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Multifunctional Nacre‑Like Nanocomposite Papers for Electromagnetic Interference Shielding via Heterocyclic Aramid/MXene Template‑Assisted In‑Situ Polypyrrole Assembly

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Nano-Micro Letters 2025年第3期17卷 37-54页

作者： Jinhua Xiong Xu Zhao Zonglin Liu He Chen Qian Yan Huanxin Lian Yunxiang Chen Qingyu Peng Xiaodong He National Key laboratory of Science and technology On Advanced composites in Special Environments Center for Composite Materials and StructuresHarbin Institute of TechnologyHarbin 150080People’s Republic of China

Robust, ultra-flexible, and multifunctional MXene-basedelectromagnetic interference (EMI) shielding nanocomposite filmsexhibit enormous potential for applications in artificial intelligence,wireless telecommunication, and portable/wearable electronic *** this work, a nacre-inspired multifunctional heterocyclic aramid(HA)/MXene@polypyrrole (PPy) (HMP) nanocomposite paper withlarge-scale, high strength, super toughness, and excellent tolerance tocomplex conditions is fabricated through the strategy of HA/MXenehydrogel template-assisted in-situ assembly of PPy. Benefiting from the"brick-and-mortar" layered structure and the strong hydrogen-bondinginteractions among MXene, HA, and PPy, the paper exhibits remarkable mechanical performances, including high tensile strength (309.7 MPa),outstanding toughness (57.6 MJ m−3), exceptional foldability, and structural stability against ultrasonication. By using the template effect ofHA/MXene to guide the assembly of conductive polymers, the synthesized paper obtains excellent electronic conductivity. More importantly,the highly continuous conductive path enables the nanocomposite paper to achieve a splendid EMI shielding effectiveness (EMI SE) of 54.1 dBat an ultra-thin thickness (25.4 μm) and a high specific EMI SE of 17,204.7 dB cm2g−1. In addition, the papers also have excellent applicationsin electromagnetic protection, electro-/photothermal de-icing, thermal therapy, and fire safety. These findings broaden the ideas for developinghigh-performance and multifunctional MXene-based films with enormous application potential in EMI shielding and thermal management.

关键词： MXene Remarkable mechanical properties Heterocyclic aramid Electromagnetic interference shielding Polypyrrole Multifunctionality

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Ballistic response mechanism and resistance-driven evaluation method of UHMWPE composite

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Defence technology(防务技术) 2025年第2期44卷 1-16页

作者： Yemao He Johnny Qing Zhou Yanan Jiao Hongshuai Lei Zeang Zhao Daining Fang Beijing Key laboratory of Lightweight Multi-functional composite Materials and Structures Beijing Institute of TechnologyBeijing 100081China Beijing Protech New Material Science Co. Ltd.Beijing 102200China School of Textile Science and Engineering Tiangong UniversityTianjin 300387China Key laboratory of Advanced Textile composite Materials Ministry of EducationInstitute of Textile Composite MaterialsTiangong UniversityTianjin 300387China

The use of ultra-high molecular weight polyethylene(UHMWPE)composite in the design of lightweight protective equipment,has gained a lot of ***,there is an urgent need to understand the ballistic response mechanism and theoretical prediction model of *** paper explores the ballistic response mechanism of UHMWPE composite through experimental and simulation ***,a resistance-driven modeling method was proposed to establish a theoretical model for predicting the bulletproof *** ballistic response mechanism of UHMWPE composite encompassed three fundamental modes:local response,structural response,and coupled *** occurrence ratio of these fundamental response modes during impact was dependent on the projectile velocity and laminate *** bulletproof performance of laminate under different response modes was assessed based on the penetration depth of the projectile,the bulging height on the rear face of the laminate,the thickness of remaining sub-laminate,and residual velocity of the *** absolute deviations of bulletproof performance indicator between theoretical value and experimental value were well within 11.13%,demonstrating that the established evaluation model possessed high degree of prediction accuracy.

关键词： UHMWPE composite Ballistic response mechanism Theoretical model Performance evaluation

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Controlled cationic ring-opening polymerization of L-lactide by organic ion pair:novel approach to isotactic-rich and crystalline polylactide

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Science China Chemistry 2025年第1期68卷 394-402页

作者： Zhiqiang Ding Mingqian Wang Zijing Zhou Bin Wang Yuesheng Li Tianjin Key laboratory of composite&Functional Materials School of Materials Science and EngineeringTianjin UniversityTianjin 300350China

Living/controlled cationic ring-opening polymerization(ROP)of L-lactide is a promising approach to isotactic-rich and crystalline poly(L-lactide).In contrast with the unsubstituted lactones,L-LA can not be polymerized by organic Lewis acids or carbenium ions,and the state of the art in this field is the cationic ROP of L-LA catalyzed by BrФnsted acid/alcohol system via activated monomer ***,we reported the first example of controlled cationic ROP of L-LA by using Meerweintype ion pair[Me_(3)O]^(+)[B(C_(6)F_(5))_(4)]^(-)as the catalyst.[Me_(3)O]^(+)[B(C_(6)F_(5))_(4)]^(-)promoted rapid L-LA cationic polymerization in the absence of alcohol,producing isotactic-rich and crystalline PLLA without transesterification and epimerization side *** activated chain end mechanism,involving twice S_(N)2 substitution and configuration-inversion(S→R→S)with the assistance of released Me_(2)O,was proposed and further verified by density functional theory and control *** work expands the catalytic toolbox of isotactic-rich and crystalline polylactide *** represents a unique example of cationic-controlled polymerization of L-LA catalyzed by an organic ion pair.

关键词： organic ion pair controlled cationic ring-opening polymerization activated chain end mechanism isotactic-rich poly-lactide

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Continuously adjustable mechanical metamaterial based on planetary gear trains and external meshing gears

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Applied Mathematics and Mechanics(English Edition) 2025年第2期46卷 233-252页

作者： Shuai MO Xu TANG Keren CHEN H. HOUJOH Wei ZHANG State Key laboratory of Featured Metal Materials and Life-cycle Safety for composite Structures School of Mechanical Engineering Guangxi University State Key laboratory of Precision Manufacturing for Extreme Service Performance Central South University State Key laboratory of Digital Manufacturing Equipment and technology Huazhong University of Science and Technology Precision and Intelligence laboratory Tokyo Institute of Technology

The metamaterial based on external meshing gears(MEG) is designed based on the principle of external meshing gear transmission. Based on the meshing transmission principle of external meshing gears and planetary gear trains, the internal and external gear rings are designed. Based on the internal and external gear rings, the metamaterial based on inner and outer planetary gear trains(MIP) is designed to study the shear modulus, Young's modulus, and amplitude-frequency characteristics of the metamaterial based on gears at different angles. The effects of the number of planetary gears on the physical characteristics of the MIP are studied. The results show that the MEG can be continuously adjusted by adjusting the shear modulus and Young's modulus due to its meshing characteristics. With the same number of gears, the adjustment range of the MIP is larger than the adjustment range of the MEG. When the number of planetary gears increases, the adjustment range of the MIP decreases. Moreover, when the metamaterial based on gears rotates, the harmonic response changes with the change of the angle.

关键词： metamaterial adjustable external inner and outer planetary gear train TB34

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Understanding excitonic behavior and electroluminescence light emitting diode application of carbon dots

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Chinese Chemical Letters 2025年第2期36卷 201-206页

作者： Yuan Liu Boyang Wang Yaxin Li Weidong Li Siyu Lu School of Chemistry and Chemical Engineering Henan University of Technology College of Chemistry Zhengzhou University College of Material Engineering Henan International Joint Laboratory of Rare Earth Composite MaterialsHenan University of Engineering

Carbon dots (CDs),due to their low cost,high stability,and high luminous efficiency,have emerged as an excellent material for the emissive layer in next-generation electroluminescent light-emitting diodes(ELEDs).However,improving the efficiency of fluorescent CDs-based ELEDs remains challenging,primarily because it is difficult to utilize triplet excitons in the electroluminescence ***,enhancing the exciton utilization efficiency of CDs during electroluminescence is *** on this,we exploited the characteristic large exciton binding energy commonly found in CDs to develop exciton-emitting *** CDs facilitate the radiative recombination of excitons during electroluminescence,thereby improving the electroluminescent *** rationally selecting precursors,we developed high quantum efficiency CDs and subsequently constructed CDs-based *** blue-light device exhibited an external quantum efficiency of over 4%.This study introduces a novel design concept for CDs,providing a new strategy for developing high-performance blue ELEDs based on CDs.

关键词： Carbon dots Controllable preparation Electroluminescence Exciton emission Light-emitting diodes

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Structure-phase transformation of bismuth oxide to Ta-Bi_(24)O_(31)Cl_(10)shoulder-by-shoulder heterojunctions for efficient photocatalytic removal of antibiotic

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Journal of Environmental Sciences 2025年第3期149卷 149-163页

作者： Man Yang Zhenzhen Shi Shaodong Sun Bian Yang Jie Cui Jianing Li Daqin Yun Nian Lei Engineering Research Center of Conducting Materials and composite technology Ministry of EducationShaanxi Engineering Research Center of Metal-Based Heterogeneous Materials and Advanced Manufacturing TechnologyShaanxi Province Key Laboratory for Electrical Materials and Infiltration TechnologySchool of Materials Science and EngineeringXi’an University of TechnologyXi’an 710048China College of Energy Xiamen UniversityXiamen 361005China Beijing Key laboratory of Ionic Liquids Clean Process Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China

Developing heterojunction photocatalyst with well-matched interfaces andmultiple charge transfer paths is vital to boost carrier separation efficiency for photocatalytic antibiotics removal,but still remains a great *** present work,a new strategy of chloride anion intercalation in Bi_(2)O_(3)via one-pot hydrothermal process is *** as-prepared Ta-bioCl/Bi_(24)O_(31)Cl_(10)(TBB)heterojunctions are featured with Ta-Bi_(24)O_(31)Cl_(10)and Ta-bioCl lined shoulder-by-shouleder via semi-coherent *** this TBB heterojunctions,the well-matched semi-coherent interfaces and shoulder-by-shoulder structures provide fast electron transfer andmultiple transfer paths,respectively,leading to enhanced visible light response and improved photogenerated charge ***,a type-II heterojunction for photocharge separation has been obtained,in which photogenerated electrons are drove from the CB(conduction band)of Ta-Bi_(24)O_(31)Cl_(10)to the both of bilateral empty CB of Ta-bioCl and gathered on the CB of Ta-bioCl,while the photogenerated holes are left on the VB(valence band)of Ta-Bi_(24)O_(31)Cl_(10),effectively hindering the recombination of photogenerated electron-hole ***,the separated electrons can effectively activate dissolved oxygen for the generation of reactive oxygen species(·O_(2)^(−)).Such TBB heterojunctions exhibit remarkably superior photocatalytic degradation activity for tetracycline hydrochloride(TCH)solution to Bi_(2)O_(3),Ta-bioCl and Ta-Bi_(24)O_(31)Cl_(10).This work not only proposes a Ta-bioCl/Bi_(24)O_(31)Cl_(10)shoulder-by-shoulder micro-ribbon architectures with semi-coherent interfaces and successive type-Ⅱheterojunction for highly efficient photocatalytic activity,but offers a new insight into the design of highly efficient heterojunction through phasestructure synergistic transformation strategy.

关键词： Heterojunction Bismuth oxide Charge separation/transfer Photocatalytic degradation Catalytic mechanism

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Fabrication and high temperature electrical conductivity of polymer-derived SiHfBCN ceramic coating

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Journal of Advanced Ceramics 2025年第1期14卷 141-149页

作者： Xichao Dong Qinghua Zhao Yao Li Shaomin Gu Xinming Xu Dianwei He Fang Ye Laifei Cheng Xingang Luan Zhaoju Yu Science and technology on Thermostructural composite Materials laboratory Northwestern Polytechnical UniversityXi’anShaanxi 710072China College of Materials Key Laboratory of High-Performance Ceramic Fibers(Xiamen University)Ministry of EducationXiamen 361005China College of Materials Xiamen Key Laboratory of Electronic Ceramic Materials and DevicesXiamen UniversityXiamen 361005China

Wireless surface acoustic wave(SAW)sensors hold great promise for in-situ,real-time monitoring and accurately assessing the health status of hot-end ***,the thin-film electrode as the SAW sensor core unit with excellent high-temperature conductivity,stability,and oxidation resistance is still a challenge,especially in harsh ultra-high-temperature *** this study,we employed a polymer-derived ceramic approach to fabricate smooth and dense SiHfBCN ceramic coatings on YCa4O(BO3)3/BN *** composition,microstructural evolution,and room-temperature and high-temperature electrical conductivity of SiHfBCN ceramic coatings were investigated to reveal the mechanism for controlling electrical *** results indicate that the electrical conductivity of the SiHfBCN ceramic coating pyrolyzed at a lower temperature of 1200℃reaches an impressive high value of 291.55 S·m−¹at 1200℃in ***,the results also demonstrate that the coating has remarkable high-temperature conductivity and excellent repeatability and ***,the typical semiconducting behavior of SiHfBCN ceramic coatings highlights their potential as thin-film electrodes for SAW high-temperature sensors in high-temperature extreme environments.

关键词： SiHfBCN coating polymer-derived ceramics high-temperatureelectrical conductivity

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Atomic cerium-doped CuO_(x) catalysts for efficient electrocatalytic CO_(2) reduction to CH_(4)

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Chinese Chemical Letters 2025年第1期36卷 326-331页

作者： Xiangyu Chen Aihao Xu Dong Wei Fang Huang Junjie Ma Huibing He Jing Xu Guangxi Key laboratory of Petrochemical Resource Processing and Process Intensification technology School of Chemistry and Chemical EngineeringGuangxi UniversityNanning 530004China State Key laboratory of Featured Metal Materials and Life-cycle Safety for composite Structures Guangxi UniversityNanning 530004China State Key laboratory of Green Chemical Engineering and Industrial Catalysis School of Chemical EngineeringEast China University of Science and TechnologyShanghai 200237China

Copper(Cu)is widely used in the electrochemical carbon dioxide reduction reaction(ECO_(2)RR)for efficient methane(CH_(4))***,the morphology and valence of Cu-based catalysts are usually unstable under reaction *** this work,we prepared Ce-doped MOF-199 precursor(Ce/HKUST-1)and further obtained nanoparticle electrocatalyst Ce/CuO_(x)-NPs by cyclic voltammetry(CV)*** Faradic efficiency of methane(FE_(CH_(4)))maintains above 62%within a broad potential window of 350 mV and the maximum FE_(CH_(4))reaches 67.4%with a partial current density of 293 mA/cm^(2)at-1.6 V vs.a reversible hydrogen *** characterization and theoretical calculations revealed that the unique electronic structure and large ionic radius of Cerium(Ce)not only promoted the generation of key intermediate*CO but also lowered energy barrier of the*CO to*CHO *** study provides a novel and efficient catalyst for methane production in ECO_(2)RR and offers profound insights into constructing high performance Cu-based catalysts.

关键词： ECO_(2)RR Cu-based catalyst Structure evolution DFT calculation

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Performance and electromagnetic mechanism of radar-and infraredcompatible stealth materials based on photonic crystals

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International Journal of Minerals,Metallurgy and Materials 2025年第3期32卷 710-717页

作者： Yanming Liu Xuan Yang Lixin Xuan Weiwei Men Xiao Wu Yuping Duan AVIC Research Institute for Special Structures of Aeronautical composite Ji’nan 250023China Aviation Key Lab of Science and technology on High Performance Electromagnetic Windows Ji’nan 250023China Key laboratory of Solidification Control and Digital Preparation technology(Liaoning Province) School of Materials Science and EngineeringDalian University of TechnologyDalian 116085China

Traditional stealth materials do not fulfill the requirements of high absorption for radar waves and low emissivity for infrared ***,they can be detected by various technologies,considerably threatening weapon ***,a stealth material compatible with radar and infrared was designed based on the photonic bandgap characteristics of photonic *** radar stealth lay-er(bottom layer)is a composite of carbonyl iron/silicon dioxide/epoxy resin,and the infrared stealth layer(top layer)is a 1D photonic crystal with alternately and periodically stacked germanium and silicon *** composition optimization and structural adjust-ment,the effective absorption bandwidth of the compatible stealth material with a reflection loss of less than-10 dB has reached 4.95 *** average infrared emissivity of the proposed design is 0.1063,indicating good stealth *** theoretical analysis proves that photonic crystals with this structural design can produce infrared waves within the photonic bandgap,achieving high radar wave transmittance and low infrared *** stealth is achieved without affecting the absorption performance of the radar stealth layer,and the conflict between radar and infrared stealth performance is *** work aims to promote the application of photonic crystals in compatible stealth materials and the development of stealth technology and to provide a design and theoretical found-ation for related experiments and research.

关键词： microwave absorption infrared stealth photonic crystal compatible stealth

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2D Plain and 3D Needle-punched C/SiC composites:Low-velocity Impact Damage Behavior and Failure Mechanism

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无机材料学报 2025年第2期40卷 205-214,I0004页

作者： LUAN Xingang HE Dianwei TU Jianyong CHENG Laifei Science and technology on Thermostructural composite Materials laboratory Northwestern Polytechnical UniversityXi’an 710072China Xi’an Golden Mountain Ceramic composites Co. Ltd.Xi’an 710118China

Continuous carbon fiber reinforced silicon carbide(C/SiC)composites are often subjected to low-velocity impacts when utilized as structural materials for thermal ***,research on in-plane impact damage and multiple impact damage of C/SiC composites is *** investigate the in-plane impact damage behavior of C/SiC composites,a drop-weight impact test method was developed for strip samples,and these results were subsequently compared with those of C/SiC composite *** show that the in-plane impact behavior of C/SiC strip samples is similar to that of C/SiC composite *** of the impact load with displacement is characterized by three stages:a nearly linear stage,a severe load drop stage,and a rebound stage where displacement occurs after the impact energy exceeds its peak *** damage behavior under single and multiple impacts on 2D plain and 3D needled C/SiC composites was investigated at different impact energies and *** propagation in C/SiC composites was studied by computerized tomography(CT)*** the 2D plain C/SiC composite,load propagation between layers is hindered during impact,leading to delamination and 90°fiber brittle *** crack length perpendicular to the impact direction increases with impact energy increases,resulting in more serious 0°fiber fracture and a larger area of fiber *** the 3D needled C/SiC composite,load propagates between the layers during impact through the connection of needled *** fibers continue to provide substantial structural support,with notable instances of fiber pull-off and ***,the impact resistance is superior to that of 2D plain C/SiC *** the 3D needled C/SiC composite undergoes two successive impacts of 1.5 J,the energy absorption efficiency of the second impact is significantly lower,accompanied by a smaller impact ***,the total energy absorption efficiency of these two impacts of 1.5 J is lowe

关键词： ceramic-matrix composite fracture low-velocity impact computerized tomography analysis

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