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Doping suppresses lattice distortion of vacant quadruple perovskites to activate self-trapped excitons emission

Nano Research 2024年第4期17卷 3068-3078页

作者： Zhipeng Chen Fei Zhang Dongwen Yang Huifang Ji Xu Chen Di Wu Xinjian Li Yu Zhang Zhifeng Shi key laboratory of Materials physics of Ministry of Education School of Physics and MicroelectronicsZhengzhou UniversityZhengzhou 450052China State key laboratory on Integrated Optoelectronics College of Electronic Science and EngineeringJilin UniversityChangchun 130012China

The vacancy-ordered quadruple perovskite Cs_(4)CdBi_(2)Cl_(12),as a newly-emerging lead-free perovskite system,has attracted great research interest due to its excellent stability and direct band ***,the poor luminescence performance limits its application in light-emitting diodes(LEDs)and other ***,for the first time,an Ag^(+)ion doping strategy was proposed to greatly improve the emission performance of Cs_(4)CdBi_(2)Cl_(12) synthesized by hydrothermal *** functional theory calculations combined with experimental results evidence that the weak orange emission from Cs_(4)CdBi_(2)Cl_(12) is attributed to the phonon scattering and energy level crossing due to the large lattice distortion under excited ***,Ag^(+)ion doping breaks the intrinsic crystal field environment of Cs_(4)CdBi_(2)Cl_(12),suppresses the crossover between ground and excited states,and reduces the energy loss in the form of nonradiative *** a critical doping amount of 0.8%,the emission intensity of Cs_(4)CdBi_(2)Cl_(12):Ag^(+)reaches the maximum,about eight times that of the pristine ***,the doped Cs_(4)CdBi_(2)Cl_(12) still maintains excellent stability against heat,ultraviolet irradiation,and environmental oxygen/*** above advantages make it possible for this material to be used as solid-state phosphors for white LEDs applications,and the Commission International de I’Eclairage color coordinates of(0.31,0.34)and high color rendering index of 90.6 were *** importantly,the white LED demonstrates remarkable operation stability in air ambient,showing almost no emission decay after a long working time for 48 *** believe that this study puts forward an effective ion-doping strategy for emission enhancement of vacancy-ordered quadruple perovskite Cs_(4)CdBi_(2)Cl_(12),highlighting its great potential as efficient emitter compatible for practical applications.

关键词： Cs_(4)CdBi_(2)Cl_(12) self-trapped excitons ion doping emission enhancement stability

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Prospect of ultrahigh-resolution fast neutron absorption spectroscopy based on a laser plasma electron accelerator

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High Power Laser Science and Engineering 2024年第1期12卷 108-115页

作者： Wen-Zhao Wang Jie Feng Xiao-Peng Zhang Yao-Jun Li Wei-Jun Zhou Wen-Chao Yan Guo-Qiang Zhang Chang-Bo Fu Li-Ming Chen key laboratory of Laser Plasma(moe) School of Physics and AstronomyShanghai Jiao Tong UniversityShanghaiChina IFSA Collaborative Innovation Center Shanghai Jiao Tong UniversityShanghaiChina Institute of High Energy physics Chinese Academy of SciencesBeijingChina Shanghai Advanced Research Institute Chinese Academy of SciencesShanghaiChina key laboratory of Nuclear physics and ion-beam Application(moe) Institute of Modern PhysicsFudan UniversityShanghaiChina

Fast neutron absorption spectroscopy is widely used in the study of nuclear structure and element analysis. However,due to the traditional neutron source pulse duration being of the order of nanoseconds, it is difficult to obtain a high-resolution absorption spectrum. Thus, we present a method of ultrahigh energy-resolution absorption spectroscopy via a high repetition rate, picosecond duration pulsed neutron source driven by a terawatt laser. The technology of single neutron count is used, which results in easily distinguishing the width of approximately 20 keV at 2 MeV and an asymmetric shape of the neutron absorption peak. The absorption spectroscopy based on a laser neutron source has one order of magnitude higher energy-resolution power than the state-of-the-art traditional neutron sources, which could be of benefit for precisely measuring nuclear structure data.

关键词： fast neutron absorption spectroscopy laser plasma accelerator photo-nuclear neutrons single neutron count

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Effect of a negative DC bias on a capacitively coupled Ar plasma operated at different radiofrequency voltages and gas pressures

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Plasma Science and Technology 2024年第5期26卷 62-71页

作者：相垚君王晓坤刘永新王友年 key laboratory of Materials Modification by Laser Ionand Electron Beams(Ministry of Education)School of PhysicsDalian University of TechnologyDalian 116024People’s Republic of China Chair of Applied Electrodynamics and Plasma Technology Ruhr University BochumBochum 44801Germany

The effect of a negative DC bias,|V_(dc)|,on the electrical parameters and discharge mode is investigated experimentally in a radiofrequency(RF)capacitively coupled Ar plasma operated at different RF voltage amplitudes and gas *** electron density is measured using a hairpin probe and the spatio-temporal distribution of the electron-impact excitation rate is determined by phase-resolved optical emission *** electrical parameters are obtained based on the waveforms of the electrode voltage and plasma current measured by a voltage probe and a current *** was found that at a low|V_(dc)|,***α-mode,the electron density and RF current decline with increasing|V_(dc)|;meanwhile,the plasma impedance becomes more capacitive due to a widened ***,RF power deposition is ***|V_(dc)|exceeds a certain value,the plasma changes toα–γhybrid mode(or the discharge becomes dominated by theγ-mode),manifesting a drastically growing electron density and a moderately increasing RF ***,the plasma impedance becomes more resistive,so RF power deposition is enhanced with|V_(dc)|.We also found that the electrical parameters show similar dependence on|V_(dc)|at different RF voltages,andα–γmode transition occurs at a lower|V_(dc)|at a higher RF *** increasing the pressure,plasma impedance becomes more resistive,so RF power deposition and electron density are *** particular,theα–γmode transition tends to occur at a lower|V_(dc)|with increase in pressure.

关键词： RF capacitively coupled plasma DC-overlapped RF discharge power deposition discharge mode transition

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Advancing mid-infrared microdisk laser emission with Tm:YAG

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Science China(physics,Mechanics & Astronomy) 2024年第7期67卷 91-96页

作者： Zhaocong Wang Huiqi Li Lei Wang Yang Tan Feng Chen School of physics State Key Laboratory of Crystal MaterialsShandong UniversityJinan 250100China

Mid-infrared microcavity lasers have important applications in biosensing,mid-infrared spectroscopy,and environmental ***,the low output power of existing mid-infrared microcavity lasers hinders their practical *** drawback is attributed to the insufficient laser gain medium,which limits the development of mid-infrared whispering-gallerymode(WGM)*** address this issue,we have employed ion implantation-enhanced etching to fabricate Tm:YAG thin films as effective gain media for mid-infrared WGM *** Tm:YAG thin film,with a thickness of 2μm,exhibits excellent fluorescence ***,the Tm:YAG thin film is processed using focused ion beam to form microdisks with a diameter of 30μ*** 785 nm laser pumping,the maximum output power of the Tm:YAG microdisk at 2023.1 nm is229μW,with a slope efficiency of 2.9%.This work demonstrates the outstanding potential of Tm:YAG as a mid-infrared laser gain medium,providing a new option for the development of mid-infrared lasers.

关键词： microdisk microlaser ultrathin film

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A polarization sensitive interferometer:Delta interferometer

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Chinese physics B 2024年第3期33卷 369-377页

作者：卫超奇刘建彬董翼飞孙雨农周宇郑淮斌刘严严闫秀生李福利徐卓 key laboratory of Multifunctional Materials and Structures Ministry of Education & International Center for Dielectric ResearchSchool of Electronic Science and EngineeringXi'an Jiaotong UniversityXi'an 710049China moe key laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter Department of Applied PhysicsXi'an Jiaotong UniversityXi'an 710049China Science and Technology on Electro-Optical Information Security Control laboratory Tianjin 300308China

A new type of polarization sensitive interferometer is proposed,named the Delta interferometer,inspired by its geometry resembling the Greek letter *** main difference between the Delta interferometer and other existing interferometers,such as Michelson,Mach-Zehnder and Young's double-slit interferometers,is that the two interfering paths are asymmetrical in the Delta *** visibility of the first-order interference pattern observed in the Delta interferometer is dependent on the polarization of the incidental *** coherence theory is employed to interpret this phenomenon and single-mode continuous-wave laser light is employed to verify the theoretical *** theoretical and experimental results are *** Delta interferometer is a perfect tool to study the reflection of electromagnetic fields in different polarizations and may find applications in polarization-sensitive scenarios.

关键词： phase sensitive interferometer Fresnel formula first-order interference

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Diameter-dependent ultra-high thermoelectric performance of ZnO nanowires

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Chinese physics B 2024年第4期33卷 86-94页

作者：聂祎楠唐桂华李一斐张敏赵欣 moe key laboratory of Thermo-Fluid Science and Engineering School of Energy and Power EngineeringXi’an Jiaotong UniversityXi’an 710049China

Zinc oxide(ZnO)shows great potential in electronics,but its large intrinsic thermal conductivity limits its thermoelectric *** this work,we explore the significant carrier transport capacity and diameter-dependent thermoelectric characteristics of wurtzite-ZnO(0001)nanowires based on first-principles and molecular dynamics *** the synergistic effect of band degeneracy and weak phonon-electron scattering,P-type(ZnO)_(73) nanowires achieve an ultrahigh power factor above 1500μW·cm^(-1)·K^(-2)over a wide temperature *** lattice thermal conductivity and carrier transport properties of ZnO nanowires exhibit a strong diameter size *** the ZnO nanowire diameter exceeds 12.72A,the carrier transport properties increase significantly,while the thermal conductivity shows a slight increase with the diameter size,resulting in a ZT value of up to 6.4 at 700 K for P-type(ZnO)_(73).For the first time,the size effect is also illustrated by introducing two geometrical configurations of the ZnO *** work theoretically depicts the size optimization strategy for the thermoelectric conversion of ZnO nanowires.

关键词： ZnO nanowire size effect thermoelectric performance deformation potential theory

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Eco-Friendly Encapsulation of Metal Clusters in Porous Organic Cages for Engineerable Microenvironment and Enhanced Catalysis

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CCS Chemistry 2024年第9期6卷 2186-2197页

作者： Siyu Ren Liangxiao Tan Jun-Hao Zhou Jian Sun Peng Zhang Xingzhong Cao Yun-Hong Zhang Jian-Ke Sun moe key laboratory of Cluster Science Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion MaterialsSchool of Chemistry and Chemical EngineeringBeijing Institute of TechnologyBeijing 102488 Institute of High Energy physics Chinese Academy of SciencesBeijing 100049

Developing artificial catalysts that mimic the functionality of enzymes and adapt to the surrounding microenvironment to achieve specific activity and selectivity is a fascinating research area yet remains a great *** this work,we present a meticulously designed strategy for the successful encapsulation of ultrasmall metal clusters(MCs)within an amine-type porous organic cage(POC)through electrostatic complexation,phase transfer,and alcohol reduction *** amine cage showcases an intriguing and customizable feature that allows for the regulation of the surrounding microenvironment of the confined MCs through a feasible postmodifi-cation *** functionalization of cage skeleton further facilitates precise adjustment to the surface electronic state of Pd cluster,thereby influencing the adsorption behavior of ***,this controlled regulation leads to modified activity and chemoselectivity in the catalytic hydrogenation of halogenated ***,the investigation of the correlation between the surrounding microenvironment,substrate adsorption,and catalytic performance in the POC-immobilized MCs system has not been previously *** anticipate that our research will provide valuable insights in this field.

关键词： metal cluster porous organic cage encapsulation microenvironment catalysis

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A nitric oxide-triggered hydrolysis reaction to construct controlled self-assemblies with complex topologies

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Science China Chemistry 2024年第4期67卷 1289-1299页

作者： Wenzhuo Chen Yuping Tang Shuai Chen Zipei Chen Jia He Hongbin Huo Juan Zhang Jiajia Li Fei Yan Wei Tian laboratory of Shaanxi Administration of Traditional Chinese Medicine for TCM Compatibility Shaanxi Key Laboratory of Chinese Medicine Fundamentals and New Drugs ResearchCollege of PharmacyShaanxi University of Chinese MedicineXianyang 712046China Shaanxi key laboratory of Macromolecular Science and Technology Xi’an Key Laboratory of Hybrid Luminescent Materials and Photonic DeviceMOE Key Laboratory of Material Physics and Chemistry under Extraordinary ConditionsSchool of Chemistry and Chemical EngineeringNorthwestern Polytechnical UniversityXi’an 710072China Department of Polymeric Materials School of Materials Science and EngineeringTongji UniversityShanghai 201804China

Hydrolysis reactions are capable of directing the non-equilibrium assembly of biomolecular scaffolds to realize sophisticated structures and functions in natural ***,utilizing the proper hydrolysis reactions to construct controlled assemblies with complex topologies is still an arduous challenge in artificial systems and needs to be ***,we report a nitric oxide(NO)-triggered slow hydrolysis strategy for the controlled construction of biomimetic supramolecular toroids(STs),thus realizing their visualization of intermediate structures and regulation of geometry *** presented protocol harnesses hydrolysis reactions to control of non-equilibrium self-assembly processes for the construction of self-assemblies with complex topologies successfully,which sheds light on how the hydrolysis reaction rate can modulate the kinetic pathway of assembly,thus realizing the artificial establishment of bio-inspired hierarchical structures.

关键词： supramolecular toroids controlled self-assembly nitic oxide-triggered hydrolysis pathway regulation

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Optimizing high-coordination shell of Co-based single-atom catalysts for efficient ORR and zinc-air batteries

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Journal of Energy Chemistry 2024年第8期95卷 306-314,I0007页

作者： Yugang Qi Qing Liang Kexin Song Xinyan Zhou Meiqi Liu Wenwen Li Fuxi Liu Zhou Jiang Xu Zou Zhongjun Chen Wei Zhang Weitao Zheng key laboratory of Automobile Materials moe School of Materials Science&Engineering Electron Microscopy Centerand International Center of Future ScienceJilin Provincial International Cooperation Key Laboratory of High-Efficiency Clean Energy MaterialsJilin UniversityChangchun 130012JilinChina Institute of High Energy physics Chinese Academy of SciencesBeijing 100049China

Atom-level modulation of the coordination environment for single-atom catalysts(SACs)is considered as an effective strategy for elevating the catalytic *** the MNxsite,breaking the symmetrical geometry and charge distribution by introducing relatively weak electronegative atoms into the first/second shell is an efficient way,but it remains challenging for elucidating the underlying mechanism of ***,a practical strategy was reported to rationally design single cobalt atoms coordinated with both phosphorus and nitrogen atoms in a hierarchically porous carbon derived from metal-organic frameworks.X-ray absorption spectrum reveals that atomically dispersed Co sites are coordinated with four N atoms in the first shell and varying numbers of P atoms in the second shell(denoted as Co-N/P-C).The prepared catalyst exhibits excellent oxygen reduction reaction(ORR)activity as well as zinc-air battery *** introduction of P atoms in the Co-SACs weakens the interaction between Co and N,significantly promoting the adsorption process of ^(*)OOH,resulting in the acceleration of reaction kinetics and reduction of thermodynamic barrier,responsible for the increased intrinsic *** discovery provides insights into an ultimate design of single-atom catalysts with adjustable electrocatalytic activities for efficient electrochemical energy conversion.

关键词： Electrocatalytic Oxygen reduction reaction Single atom catalyst Shell coordination optimization

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Solar neutrino background in high-pressure gaseous ^(82)SeF_(6) TPC neutrinoless double beta decay experiments

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Chinese physics C 2024年第4期48卷 20-33页

作者：王杰妙汪虎林张冬亮 PLAC Key Laboratory of Quark and Lepton Physics(MOE)Central China Normal UniversityWuhan 430079China Hubei Provincial Engineering Research Center of Silicon Pixel Chip&Detection Technology Wuhan 430079China

In this study,the possibility of observing a solar neutrino background in a future neutrinoless double beta decay experiment using a high-pressure gaseous ^(82)SeF_(6) TPC is *** contributions are simulated,and possible features that could be used for event classification are discussed;two types of backgrounds are *** rate of multi-site background events is approximately 0.63 events/(ton·yr)in a 30 keV ROI *** background could be effectively reduced to less than 0.0001 events/(ton·yr)(95%C.L.)while maintaining a high signal efficiency of 93%by applying a selection based on the number of clusters and energy of the leading *** rate of the single-electron background events is approximately 0.01 events/(ton·yr)in the *** a reduction factor of 10 for the single-electron background events obtained via the algorithms developed for radioactive background rejection,the total background induced by the solar neutrino would be 0.001 events/(ton·yr),which is sufficiently small for conducting ton-level experiments.

关键词： neutrinoless double beta decay SeF6 high-pressure TPC solar neutrino

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