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Influence of pore structure heterogeneity on channeling channels during hot water flooding in heavy oil reservoir based on CT scanning

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Petroleum Science 2024年第4期21卷 2407-2419页

作者： Qing-Jun Du Hao-Yu Zheng Jian Hou Yong-Ge Liu Jian-Fang Sun Dong Zhao State Key laboratory of Deep oil and Gas China University of Petroleum (East China) School of Petroleum Engineering China University of Petroleum (East China) laboratory for Marine Mineral Resources Qingdao National Laboratory for Marine Science and Technology Petroleum Exploration and Production Research Institute

Hot water flooding is an effective way to develop heavy oil reservoirs. However, local channeling channels may form, possibly leading to a low thermal utilization efficiency and high water cut in the reservoir. The pore structure heterogeneity is an important factor in forming these channels. This study proposes a method that mixes quartz sand with different particle sizes to prepare weakly heterogeneous and strongly heterogeneous models through which hot water flooding experiments are *** the experiments, computer tomography(CT) scanning identifies the pore structure and micro remaining oil saturation distribution to analyze the influence of the pore structure heterogeneity on the channeling channels. The oil saturation reduction and average pore size are divided into three levels to quantitatively describe the relationship between the channeling channel distribution and pore structure heterogeneity. The zone where oil saturation reduction exceeds 20% is defined as a channeling *** scanning area is divided into 180 equally sized zones based on the CT scanning images, and threedimensional(3D) distributions of the channeling channels are developed. Four micro remaining oil distribution patterns are proposed, and the morphology characteristics of micro remaining oil inside and outside the channeling channels are analyzed. The results show that hot water flooding is more balanced in the weakly heterogeneous model, and the oil saturation decreases by more than 20% in most zones without narrow channeling channels forming. In the strongly heterogeneous model, hot water flooding is unbalanced, and three narrow channeling channels of different lengths form. In the weakly heterogeneous model, the oil saturation reduction is greater in zones with larger pores. The distribution range of the average pore size is larger in the strongly heterogeneous model. The network remaining oil inside the channeling channels is less than outside the channeling channels,

关键词： Heavy oil Hot water flooding Pore structure Channeling channels CT scanning

Quantitative characterizations of anisotropic dynamic properties in organic-rich shale with different kerogen content

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Petroleum Science 2024年第2期21卷 855-865页

作者： Jian-Yong Xie Yan-Ping Fang Xing-Hua Wu Jian'er Zhao Jun-Cheng Dai Jun-Xing Cao Ji-Xin Deng State Key laboratory of oil and Gas Reservoir Geology and Exploitation Chengdu University of TechnologyChengdu610059SichuanChina Key Lab of Earth Exploration&Information Techniques of Ministry of Education Geophysical InstituteChengdu University of TechnologyChengdu610059SichuanChina PetroChina Southwest oil&Gasfield Company Chengdu610017SichuanChina

Understanding the quantitative responses of anisotropic dynamic properties in organic-rich shale with different kerogen content(KC)is of great significance in hydrocarbon exploration and *** controlled experiments with a single variable is challenging for natural shales due to their high variations in components,diagenesis conditions,or pore *** employed the hot-pressing technique to construct 11 well-controlled artificial shale with varying *** artificial shale samples were successive machined into prismatic shape for ultrasonic measurements along different *** revealed bedding perpendicular P-wave velocities are more sensitive to the increasing KC than bedding paralleling velocities due to the preferential alignments of *** elastic stiffnesses except C_(13)are generally decreasing with the increasing KC,the variation of C_(1) and C_(33)on kerogen content are more sensitive than those of C_(44)and C_(66).Apparent dynamic mechanical parameters(v and E)were found to have linear correlation with the true ones from complete anisotropic equations independent of KC,which hold value towards the interpretation of well logs consistently across formations,Anisotropic mechanical parameters(ΔE and brittlenessΔB)tend to decrease with the reducing KC,withΔB showing great sensitivity to KC *** the range of low KC(10%)shale,compilation of data from natural organic rich-shales globally verified the similar systematic relationships that can be empirically used to predict the fraction of KC in shales.

关键词： Elastic properties Organic shale Anisotropy Kerogen content Physical modeling

Integrated wellbore-reservoir-geomechanics modeling for enhanced interpretation of distributed fiber-optic strain sensing data in hydraulicfracture analysis

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第8期16卷 3136-3148页

作者： Lijun Liu Xinglin Guo Xiaoguang Wang State Key laboratory of Geohazard Prevention and Geoenvironment Protection Chengdu University of TechnologyChengdu610059China Tianfu Yongxing laboratory Chengdu610213China College of Energy Chengdu University of TechnologyChengdu610059China State Key laboratory of oil and Gas Reservoir Geology and Exploitation Chengdu610059China

Fiber-optic distributed strain sensing(FO-DSS)has been successful in monitoring strain changes along horizontal wellbores in hydraulically fractured ***,the mechanism driving the various FO-DSS responses associated with near-wellbore hydraulic fracture properties is still *** address this knowledge gap,we use coupled wellbore-reservoir-geomechanics simulations to study measured strain-change behavior and infer hydraulic fracture *** crossflow among fractures is captured through explicit modeling of the transient wellbore *** addition,local grid refinement is applied to accurately capture strain changes along the fiber.A Base Case model was designed with four fractures of varying properties,simulating strain change signals when the production well is shut-in for 10 d after 240 d of production and reopened for 2 ***-pressure plots for different fracture clusters were used to gain insights into inferring fracture properties using DSS *** comparing the model with and without the wellbore,distinct strain change signals were observed,emphasizing the importance of incorporating the wellbore in FO-DSS *** effects of fracture spacing and matrix permeability on strain change signals were thoroughly *** results of our numerical study can improve the understanding of the relation between DSS signals and fracture hydraulic properties,thus maximizing the value of the dataset for fracture diagnostics and characterization.

关键词： Distributed strain sensing Fracture diagnostic Coupled flow and geomechanics Transient wellbore flow

Highly efficient CO_(2) capture using 2-methylimidazole aqueous solution on laboratory and pilot-scale

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Chinese Journal of Chemical Engineering 2024年第3期67卷 148-156页

作者： Kun Li Han Tang Shuangshuang Li Zixuan Huang Bei Liu Chun Deng Changyu Sun Guangjin Chen State Key laboratory of Heavy oil Processing China University of PetroleumBeijing 102249China Zhejiang Tiandi Environmental Protection technology Co. Ltd.Hangzhou 310012China

To date,the primary industrial carbon capture approach is still absorption using aqueous solutions of ***,to pursue a substitute for the amine-based approach to improve the CO_(2) capture efficiency and decrease the energy cost further,we report a new carbon capture approach using a 2-methylimidazole(mIm)aqueous *** properties and sorption behaviors of this approach have been experimentally *** results show that the mIm solution has higher CO_(2) absorption capacity under relatively higher equilibrium pressure(>130 kPa)and lower desorption heat than the methyldiethanolamine solution.91.6%sorption capacity of mIm solution can be recovered at 353.15 K and 80 *** selectivity for CO_(2)/N_(2) and CO_(2)/CH_(4) can reach an exceptional 7609 and 4324,***,the pilot-scale tests were also performed,and the results demonstrate that more than 98%of CO_(2) in the feed gas could be removed and cyclic absorption capacity can reach 1 mol·L^(-1).This work indicates that mIm is an excellent alternative to alkanolamines for carbon capture in the industry.

关键词： CO_(2) capture Absorption 2-Methylimidazole Separation Pilot-scale tests

Impacts of proppant distribution on development of tight oil reservoirs with threshold pressure gradient

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Petroleum Science 2024年第1期21卷 445-457页

作者： Ming Yue Wei-Yao Zhu Fei-Fei Gou Tian-Ru Song Yu-Chun You Qi-Tao Zhang State Key laboratory of Shale oil and Gas Enrichment Mechanisms and Effective Development Beijing102206China School of Civil and Resource Engineering University of Science and Technology BeijingBeijing100083China

Field evidence indicates that proppant distribution and threshold pressure gradient have great impacts on well *** at the development of unconventional oil reservoirs in Triassic Chang-7 Unit,Ordos Basin of China,we presented an integrated workflow to investigate how(1)proppant placement in induced fracture and(2)non-linear flow in reservoir matrix would affect well productivity and fluid flow in the *** with our research before(Yue et al.,2020),here we extended this study into the development of multi-stage fractured horizontal wells(MFHWs)with large-scale complicated fracture *** integrated workflow is based on the finite element method and consists of simulation models for proppant-laden fluid flow,fracture flow,and non-linear seepage flow,*** results indicate that the distribution of proppant inside the induced cracks significantly affects the productivity of the *** we assign an idealized proppant distribution instead of the real distribution,there will be an overestimation of 44.98%in daily oil rate and 30.63%in cumulative oil production after continuous development of 1000 ***,threshold pressure gradient(TPG)also significantly affects the well performance in tight oil *** we simply apply linear Darcy’s law to the reservoir matrix,the overall cumulative oil production can be overrated by 77%after 1000 days of *** general,this research provides new insights into the development of tight oil reservoirs with TPG and meanwhile reveals the significance of proppant distribution and non-linear fluid flow in the production scenario design.

关键词： Proppant distribution Tight oil reservoir Multi-stage fractured horizontal well Threshold pressure gradient Moving boundary

Enhanced gas production and CO_(2) storage in hydrate-bearing sediments via pre-depressurization and rapid CO_(2) injection

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Chinese Journal of Chemical Engineering 2024年第3期67卷 126-134页

作者： Hongnan Chen Yifei Sun Bojian Cao Minglong Wang Ming Wang Jinrong Zhong Changyu Sun Guangjin Chen State Key laboratory of Heavy oil Processing China University of PetroleumBeijing 102249China School of Chemistry and Chemical Engineering Changsha University of Science&TechnologyChangsha 410114China

Carbon emission reduction and clean energy development are urgent demands for mankind in the coming *** an efficient CO_(2) storage method can significantly reduce CO_(2) emissions in the short *** this study,we attempted to construct sediment samples with different residual CH_(4) hydrate amounts and reservoir conditions,and then investigate the potentials of both CO_(2) storage and enhanced CH_(4) recovery in depleted gas hydrate deposits in the permafrost and ocean zones,*** results demonstrate that CO_(2) hydrate formation rate can be significantly improved due to the presence of residual hydrate seeds;However,excessive residual hydrates in turn lead to the decrease in CO_(2) storage *** by the T-P conditions of the reservoir,the storage amount of liquid CO_(2) can reach 8 times that of gaseous CO_(2),and CO_(2) stored in hydrate form reaches 2-4 ***,we noticed two other advantages of this *** is that CO_(2) injection can enhance CH_(4) recovery rate and increases CH_(4) recovery by 10%-20%.The second is that hydrate saturation in the reservoir can be restored to 20%-40%,which means that the solid volume of the reservoir avoids serious ***,this is crucial for protecting the goaf *** summary,this approach is greatly promising for high-efficient CO_(2) storage and safe exploitation of gas hydrate.

关键词： Hydrate Depressurization CO_(2) storage CH_(4) production Reservoir remediation

The formation and evolutionary characteristics of organic matter and pyrites in the continental shales of the 3^(rd)submember of Chang 7 Member,Yanchang formation,Ordos Basin,China

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Energy Geoscience 2024年第2期5卷 31-39页

作者： Ruikang Bian State Key laboratory of Shale oil and Gas Enrichment Mechanisms and Effective Development Beijing 102206China Key laboratory of Shale oil and Gas Exploration&Production technology SinopecBeijing 102206China SINOPEC Exploration&Production Research Institute Beijing102206China

Through microscopic analyses(e.g.,organic macerals,thin section observation,scanning electron microscope(SEM)imaging of fresh bedding planes via argon ion milling,and energy spectrum tests)combined with Rock-Eval analyses,this study systematically investigated the organic matter and pyrites in the continental shales in the 3^(rd)submember of the Chang 7 Member(Chang 7^(3)submember)in the Yanchang Formation,Ordos Basin and determined their types and the formation and evolutionary *** results are as *** organic matter of the continental shales in the Chang 7^(3)submember is dominated by amorphous bituminites and migrabitumens,which have come into being since the early diagenetic stage and middle diagenetic stage A,*** formation and transformation of organic matter is a prerequisite for the formation of *** Ordos Basin was a continental freshwater lacustrine basin and lacked sulphates in waters during the deposition of the Chang 7 ***,the syndiagenetic stage did not witness the formation of large quantities of *** the basin entered early diagenetic stage A,large quantities of sulfur ions were released as the primary organic matter got converted into bituminites and,accordingly,pyrites started to ***,this stage featured poorer fluid and spatial conditions compared with the syndepositional stage due to withdraw of water,the partial formation of bituminites,and a certain degree of *** a result,large quantities of pyrrhotite failed to transition into typical spherical framboidal pyrites but grew into euhedral monocrystal *** addition,pyrites are still visible in the migrabitumens in both microfractures and inorganic pores of mudstones and shales,indicating that the pyrite formation period can extend until the middle diagenetic stage A.

关键词： Organic matter Pyrite Formation and evolution Continental shale Chang 7^(3)submember Ordos Basin

Rheological study of methane gas hydrates in the presence of micron-sized sand particles

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Chinese Journal of Chemical Engineering 2024年第6期70卷 149-161页

作者： Bohui Shi Shangfei Song Yuchuan Chen Shunkang Fu Lihao Liu Xinyao Yang Haihao Wu Guangjin Chen Jing Gong National Engineering Research Center of oil and Gas Pipeline Transportation Safety MOE Key Laboratory of Petroleum EngineeringBeijing Key Laboratory of Urban Oil and Gas Distribution TechnologyChina University of Petroleum-BeijingBeijing 102249China China's oil and Gas Exploration and Development Company(CNODC) Beijing 100034China China National Petroleum Corporation Mozambique LDA MaputoMozambique PipeChina West East Pipeline Company Shanghai 200122China

Natural gas hydrates,intricate crystalline structures formed by water molecules and small gas molecules,have emerged as a significant and globally impactful clean energy ***,their commercial exploitation faces challenges,particularly operational disruptions caused by sand-related *** the rheological properties of hydrate slurry,especially in the presence of micron-sized sand particles,is imperative for ensuring the flow assurance of subsea hydrate *** study extensively investigates the rheological properties of sand-containing hydrate *** findings reveal that these slurries exhibit non-Newtonian fluid characteristics,including yield stress,thixotropy,and shear-thinning ***-like elastic features are observed in sand-containing hydrate slurries before yielding,transitioning to viscous behavior after *** with a minimal amount of sand,both static yield stress and yield strain experience substantial changes,correlating with the increase in sand *** research conclusively establishes the thixotropic nature of sand-hydrate slurries,where the viscosity decay rate is directly influenced by the shear *** insights aim to contribute comprehensively to the development of effective flow assurance strategies,ensuring the safe and stable operation of subsea hydrate exploitation.

关键词： Natural gas hydrate production Sand-containing hydrate slurries Yield stress Thixotropy Shear-thinning behavior

Key geological factors governing sweet spots in the Wufeng-Longmaxi shales of the Sichuan Basin,China

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Energy Geoscience 2024年第3期5卷 163-174页

作者： Zongquan Hu Zengqin Liu Wei Du Zhenrui Bai Ruyue Wang Chuanxiang Sun Dongjun Feng State Key laboratory of Shale oil and Gas Enrichment Mechanisms and Effective Development SINOPECBeijing102206China Key laboratory of Shale oil/Gas Exploration and Production technology SINOPECBeijing102206China Petroleum Exploration and Production Research Institute SINOPECBeijing102206China

Production performance of the Wufeng-Longmaxi shales varies significantly among Fuling,Weirong,and Wulong fields in the Sichuan *** organic carbon(TOC)content,mineralogy,and organic matter(OM)pore characteristics are investigated to identify key factors governing sweet *** shales with good preservation conditions in the Fuling Field exhibit large thickness,high TOC content and thin-section porosity(TSP),and well-developed OM macropores,thus high initial production and estimated ultimate recovery(EUR).Thin carbonate-containing siliceous shales with good preservation conditions in the Weirong Field feature medium-to-high TOC and well-developed OM macropores but low TSP,leading to high initial production but low *** shales with poor preservation conditions in the Wulong Field are characterized by large thickness,high TOC,low TSP and poorly-developed OM macropores,causing low initial production and *** sedimentary and preservation conditions are intrinsic decisive factors of sweet spots,as they control the mineral composition,TOC,and OM macropore ***-water shales in transgressive systems tracts(TSTs)exhibit better-developed OM macropores and greater TOC compared to highstand systems tracts(HSTs).OM macropores are most prevalent in siliceous shales,followed by carbonate-containing siliceous shales and then argillaceous ***,good preservation conditions are conducive to retain OM macropores with low pore aspect ratio(PAR).Comparison among the three fields shows that high-TOC silicious shales with good preservation conditions are the highest in TSP and ***,organic richness,lithofacies,and preservation conditions are the major factors which determine OM pore development,governing the sweet spots of the Wufeng-Longmaxi shales.

关键词： Shale gas Organic matter pores Sweet spot Wufeng-Longmaxi shales Sichuan basin