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Lifetime-tunable circularly polarized luminescent system based on triplet-to-singlet F?rster resonance energy transfer

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Science China Chemistry 2024年第9期67卷 2918-2922页

作者： Zhenyi He Zizhao Huang Xiang Ma Key laboratory for Advanced materials and Feringa Nobel Prize Scientist Joint Research Center Institute of Fine Chemicals School of Chemistry and Molecular Engineering East China University of Science and Technology

Circularly polarized luminescence(CPL) materials have received widespread attention due to their remarkable performance and broad applications. However, current CPL material research primarily focuses on tunable color, intensity, and *** CPL with adjustable lifetime remains a significant challenge. Herein, a series of CPL polymeric materials with tunable lifetime were obtained by employing phosphorescent terephthalic acid and chiral organic small molecule R/S-BNAF(a luminescent binaphthol derivative) to copolymerize with acrylamide in different ratios. It was verified that this performance results from the different energy transfer efficiency between luminophores with varying ratios of the monomers for copolymerization. This strategy to realize CPL with tunable lifetime by modulating the energy transfer efficiency will provide a new perspective to broaden the applications of CPL materials.

关键词： circularly polarized luminescence tunable lifetime Förster resonance energy transfer room temperature phosphorescence

Triplet-triplet annihilation upconversion materials as electrophoretic inks

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Chinese Chemical Letters 2024年第3期35卷 439-442页

作者： Qiaoyu Zhang Guiwen Luo Jinping Chen Tianjun Yu Rui Hu Guoqiang Yang Yi Zeng Yi Li Key laboratory of Photochemical Conversion and Optoelectronic materials Technical Institute of Physics and ChemistryChinese Academy of SciencesBeijing 100190China Key laboratory of Photochemistry Institute of ChemistryChinese Academy of SciencesBeijing 100190China University of Chinese Academy of Sciences Beijing 100049China

luminescent materials that can be reversibly switched by electric field stimulation are attractive since the potential application for optoelectronic *** we report a triplet-triplet annihilation upconversion(TTA-UC)system with electrophoretic response which is developed as the electrophoretic *** TTA-UC system consists of an ionic derivative of 9,10-diphenyl anthracene(DPA)as the annihilator and Pt(II)octaethylporphyrin(PtOEP)as the *** applying an electric field,migration and enrichment of positively charged DPA derivatives towards the cathode results in a 20%enhancement of TTA-UC.A quasi-solid film for electrically writing is made using the electrophoretic TTA system as the ink and a platinum electrode as a *** prototype of TTA-UC ink demonstrates unique luminescence functions upon electrically writing and erasing,providing a promising strategy to develop electronic devices for display,information storage and encryption.

关键词： Triplet-triplet annihilation Photon upconversion Electrophoresis Electrophoretic ink Luminescence display

Multidisciplinary and multiscale nanoscience research roadmap based on large scientific facilities

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Science China Chemistry 2024年第8期67卷 2497-2523页

作者： Yuan Zeng Shuhan Zhang Yuecong Guo Yalin Cong Xu Ding Peihua Li Yunxiang Lin Wenzhi Ren Hui Su Weigang Sun Liuxin Xu Guikai Zhang Shihua Chen Yu Chen Weiren Cheng Shengqi Chu Yong Guan Jinru Han Jie Lin Hengjie Liu Zheyi Liu Pan Luo Fanchun Meng Sicong Qiao Zongyin Song Ying Wang Zhao Wu Chenyu Yang Meng Yang Shirui Yang Zi Yin Zhibin Yin Pengjun Zhang Hongyu Zhang Pingping Zheng Jia Zhou Wanlin Zhou Pengfei An He Cheng Chunhai Fan Xingjiu Huang Yong Lei Lina Li Mu Li Qinghua Liu Shuming Peng Li Song Zhihu Sun Yangchao Tian Fangjun Wang Lihua Wang Liming Wang Shiqiang Wei Aiguo Wu Chunlei Xiao Xueming Yang Panchao Yin Jing Zhang Mingxin Zhang Yaling Wang Chunying Chen CAS Key laboratory for Biomedical Effects of Nanomaterials and Nanosafety New Cornerstone Science LaboratoryNational Center for Nanoscience and TechnologyBeijing 100190China University of Chinese Academy of Sciences Beijing 100049China National Synchrotron Radiation laboratory University of Science and Technology of ChinaHefei 230029China Institute of Solid State Physics Hefei Institutes of Physical ScienceChinese Academy of SciencesHefei 230031China Institutes of Physical Science and Information Technology Anhui UniversityHefei 230601China Ningbo Key laboratory of Biomedical Imaging Probe materials and Technology Zhejiang International Cooperation Base of Biomedical Materials Technology and ApplicationCAS Key Laboratory of Magnetic Materials and DevicesNingbo Cixi Institute of Biomedical EngineeringZhejiang Engineering Research Center for Biomedical MaterialsNingbo Institute of Materials Technology and EngineeringChinese Academy of SciencesNingbo 315201China Advanced Energy Science and Technology Guangdong laboratory Huizhou 516000China College of Chemistry and Chemical Engineering Hunan Normal UniversityChangsha 410081China State Key laboratory of luminescent materials and Devices South China Advanced Institute for Soft Matter Science and TechnologySouth China University of TechnologyGuangzhou 510640China Beijing Synchrotron Radiation Facility Institute of High Energy PhysicsChinese Academy of SciencesBeijing 100049China CAS Key laboratory of Separation Sciences for Analytical Chemistry Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023China State Key laboratory of Molecular Reaction Dynamics Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023China Institute of Advanced Science Facilities Shenzhen 518107China State Key laboratory of Coal Conversion Institute of Coal ChemistryChinese Academy of SciencesTaiyuan 030001China State Key laboratory of Particle Detection and Electronics Institute of High Energy PhysicsChinese Acade

With the advancement of modern science and technology, large scientific facilities are increasingly oriented toward demand and application, and can be used for basic research as well as serving multiple disciplines. Developing large scientific facilities and related analytical technologies enhances understanding of large scientific facilities and popularizes their application in research across multiple disciplines. The combination of light or neutron sources from large scientific facilities and advanced analytical technologies can be achieved for materials structure information, dynamics study of chemical reactions, high dissociation of biomolecules, 3D visualization of energy materials or biological samples, etc. We first introduce the progress of domestic large scientific facilities of synchrotron radiation(SR) and free electron lasers(FELs) with different wavelengths and neutron *** further discuss the comparison between Chinese and typical foreign facilities in X-ray radiation from X-ray tubes, synchrotrons, X-ray FELs, and neutron sources based on physical parameters of light and neutron sources. In addition, we focus on the technological progress and perspectives combined with advanced X-ray radiation and neutron sources of large scientific facilities in China, especially in the nanoscience fields of energy catalysis and biological science. We hope that this roadmap will provide references on technology and methods to experimental users, as well as prospects for future development of technologies based on large research infrastructure facilities. Comprehensive studies and guidelines for basic research to practical application in various disciplines can be made with the assistance of large scientific facilities.

关键词： large scientific facilities synchrotron radiation FEL light sources neutron sources spectroscopic analysis methods X-ray imaging techniques structural information chemical dynamics

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揭示银关联缺陷的双重作用:环保型AgIn0.5Ga0.5S2中发光和载流子动力学的操纵者

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Science China materials 2024年第1期67卷 214-222页

作者：刘高豫徐丽丽胡扬李晓明 Seokwoo Jeon 张胜利曾海波 MIIT Key laboratory of Advanced Display materials and Devices School of Materials Science and EngineeringNanjing University of Science and TechnologyNanjing 210094China Department of materials Science and Engineering Korea UniversitySeoul02841Republic of Korea

AgIn_(0.5)Ga_(0.5)S_(2)由于环境友好、合成成本低、成分灵活可调等优点在许多领域受到广泛关注.适当的直接带隙、无禁戒跃迁和高激子结合能使其成为一种有前途的发光材料.多组分体系的演化丰富了光电特性,并使其本征缺陷更加复杂.反过... 详细信息

AgIn_(0.5)Ga_(0.5)S_(2)由于环境友好、合成成本低、成分灵活可调等优点在许多领域受到广泛关注.适当的直接带隙、无禁戒跃迁和高激子结合能使其成为一种有前途的发光材料.多组分体系的演化丰富了光电特性,并使其本征缺陷更加复杂.反过来,这些缺陷对光电性能有重要影响,从而影响其发光性能.然而,对于这类半导体,在实验中观察到的与发光相对应的点缺陷的微观机制大多是未知的或间接推断的.本工作系统地揭示了AgIn_(0.5)Ga_(0.5)S_(2)的微观缺陷与发光之间的机制.热力学稳定性表明AgIn_(0.5)Ga_(0.5)S_(2)是亚稳态的并且与次生相之间存在显著的竞争.此外,计算的缺陷结果表明,与银关联的缺陷是幕后操纵者.两个浅能级缺陷(VAg和Agi)充当载流子提供者,而四个深能级反位缺陷(AgIn,AgGa,InAg和GaAg)充当载流子湮灭者.最后,载流子动力学的研究揭示了四种深能级反位缺陷对载流子辐射过程的不利影响.这些旨在为AgIn_(0.5)Ga_(0.5)S_(2)在发光领域的功能应用提供重要指导.

关键词：深能级反位缺陷发光材料本征缺陷浅能级热力学稳定性禁戒跃迁多组分体系

Composite structure Al_(2)O_(3)/Al_(2)O_(3)-YAG:Ce/YAG ceramics with high color spatial uniformity for white laser lighting

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Journal of Advanced Ceramics 2024年第2期13卷 189-197页

作者： Pengfei Sang Le Zhang Jian Kang Mingzhou Li Shiwei Chen Peng Yang Bingheng Sun Yang Li Wieslaw Strek Hao Chen Jiangsu Key laboratory of Advanced Laser materials and Devices School of Physics and Electronics EngineeringJiangsu Normal UniversityXuzhou 221116China Jiangsu Xiyi Advanced materials Research Institute of Industrial Technology Xuzhou 221400China Xuzhou EAGLED Technology Co. Ltd.Xuzhou 221116China Xuzhou Kangna Advanced materials Technology Co. Ltd.Xuzhou 221116China Xuzhou Fuchang Electronic Technology Co. Ltd.Xuzhou 221116China Shanghai Institute of Optics Fine Mechanics Chinese Academy of SciencesShanghai 201800China School of Material Science and Engineering Shanghai Institute of TechnologyShanghai 201418China State Key laboratory of Crystal materials Shandong UniversityJinan 250100China Institute of Low Temperature and Structure Research Polish Academy of SciencesWroclaw 50-422Poland

Composite ceramic phosphor(CCP)is a candidate light-conversion material to obtain the high-quality laser lighting *** based on the transmissive configuration model could not simultaneously meet the requirements of angular color uniformity and high thermal *** this study,a novel composite structure ceramic was designed,including Al_(2)O_(3)-YAG:Ce/YAG layered ceramic with a size of 1 mm×1 mm for lighting,and Al_(2)O_(3) ceramic(φ=16.0 mm)was used as the wrapping material due to its outstanding thermal *** prepared ceramics exhibited excellent thermal performance and no yellow ring *** this design,we achieved the match of the intensity distribution of the blue and yellow lights,resulting in a high angular color uniformity of 0.9 with a view angle of±80°.All ceramics showed no luminous saturation phenomenon,even the laser power density was increased up to 47.51 W/mm^(2).A high-brightness white-light source with a luminous flux of 618 lm,a luminous efficiency of 126 lm/W,a CCT of 6615 K,and a CRI of 69.9 was obtained in the transmissive *** particular,the surface temperature of the ceramic was as low as 74.1℃ under a high laser radiation(47.51 W/mm^(2)).These results indicate that Al_(2)O_(3)/Al_(2)O_(3)-YAG:Ce/YAG composite structure ceramic is a promising luminescent material in the high-power laser lighting applications.

关键词： Al_(2)O_(3)/Al_(2)O_(3)-YAG:Ce/YAG angular color uniformity high thermal stability high-power laser lighting

发射峰为875 nm的高热稳定性立方相Sc(PO_(3))_(3):Cr^(3+)荧光粉

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Science China materials 2024年第3期67卷 931-938页

作者：刘乐聂文东吴会杰张景荣梁思思朱浩淼 CAS Key laboratory of Design and Assembly of Functional Nanostructures Fujian Key Laboratory of NanomaterialsFujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China College of Chemistry and materials Science Fujian Normal UniversityFuzhou 350007China Xiamen Key laboratory of Rare Earth Photoelectric Functional materials Xiamen Research Center of Rare Earth MaterialsHaixi InstituteChinese Academy of SciencesXiamen 361021China

近红外(NIR)荧光粉转换型发光二极管(pc-LED)具有尺寸小、效率高以及光谱易于调节的特点,在特种照明、传感、微型近红外光谱仪等各领域有很好的应用前景.目前,已报道的发射波长超过850 nm的近红外荧光粉的荧光热稳定性较差.在本项研究中... 详细信息

近红外(NIR)荧光粉转换型发光二极管(pc-LED)具有尺寸小、效率高以及光谱易于调节的特点,在特种照明、传感、微型近红外光谱仪等各领域有很好的应用前景.目前,已报道的发射波长超过850 nm的近红外荧光粉的荧光热稳定性较差.在本项研究中,我们合成了一种立方相结构的Sc(PO_(3))_(3):xCr^(3+)(x=0,1,5,10,12,14,16,18 at%)荧光粉,其具有725–1150 nm的宽发射带,发射峰为875 nm,与之前报道的发射峰超过850 nm的荧光粉相比,其表现出优异的热稳定性,在423 K下,5 at%样品的积分发光强度保留了室温下的73.4%.通过对比研究立方相和单斜相Sc(PO_(3))_(3):Cr^(3+)荧光粉变温X射线衍射,发现立方相荧光粉优异的荧光热稳定性可能归因于高温下较小的键长和键角变化.利用该荧光粉制备的NIR pc-LED在150 mA电流驱动下,产生了26.62 mW的NIR辐射功率.驱动电流为10 mA时,最高电光转换效率为11.87%.这项工作为开发具有优异荧光热稳定性的Cr^(3+)离子掺杂近红外荧光粉提供了思路.

关键词： near infrared phosphor pc-LEDs broadband emission Sc(PO_(3))_(3) luminescent materials

Aggregation-induced delayed electrochemiluminescence of organic dots in aqueous media

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Aggregate 2024年第1期5卷 167-174页

作者： Hang Gao Shen-Yu Shi Shu-MinWang Qian-Qian Tao Hui-Li Ma Jun Hu Hong-Yuan Chen Jing-Juan Xu State Key laboratory of Analytical Chemistry for Life Science School of Chemistry and Chemical EngineeringNanjing UniversityNanjingChina Key laboratory of Flexible Electronics(KLOFE)and Institute of Advanced materials(IAM) Nanjing Tech UniversityNanjingChina School of Life Science and Health Engineering Jiangnan UniversityWuxiChina

Full utilization of the excited species at both singlet states(1R*)and triplet states(3R*)is crucial to improving electrochemiluminescence(ECL)efficiency but is challenging for organic luminescent ***,an aggregation-induced delayed ECL(AIDECL)active organic dot(OD)containing a benzophenone acceptor and dimethylacridine donor is reported,which shows high ECL efficiency via reverse intersystem crossing(RISC)of non-emissive 3R*to emissive 1R*,overcoming the spin-forbidden radiative decay from 3R*.By introducing dual donor-acceptor pairs into luminophores,it is found that nonradiative pathway could be further suppressed via enhanced intermolecular weak interactions,and multiple spin-up conversion channels could be *** a consequence,the obtained OD enjoys a 6.8-fold higher ECL efficiency relative to the control AIDECL-active ***-crystal studies and theoretical calculations reveal that the enhanced AIDECL behaviors come from the acceleration of both radiative transition and *** work represents a major step towards purely organic,high-efficiency ECL dyes and a direction for the design of next-generation ECL dyes at the molecular level.

关键词： aggregation-induced delayed electrochemiluminescence benzophenone dimethylacridine organic dots reverse intersystem crossing

Effects of water molecules on luminescence in europium and terbium coordination polymers with p-fluorobenzoic acid as ligand

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Journal of Rare Earths 2024年第7期42卷 1258-1264,I0003页

作者： Xiaoqi Zhao Puyan Hao Yami Ling Mengzhen Jia Rui Zhu Jiawen Liu Qiang Xu Jianhong Zhou Collaborative Innovation Center of Rare-Earth Optical Functional materials and Devices Development Baoji Key Laboratory of Micro-Nano Optoelectronics and Terahertz TechnologySchool of Physics and Opto-Electronic TechnologyBaoji University of Arts and SciencesBaoji721016China

Our previous experimental observations show that the crystal structure of lanthanide luminescent complexes synthesized in aqueous solution usually contains a large number of coordination water molecules or free water *** order to probe the influence of water molecules on luminescent processes of lanthanide complexes,the photoluminescence properties of Ln-FBA(Ln=Eu and Tb,FBA=p-fluorobenzoic acid)coordination polymers at different ambient temperatures,in different solvents and aqueous DMSO solutions with different volume concentrations were systematically *** experiment results show that the presence of water molecules can promote the energy transfer from FBA ligand to Ln3+,at the same time,can cause luminescent non-radiation quenching of lanthanide *** addition,the variation of emission intensity ratio of 615 nm/591 nm peaks of Eu^(3+)with increasing the volume concentration of H_(2)O can be potentially used for the quantitatively detection of water traces in organic *** order to suppress the non-radiation quenching caused by the water molecules,Ln-FBA(Ln=Eu and Tb)coordination polymers were embedded into the PVP matrix to prepare Ln-FBA@PVP hybrid *** photoluminescence investigation indicates that PVP can not only block the quenching effect of water molecules on luminescence,but also effectively sensitize Eu^(3+)and Tb^(3+)*** experimental conclusions are useful for probing the influence of water molecules on luminescent processes of lanthanide complexes,quantitatively detecting water traces in organic solvents and enhancing the photoluminescence intensity in lanthanide complexes.

关键词： Lanthanide complexes Photoluminescence luminescent quenching Rare earths

用于伪装和信息显示的具有快速切换、高循环稳定性的多彩VO/TiO电致变色薄膜（英文）

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Science China materials 2024年

作者：王杏如郑洋陈莉蓉葛锐江成玉徐刚肖秀娣 School of Energy Science and Engineering University of Science and Technology of China Guangdong Provincial Key laboratory of New and Renewable Energy Research and Development Guangzhou Institute of Energy Conversion ChineseAcademy of Sciences School of Physics and Optoelectronics South China University of Technology State Key laboratory of luminescent materials and Devices South China University of Technology

V2O5具有多色和储能特性,是一种有前景的电致变色材料,但由于其寿命短、切换时间长等使其应用受到限制.本文通过在原位生长的TiO2纳米棒上喷涂V2O5溶液制备了高性能的V2O5/TiO2薄膜.通过X射线衍射（XRD）、扫描电子显微镜（SEM）、原子...

V2O5具有多色和储能特性,是一种有前景的电致变色材料,但由于其寿命短、切换时间长等使其应用受到限制.本文通过在原位生长的TiO2纳米棒上喷涂V2O5溶液制备了高性能的V2O5/TiO2薄膜.通过X射线衍射（XRD）、扫描电子显微镜（SEM）、原子力显微镜（AFM）以及电化学阻抗谱（EIS）等方法对薄膜进行了表征,并阐述了改善机理.V2O5/TiO2薄膜具有较大的光学调制幅度（668 nm处为47.8%）、较快的响应速度（τc/τb=5.1 s/4.2 s）和高循环稳定性.基于V2O5/TiO2薄膜设计了电致变色储能器件,通过颜色叠加器件显示出6种颜色的变化:深橙色、沙黄色、绿黄色、黄绿色、深绿色和深棕色.通过分割薄膜使电致变色和离子存储层交错显示制备了信息显示电致变色器件,不同的颜色组合可呈现11种类型的信息.本文中基于V2O5/TiO2薄膜的多功能电致变色器件可应用于伪装、信息显示以及能量可视化监测等领域.

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