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Reduced Macrophage Uptake of nanoparticles through Surface Modification of Polypeptides with Valine Residues

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Chinese Journal of Chemistry 2024年第11期42卷 1209-1216页

作者： Ning Li Shanshan Xiao Xiaoxiong Jin Ziyuan Song Institute of functional nano&Soft materials(FUNSOM) Jiangsu Key Laboratory for Carbon-Based Functional Materials and DevicesSoochow UniversitySuzhouJiangsu215123 China

The structural and surface properties of nanomedicines play an important role in determining their biological fate. Surface chemistry of nanomedicines is one of the key parameters, where researchers used various strategies such as PEGylation to avoid the undesired clearance of nanoparticles (NPs) for enhanced targeting effect. Nevertheless, the fine-tuning of surface chemistry through polymer functionalization remains largely unexplored. In this concise report, we find that the incorporation of only 10 mol% valine residues into the surface-anchored poly(L-glutamic acid) significantly lowered the macrophage uptake of NPs. The introduction of other hydrophobic amino acid residues, however, increased the NPs internalization instead. The chirality and the side-chain structure of valine played an important role in the unexpected uptake behavior. We believe this work highlights the impact of slight changes of the surface-anchored polymer structure on the behavior of NPs, drawing people's attention to the careful design of surface chemistry to optimize the nanomedicine design.

关键词： nanoparticles Copolymers Structure-activity relationships Surface chemistry Polypeptide Macrophage uptake

Dynamic response of a thermal transistor to time-varying signals

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Chinese Physics B 2024年第5期33卷 13-19页

作者：阮琴丽刘文君王雷 Department of Physics Beijing Key Laboratory of Opto-electronic Functional Materials and Micro-nano Devicesand Key Laboratory of Quantum State Construction and Manipulation (Ministry of Education)Renmin University of ChinaBeijing 100872China

Thermal transistor,the thermal analog of an electronic transistor,is one of the most important thermal devices for microscopic-scale heat *** is a three-terminal device,and the heat current flowing through two terminals can be largely controlled by the temperature of the third *** response plays an important role in the application of electric devices and also thermal devices,which represents the devices’ability to treat fast varying *** this paper,we systematically study two typical dynamic responses of a thermal transistor,i.e.,the response to a step-function input(a switching process)and the response to a square-wave *** role of the length L of the control segment is carefully *** is revealed that when L is increased,the performance of the thermal transistor worsens *** the relaxation time for the former process and the cutoff frequency for the latter one follow the power-law dependence on L quite well,which agrees with our analytical ***,the detailed power exponents deviate from the expected values *** implies the violation of the conventional assumptions that we adopt.

关键词： phonon phononics thermal transistor dynamic response heat conduction

Controlled fabrication of freestanding monolayer SiC by electron irradiation

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Chinese Physics B 2024年第8期33卷 31-37页

作者：笪蕴力罗瑞春雷宝季威周武 School of Physical Sciences University of Chinese Academy of SciencesBeijing 100049China Department of Physics and Beijing Key laboratory of Optoelectronic functional materials&micro-nano devices Renmin University of ChinaBeijing 100872China

The design and preparation of novel quantum materials with atomic precision are crucial for exploring new physics and for device *** irradiation has been demonstrated as an effective method for preparing novel quantum materials and quantum structures that could be challenging to obtain *** features the advantages of precise control over the patterning of such new materials and their integration with other materials with different ***,we present a new strategy for fabricating freestanding monolayer SiC within nanopores of a graphene *** regulating the energy of the incident electron beam and the in-situ heating temperature in a scanning transmission electron microscope(STEM),we can effectively control the patterning of nanopores and subsequent growth of monolayer SiC within the graphene *** resultant SiC monolayers seamlessly connect with the graphene lattice,forming a planar structure distinct by a wide direct *** in-situ STEM observations further uncover that the growth of monolayer SiC within the graphene nanopore is driven by a combination of bond rotation and atom extrusion,providing new insights into the atom-by-atom self-assembly of freestanding two-dimensional(2D)monolayers.

关键词： monolayer SiC 2D semiconductor in-situ growth in-situ STEM defect engineering graphene nanopores

Coexistence of Dirac and Weyl points in non-centrosymmetric semimetal NbIrTe_(4)

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Chinese Physics B 2024年第4期33卷 146-151页

作者：刘清馨付阳丁鹏飞马欢郭朋杰雷和畅王善才 Department of Physics Key Laboratory of Quantum State Construction and ManipulationRenmin University of ChinaBeijing 100872China Beijing Key laboratory of Opto-Electronic functional materials&micro-nano devices Renmin University of ChinaBeijing 100872China

Using angle-resolved photoemission spectroscopy and density functional theory calculations methods,we investigate the electronic structures and topological properties of ternary tellurides NbIrTe_(4),a candidate for type-II Weyl *** demonstrate the presence of several Fermi arcs connecting their corresponding Weyl points on both termination surfaces of the topological *** analysis reveals the existence of Dirac points,in addition to Weyl points,giving both theoretical and experimental evidences of the coexistence of Dirac and Weyl points in a single *** findings not only confirm NbIrTe_(4) as a unique topological semimetal but also open avenues for exploring novel electronic devices based on its coexisting Dirac and Weyl fermions.

关键词： Fermi arc Weyl point Dirac point angle-resolved photoemission spectroscopy

Semiclassical approach to spin dynamics of a ferromagnetic S = 1 chain

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Chinese Physics B 2024年第6期33卷 95-100页

作者：李承晨崔祎于伟强俞榕 Department of Physics and Beijing Key laboratory of Opto-electronic functional materials and micro-nano devices Renmin University of ChinaBeijing 100872China Key laboratory of Quantum State Construction and Manipulation(Ministry of Education) Renmin University of ChinaBeijing 100872China

Motivated by recent experimental progress on the quasi-one-dimensional quantum magnet Ni Nb2O6, we study the spin dynamics of an S = 1 ferromagnetic Heisenberg chain with single-ion anisotropy by using a semiclassical molecular dynamics approach. This system undergoes a quantum phase transition from a ferromagnetic to a paramagnetic state under a transverse magnetic field, and the magnetic response reflecting this transition is well described by our semiclassical *** show that at low temperature the transverse component of the dynamical structure factor depicts clearly the magnon dispersion, and the longitudinal component exhibits two continua associated with single-and two-magnon excitations,respectively. These spin excitation spectra show interesting temperature dependence as effects of magnon interactions. Our findings shed light on the experimental detection of spin excitations in a large class of quasi-one-dimensional magnets.

关键词： one-dimensional ferromagnetism spin dynamics magnon excitation molecular dynamics

Effects of water molecules on luminescence in europium and terbium coordination polymers with p-fluorobenzoic acid as ligand

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Journal of Rare Earths 2024年第7期42卷 1258-1264,I0003页

作者： Xiaoqi Zhao Puyan Hao Yami Ling Mengzhen Jia Rui Zhu Jiawen Liu Qiang Xu Jianhong Zhou Collaborative Innovation Center of Rare-Earth Optical functional materials and devices Development Baoji Key Laboratory of Micro-Nano Optoelectronics and Terahertz TechnologySchool of Physics and Opto-Electronic TechnologyBaoji University of Arts and SciencesBaoji721016China

Our previous experimental observations show that the crystal structure of lanthanide luminescent complexes synthesized in aqueous solution usually contains a large number of coordination water molecules or free water *** order to probe the influence of water molecules on luminescent processes of lanthanide complexes,the photoluminescence properties of Ln-FBA(Ln=Eu and Tb,FBA=p-fluorobenzoic acid)coordination polymers at different ambient temperatures,in different solvents and aqueous DMSO solutions with different volume concentrations were systematically *** experiment results show that the presence of water molecules can promote the energy transfer from FBA ligand to Ln3+,at the same time,can cause luminescent non-radiation quenching of lanthanide *** addition,the variation of emission intensity ratio of 615 nm/591 nm peaks of Eu^(3+)with increasing the volume concentration of H_(2)O can be potentially used for the quantitatively detection of water traces in organic *** order to suppress the non-radiation quenching caused by the water molecules,Ln-FBA(Ln=Eu and Tb)coordination polymers were embedded into the PVP matrix to prepare Ln-FBA@PVP hybrid *** photoluminescence investigation indicates that PVP can not only block the quenching effect of water molecules on luminescence,but also effectively sensitize Eu^(3+)and Tb^(3+)*** experimental conclusions are useful for probing the influence of water molecules on luminescent processes of lanthanide complexes,quantitatively detecting water traces in organic solvents and enhancing the photoluminescence intensity in lanthanide complexes.

关键词： Lanthanide complexes Photoluminescence Luminescent quenching Rare earths

Relationship between disorder,magnetism and band topology in Mn(Sb_(1-x)Bi_(x))_(2)Te_(4) single crystals

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Chinese Physics B 2024年第6期33卷 102-107页

作者：席明雷和畅 Department of Physics and Beijing Key laboratory of Opto-electronic functional materials&micro-nano devices Renmin University of ChinaBeijing 100872China Key laboratory of Quantum State Construction and Manipulation(Ministry of Education) Renmin University of ChinaBeijing 100872China

We investigate the evolution of magnetic properties as well as the content and distribution of Mn for Mn(Sb_(1-x)Bi_(x))_(2)Te_(4) single crystals grown by large-temperature-gradient chemical vapor transport *** is found that the ferromagnetic MnSb_(2)Te_(4) changes to antiferromagnetism with Bi doping when x≥*** analysis implies that the occupations of Mn ions at Sb/Bi site Mn_(Sb/Bi) and Mn site Mn_(Mn) have a strong influence on the magnetic ground states of these *** the decrease of Mn_(Mn) increase of Mn_(Sb/Bi),the system will favor the ferromagnetic ground *** addition,the rapid decrease of T_(C/N) with increasing Bi content when x ≤0.25 and the insensitivity of T_(N) to x when x> 0.25 suggest that the main magnetic interaction may change from the Ruderman-Kittel-Kasuya-Yosida type at low Bi doping region to the van-Vleck type in high Bi doped samples.

关键词： magnetic topological insulator magnetic properties antisite defects chemical vapor transport

Sulfonated carbon dots modified IrO_(2)nanosheet as durable and high-efficient electrocatalyst for boosting acidic oxygen evolution reaction

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nano Research 2024年第9期17卷 8017-8024页

作者： Mengjie Ma Wenxiang Zhu Fan Liao Kui Yin Hui Huang Kun Feng Dongdong Gao Jinxin Chen Zenan Li Jun Zhong Lai Xu Yang Liu Mingwang Shao Zhenhui Kang Institute of functional nano and Soft materials(FUNSOM) Jiangsu Key Laboratory for Carbon-based Functional Materials and DevicesSoochow UniversitySuzhou 215123China Macao Institute of materials Science and Engineering(MIMSE) Macao University of Science and TechnologyTaipaMacao 999078China

Oxygen evolution reaction(OER)plays a crucial role in developing energy conversion and adjusting electronic structure of the electrocatalysts can effectively improve the catalytic activity and ***,it is a challenge to adjust the electronic structure on two-dimensional iridium dioxide nanosheets(IrO_(2)NS),which have the advantages of high atom ***,we regulate the surface properties of IrO_(2)NS through sulfonated carbon dots(SCDs)to promote the OER catalytic *** catalyst IrO_(2)NS/SCDs-2 exhibited excellent catalytic activity with a lower overpotential of 180 mV than IrO_(2)NS(230 mV)at the current density of 10 mA·cm^(-2)in a 0.5 M H_(2)SO_(4) *** after 160 h of stability testing,the overpotential of IrO_(2)NS/SCDs-2 only decreased by 4 ***,transient potential scanning test can visually demonstrate that the addition of SCDs improves the conductivity of the catalyst and increases the electron transfer rate.

关键词： sulfonated carbon dots oxygen evolution reaction electrocatalysis transient potential scanning

Narrowband blue emitter based on fused nitrogen/carbonyl combination with external quantum efficiency approaching 30%

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Science China Chemistry 2024年第1期67卷 351-359页

作者： Long Chen Jia-Heng Cai You-Jun Yu Yang-Kun Qu Sheng-Yi Yang Sheng-Nan Zou Rui-Hong Liu Dong-Ying Zhou Liang-Sheng Liao Zuo-Quan Jiang Institute of functional nano&Soft materials(FUNSOM) Jiangsu Key Laboratory for Carbon-Based Functional Materials&DevicesSoochow UniversitySuzhou 215123China Macao Institute of materials Science and Engineering Macao University of Science and TechnologyMacao 999078China

Multi-resonance thermally activated delayed fluorescence(MR-TADF)emitters can enable narrowband emission with high color purity and electroluminescence ***/carbonyl(N/C=O)system is receiving increasing attention while the nitrogen/boron(N/B)system has been widely *** decoration is an effective approach for N/B type MR-TADF system but always leads to broadening and red-shifting of the emission band in N/C=O MR-TADF *** attribute these unfavorable phenomena to the formation of intramolecular charge transfer between the MR-core and peripheral *** address this issue,we have developed a new strategy by decorating DMQAO(a fused N/C=O MR-core)with a triazine acceptor and a neutral terphenyl group to construct MTDMQAO and MBDMQAO,*** introduction of the triazine acceptor not only realizes efficient narrowband emission in MTDMQAO,but also accelerates the reverse intersystem crossing process through enhanced spin-orbital *** a result,MTDMQAO exhibits a significantly higher external quantum efficiency of 29.4%compared to the referent emitters,validating the rationality of our derivation *** study highlights the potential of the N/C=O system for MR-TADF emitters and provides important insights for understanding the difference between N/B and N/C=O systems.

关键词： carbonyl group narrowband acceptor decoration thermally activated delayed fluorescence OLEDs