fuel economy 5W-20 engine oil which could improve automobile fuel economy by ∼ 5% resulting in significant saving of gasoline. The VHDC Group III base oil improves the performance of industrial lubricant, such as turbine oils. To continue to supply such high quality of lubricating oil, NMOC and NMPRC have developed the hydrocracking catalyst which contains zeolite as one of its components and makes the higher conversion rate possible. After many bench scale tests, the new catalyst was loaded into the commercial hydrocracker and is still running well.

关键词：润滑油质量管理原油加工加氢裂化 HDC

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Protective effects of ursodeoxycholic acid on chenodeoxycholic acid-induced liver injury in hamsters

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World Journal of Gastroenterology 2007年第37期13卷 5003-5008页

作者： Tomomichi Iwaki Kaoru Ishizaki Shuji Kinoshita Hideki Tanaka Atsushi Fukunari Makoto Tsurufuji Teruaki Imada Research Laboratory Ⅲ (Immunology) Pharmaceuticals Research Division Mitsubishi Pharma Corporation Yokohama Japan Pharmacokinetics Laboratory Pharmaceuticals Research Division Mitsubishi Pharma Corporation Chiba Japan Discovery Technology Laboratory Pharmaceuticals Research Division Mitsubishi Pharma Corporation Yokohama Japan

AIM： TO investigate the effects of ursodeoxycholic acid （UDCA） on chenodeoxycholic acid （CDCA）-induced liver injury in hamsters, and to elucidate a correlation between liver injury and bile acid profiles in the liver.METHODS： Liver injury was induced in hamsters by administration of 0.5% （w/w） CDCA in their feed for 7 d. UDCA （50 mg/kg and 150 mg/kg） was administered for the last 3 d of the experiment.RESULTS： At the end of the experiment, serum alanine aminotransferase （ALl） increased more than 10 times and the presence of liver injury was confirmed histologically. Marked increase in bile acids was observed in the liver. The amount of total bile acids increased approximately three-fold and was accompanied by the increase in hydrophobic bile acids, CDCA and lithocholic acid （LCA）. UDCA （50 mg/kg and 150 mg/kg） improved liver histology, with a significant decrease （679.3 ±77.5 U/L vs 333.6 ± 50.4 U/L and 254.3 ±35.5 U/ L, respectively, P 〈 0.01） in serum ALT level. UDCA decreased the concentrations of the hydrophobic bile acids, and as a result, a decrease in the total bile acid level in the liver was achieved.CONCLUSION： The results show that UDCA improves oral CDCA-induced liver damage in hamsters. The protective effects of UDCA appear to result from a decrease in the concentration of hydrophobic bile acids, CDCA and LCA, which accumulate and show the cytotoxicity in the liver.

关键词： Chenodeoxycholic acid Hamster Liver bileacids Ursodeoxycholic acid

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