检索结果-南通市图书馆

Stabilizing perovskite precursors with the reductive natural amino acid for printable mesoscopic perovskite solar cells

引用

Journal of Energy Chemistry 2024年第3期90卷 32-39,I0003页

作者： Wenjing Hu Jian Yang Chuang Yang Xufeng Xiao Chaoyang Wang Zhaozhen Cui Qiaojiao Gao Jianhang Qi Minghao Xia Yaqiong Su Anyi Mei Hongwei Han michael gratzel center for mesoscopic solar cells Wuhan National Laboratory for OptoelectronicsKey Laboratory of Materials Chemistry for Energy Conversion and Storage of Ministry of Education Huazhong University of Science and TechnologyWuhan 430074HubeiChina School of Chemistry Xi'an Key Laboratory of Sustainable Energy Materials ChemistryState Key Laboratory of Electrical Insulation and Power EquipmentXi'an Jiaotong UniversityXi'an 710049ShaanxiChina

Solution processability significantly advances the development of highly-efficient perovskite solar ***,the precursor solution tends to undergo irreversible degradation reactions,impairing the device performance and ***,we utilize a reductive natural amino acid,Nacetylcysteine(NALC),to stabilize the precursor solution for printable carbon-based hole-conductorfree mesoscopic perovskite solar *** find that I_(2) can be generated in the aged solution containing methylammonium iodide(MI) in an inert atmosphere and speed up the MA-FA^(+)(formamidinium) reaction which produces large-size cations and hinders the formation of perovskite *** effectively stabilizes the precursor via its sulfhydryl group which reduces I_(2) back to I^(-)and provides H^(+).The NALC-stabilized precursor which is aged for 1440 h leads to devices with a power conversion efficiency equivalent to 98% of that for devices prepared with the fresh ***,NALC improves the device power conversion efficiency from 16.16% to 18.41% along with enhanced stability under atmospheric conditions by modifying grain boundaries in perovskite films and reducing associated defects.

关键词： Perovskite solar cells Perovskite precursor Degradation Stabilization Reductive natural amino acid

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Tailored multifunctional hydrazine derivatives for efficient printable hole-conductive-free mesoscopic perovskite solar cells via enhancing defect passivation

引用

Journal of Energy Chemistry 2024年第8期95卷 357-363,I0008页

作者： Minghao Xia Ziwei Zheng Yanjie Cheng Chaoyang Wang Zhaozhen Cui Guodong Zhang Jinwei Gonga Anyi Mei Hongwei Han michael Grätzel center for mesoscopic solar cells Wuhan National Laboratory for OptoelectronicsKey Laboratory of Materials Chemistry for Energy Conversion and Storage of Ministry of EducationHuazhong University of Science and TechnologyWuhan 430074HubeiChina Key Laboratory of Flexible Electronics(KLoFE)&Institute of Advanced Materials(IAM) School of Flexible Electronics(Future Technologies)Nanjing Tech University(NanjingTech)Nanjing 211816JiangsuChina

The low-cost and easy large-scale fabrication advantages of printable mesoscopic perovskite solar cells(p-MPSCs)are overshadowed by their limited photovoltaic conversion efficiency(PCE).Here,we introduce the hydrazide derivative of 4-Hydroxybenzoylhydrazine(4-HBH)to improve the PCE of p-MPSCs by inducing enhanced defect *** carbonyl and hydrazine groups in hydrazide groups present strong interaction with *** hydroxyl group,as an electron donor group,increases the electron cloud density of the hydrazide group in 4-HBH under the conjugation of the benzene ring,and thus enhances its interaction with ***,the hydroxy group itself interacts with perovskite and passivates defects *** hydrazine agents can also reduce I2and suppress the loss of iodine in perovskite films,which inhibits the formation of iodine-related ***,p-MPSCs with 4-HBH achieve a high PCE of 19.21%,and present well improved stability.

关键词： Printable mesoscopic perovskite solar cells Multifunctional hydrazine derivatives Cooperative coordination Conjugation redox activity

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

The rising star in photovoltaics-perovskite solar cells: The past, present and future

引用

Science China(Technological Sciences) 2016年第7期59卷 989-1006页

作者： FANG Rui ZHANG WenJun ZHANG ShaSha CHEN Wei michael gratzel Centre for mesoscopic solar cells Wuhan National Laboratory for OptoelectronicsHuazhong University of Science and TechnologyWuhan 430074China

Perovskite solar cell(PVSC), after its invention since 2009, has attracted tremendous attention from both academia and industry, because of its low cost, ease of manufacturing features and the sky-rocketing efficiencies being achieved within such a short period of time. Currently, the new efficiency record has reached 21.0%, comparable to that of the commercialized PV technologies developed for decades, such as multi-crystalline Si, CIGS and Cd Te thin film solar cells. It is very possible that PVSCs would one day step over the threshold of marketization, share or even overturn the current PV market dominated by crystalline-Si solar cells. However, there are still several obstacles to be overcome on the road towards PVSC industrialization. This paper has reviewed the brief developing history and the current research status of PVSCs, and explained: Why PVSCs are so important in the next-generation solar cells, why organometal halide perovskites work so well as light absorbers, and what the inherent differences are among different cell configurations. The prospects on how to realize scale-up industrialization of PVSCs have also been given in the sequence of efficiency, stability, cost, toxicity, and short-term objectives. Resolutions to the remaining challenges according to their orders of technical difficulty and importance have also been discussed.

关键词： organometal halides perovskite solar cells cell configurations efi ciency records stability industrialization prospects

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Homogeneous permeation and oriented crystallization in nanostructured mesopores for efficient and stable printable mesoscopic perovskite solar cells

引用

Science China Chemistry 2024年

作者： Guodong Zhang Yanjie Cheng Tingting Niu Ziwei Zheng Zongwei Li Junwei Xiang Qiaojiao Gao Minghao Xia Lijuan Guo Yiming Liu Mengru Zhang Yiran Tao Xueqin Ran Mingjie Li Guichuan Xing Yingdong Xia Lingfeng Chao Anyi Mei Hongwei Han Yonghua Chen Key Laboratory of Flexible Electronics (KLoFE) and Institute of Advanced Materials (IAM) School of Flexible Electronics (Future Technologies) Nanjing Tech University michael Gr?tzel center for mesoscopic solar cells Wuhan National Laboratory for Optoelectronics Key Laboratory of Materials Chemistry for Energy Conversion and Storage of Ministry of Education Huazhong University of Science and Technology Department of Physics The Chinese University of Hong Kong Department of Applied Physics The Hong Kong Polytechnic University Shenzhen Research Institute The Hong Kong Polytechnic University Joint Key Laboratory of the Ministry of Education Institute of Applied Physics and Materials Engineering University of Macau

The low-cost and scalable printable mesoporous perovskite solar cells(p-MPSCs) face significant challenges in regulating perovskite crystal growth due to their nanoscale mesoporous scaffold structure, which limits the improvement of device power conversion efficiency(PCE). In particular, the most commonly used solvents, N,N-dimethylformamide(DMF) and dimethyl sulfoxide(DMSO), have a single chemical interaction with the precursor components and high volatility, which is insufficient to self-regulate the perovskite crystallization process, leading to explosive nucleation and limited growth within mesoporous scaffolds. Here, we report a mixed solvent system composed of methylamine formaldehyde(MAFa)-based ionic liquid and acetonitrile(ACN) with the strong C=O–Pb coordination and N–H···I hydrogen bonding with perovskite components. We found that the mixed solvent system is beneficial for the precursor solution to homogeneously penetrate into the mesoporous scaffold,and the strong C=O–Pb coordination and N–H···I hydrogen bonding interaction can promote the oriented growth of perovskite crystals. This synergistic effect increased the PCE of the p-MPSCs from 17.50% to 19.21%, which is one of the highest records for p-MPSC in recent years. Additionally, the devices exhibit positive environmental stability, retaining over 90% of the original PCE after 1,200 h of aging under AM 1.5 illumination conditions at 55 °C and 55% humidity.

关键词：

来源：

同方期刊数据库评论

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Alternate redox electrolytes in dye-sensitized solar cells

引用

Chinese Science Bulletin 2012年第32期57卷 4131-4142页

作者： LU JianFeng BAI Jie XU XiaoBao LI ZhiHong CAO Kun CUI Jin WANG MingKui michael Griitzel center for mesoscopic solar cells Wuhan National Laboratory for OptoelectronicsHuazhong University of Science and TechnologyWuhan 430074China

Dye-sensitized mesoscopic solar cell(DSC) has been intensively investigated as a promising photovoltaic *** electrolyte is important to determine the photovoltaic(PV) performance of the DSC devices,which has become the focus of this *** this contribution,recent advances in understanding and controlling of various redox couples are ***,we extend our discussion on the trends that enable iodide-free redox couples to be controllable and feasible for applications in the DSC with promising features.

关键词：染料敏化太阳能电池氧化还原电对电解光伏电池 DSC

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Influence of precursor concentration on printable mesoscopic perovskite solar cells

引用

Frontiers of Optoelectronics 2020年第3期13卷 256-264页

作者： Shuangquan JIANG Yusong SHENG Yue HU Yaoguang RONG Anyi MEI Hongwei HAN michael gratzel center for mesoscopic solar cells Wuhan National Laboratory for OptoelectronicsHuazhong University of Science and TechnologyWuhan 430074China

Over the last decade,the power conversion efficiency of hybrid organic-inorganic perovskite solar cells(PSCs)has increased dramatically from 3.8%to 25.2%.This rapid progress has been possible duc to the accurate control of the morphology and crystallinity of solution-processed perovskites,which are significantly affected by the concentration of the precursor *** study explores the influence of precursor concentrations on the performance of printable hole-conductor-free meso-scopic PSCs via a simple one-step drop-coating *** results reveal that lower concentrations lead to larger grains with inferior pore flling,while higher concentra-tions result in smaller grains with improved pore *** concentrations ranging from 0.241.20M,devices based on a moderate strength of 0.70M were confirmed to exhibit the best efficiency at 16.32%.

关键词： printable perovskite solar cell(PSC) precur-sor concentration crystallization morphology

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Enhancement and recovery of photoluminescence and stability by multifunctional etching ligands treatment for perovskite nanocrystals

引用

Journal of Energy Chemistry 2023年第1期76卷 495-502,I0013页

作者： Yang Zhao Haipeng Zeng Xueqing Cai Yingshan Zhou Yangming Jiang Xin Zheng Lin Li Shujing Zhang Long Luo Weixi Li Xiaoru Zhang Ranran Liu Wenxi Liang Rui Guo Xiong Li michael gratzel center for mesoscopic solar cells Wuhan National Laboratory for OptoelectronicsHuazhong University of Science and TechnologyWuhan 430074HubeiChina State Key Laboratory of New Textile Materials and Advanced Processing Technologies Wuhan Textile UniversityWuhan 430073HubeiChina State Key Laboratory of Functions and Applications of Medicinal Plants Guizhou Medical University Guiyang 550014GuizhouChina

Perovskite nanocrystals(PNCs)have recently become promising optoelectronic materials due to their excellent photophysical ***,the highly dynamic binding state between ligands and the surface of PNCs has severely restricted their luminescent properties and *** this work,1,3-bisbenzyl-2-oxoimidazolidine-4,5-dicarboxylic acid(cycle acid,CA)is introduced as both an etchant and a ligand upon post-synthetic surface treatment of *** removing the imperfect octahedrons[Pb X_(6)]^(4-)and passivating the surface defects synergistically,this treatment improves photoluminescence quantum yields from 76%to 95%and enhances the stability of PNCs against polar solvent,moisture,heat,and ***,CA can effectively and instantly recover the luminescence emission for aged *** a result,the CA-Cs Pb Br_(3)PNCs and CA-Cs Pb IxBr_(3-x)PNCs are applied as color-converting layers on a blue LED chip for warm white light-emitting diodes(WLEDs)with a color coordinate of(0.41,0.40).Importantly,the CA-based WLED device exhibits superior stability in operational conditions.

关键词： Perovskite nanocrystals Synergistic effect Emission recovery White light emitting diodes Stability

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Unveiling the effect of amino acids on the crystallization pathways of methylammonium lead iodide perovskites

引用

Journal of Energy Chemistry 2022年第6期31卷 253-260,I0008页

作者： Wenhao Zhang Jiankang Du Weihua Zhang Yanmeng Chu Anyi Mei Yaoguang Rong Xinyu Gao Hongwei Han Yue Hu michael Grätzel center for mesoscopic solar cells Wuhan National Laboratory for OptoelectronicsKey Laboratory of Materials Chemistry for Energy Conversion and Storage of Ministry of EducationHuazhong University of Science and TechnologyWuhan 430074HubeiChina Shanghai Synchrotron Radiation Facility(SSRF) Chinese Academy of SciencesShanghai 201204China

Multifunctional additives are widely used to improve crystallization and to passivate defects in perovskite solar cells. The roles of these additives are usually related to the various functional groups contained in such additives. Here, we introduce a serious of analogues of amino acids into methylammonium lead iodide perovskites and find they play different roles in the crystallization process despite the fact that these additives share exactly the same terminal groups, namely one amino group and one carboxyl group. The corresponding crystallization pathways are established for the first time via monitoring the time-resolved phase formation and transformation. We find that avoiding the rapid formation of perovskites from precursor solution can facilitate the uniform nucleation and growth of perovskite crystals with enhanced crystallinity and reduced defects. Further, we find the different crystallization behaviors probably arise from the inherent structural characteristic of these additives, leading to different interactions in the precursors. This study unveils the effects of amino acids on the liquid–solid crystallization process and helps better understand the role of multifunctional additives beyond their functional groups.

关键词： Perovskite solar cells Multifunctional additives Amino acids Crystallization process

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

SiO2 nanoparticle-regulated crystallization of lead halide perovskite and improved efficiency of carbon-electrode-based low-temperature planar perovskite solar cells

引用

Chinese Physics B 2020年第7期29卷 576-582页

作者： Zerong Liang Bingchu Yang Anyi Mei Siyuan Lin Hongwei Han Yongbo Yuan Haipeng Xie Yongli Gao Conghua Zhou Hunan Key Laboratory of Super-microstructure and Ultrafast Process School of Physics and ElectronicsCentral South UniversityChangsha 410083China michael Grä tzel Center for Mesoscopic Solar CellsWuhan National Laboratory for OptoelectronicsHuazhong University of Science and TechnologyWuhan 430074China Department of Physics and Astronomy University of RochesterRochesterNY 14627USA

SiO2 nanoparticles were used to regulate the crystallizing process of lead halide perovskite films prepared by the sequential deposition method,which was used in the low-temperature-processed,carbon-electrode-basing,hole-conductor-free planar perovskite solar *** was observed that,after adding small amount of SiO2 precursor(1 vol%)into the lead iodide solution,performance parameters of open-circuit voltage,short-circuit current and fill factor were all upgraded,which helped to increase the power conversion efficiency(reverse scan)from 11.44(±1.83)%(optimized at 12.42%)to 14.01(±2.14)%(optimized at 15.28%,AM 1.5G,100 mW/cm^2).Transient photocurrent decay curve measurements showed that,after the incorporation of SiO2 nanoparticles,charge extraction was accelerated,while transient photovoltage decay and dark current curve tests both showed that recombination was *** improvement is due to the improved crystallinity of the perovskite film.X-ray diffraction and scanning electron microscopy studies observed that,with incorporation of amorphous SiO2 nanoparticles,smaller crystallites were obtained in lead iodide films,while larger crystallites were achieved in the final perovskite *** study implies that amorphous SiO2 nanoparticles could regulate the coarsening process of the perovskite film,which provides an effective method in obtaining high quality perovskite film.

关键词： perovskite solar cell carbon-electrode crystallization low temperature SiO2 lead iodide

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Recent progress on tandem structured dye-sensitized solar cells

引用

Frontiers of Optoelectronics 2012年第4期5卷 371-389页

作者： Dehua XIONG Wei CHEN michael gratzel Centre for mesoscopic solar cells Wuhan National Laboratory for OptoelectronicsCollege of Optoelectronic Science and EngineeringHuazhong University of Science and TechnologyWuhan 430074China

Tandem structured dye-sensitized solar cells （DSSCs） can take full advantage of sunlight, effectively broadening the absorption spectrum of the cell, resulting in a higher open circuit voltage or short circuit current than that of the conventional DSSC with single light absorber. The theoretical maximum efficiency is therefore suggested to be over the Schottky-Queisser limit of 33%. Accord- ingly, tandem design of DSSC is thought to be a promising way to break the performance bottleneck of DSSC. Besides, the tandem designs also broaden the application diversity of DSSC technology, which will accelerate its scale-up industrial application. In this paper, we have reviewed the recent progress on photo-electrochemical applications associated with kinds of tandem designs of DSSCs, in general, which are divided into three kinds：＂n- type DSSC ＋ n-type DSSC,＂＂n-type DSSC ＋ p-type DSSC＂ and ＂n-type DSSC ＋other solar conversion devices.＂ The working principles, advantages and chal- lenges of these tandem structured DSSCs have been discussed. Some possible solutions for further studies have been also pointed out together.

关键词： dye-sensitized solar ceils (DSSCs) tandemstructure photo-electrochemical cell

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：