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Effect of Ca Micro-Alloying on the Microstructure and Anti-Corrosion Property of Mg0.5Zn0.2Ge Alloy

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Acta Metallurgica Sinica(English Letters) 2024年第7期37卷 1147-1160页

作者： Bishan Cheng Depeng Li Baikang Xing Ruiqing Hou Pingli Jiang Shijie Zhu Shaokang Guan School of materials Science and Engineering and Henan key laboratory of advanced Magnesium Alloys Zhengzhou UniversityZhengzhou450001China Center of advanced Analysis and Gene Sequencing Zhengzhou UniversityZhengzhou450001China key laboratory of materials Processing and Mold Technology Ministry of EducationZhengzhou450002China

Magnesium and its alloys have attracting rising attention as one of biodegradable metallic ***,the rapid corrosion and severe localized corrosion still hinder their extensive applications in *** this study,micro-alloying of Ca(≤0.1 wt%)into Mg0.5Zn0.2Ge alloy developed in our previous work was explored to further enhance the corrosion resistance and alleviate the localized corrosion of the *** results reveal that the addition of Ca leads to the transformation of the cathodic Mg_(2)Ge phase in Mg0.5Zn0.2Ca alloy into anodic MgCaGe phase in Ca-containing alloys,thereby changing the galvanic couples in alloys during *** preferential dissolution of MgCaGe phase promotes the participation of Ca and Ge into the formation of corrosion products,resulting in the enrichment of Ca and Ge in the outmost of corrosion product layer,which stabilizes and passivates the corrosion product layer on Mg alloy ***,the enrichment of Zn at the corrosion interface seems to further hinder the corrosion of Mg *** of these factors confer a slower and more uniform corrosion on Mg0.5Zn0.2GexCa(x<0.1 wt%)alloy,which provides favorable candidates for the further processing to gain suitable biodegradable Mg alloys.

关键词： Magnesium alloy Micro-alloying Calcium Corrosion resistance

Rational design of robust and transparent superrepellent surfaces for long-term marine antifouling

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Science China(Technological Sciences) 2024年第7期67卷 2031-2039页

作者： CHEN Hui WANG Zhi WANG DaHeng XIAO Feng FU Guang-En BU XueLing ZHAO Lei ZHANG Tao WU DaHeng PU JiBin The State key laboratory of Refractories and Metallurgy Wuhan University of Science&TechnologyWuhan 430081China key laboratory of advanced Marine materials Ningbo Institute of Materials Technology and EngineeringChinese Academy of SciencesNingbo 315201China

Superhydrophobic surfaces have demonstrated exceptional efficacy in combatting biofouling contaminations of optical devices and equipment in marine applications. However, the fabrication of highly transparent superhydrophobic materials remains a formidable challenge due to the inherent trade-off between surface roughness for superhydrophobicity and optical ***, we design a robust and transparent superhydrophobic coating(Si-POSS) embedded silica nanoparticles(200 nm) with fluorinated polyhedral oligomeric silsesquioxanes(F-POSS) and zinc pyrithione(ZPT). The Si-POSS coating exhibits excellent water repellence toward diverse liquids and optical transmittance exceeding 90% in the visible spectrum. Moreover, the Si-POSS coating sustains long-term anti-bacterial(> 99.11%) and anti-algal effects for over 30 days, accompanied by mechanical,chemical, and thermal stability. This research asserts that the Si-POSS coating with outstanding combined characteristics holds significant potential for marine applications, particularly in self-cleaning and antifouling endeavors.

关键词： superhydrophobic surface transparent marine antifouling nanoparticles

维普期刊数据库

β-C(sp^(3))−H chlorination of amide derivatives via photoinduced copper charge transfer catalysis

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Chinese Chemical Letters 2024年第2期35卷 361-365页

作者： Yuhang He Chao Tian Guanghui An Guangming Li key laboratory of Functional Inorganic Material Chemistry (moe) School of Chemistry and Materials ScienceHeilongjiang UniversityHarbin 150080China

An atom economicβ-C(sp^(3))−H chlorination of amide derivatives has been *** mild protocol employs CuCl_(2) instead of palladium catalysts with atom-economic HCl as chlorine sources and enables the late-stage functionalization of medicine *** studies suggest a plausible visible light triggered ligand-to-metal charge transfer(LMCT)/1,4-hydrogen atom transfer(HAT)cascade.

关键词： Photoinduced copper catalysis Ligand-to-metal charge transfer 1,4-Hydrogen atom transfer β-Halogenated amide Late-stage functionalization

维普期刊数据库

A High-Performance MoS_(2)-Based Visible-Near-Infrared Photodetector from Gateless Photogating Effect Induced by Nickel Nanoparticles

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Research 2024年第2期6卷 171-179页

作者： Ran Duan Weihong Qi Panke Li Kewei Tang Guoliang Ru Weimin Liu State key laboratory of Solidification Processing Center of Advanced Lubrication and Seal MaterialsNorthwestern Polytechnical UniversityXi'an 710072China Shandong laboratory of Yantai advanced materials and Green Manufacturing Yantai 265503China State key laboratory of Solid Lubrication Lanzhou Institute of Chemical PhysicsChinese Academy of SciencesLanzhou 730000China

Recent advancements in two-dimensional materials have shown huge potential for optoelectronic *** is challenging to achieve highly effective and sensitive broadband photodetection based on MoS_(2)*** engineering,such as introducing vacancies,can narrow the bandgap and boost the separation of photogenerated carriers by defect states but leads to a slow response ***,we propose a nickel nanoparticle-induced gateless photogating effect with a unique energy band structure to enable the application of defect engineering and achieve high optoelectronic *** device based on Ni nanoparticle-decorated MoS_(2)with S vacancies exhibited high responsivities of 106.21 and 1.38 A W^(-1)and detectivities of 1.9×10^(12)and 8.9×10^(9)Jones under 532 and 980 nm illumination(visible to near infrared),respectively,with highly accelerated response *** strategy provides new insight into optimizing defect engineering to design high-performance optoelectronic devices capable of broadband photodetection.

关键词： defect Infrared illumination

Highly-efficient CoRuO_(x)nanocatalysts for acidic oxygen evolution:The merit of optimum ordering degree of carbon nanotube support

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Particuology 2024年第7期90卷 470-477页

作者： Wenwen Li Yanni Wang Zhenzhen Zhao Meiqi Liu Qing Liang Yuhua Liu Fuxi Liu Zhou Jiang Xu Zou Bingsen Zhang Wei Zhang key laboratory of Automobile materials moe School of Materials Science&EngineeringJilin Provincial International Cooperation Key Laboratory of High-Efficiency Clean Energy MaterialsElectron Microscopy CenterInternational Center of Future ScienceJilin UniversityChangchun 130012China Shenyang National laboratory for materials Science Institute of Metal ResearchChinese Academy of Sciences110016ShenyangChina

Hydrogen production from proton exchange membrane water electrolysis is constrained by the sluggish kinetics of the anodic oxygen evolution ***_(2)has attracted considerable attention due to its low reaction overpotential,but its inferior stability remains a major ***,a strategy is proposed to enhance the catalytic activity and stability of CoRuOx nanoparticles by doping Co and regulating the ordering degree of carbon nanotubes(CNTs)by air *** was found that the CoRuOx@CNTs-300 catalyst exhibited the best catalytic activity and stability when the annealing temperature was 300°*** the current density of 10 mA cm−2,the overpotential of this catalyst was only 201 mV,which was nearly 100 mV lower than that of commercial RuO_(2)(300 mV).Surprisingly,there was no significant increase in the overpotential when tested at a current density of 10 mA cm−2 for 50 *** density functional theory calculations indicate that the high activity of the catalyst is due to the electronic coupling of CoRuOx nanoparticles and CNTs,and that the introduction of Co and CNTs improves the electronic structure and solvation energies of the Ru in the active site,dramatically increasing the structural stability.

关键词： Electrocatalysis RuO_(2) CNTs Oxygen evolution reaction

Injection molding of highly filled microcrystalline cellulose/polycaprolactone composites with the aid of reversible Diels-Alder reaction

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Journal of materials Science & Technology 2024年第3期170卷 246-254页

作者： Ze Pu Wang WenHong Ruan MinZhi Rong MingQiu Zhang key laboratory for Polymeric Composite and Functional materials of moe GD HPPC LabIGCMESchool of ChemistrySun Yat-Sen UniversityGuangzhou 510275China

To tackle the challenge of producing highly filled polymer composites using the traditional injection molding technique,which is characterized by the fairly high melt viscosity that makes mold filling difficult,the authors propose a solution based on dynamic covalent *** demonstrated by the proof-of-concept experiments,the 4-arm starshaped polycaprolactone(PCL)oligomers and microcrystalline cel-lulose(MCC)are crosslinked by the reversible Diels-Alder(DA)*** flowability of the compounds greatly decreases due to the dissociation of the intercomponent DA bonds at the retro-reaction tempera-ture,and the networked architecture is reconstructed during cooling as a result of the forward DA ***,the high-loading MCC fillers are well distributed in the matrix and covalently bonded to the nearby PCL,forming a striking contrast to the control in which linear PCL acts as the *** DA bonds crosslinked biodegradable PCL composites exhibit decent mechanical strength(20.7 MPa)even at the MCC fraction of 65 wt%,which is superior to those(5-12.2 MPa)of the highly filled PCL composites(with filler contents of 50-63.8 wt%)reported so *** proposed approach has sufficient expansibility for the fabrication of the highly filled polymer composites constructed by other types of matrix and fillers.

关键词： Polymer composites Microcrystalline cellulose Polycaprolactone Injection molding Dynamic reversible chemistry

Universal Encapsulation Adhesive for Lead Sedimentation and Attachable Perovskite Solar Cells with Enhanced Performance

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Energy & Environmental materials 2024年第03期7卷 307-314页

作者： Xuehao Zhu Haoyu Cai Cong Bai Zhengzhe Wu Wenjian Shen Yiming Xiong Juan Zhao Fuzhi Huang Yibing Cheng Jie Zhong Research Centre for advanced Thin Film Photovoltaics State Key Laboratory of Advanced Technology for Materials Synthesis and ProcessingWuhan University of Technology Foshan Xianhu laboratory of the advanced Energy Science and Technology Guangdong laboratory School of Automobile Engineering Wuhan University of Technology

In this work,a modified polyurethane adhesive (PUA) was prepared to realize a convenient encapsulation strategy for lead sedimentation and attachable perovskite solar cells (A-PSCs).The modified PUA can completely self-heal within 45 min at room temperature with an efficient lead ionblocking rate of 99.3%.The PUA film can be coated on a metal electrode with slight efficiency improvement from 23.96%to 24.15%.The thermal stability at 65℃and the humidity stability at 55%relative humidity (RH)are superior to the devices encapsulated with *** PUA film has strong adhesion to the flexible substrate and the initial efficiency of the flexible perovskite module (17.2%) encapsulated by PUA remains 92.6%within 1825 *** results suggest that PUA encapsulation is universal for rigid and flexible PSCs with enhanced stability and low lead ***,it was found that flexible PSCs can be well attached to various substrates with PUA,providing a facile route for the A-PSCs in various scenarios without additional encapsulation and installation.

关键词： adhesive attachable device flexible module lead leakage polyurethane

Corrosion of Duplex Stainless Steel Manufactured by Laser Powder Bed Fusion: A Critical Review

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Acta Metallurgica Sinica(English Letters) 2024年第4期37卷 587-606页

作者： Yiqi Zhou Decheng Kong Ruixue Li Xing He Chaofang Dong Beijing advanced Innovation Center for materials Genome Engineering Institute for Advanced Materials and TechnologyUniversity of Science and Technology BeijingBeijing100083China Shanghai key laboratory of advanced High-Temperature materials and Precision Forming School of Materials Science and EngineeringShanghai Jiao Tong UniversityShanghai200240China

Laser powder bed fusion (LPBF) is a commonly used additive manufacturing (AM) method for efficiently producing intricate geometric components. This investigation examines factors such as pores, cellular structure, grain size, and inclusions from the manufacturing process that contribute to the corrosion resistance of LPBF DSS. Furthermore, the as-built LPBF duplex stainless steel (DSS) is primarily ferrite due to the rapid cooling process. Therefore, the transformation of ferrite to austenite after various heat treatments in LPBF DSS and its corresponding corrosion resistance are presented. Additionally, a new mixed powder method is proposed to increase the austenite content in the as-built LPBF DSS. This review also focuses on the passivation capability and pitting corrosion performance in LPBF and conventional DSS. This article summarizes the variations in microstructure between as-built and heat-treated LPBF DSS, with their impacts on corrosion resistance, offering insights for manufacturing highly corrosion-resistant LPBF DSS.

关键词： Laser powder bed fusion Duplex stainless steel Microstructure Heat treatment Passivation Pitting corrosion

Cobalt-nanoparticle catalysts derived from zeolitic imidazolate framework@MXene composites for efficient oxidative self-coupling of benzylamines

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Frontiers of Chemical Science and Engineering 2024年第1期18卷 95-106页

作者： Jie Chen Mingyuan Jian Deqiong Xie Kecan Dou Deli Chen Weidong Zhu Fumin Zhang key laboratory of the Ministry of Education for advanced Catalysis materials Institute of Physical ChemistryZhejiang Normal UniversityJinhua 321004China

In this study,we synthesize a catalyst comprising cobalt nanoparticles supported on MXene by pyrolyzing a composite in a N2 ***,the composite comprises a bimetallic Zn/Co zeolitic imidazole framework grown in situ on the outer surface of *** catalytic efficiency of the catalyst is tested for the self-coupling of 4-methoxybenzylamine to produce value-added imine,where atmospheric oxygen(1 atm)is used as the *** on the results,the catalyst displayed impressive catalytic activity,achieving 95.4%yield of the desired imine at 383 K for 8 ***,the catalyst showed recyclability and tolerance toward benzylamine substrates with various functional *** outstanding performance of the catalyst is primarily attributed to the synergetic catalytic effect between the cobalt nanoparticles and MXene support,while also benefiting from the three-dimensional porous ***,a preliminary investigation of potential reaction mechanisms is conducted.

关键词： MXene sacrificial template oxidative self-coupling Co nanoparticles imine