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Double-kill contribution of high-roughness high-density porous carbon electrodes to mechanically self-sensing supercapacitors

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Nano Research 2024年第7期17卷 6157-6167页

作者： Jue Huang Pengyu Liu Yiqun Wang Keren Dai Qingyun Dou Yajiang Yin Xiaofeng Wang Zheng You Department of Precision Instrument Tsinghua UniversityBeijing 100084China State Key laboratory of Precision measurement Technology and Instruments Beijing 100084China Department of materials Science and Engineering Sun Yat-Sen UniversityGuangzhou 510275China ZNDY of Ministerial Key laboratory School of Mechanical EngineeringNanjing University of Science and TechnologyNanjing 210094China Qiyuan laboratory Beijing 100095China

Impact detecting and counting are fundamental functions of fuses used in hard target penetration ***,detection failure caused by battery breakdown in high-g acceleration environments poses a vulnerability for such *** paper introduces a novel supercapacitor that combines energy storage and high-g impact detection,called self-sensing *** deliberately inducing a transient soft short-circuit during shock in the supercapacitor,it is possible to detect external impact by its transient voltage *** realize this concept,firstly,by introducing the contact theory and force-induced percolation model,the electrode strength and roughness are found to have key impacts on the formation of soft ***,to meet the needs for sensitivity and capacity,a high-density porous carbon(HDPC)that combines high mechanical strength and porosity,is selected as a suitable candidate based on the analysis ***,a two-step curing method is proposed to prepare the high-roughness HDPC(HRHDPC)electrode and to assemble the self-sensing *** to the rich specific surface of the electrodes and the high surface strength and roughness conducive to the formation of transient soft short circuits,the self-sensing supercapacitor not only possesses an excellent specific capacitance(171 F/g at 0.5 A/g)but also generates significant voltage response signals when subjected to high-g impacts ranging from 8000g to 31,***,the self-sensing supercapacitor is applied to compose a successive high-g impact counting system and compared to traditional solutions(sensors and tantalum capacitors)in the military *** results show that the self-sensing supercapacitor-based system exhibits advantages in terms of size,power consumption,and counting accuracy.

关键词： supercapacitor self-sensing soft short-circuit impact sensing

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Exceptional mechanical performance and macroscale superlubricity enabled by core-shell-like MoS_(2)/B_(4)C film

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Science China(Technological Sciences) 2024年第7期67卷 2018-2030页

作者： REN SiMing GAO ZhenRong FAN Xin WANG HaiXin WANG LiPing Key laboratory of Advanced Marine materials Ningbo Institute of Materials Technology and EngineeringChinese Academy of SciencesNingbo 315201China

Molybdenum disulfide(MoS_(2)) films are widely deployed in industrial applications owing to their inherent interlayer slip characteristics, offering energy consumption savings and prolonged mechanical part performance. Nevertheless, their practical utility is limited by environmental constraints and the limitations of preparation techniques, which hinder the attainment of robust superlubricity(friction coefficient < 0.01). Herein, through magnetron sputtering technology, we synthesize a core-shell-like nanocomposite composed of MoS_(2)nanosheets encapsulating B_(4)C. The core-shell-like structure enables the resulting films to preferentially grow crystalline MoS_(2), providing them with outstanding mechanical properties and efficient lubrication over a wide range of temperatures. Remarkably, such film achieves robust macroscale superlubricity and an ultralow wear rate(1.7 ×10^(-8)mm^(3)N-1m^(-1)) under high contact stress in a mild vacuum environment. This noteworthy outcome is primarily attributable to the self-segmentation of the macroscale contact interface during the friction process, involving:(1) a large amount of wear debris is embedded into the wear track to create extensive micro-sized asperities;(2) a nanolayer of amorphous carbon enriched with oxide nanoparticles is formed on the uppermost part of these asperities;(3) numerous incommensurate nanocontacts comprising nanoparticles and highly oriented MoS_(2)nanosheets are established, culminating in the achievement of robust superlubricity. Our pioneering design, coupled with the elucidation of the underlying superlubricity mechanism, holds significant promise for advancing the development of robust and high-performance lubricants.

关键词： MoS_(2)/B_(4)C nanocomposites core-shell-like structure H/E ratio high-temperature friction macroscale superlubricity

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Large-area flexible organic photovoltaic modules

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Science China Chemistry 2024年第10期67卷 3189-3190页

作者： Yongfang Li Beijing National laboratory for Molecular Sciences CAS Key Laboratory of Organic SolidsInstitute of ChemistryChinese Academy of SciencesBeijing 100190China laboratory of Advanced Optoelectronic materials Suzhou Key Laboratory of Novel Semiconductor-optoelectronics Materials and DevicesCollege of ChemistryChemical Engineering and Materials ScienceSoochow UniversitySuzhou 215123China

Organic solar cells(OSCs)have the advantages of light weight and excellent mechanical stability[1].The OSCs can be an ideal candidate as portable and wearable energy sources to power portable electronics,internet of things,***,power conversion efficiency(PCE)of the small-area OSCs have reached around 20%[2].This makes the community more confident about this technology moving into practical applications.

关键词： portable internet stability

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Revealing the Multifunctional Electrocatalysis of Indium-Modulated Phthalocyanine for High-Performance Lithium-Sulfur Batteries

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Energy & Environmental materials 2024年第1期7卷 1-8页

作者： Yang Guo Zhaoqing Jin Jianhao Lu Zilong Wang Zihao Song Anbang Wang Weikun Wang Yaqin Huang Beijing Key laboratory of Electrochemical Process and Technology for materials Key Laboratory of Biomedical Materials of Natural MacromoleculesMinistry of EducationBeijing University of Chemical TechnologyBeijing 100029China Research Institute of Chemical Defense Beijing Key Laboratory of Advanced Chemical Energy Storage Technology and MaterialsBeijing 100191China

The sluggish kinetics of complicated multiphase conversions and the severe shuttling effect of lithium polysulfides(LiPSs)significantly hinder the applications of Li-S battery,which is one of the most promising candidates for the next-generation energy storage ***,a bifunctional electrocatalyst,indium phthalocyanine self-assembled with carbon nanotubes(InPc@CNT)composite material,is proposed to promote the conversion kinetics of both reduction and oxidation processes,demonstrating a bidirectional catalytic effect on both nucleation and dissolution of Li_(2)S *** theoretical calculation shows that the unique electronic configuration of InPc@CNT is conducive to trapping soluble polysulfides in the reduction process,as well as the modulation of electron transfer dynamics also endows the dissolution of Li_(2)S in the oxidation reaction,which will accelerate the effectiveness of catalytic conversion and facilitate sulfur ***,the InPc@CNT modified separator displays lower overpotential for polysulfide transformation,alleviating polarization of electrode during *** integrated spectroscopy analysis,HRTEM,and electrochemical study reveal that the InPc@CNT acts as an efficient multifunctional catalytic center to satisfy the requirements of accelerating charging and discharging ***,the Li-S battery with InPc@CNT-modified separator obtains a discharge-specific capacity of 1415 mAh g^(-1)at a high rate of 0.5 ***,the 2 Ah Li-S pouch cells deliver 315 Wh kg^(-1)and achieved 80%capacity retention after 50 cycles at 0.1 C with a high sulfur loading of 10 mg cm^(-2).Our study provides a practical method to introduce bifunctional electrocatalysts for boosting the electrochemical properties of Li-S batteries.

关键词： bidirectional catalyst indium phthalocyanine lithium-sulfur batteries pouch cells

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Inducing piezoelectricity in distorted rutile TiO_(2)for enhanced tetracycline hydrochloride degradation through photopiezocatalysis

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Journal of Advanced Ceramics 2024年第3期13卷 323-331页

作者： Taotao Xia Lizhen Lu Haoyu Zhang Jinghui Wang Zonghe Huang Hongyang Wang Weiyi Yang Shuang Gao Qi Li Key laboratory of Advanced Technologies of materials(Ministry of Education) School of Materials Science and EngineeringSouthwest Jiaotong UniversityChengdu 610031China Shenyang National laboratory for materials Science Institute of Metal ResearchChinese Academy of SciencesShenyang 110016China

Various material design strategies have been developed to enhance photocatalytic performance of TiO_(2).However,no report is available on applications of the photopiezocatalysis strategy on TiO_(2)due to its lack of *** we developed a low-temperature molten salt etching process to create rutile TiO_(2)nanoparticles by etching[MgO_(6)]octahedrons away from MgTiO_(3)by molten NH_(4)Cl,during which a lattice distortion occurred in TiO_(2).The lattice distortion broke the structure symmetry of rutile TiO_(2)and subsequently endowed these rutile TiO_(2)nanoparticles with an unusual piezoelectric response with the maximum effective piezoelectric coefficient(d_(33))of~41.6 pm/V,which had not previously been found in TiO_(2)***,the photopiezocatalysis strategy was applied for the first time to enhance the photocatalytic performance of these TiO_(2)*** creation of lattice distortion to induce piezoelectricity could be extended to other photocatalysts that the photopiezocatalysis strategy has not been applied to and may generate novel functionalities for various technical applications.

关键词： photocatalysis TiO_(2) piezocatalysis molten salt etching process photopiezocatalysis

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In situ Hydrothermal Oxidation of Ternary FeCoNi Alloy Electrode for Overall Water Splitting

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Energy & Environmental materials 2024年第2期7卷 161-170页

作者： Yuwei Chen Lixia Yang Chao Li Yuqiu Wu Xiao Lν Hairen Wang Jun'e Qu Key laboratory for the Green Preparation and Application of Functional materials Hubei Key Laboratory of Polymer MaterialsSchool of Materials Science and EngineeringHubei UniversityWuhan 430062China Faculty of Material science and Chemistry China University of GeosciencesWuhan 430074China

Exploring noble metal-free catalyst materials for high efficient electrochemical water splitting to produce hydrogen is strongly desired for renewable energy *** this article,a novel bifunctional catalytic electrode of insitu-grown type for alkaline water splitting based on FeCoNi alloy substrate has been successfully prepared via a facile one-step hydrothermal oxidation route in an alkaline hydrogen peroxide *** shows that the matrix alloy with the atom ratio 4∶3∶3 of Fe∶Co∶Ni can obtain the best catalytic performance when hydrothermally treated at 180℃for 18 h in the solution containing 1.8 M hydrogen peroxide and 3.6 M sodium *** as-prepared Fe_(0.4)Co_(0.3)Ni_(0.3)-1.8 electrode exhibits small overpotentials of only 184 and 175 mV at electrolysis current density of 10 mA cm^(-2)for alkaline OER and HER processes,*** overall water splitting at electrolysis current density of 10 mA cm^(-2)can be stably delivered at a low cell voltage of 1.62 *** characteristics including the large specific surface area,the high surface nickel content,the abundant catalyst species,the balanced distribution between bivalent and trivalent metal ions,and the strong binding of in-situ naturally growed catalytic layer to matrix are responsible for the prominent catalytic performance of the Fe_(0.4)Co_(0.3)Ni_(0.3)-1.8 electrode,which can act as a possible replacement for expensive noble metal-based materials.

关键词： alkaline water electrolysis bifunctional electrocatalyst FeCoNi alloy hydrothermal oxidation in-situ growing

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Nitrogen and fluorine co-doped graphene for ultra-stable lithium metal anodes

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Nano Research 2024年第8期17卷 7212-7220页

作者： Pan Li Yifan Liu Xujian Bao Jinghao Xie Zhao Li Hongcheng Li Qiang Ren Xiaomiao Feng Yue Hu Yanwen Ma State Key laboratory for Organic Electronics and Information Displays(KLOEID)and Jiangsu Key laboratory for Biosensors Institute of Advanced Materials(IAM)Nanjing University of Posts and TelecommunicationsNanjing 210023China Key laboratory of Carbon materials of Zhejiang Province College of Chemistry and Materials EngineeringWenzhou UniversityWenzhou 325000China

The heteroatom doping strategies have been utilized to effectively improve the performance of the carbon-based hosts,such as graphene,for lithium(Li)metal in high energy density lithium metal ***,solely doped graphene hosts often need the assistance of other materials with either better lithiophilicity or electronic conductance to achieve smooth and efficient deposition of Li,which adds extra weight or ***,graphene co-doped by nitrogen and fluorine(NFG)is employed as a stable host for Li,where the N-doping provides lithiophilicity and electronic conductivity lacked by F-doping and the F-doping facilitates fast formation of solid electrolyte interphase(SEI)retarded by *** well regulation of Li plating/stripping and SEI formation is verified by quickly stabilized and small-magnitude voltage hysteresis,which stands out in Li hosts based on doped graphene and leads to excellent long-term cycling performance of NFG based electrodes.A voltage hysteresis of 20 mV is observed for more than 850 h in the symmetrical *** remarkable efficiency of lithium usage is confirmed by the highcapacity retention of a full cell paired with LiFePO_(4)(LFP),which exceeds 70%after 500 *** work presents an innovative perspective on the control of Li plating/stripping by simultaneously introducing two kinds of dopants into graphene and paving the way for exploring practical Li metal batteries.

关键词： Co-doped graphene lithium metal anode dendrite suppression lithiophilic skeleton solid electrolyte interphase(SEI)formation

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Top priority current path between SiC particles during ultra-high temperature flash sintering: Presence of PyC “bridges”

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Journal of Advanced Ceramics 2024年第2期13卷 255-262页

作者： Le Lu Tianlong Liu Zhaofeng Chen Fei Wang Mengmeng Yang Qiong Wu Lixia Yang Huanyong Li International laboratory for Insulation and Energy Efficiency materials College of Materials Science and TechnologyNanjing University of Aeronautics and AstronauticsNanjing 211106China State Key laboratory of Solidification Processing School of Materials and EngineeringNorthwestern Polytechnical UniversityXi’an 710072China

Flash sintering(FS)is a novel technique for rapidly densifying silicon carbide(SiC)*** work achieved a rapid sintering of SiC ceramics by the utilization of ultra-high temperature flash sintering within 60 *** carbon(PyC)“bridges”were constructed between SiC particles through the carbonisation of phenolic resin,providing a large number of current *** incubation time of the flash sintering process was significantly reduced,and the sintering difference between the centre and the edge regions of the ceramics was minimized,with an average particle size of the centre region and edge region being 12.31 and 9.02μm,*** results showed that the porosity of the SiC ceramics after the flash sintering was reduced to 14.79% with PyC“bridges”introduced,and the Vickers hardness reached 19.62 ***“bridges”gradually evolved from amorphous eddy current carbon to oriented graphite carbon,indicating that the ultra-high temperature environment in which the sample was located during the flash sintering was successfully ***-high temperature flash sintering of SiC is expected to be applied to the local repair of matrix damage in SiC ceramic matrix composites.

关键词： silicon carbide(SiC) flash sintering(FS) pyrolytic carbon(PyC)"bridges" current path instantaneous

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Properties and Characteristics of Regolith-Based materials for Extraterrestrial Construction

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Engineering 2024年第6期37卷 159-181页

作者： Cheng Zhou Yuyue Gao Yan Zhou Wei She Yusheng Shi Lieyun Ding Changwen Miao National Center of Technology Innovation for Digital Construction Huazhong University of Science and TechnologyWuhan 430074China School of Civil and Hydraulic Engineering Huazhong University of Science and TechnologyWuhan 430074China School of materials Science and Engineering Southeast UniversityNanjing 214135China State Key laboratory of materials Processing and Die&Mould Technology School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhan 430074China

The construction of extraterrestrial bases has become a new goal in the active exploration of deep *** the construction techniques,in situ resource-based construction is one of the most promising because of its good sustainability and acceptable economic cost,triggering the development of various types of extraterrestrial construction materials.A comprehensive survey and comparison of materials from the perspective of performance was conducted to provide suggestions for material selection and *** types of typical construction materials are discussed in terms of their reliability and applicability in extreme extraterrestrial ***,thermal and optical,and radiation-shielding properties are *** influencing factors and optimization methods for these properties are *** the perspective of material properties,the existing challenges lie in the comprehensive,long-term,and real characterization of regolith-based construction ***,the suggested future directions include the application of high-throughput characterization methods,accelerated durability tests,and conducting extraterrestrial experiments.

关键词： Extraterrestrial construction Characterization Mechanical property Thermal property Optical property Radiation-shielding

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Boosting thermal stability and crystallization of closed-loop-recyclable biodegradable poly(p-dioxanone) by end-group regulation

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Science China Chemistry 2024年第2期67卷 642-651页

作者： Jin Lei Zhu-Xin Gui Wan-Ting Xiong Gang Wu Si-Chong Chen Yu-Zhong Wang The Collaborative Innovation Center for Eco-Friendly and Fire-Safety Polymeric materials(MoE) National Engineering Laboratory of Eco-Friendly Polymeric Materials(Sichuan)State Key Laboratory of Polymer Materials EngineeringCollege of ChemistrySichuan UniversityChengdu610064China

A chemically closed-loop-recyclable biodegradable polymer,poly(p-dioxanone)(PPDO),is one of the ideal candidates for single-use plastic products due to its suitability for different application ***,when PPDO wastes can be collected,its monomer p-dioxanone(PDO) will be obtained through chemical recycling of these wastes;when cannot be collected,the wastes are able to be biodegraded into harmless ***,unsatisfied thermal stability and low crystallization rate of PPDO restrict its wider ***,based on end-group regulation,we simultaneously realized the significant enhancement of thermal stability and crystallization of PPDO through the simple melt processing with tributyl phosphite(TBP) or triphenyl phosphite(TPP).The model reactions were conducted to investigate the reaction mechanism and theoretical products during the preparation of PPDO/phosphite *** kinds of phosphites were proved to act as the end-capped reagent and chain extender in the melt processing,while TBP presented better *** a result,the activation energy of thermal decomposition was largely elevated,and the unprecedented T_(5%)(the temperature at a weight loss of 5%) and Tmax(the temperature at a maximum rate of weight loss) of PPDO were obtained,i.e.,T_(5%)of ~330 ℃ and Tmaxof ~385 ℃ in N_(2) atmosphere,T_(5%)of ~240 ℃ and Tmaxof ~317 ℃ in air atmosphere,***,the increased crystallization rate,crystallinity,crystalline orderliness,and realizable monomer recovery(yield >90%,purity >99.9%) of PPDO/phosphite compounds were confirmed.

关键词： poly(p-dioxanone) phosphite thermal stability crystallization end-group regulation

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