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Using cemented paste backfill to tackle the phosphogypsum stockpile in China:A down-to-earth technology with new vitalities in pollutant retention and CO_(2) abatement

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International Journal of Minerals,Metallurgy and Materials 2024年第7期31卷 1480-1499页

作者： Yikai Liu Yunmin Wang Qiusong Chen School of Resources and Safety engineering Central South UniversityChangsha 410083China department of Geosciences and CIRCe Centre University of PaduaPadua 35129Italy Sinosteel Maanshan General Institute of mining Research Co. Ltd.Ma'anshan 24300China

Phosphogypsum(PG),a hard-to-dissipate by-product of the phosphorus fertilizer production industry,places strain on the biogeochemical cycles and ecosystem functions of storage *** pervasive problem is already widespread worldwide and requires careful *** this study,we review the presence of potentially toxic elements(PTEs)in PG and describe their associations with soil properties,anthropogenic activities,and surrounding ***,we review different ex-/in-situ solutions for promoting the sustainable management of PG,with an emphasis on in-situ cemented paste backfill,which offers a cost-effective and highly scalable opportunity to advance the value-added recovery of ***,concerns related to the PTEs'retention capacity and long-term effectiveness limit the implementation of this ***,given that the large-scale demand for ordinary Portland cement from this conventional option has resulted in significant CO_(2) emissions,the technology has recently undergone additional scrutiny to meet the climate mitigation ambition of the Paris Agreement and China's Carbon Neutrality ***,we discuss the ways by which we can integrate innovative strategies,including supplementary cementitious materials,alternative binder solutions,CO_(2) mineralization,CO_(2) curing,and optimization of the supply chain for the profitability and sustainability of PG ***,to maximize the co-benefits in environmental,social,and economic,future research must bridge the gap between the feasibility of expanding these advanced pathways and the multidisciplinary needs.

关键词： cemented paste backfill phosphogypsum carbon dioxide mitigation potentially toxic elements solidification and stabilization

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Boosting the Activity and Stability of the Photoreduction of Diluted CO_(2) by Copper Oxide Decorated CeO_(2) Hetero-shells

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Chemical Research in Chinese Universities 2024年第3期40卷 513-520页

作者： XIAO Mingjiao LI Di WEI Yanze HE Yilei WANG Zumin YU Ranbo department of Physical Chemistry School of Metallurgical and Ecological EngineeringUniversity of Science&Technology BejingBeijing 100083P.R.China State Key Laboratory of Biochemical engineering Institute of Process EngineeringChinese Academy of SciencesBeijing 100190P.R.China Key Laboratory of Biopharmaceutical Preparation and Delivery Chinese Academy of SciencesBeijing 100190P.R.China

Inspired by the natural photosynthesis systems,the integrated harnessing and conversion of CO_(2) present a promising solution for addressing the ever-rising global atmospheric concentration of CO_(2).Hollow multi-shelled structured(HoMS)photocatalysts,featuring alternating shells and cavities,have recently gained recognition as efficient nano-reactors for capturing CO_(2) molecules and facilitating effective photoreduction within these hierarchical structures,leveraging the preeminent enrichment *** this work,to augment the photocatalytic efficacy of HoMS in CO_(2) treatment,highly dispersed Cu_(x)O nanoparticles(NPs)were incorporated on the CeO2 shells through a polymer-assisted impregnation method to create more active sites and strengthen the interaction between the hetero-shells and CO_(2) *** photoreduction of the CO_(2)-to-CO rate under a diluted CO_(2)(15%,volume fraction)atmosphere is improved by the introduction of Cu_(x)O NPs,with the highest CO yielding rate reaching 120µmol·h^(−1)·g^(−1) without any sacrificial *** comparison experiments and theoretical calculations reveal that the Cu_(x)O NPs promote the adsorption of CO_(2) molecules in HoMS,accelerate the charge transfer efficiency,and stabilize the surface oxygen vacancies(Ovs)during the photoreduction CO_(2) conversion *** hope these easy-to-prepare HoMS nanoreactors can contribute to the effective enrichment and valorization of CO_(2) in industrial exhaust gases.

关键词： Photoreduction CO_(2) Cu_(x)O/CeO_(2)hollow multi-shell structure(HoMS) Hetero-shell

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Mobility of Major and Trace Elements during the Bauxitization Processes in Ngaoundal Area (Adamawa Cameroon): Implication on mining Perspectives

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Open Journal of Geology 2024年第1期14卷 81-100页

作者： André Sini Harouna Boukari Ondoa Augustin Désiré Balla Djetenbe Beral Salomon Wangmené Awé Simon Djakba Basga Jean Pierre Nguetnkam department of mining engineering School of Geology and Mining Engineering University of Ngaoundere Ngaoundere Cameroon department of mining engineering and Environment School of Mining Industry and Geology University of Abdou-Moumouni Niamey Niger department of Earth Sciences Faculty of Science University of Ngaoundere Ngaoundere Cameroon department of mining engineering Saint Jerome Polytechnic Saint Jerome Catholic University Institute of Douala Douala Cameroon Institute of Agricultural Research for Development (IRAD) Garoua Cameroon

This study was focused to assess major and trace elements in bauxitic duricrusts from Ngaoundal and its surroundings in order to establish their mining interest. To this end, fieldworks, mineralogical and geochemical analyses were carried out. Four facies of duricrust were identified and characterized from the summit to the top of the slope of the Ngaoundal mountain: scoriaceous, pisolitic, nodular and massive. Mineralogical and geochemical analyses performed on 16 samples, revealed a significant concentration of Al2O3 mainly in the scoriaceous facies (over 45% in grade), moderate in Fe2O3 (averaging 23.69%) and SiO2 (averaging 21.7%). Trace elements were generally low, excluding Cr (421 ppm on average), Zr (327 ppm on average and V (213 ppm on average). In addition, the limited quantities of alkalis (Na2O, K2O) and alkaline earths metals (MgO, CaO) coupled with the very high values of Chemical Index of Alteration (CIA) and Mineralogical Index of Alteration (MIA), (more than 99%) attest to the intense weathering of the studied materials. Allitization and monosiallitization constituted the crystallochemical phenomena that have led to the development of bauxitic minerals. More than 90% of gibbsite in scoriaceous facies, 52.21% - 76.01% of kaolinite in pisolitic facies and more than 40% of hematite in nodular facies were quantified. The relationships between the constitutive components indicated their interdependency during the bauxitization phenomenon. The mineralogical and geochemical properties highlighted the mining interest of the studied duricrusts to be valorized.

关键词： Duricrust Bauxitization Phenomenon Mineralogical and Geochemical Characterization Major and Trace Elements mining Potential

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Digital monitoring of rotary-percussive drilling with down-the-hole hammer for profiling weathered granitic ground

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Journal of Rock Mechanics and Geotechnical engineering 2024年第5期16卷 1615-1636页

作者： Wendal Victor Yue Siyuan Wu Manchao He Yafei Qiao Zhongqi Quentin Yue department of Geotechnical engineering College of Civil EngineeringTongji UniversityShanghai200092China department of Civil engineering Faculty of EngineeringThe University of Hong KongPokfulam RoadHong KongChina State Key Laboratory for Geomechanics and Deep Underground engineering China University of Mining and TechnologyBeijing100083China Key Laboratory of Geotechnical and Underground engineering of Ministry of Education Tongji UniversityShanghai200092China

Rock and geotechnical engineering investigations involve drilling holes in ground with or without retrieving soil and rock samples to construct the subsurface ground *** the basis of an actual soil nailing drilling for a slope stability project in Hong Kong,this paper further develops the drilling process monitoring(DPM)method for digitally profiling the subsurface geomaterials of weathered granitic rocks using a compressed airflow driven percussive-rotary drilling machine with down-the-hole(DTH)*** transducers are installed on the drilling machine and record the chuck displacement,DTH rotational speed,and five pressures from five compressed airflows in real-time *** mechanism and operations of the drilling machine are elaborated in detail,which is essential for understanding and evaluating the drilling data.A MATLAB program is developed to automatically filter the recorded drilling data in time series and classify them into different drilling processes in sub-time *** processes include penetration,push-in with or without rod,pull-back with or without rod,rod-tightening and *** drilling data are further reconstructed to plot the curve of drill-bit depth versus the net drilling time along each of the six *** curve is found to contain multiple linear segments with a constant penetration rate,which implies a zone of homogenous geomaterial with different weathering *** effect from fluctuation of the applied pressures is evaluated *** analyses are presented for accurately assess and verify the underground profiling and strength in weathered granitic rock,which provided the basis of using DPM method to confidently assess drilling measurements to interpret the subsurface profile in real time.

关键词： Drilling process monitoring(DPM) Down-the-hole(DTH)hammer Percussive-rotary drilling Weathering granitic rocks

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Quantitative discrimination of surface adsorbed NO_(x) species on CeO_(2) via spectrophotometry for SCR denitration investigation

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Journal of Rare Earths 2024年第6期42卷 1066-1072,I0003页

作者： Songil Sin Jiawei Ji Lijun Cheng Zhiwen Gu Chong Tan Kwangchol Ri Changjin Tang School of Environment Nanjing Normal UniversityNanjing210023China department of mining engineering Kim Chaek University of TechnologyPyongyang999093Democratic People's Republic of Korea Laboratory of Mesoscopic Chemistry of MOE School of Chemistry and Chemical EngineeringNanjing UniversityNanjing20023China Institute of Chemical engineering Hamhung University of Chemical EngineeringHamhungDemocratic People's Republic of Korea Jiangsu Province engineering Research Center of Environmental Risk Prevention and Emergency Response Technology Nanjing210023China

CeO_(2)-based catalysts are widely investigated for selective catalytic reduction(SCR)of NO with *** of NO/O_(2) with CeO_(2) generally produces two surface species,i.e.,nitrates and ***,the explicit quantification of these two species is still ***,we reported that spectrophotometry characterization was effective in determining surface adsorbed NOx species on CeO_(2) by measuring the corresponding ions(NO_(2)-and NO_(3)^(-))dissolved in aqueous *** results show that both nitrate(-NO_(3))and nitrite(-NO_(2))species can be quantitatively evaluated and the accuracy is verified by calibrating with NOx-TPD *** transfer of adsorbed NOx from catalyst surface to aqueous solution is confirmed and the dissolution process can be accelerated by ultrasonic ***,useful information related to evolution of surface NOx species under various conditions(O_(2) treatment,different adsorption temperature and duration)and over different catalysts(Fe_(2)O_(3),MnO_(2) and MnOx—CeO_(2))are *** result of present study demonstrates the potential of spectrophotometry for quantitative discrimination of surface NOx species on CeO_(2) and other oxide-based materials,which is conducive to mechanism analysis of SCR reaction.

关键词： Quantitative evaluation Spectrophotometry analysis Nitrate species Nitrite species CeO_(2)catalyst NH_(3)-SCR

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Experimental and theoretical insight into carbamazepine degradation by chlorine-based advanced oxidation processes:Efficiency,energy consumption,mechanism and DBPs formation

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Journal of Environmental Sciences 2024年第5期139卷 72-83页

作者： Chunwei Liu Zuo Tong How Yue Ju Li Feng Xuefeng Ren Mohamed Gamal El-Din Key Laboratory ofCoal Processing and Efficient Utilization of Ministry of Education School of Chemical Engineering and TechnologyChina University of Mining and TechnologyJiangsu 221116China department of Civil and Environmental engineering University of AlbertaEdmonton T6G 1H9AlbertaCanada School of Environment and Spatial Informatics China University of Mining and TechnologyJiangsu 221116China Key Laboratory of Agro-Forestry Environmental Processes and Ecological Regulation ofHainan Province School of Ecology and EnvironmentHainan UniversityHainan 570228China

Chlorine has been widely used in different advanced oxidation processes(AOPs)for micropollutants *** this study,different chlorine-based AOPs,namely medium pressure(MP)UV/chlorine,low pressure(LP)UV/chlorine,and in-situ chlorination,were compared for carbamazepine(CBZ)removal efficiency,energy consumption,and disinfection by-products(DBPs)*** three processes could achieve nearly 100%CBZ removal,while the reaction time needed by in-situ chlorination was double the time required by UV/chlorine *** energy consumed per magnitude of CBZ removed(EE/O)of MP UV/chlorine was 13 times higher than that of LP UV/chlorine,and relative to that of in-situ chlorination ***,MP and LP UV/chlorine processes generated one to two orders of magnitude more hydroxyl radicals(^(·)OH)and reactive chlorine species(RCS)than in-situ ***,RCS were the dominant reactive species,contributing to 78.3%,75.6%,and 71.6% of CBZ removal in MP,LP UV/chlorine,and in-situ chlorination,*** to the Gibbs free energy barriers between CBZ and RCS/^(·)OH calculated based on density functional theory(DFT),RCS had more reaction routes with CBZ and showed lower energy barrier in the main CBZ degradation pathways like epoxidation and formation of *** applied to secondary wastewater effluent,UV/chlorine and in-situ chlorination produced overall DBPs ranging from 104.77 to 135.41μg/***,the production of chlorate during UV/chlorine processes was 15 times higher than that during in-situ chlorination.

关键词： UV/chlorine In-situ chlorination Energy efficiency Role of reactive species DFT calculation Disinfection by-products

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Wireless Positioning:Technologies,Applications,Challenges,and Future Development Trends

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Computer Modeling in engineering & Sciences 2024年第5期139卷 1135-1166页

作者： Xingwang Li Hua Pang Geng Li Junjie Jiang Hui Zhang Changfei Gu Dong Yuan School of Physics and Electronic Information engineering University of Henan PolytechnicJiaozuo454000China Jiaozuo Key Laboratory of Crow-Sensing Network Jiaozuo454000China Institute of mining engineering Guizhou Institute of TechnologyGuiyang550003China Coal Supervision department Panzhou Energy BureauPanzhou553599China

The development of the fifth-generation(5G)mobile communication systems has entered the commercialization stage.5G has a high data rate,low latency,and high reliability that can meet the basic demands of most industries and daily life,such as the Internet of Things(IoT),intelligent transportation systems,positioning,and *** continuous progress and development of society have aroused wide *** accuracy is the core demand for the applications,especially in complex environments such as airports,warehouses,supermarkets,and ***,many factors also affect the accuracy of positioning in those environments,for example,multipath effects,non-line-of-sight,and clock synchronization *** paper provides a comprehensive review of the existing works about positioning for the future wireless network and discusses its key techniques and algorithms,as well as the current development and future *** first outline the current traditional positioning technologies and algorithms,which are discussed and analyzed with the relevant *** addition,we also discuss application scenarios for wireless *** comparing different positioning systems,the challenges and future development directions of existing wireless positioning systems are prospected.

关键词： 5G wireless positioning reconfigurable intelligent surface Internet of Vehicles

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脆性材料I型(张开)-断裂韧性测定的PFC2D和试验研究:一种新方法

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Acta Mechanica Sinica 2024年第2期40卷 116-130页

作者：付金伟 Hadi Haeri Joseph FLabuz Vahab Sarfarazi Pouyan Ebneabbasi MRM Aliha Hamid Reza Karimi Shirin Jahanmiri Mohammad Fatehi Marji School of Civil engineering and Transportation North China University of Water Resources and Electric PowerZhengzhou450046China department of mining engineering Higher Education Complex of ZarandShahid Bahonar University of KermanKermanIran department of Civil Environmentaland Geo-EngineeringUniversity of MinnesotaMinneapolis55455USA department of mining engineering Hamedan University of TechnologyHamedanIran Research Scholar Civil Engineering DepartmentIslamic Azad UniversityHamedanIran Welding and Joining Research Center School of Industrial EngineeringIran University of Science and TechnologyNarmakTehranIran School of Civil engineering Iran University of Science and Technology(IUST)NarmakTehranIran department of Mine Exploitation engineering Faculty of Mining and MetallurgyInstitute of EngineeringYazd UniversityYazdIran

在本文研究中,通过利用优势边缘缺口盘型(END)试样,确定了石灰石的断裂韧性,提出了一种新的石灰石归一化相应力、高相变的计算方法.采用柔性有限元法(FEM)对试样的I型(张开)-断裂韧性进行了精确计算,并得到了相应实用公式.在试验中,还... 详细信息

在本文研究中,通过利用优势边缘缺口盘型(END)试样,确定了石灰石的断裂韧性,提出了一种新的石灰石归一化相应力、高相变的计算方法.采用柔性有限元法(FEM)对试样的I型(张开)-断裂韧性进行了精确计算,并得到了相应实用公式.在试验中,还使用含缺口巴西圆盘(NBD)试件,测试了END程序的准确性.为了在数值上重现这些测试并验证断裂韧性测量的正确性,还对END测试进行了离散元分析.数值模拟结果与实验结果吻合良好.然而,END研究所确定的韧性水平低于NBD测试规定的韧性水平,这是因为END石灰石样品中的缺口具有均匀的拉伸应力分布.

关键词：断裂韧性脆性材料实用公式拉伸应力巴西圆盘离散元分析相变归一化

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The Topology Optimization of Oil Cylinder Mounting

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International Journal of Plant engineering and Management 2024年第1期29卷 55-62页

作者： LI Zhibin Zhangjiakou Xuanhua Huatai mining&metallurgical Machinery Co. Ltd.Zhangjiakou 075100China

The method of the structural topology optimization is often used to design machine in the early stage of the mechanical *** the mechanical structures use the topology design to produce a new still and lightweight part... 详细信息

关键词： static analysis negative force positive force topology optimization angle range

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Difference in microstructural characteristics of stamp-charged coke and gravity-charged coke with approximate macroscopic performance

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Journal of Iron and Steel Research(International) 2024年第5期31卷 1050-1062页

作者： Chong Zou Zheng-yan Huang Jian-yun Li Bin Li Shi-wei Liu Yuan She School of metallurgical engineering Xi’an University of Architecture and TechnologyXi’an710311ShaanxiChina Technical Center of Shandong Iron and Steel Co. Ltd.(Laiwu Branch)Jinan271104ShandongChina

The microstructural characteristics including optical texture,porosity and pore structure and chemical structure of stamp-charged coke(SCC)and gravity-charged coke(GCC)with similar conventional macro-indicators were investigated,and the properties including micro-strength,reactivity of coke matrix and that after alkali enrichment were comparatively studied by various characterization *** anisotropic structure of SCC is composed of high content of fine mosaic texture,while the content of medium mosaic texture,coarse texture and fibrous texture is *** statistical average shows that the fine mosaic average of SCC(24.89%)is 3.78 times the GCC average(6.58%),and the coarse mosaic average(1.24%)is only about 1/3 of the GCC average(3.43%).The porosity of SCC is lower than that of GCC,but tamping process does not lead to the fact that the number of closed pores of SCC is significantly lower than that of *** the structure of SCC is compact,its pore number is large and the pore wall is *** of coke with diameter less than 150 nm seem unaffected by tamping *** aromatic structure of SCC was less ordered than that of GCC,which was speculated to be related to the addition of more low metamorphic coal in *** microscopic strength and structural strength of SCC are lower than those of *** reactivity of coke matrix is affected by the specific surface area,but it is not the determining factor of its *** improvement in dissolution reactivity of coke after potassium enrichment is independent of coke type.

关键词： Stamp-charged coke Optical texture Porosity Microstructure Reactivity

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