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Chinese Chemical Letters 2024年第8期35卷 282-287页

作者： Zhirong Yang Shan Wang Ming Jiang Gengchen Li Long Li Fangzhi Peng Zhihui Shao key laboratory of Medicinal Chemistry for Natural resource Ministry of EducationSchool of Chemical Science and TechnologyYunnan Provincial Center for Research&Development of Natural Productsand State Key Laboratory for Conservation and Utilization of Bio-Resources in YunnanYunnan UniversityKunming 650091China

The development of low-cost,earth-abundant and environmentally benign transition metal catalysts,which can catalyze multiple different types of asymmetric reactions,is an important objective in mod-ern asymmetric *** we demonstrate that a chiral Ni/P-Phos catalyst achieves three types of asymmetric reactions:allenylic substitution of racemic allenic ethers,1,4-hydroalkylation of prochiral 1,3-enynes and double alkylation of newly designed enynyl ether *** methods complement each other and produce various axially chiral allene derivatives bearing a pyrazolidine-3,5-dione unit,which is widely present in drugs and biologically active molecules with versatile pharmacological activities.

关键词： Nickel Asymmetric catalysis Allenylic substitution Hydroalkylation Double alkylation Allene 1,3-Enyne Pyrazolidine-3,5-dione

Ionization Engineering of Hydrogels Enables Highly Efficient Salt‑Impeded Solar Evaporation and Night‑Time Electricity Harvesting

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Nano-Micro Letters 2024年第1期16卷 131-146页

作者： Nan He Haonan Wang Haotian Zhang Bo Jiang Dawei Tang Lin Li School of Energy and Power Engineering Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of EducationDalian University of TechnologyDalian 116024People’s Republic of China

Interfacial solar evaporation holds immense potential for brine desalination with low carbon footprints and high energy ***,as a tunable material platform from the molecular level to the macroscopic scale,have been considered the most promising candidate for solar ***,the simultaneous achievement of high evaporation efficiency and satisfactory tolerance to salt ions in brine remains a challenging scientific bottleneck,restricting the widespread ***,we report ionization engineering,which endows polymer chains of hydrogels with electronegativity for impeding salt ions and activating water molecules,fundamentally overcoming the hydrogel salt-impeded challenge and dramatically expediting water evaporating in *** sodium dodecyl benzene sulfonate-modified carbon black is chosen as the solar *** hydrogel reaches a ground-breaking evaporation rate of 2.9 kg m−2 h−1 in 20 wt%brine with 95.6%efficiency under one sun irradiation,surpassing most of the reported *** notably,such a hydrogel-based evaporator enables extracting clean water from oversaturated salt solutions and maintains durability under different high-strength deformation or a 15-day continuous ***,on the basis of the cation selectivity induced by the electronegativity,we first propose an all-day system that evaporates during the day and generates salinity-gradient electricity using waste-evaporated brine at night,anticipating pioneer a new opportunity for all-day resource-generating systems in fields of freshwater and electricity.

关键词： Solar evaporation Hydrogel evaporators Salt impeding Ionization engineering Cyclic vapor-electricity generation

Evolution and conservation genetics of pangolins

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Integrative Zoology 2024年第3期19卷 426-441页

作者： Tongtong GU Jingyang HU Li YU State key laboratory for conservation and utilization of Bio-resource in Yunnan School of Life SciencesYunnan UniversityKunmingChina

Pangolins(Pholidota,Manidae)are classified as an evolutionarily distinct and globally endangered mammal due to their unique morphology(nail-like scales and a myrmecophagous diet)and being the victim of heavy poaching and worldwide *** such,pangolins serve as a textbook example for studying the special phenotypic evolutionary adaptations and conservation genetics of an endangered *** years have demonstrated significant advancements in the fields of molecular genetics and genomics,which have translated to a series of important research achievements and breakthroughs concerning the evolution and conservation genetics of *** review comprehensively presents the hitherto advances in phylogeny,adaptive evolution,conservation genetics,and conservation genomics that are related to pangolins,which will provide an ample understanding of their diversity,molecular adaptation mechanisms,and evolutionary *** addition,we highlight the priority of investigating species/population diversity among pangolins and suggest several avenues of research that are highly relevant for future pangolin conservation.

关键词： adaptive evolution conservation genetics conservation genomics pangolins phylogeny

Do nocturnal birds use acoustic and visual cues to avoid predation by bats?

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Integrative Zoology 2024年第3期19卷 524-537页

作者： Lixin GONG Huan WU Zhiqiang WANG Hui WU Jiang FENG Tinglei JIANG Jilin Provincial key laboratory of Animal resource conservation and utilization Northeast Normal UniversityChangchunChina key laboratory of Vegetation Ecology of education ministry Institute of Grassland ScienceNortheast Normal UniversityChangchunChina College of Life Science Jilin Agricultural UniversityChangchunChina

Anti-predation strategies are critical to animal survival and are fundamental to deciphering predator–prey *** an important defense strategy,sensory predator detection(such as through acoustic and visual cues)enables animals to assess predation risk and execute predator-avoidance behavior;however,there are limited studies on the anti-predation behavior of nocturnal *** prey of bats provides an excellent representative system for examining the anti-predation behavior of nocturnal ***,we broadcasted different types of echolocation calls of the bird-eating bat Ia io to two wild passerine birds,namely,Zosterops japonicus and Sinosuthora webbiana,that are preyed upon by ***,and presented the birds with individual bats under different light *** results showed that both bird species were able to perceive the low-frequency audible portion of the bats’echolocation calls;however,they did not exhibit escape responses to the acoustic *** the dark and under moonlit conditions,both bird species were unable to respond to active bats at close range and the birds only exhibited evasive flight behavior when bats approached or touched *** results suggest that nocturnal passerine birds may not be able to use acoustic or visual cues to detect bats and adopt evasive maneuvers to avoid *** work suggests that bat predation pressure may not elicit primary predator-avoidance responses in nocturnal passerine *** results provide new insights into the anti-predation behavior of nocturnal animals.

关键词： anti-predation behavior nocturnal animals sensory cues sensory defenses

Opportunities and challenges in studies of mammalian hybrid speciation

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Science China(Life Sciences) 2024年第3期67卷 614-617页

作者： Hong Wu Yuxing Zhang Li Yu State key laboratory for conservation and utilization of Bio-resource in Yunnan School of Life SciencesYunnan UniversityKunming 650091China

Revealing the mechanisms of speciation remains one of the most attractive and challenging issues in the field of evolutionary biology, and is also key to understanding the biodiversity present in nature.

关键词： biodiversity attractive evolutionary

Effects of Different Light Qualities on the Growth Characteristics of Populus trinervis

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Phyton-International Journal of Experimental Botany 2024年第5期93卷 1043-1056页

作者： Jiaqi Li Zhensheng Qiao Dan Zong Chengzhong He key laboratory for Forest Genetics and Tree Improvement and Propagation in Universities of Yunnan Province Southwest Forestry UniversityKunmingChina key laboratory of Biodiversity conservation in Southwest China State Forestry AdministrationSouthwest Forestry UniversityKunmingChina key laboratory for Forestry resources conservation and utilization in the Southwest Mountains of China Ministry of EducationSouthwest Forestry UniversityKunmingChina

Populus trinervis is native to China and plays an irreplaceable role in maintaining the ecological balance of boreal and temperate *** mainly grows in high-altitude *** present,there are limited studies on the response of *** to different light qualities,so it is necessary to investigate the photosynthetic physiological changes of *** in different light *** our study,*** was grown for 8 months under light filtered by three different colored *** three treatments were blue film,green film,and white plastic *** effects of blue(B),green(G),and white(W)light on photosynthetic pigment content,absolute growth,photosynthetic parameters,soluble sugar content,and chlorophyll fluorescence parameters were studied,*** to the Wtreatment,the chlorophyll a and b,carotenoids,total chlorophyll content(a+b),absolute growth of seedling height,net photosynthetic rate(PN),water use efficiency(WUE),total soluble sugars,sucrose,and nonphotochemical quenching(NPQ)of *** were significantly increased under B ***,chlorophyll a and b,carotenoids,total chlorophyll(a+b),transpiration rate(Tr),intercellular CO_(2) concentration(Ci),stomatal conductance(gs),absolute growth of seedling height and leaf length,reducing sugar,total soluble sugar content,and NPQ were significantly increased under G *** results showed that the absolute growth and chlorophyll content of *** were increased under B light,while the sugar and photosynthetic parameters were increased under G *** studies may look into how B light impacts absolute growth and promotional mechanisms,as well as how G light affects the accumulation of sugar levels.

关键词： Blue light green light white light photosynthetic pigment soluble sugar

Chemical defense mediates population density-driven on anuran brain size evolution

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Science China(Life Sciences) 2024年第5期67卷 1076-1078页

作者： Ying Jiang Lianju Yuan Wenbo Liao key laboratory of Southwest China Wildlife resources conservation(ministry of education) China West Normal UniversityNanchong 637009China key laboratory of Artificial Propagation and utilization in Anurans of Nanchong City China West Normal UniversityNanchong 637009China

Dear Editor,The evolutionary arms race between predator and prey is a strong selective force for producing a wide array of defense strategies in animals,including strong limbs,body armor,poisonousness,mimicry,or cryps... 详细信息

关键词： evolution size media

Stomatal dynamics are regulated by leaf hydraulic traits and guard cell anatomy in nine true mangrove species

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Plant Diversity 2024年第3期46卷 395-405页

作者： Ya-Dong Qie Qi-Wei Zhang Scott A.M.McAdam Kun-Fang Cao State key laboratory for conservation and utilization of Subtropical Agro-Bioresources College of ForestryGuangxi UniversityNanning 530004China Guangxi key laboratory of Forest Ecology and conservation College of ForestryGuangxi UniversityNanning 530004China key laboratory of Ecology of Rare and Endangered Species and Environmental Protection Ministry of EducationGuangxi Normal UniversityGuilin 541001China Guangxi key laboratory of Landscape resources conservation and Sustainable utilization in Lijiang River Basin Guangxi Normal UniversityGuilin 541001China Purdue Center for Plant Biology Department of Botany and Plant PathologyPurdue UniversityWest LafayetteIN 47907USA

Stomatal regulation is critical for mangroves to survive in the hyper-saline intertidal zone where water stress is severe and water availability is highly ***,very little is known about the stomatal sensitivity to vapour pressure deficit(VPD)in mangroves,and its co-ordination with stomatal morphology and leaf hydraulic *** measured the stomatal response to a step increase in VPD in situ,stomatal anatomy,leaf hydraulic vulnerability and pressure-volume traits in nine true mangrove species of five families and collected the data of genome *** aimed to answer two questions:(1)Does stomatal morphology influence stomatal dynamics in response to a high VPD in mangroves?with a consideration of possible influence of genome size on stomatal morphology;and(2)do leaf hydraulic traits influence stomatal sensitivity to VPD in mangroves?We found that the stomata of mangrove plants were highly sensitive to a step rise in VPD and the stomatal responses were directly affected by stomatal anatomy and hydraulic ***,denser stomata was correlated with faster stomatal closure at high VPD across the species of Rhizophoraceae,and stomata size negatively and vein density positively correlated with genome *** negative leaf osmotic pressure at the full turgor(πo)was related to higher operating steady-state stomatal conductance(gs);and a higher leaf capacitance(Cleaf)and more embolism resistant leaf xylem were associated with slower stomatal responses to an increase in *** addition,stomatal responsiveness to VPD was indirectly affected by leaf morphological traits,which were affected by site salinity and consequently leaf water *** results demonstrate that mangroves display a unique relationship between genome size,stomatal size and vein packing,and that stomatal responsiveness to VPD is regulated by leaf hydraulic traits and stomatal *** work provides a quantitative framework to better understand of stomatal regulation in mangroves

关键词： Stomatal temporal kinetics Vapour-pressure deficit(VPD) Leaf water relations Leaf hydraulic vulnerability Leaf osmotic potential Genome size

Dimethylamine oxalate manipulating CsPbI_(3) perovskite film crystallization process for high efficiency carbon electrode based perovskite solar cells

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Journal of Energy Chemistry 2024年第6期93卷 221-228,I0006页

作者： Wenran Wang Xin Peng Jianxin Zhang Jiage Lin Rong Huang Guizhi Zhang Huishi Guo Zhenxiao Pan Xinhua Zhong Huashang Rao key laboratory for Biobased Materials and Energy of ministry of education College of Materials and EnergySouth China Agricultural UniversityGuangzhou 510642GuangdongChina College of Chemistry and Civil Engineering Shaoguan UniversityShaoguan 512005GuangdongChina Guangdong Provincial key laboratory of utilization and conservation of Food and Medicinal resources in Northern Region Shaoguan UniversityShaoguan 512005GuangdongChina

Crystallization process determines the quality of perovskite films and the performances of resultant perovskite solar cells(PSCs).Dimethylamine oxalate has been proven as a multifunctional modulator,and is explored as an efficient additive in manipulating the crystallization process of CsPbI_(3) perovskite *** one hand,oxalate serves as the precipitator that facilitates the nucleation process of *** larger size of intermediate is conductive to the larger size and smaller grain boundaries of resultant *** the other hand,in subsequent annealing process,the phase conversion and growth process of transient perovskite can be decelerated due to the strong interactions of oxalate with both dimethylamine cation(DMA^(+))and Pb^(2+).Due to the optimized crystallization kinetics,the morphology and quality of CsPbI_(3) perovskite films are comprehensively improved with lower defect concentrations,and charge recombination loss is effectively *** from the optimized crystal quality of perovskite films,the carbon electrode-based CsPbI_(3) PSCs exhibit a champion efficiency of 18.48%.This represents one of the highest levels among all hole transport layer-free inorganic perovskite solar cells.

关键词： Solar cells Perovskite CsPbI_(3) Carbon electrodes Oxalate

Identification and functional characterization of female antennae-biased odorant receptor 23 involved in acetophenone detection of the Indian meal moth Plodia interpunctella

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Insect Science 2024年第1期31卷 59-78页

作者： Qi Chen Xiaoyan Zhu Guoqing Kang Qiling Yu Qingxin Liu Lin Du Yi Yang Xinyu He Ying Zhao Junjie Zhang Ying Hu Bingzhong Ren Jilin Provincial key laboratory of Animal resource conservation and utilization School of Life SciencesNortheast Normal UniversityChangchunChina key laboratory of Vegetation Ecology Ministry of EducationNortheast Normal UniversityChangchunChina Jilin Provincial Engineering laboratory of Avian Ecology and conservation Genetics Northeast Normal UniversityChangchunChina Engineering Research Center of Natural Enemies Institute of Biological ControlJilin Agricultural UniversityChangchunChina

The Indian meal moth,Plodia interpunctella(Lepidoptera:Pyralidae),a globally distributed storage pest,relies on odors that are emitted from stored foods to select a suitable substrate for ***,the molecular mechanism underlying the chemical communication between *** and its host remains *** this study,130 chemosensory genes were identified from the transcriptomes of 7 *** tissues,and the quantitative expression levels of all 56 *** odorant receptor genes(PintORs)were validated using real-time quantitative polymerase chain *** functional characteristics of 5 PintORs with female antennae-biased expression were investigated using 2-electrode voltage clamp recordings in Xenopus laevis ***23 was found to be specifically tuned to *** could elicit a significant electrophysiological response and only attracted mated females when compared with males and virgin *** addition,molecular docking predicted that the hydrogen bonding sites,TRP-335 and ALA-167,might play key roles in the binding of PintOR23 to *** study provides valuable insights into the olfactory mechanism of oviposition substrate detection and localization in *** and points toward the possibility of developing eco-friendly odorant agents to control pests of stored products.

关键词： acetophenone docking EAG odorant receptor Plodia interpunctella TEVC