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A scalable versatile methodology to construct micro/nano open-cell polypropylene foam with high oil adsorption capacity and speed

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Nano Research 2024年第4期17卷 2814-2823页

作者： Chenguang Yang Dechang Tao Kun Yan Zhiyao Li Qingshi Guo Wenwen Wang Dong Wang Key Laboratory of textile Fiber and Products(Wuhan textile University) Ministry of EducationWuhan Textile UniversityWuhan 430200China college of Chemistry Chemical Engineering and BiotechnologyDonghua UniversityShanghai 201620China

Oil pollution is a serious environmental and natural resource problem.Traditional adsorption materials for oil–water separation have limitations in terms of their preparation cost,reusability,and mechanical properties.Among the conventional adsorption materials,super-hydrophobic/super-lipophilic materials are easily contaminated by oil.In this study,polypropylene(PP)is used as a foam substrate to prepare an open-cell PP foam via hot pressing,supercritical CO_(2) foaming,and electron beam(EB)irradiation.The impact of EB irradiation dose on the open-cell content of PP foam can lead to cell wall rupture,resulting in an open-cell structure that enhances oil-water separation performance.At an absorbed radiation dose of 200 kGy,the PP foams exhibit optimal oil–water separation performance,cyclic compression stability,heat insulation,and preparation cost.The open-cell content of PP foam is increased to 86.5%,the adsorption capacity for diesel oil is 42.8 g/g,and the adsorption efficiency remains at 99.6%after 100 cycles of oil desorption in a complex pH environment.Meanwhile,cracks and nano-voids simultaneously promote the capillary action of oil,and the oil transport rate is 0.0713 g/(g·s).This study provides a new concept for the preparation of open-cell polymer foams that can meet the demand for high oil-absorption capacity under complex acid-base pH conditions.

关键词： open-cell polypropylene(PP)foam electron beam irradiation oil/water separation cyclic compression complex acid-base pH conditions

High-efficiency preparation of multifunctional conjugated electrospun graphene doped PVDF/CF yarns for energy harvesting and human movement monitoring in TENG textile

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Nano Research 2024年第5期17卷 4478-4488页

作者： Ting Yang Chengwei Wan Xiaoyu Zhang Tong Liu Li Niu Jian Fang Yuqing Liu college of textile and Clothing Engineering Soochow UniversitySuzhou 215123China

Portable power is an effective solution to realize self-powered sensors for wearable devices,promoting future sustainable development.Membrane-based triboelectric nanogenerators(M-TENGs)have emerged as a promising technology for harvesting biomechanical energy from human motion owing to their advantages,such as simple structure,lightweight design,and efficient energy conversion.However,the poor durability,low adaptability,and un-washability of two-dimensional membrane materials have largely hindered their application in wearable electronics.In this study,we propose a sheath-core polyvinylidene fluoride(PVDF)/graphene(G)-carbon fiber(CF)yarn fabricated via conjugate electrospinning,comprising a commercial CF core and an electrospun graphene-doped PVDF sheath,which improves the fatigue resistance of electrospun nanofiber films under prolonged friction and keeps a high degree of freedom.The resulting electronic textile,woven with the large-scale electrospun PVDF/G-CF yarn,demonstrates a remarkable power density of 25.5 mW·m^(-2).The tight distribution of PVDF/G nanofibers on the textile surface ensures excellent softness,washability,and durability.Furthermore,the electrospun PVDF/G-CF textile exhibits significant potential in pressure sensing,self-powered operation,and motion detection,making it highly suitable for wearable electronics applications.

关键词： yarn-based triboelectric nanogenerator(TENG) graphene polyvinylidene fluoride(PVDF) conjugated-electrospinning multifunctional

Recent Progress of Bionic Hierarchical Structure in the Field of Thermal Insulation Protection

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Journal of Bionic Engineering 2024年第1期21卷 1-18页

作者： Yina Zhuge Fujuan Liu National Engineering Laboratory for Modern Silk College of Textile and Clothing EngineeringSoochow UniversitySuzhou 215123China

Some living organisms with hierarchical structures in nature have received extensive attention in various fields.The hierarchical structure with multiple pores,a large number of solid-gas interfaces and tortuous conduction paths provide a new direction for the development of thermal insulation materials,making the living creatures under these extreme conditions become the bionic objects of scientific researchers.In this review,the research progress of bionic hierarchical structure in the field of heat insulation is highlighted.Polar bears,cocoons,penguin feathers and wool are typical examples of heat preservation hierarchy in nature to introduce their morphological characteristics.At the same time,the thermal insulation mechanism,fractal model and several preparation methods of bionic hierarchical structures are emphatically discussed.The application of hierarchical structures in various fields,especially in thermal insulation and infrared thermal stealth,is summarised.Finally,the hierarchical structure is prospected.

关键词： Hierarchical structure Bionic Heat insulation Fractal model Cocoons

Chiral transfer amidst one-dimensional linear polymers and twodimensional network covalent organic frameworks:Striking a fine balance between helicity and crystallinity

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Nano Research 2024年第6期17卷 5726-5734页

作者： Xinlin Zha Mengjuan Zuo Guilin Xu Zhong Yan Haining You Yi Xiong Ying Liu Yingying Li Liyan Yang Ke Liu Mufang Li Tao Zhao Dong Wang college of Chemistry and Chemical Engineering Donghua UniversityShanghai 201620China Key Laboratory of textile Fiber and Products Ministry of EducationWuhan Textile UniversityWuhan 430200China

The current landscape of chiral covalent organic frameworks(COFs)predominantly centered on constructing asymmetric molecular-scale chirality,often introducing an inherent contradiction to the COF symmetry and limiting diversity.Herein,we overcome these challenges by achieving chiral transfer between one-dimensional(1D)imine linear polymers(LPs)and two-dimensional(2D)networkβ-ketoenamine COFs composed of achiral monomers.We successfully synthesize several 1D imine LPs with mesoscopic helical chirality,comprising achiral C2-symmetric terephthalaldehyde and diamine linkers in a chiral supramolecular transcription system.Leveraging the irreversible tautomerism mechanism within the linker replacement approach,terephthalaldehyde(TPA)units in these helical 1D LPs are substituted with C3-symmetric 1,3,5-triformylphloroglucinol(TP),yielding the corresponding 2D networkβ-ketoenamine COFs.Crystallinity and helicity of the resultantβ-ketoenamine COFs intimately hinge on reaction conditions,including the aldehyde stoichiometry of Tp and TPA,as well as the quantity and concentration of the catalyst employed.Under optimized conditions,the nucleation and growth were precisely governed,achieving a harmonious equilibrium of crystallinity and helicity within the generated 2D networkβ-ketoenamine COFs,even with covalent bond rupture,recombination,and topological transition(from[C2+C2]to[C3+C2]).Impressively,the ground state chirality inherent to helical 1D LPs seamlessly transfers to helical 2D networkβ-ketoenamine COFs.This study not only offers new perspectives on the development of chiral functional COFs,but also provides fresh insights into the precise control of COFs'microscopic morphology.

关键词： chiral covalent organic frameworks chiral transfer dimensional transformation helicity

Multiporphyrinic architectures:Advances in structural design for photodynamic therapy

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Aggregate 2024年第1期5卷 67-84页

作者： Yuwei Gao Yan Li Zhengwei Xu Shuangjiang Yu Junqiu Liu Hongcheng Sun college of material Chemistry and Chemical EngineeringKey Laboratory of Organosilicon Chemistry and Material TechnologyMinistry of EducationHangzhou Normal UniversityHangzhouChina

Rationally designed multiporphyrinic architectures for boosting photodynamic therapy(PDT)have attracted significant attentions recently years due to their great potential for light-mediated generation of reactive oxygen species.However,there is still a gap between the structure design and their PDT performance for biomedical applications.This tutorial review provides a historical overview on(i)the basic concept of PDT for deeply understanding the porphyrin-mediated PDT reactions,(ii)developing strategies for constructing porphyrinic architectures,like nanorings,boxes,metal-organic frameworks(MOFs),covalent-organic frameworks(COFs),vesicles,etc.,where we classified into the following three categories:multiporphyrin arrays,porphyrinic frameworks,and others porphyrin assemblies,(iii)the various application scenarios for clinical cancer therapy and antibacterial infection.Also,the existing challenges and future perspectives on the innovation of porphyrinic architectures for clinical PDT applications are mentioned in the end section.Moreover,the porphyrinic nanomaterials with atomically precise architectures provide an ideal platform for investigating the relationship between structures and PDT outputs,design of personalized“all-in-one”theranostic agents,and the popularization and application in wider biomedical fields.

关键词： covalent-organic frameworks(COFs) metal-organic frameworks(MOFs) multiporphyrin arrays photodynamic therapy(PDT) porphyrinic architectures

A novel long persistent luminescent material CaGeO3:Tb3+ with photo-stimulation properties

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Journal of Rare Earths 2024年第7期42卷 1233-1239页

作者： Wei Meng Xiaoyan Fu Tongyan Lin Zewen Liu Naihui Chen Jiaxu Zhang Runyao Liu Rujun Yang Long Chen Hongwu Zhang School of Chemistry and material Sciences Ludong University college of materials Science and Engineering Xiamen University of Technology college of materials Xiamen University

A novel green long afterglow material CaGeO3:Tb3+was synthesized by high temperature solid phase method.According to the experimental results,CaGeO3:Tb3+is a green long persistent luminescent（LPL）material with excellent performance.CaGeO3:Tb3+shows LPL emission peak at 442,490.9,548.7,588.5and 623.8 nm,corresponding to5D3to7F4and5D4to7FJ（J=6,5,4,3） transitions of Tb3+,Its CIE coordinates are（0.27,0.50）,indicating that the afterglow emission is close to the light of green region.In addition,after the excitation source is turned off,the afterglow time is longer than 90 min.After an interval of 7 h,the photo-stimulation luminescence（PSL） can be observed by using 980 nm laser cyclic excitation.The thermoluminescence（ThL） results show that there are three types of traps in the material and their depths are 0.666,0.774 and 0.892 eV respectively,which are caused by the doping of Tb3+.All the results show that CaGeO3:Tb3+is an excellent long afterglow luminescent material.

关键词： CaGeO3:Tb3+ Long persistent luminescence Photo-stimulation Rare earths Trap

Controlled Synthesis of Metal-Nanoparticles Decorated Block Copolymer Hybrid Particles via Emulsion Confined Self-assembly and Their Catalytic Applications

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Chinese Journal of Chemistry 2024年第8期42卷 835-840页

作者： Xiaohua Chang Qunli Yu Dan Ji Yutian Zhu college of material Chemistry and Chemical EngineeringKey Laboratory of Organosilicon Chemistry and Material TechnologyMinistry of EducationHangzhou Normal UniversityHangzhouZhejiang311121 China

Comprehensive Summary Metal nanoparticles(NPs)decorated block copolymer(BCP)hybrid nanoparticles have attracted enormous attention for their actual value in catalysis,medical therapy,and bioengineering.The confined assembly of BCPs within evaporative emulsion droplet is verified as an effective method to provide polymeric scaffolds to load metal NPs.However,to date,it remains challenging to generate different types of metal NPs decorated BCP hybrid nanoparticles.Herein,we employed the emulsion confined self-assembly of poly(styrene-b-2-vinylpyridine)(PS-b-P2VP)and the followed seed-mediated growth of Au and palladium(Pd)NPs onto well-defined BCP particles to design a series of Au/Pd decorated BCP hybrid nanoparticles,which exhibited excellent catalytic activity for the reduction of 4-nitrophenol to 4-aminophenol with the reductant of NaBH4.This work may inspire more researchers to investigate the selective decoration of different metal NPs onto the polymeric scaffolds,broadening the potential applications of the inorganic/organic hybrid nanoparticles.

关键词： Block copolymers Emulsion confined self-assembly Hybrid nanoparticles Catalytic activity Recyclability

Construction and properties of venlafaxine hydrochloride sustained release system based on hollow mesoporous silica microspheres

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Particuology 2024年第3期86卷 205-210页

作者： Chenjing Liang Lingling Shi Zhengguo Chen Lan Zhou Zhaoxia Zhang Guoqing Zhang School of materials Science and Engineering Zhejiang Sci-tech UniversityHangzhouChina college of textile Science and Engineering Zhejiang Sci-tech UniversityHangzhouChina Zhejiang Provincial Innovation Center of Advanced textile Technology ShaoxingChina

The aim of this work is to develop a venlafaxine hydrochloride sustained release system based on hollow mesoporous silica microspheres(HMSMs).HMSMs were innovatively prepared with tetraethyl silicate(TEOS)as the precursor and volatile n-heptane as a soft template.The obtained HMSMs show a well-defined hollow structure with an average size of 967 nm and pore volume of 0.85 cm^(3)/g,implying it is a potential drug carrier.Subsequently,venlafaxine hydrochloride(VF)was absorbed in the HMSMs with a content of 37.67% or so.The sustained release effect is further measured by the dissolution in-strument at 37℃ and 50 rpm in ultrapure water.The results showed that the HMSMs/VF system shows good sustained release properties compared with sustained release tablets with hydroxypropyl meth-ylcellulose as the main component.This HMSMs sustained release system appears to be a promising candidate for a sustained drug release.

关键词： Hollowmesoporous silica microspheres(HMSMs) Venlafaxine hydrochloride Drug loading Sustained release

Optimization on magnetic properties of Nd-doped Fe_(3)O_(4) nanoparticles for magnetic shielding fabrics

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Journal of Rare Earths 2024年第4期42卷 683-689页

作者： Xiaolei Song Congzhu Xu Yuyan Wang Huizhen Ke Yonggui Li Qufu Wei Xinqun Feng Faculty of Clothing and Design Minjiang UniversityFuzhou350108China Fujian Key Laboratory of Novel Functional textile Fibers and materials Minjiang UniversityFuzhou350108China college of textile and Clothing Jiangnan UniversityWuxi214122China college of Fashion and Design Donghua UniversityShanghai201620China

High magnetic protective fabrics with rare earth Nd doped Fe_(3)O_(4) nanoparticles were fabricated via a grafting method.The structure,crystal form,and elemental composition of nanoparticles were investigated by transmission electron microscopy,energy dispersive X-ray,X-ray powder diffraction,and X-ray photoelectron spectroscopy.The obtained NdFe_(2)O_(4) nanoparticles show spherical shape with fine dispersion and reasonable element composition.However,they demonstrate fine superparamagnetic properties with a magnetic saturation value of 29.25 A·m^(2)/g and low coercivity of 1.902 mT through the vibrating sample magnetometry technique,which can be well developed in magnetic shielding protective applications.Then,the cotton fabrics with plain weave were finished by a proofing rapier loom as a carrier.The NdFe_(2)O_(4) nanoparticles underwent some appropriate surface modification and then were grafted onto the cotton fabrics by a bridge agent of N,N’-dissuccinimidyl carbonate.The morphology,structure,dispersion effect,and electromagnetic protective properties of the fabrics were observed through scanning electron microscopy,Fourier infrared spectroscopy,thermogravimetric analysisdifferential scanning calorimetry(TG-DSC),and a vector network analyzer.The reliable fabrics with grafting reaction on the interface are expected to have potential applications in the field of electromagnetic protection and biomedicine fields.

关键词： Magnetic property Nd Fe_(3)O_(4)nanoparticles Magnetic shielding Fabrics Rare earths