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Nano-Micro Letters 2025年第3期17卷 102-116页

作者： Xin Tang Hongsheng Jiang Zhengliang Lin Xuan Wang Wenliang Wang Guoqiang Li State Key laboratory of Luminescent materials and Devices South China University of TechnologyGuangzhou 510640People’s Republic of China Department of Electronic materials School of Materials Science and EngineeringSouth China University of TechnologyGuangzhou 510640People’s Republic of China

van der Waals(vdW)heterostructures constructed by lowdimensional(0D,1D,and 2D)materials are emerging as one of the most appealing systems in next-generation flexible ***,hand-stacked vdW-type photodetectors are not compatible with large-areaarray fabrication and show unimpressive performance in self-powered ***,vertical 1D GaN nanorods arrays(NRAs)/2D MoS_(2)/PEDOT:PSS in wafer scale have been proposed for self-powered flexible photodetectors arrays *** as-integrated device without external bias under weak UV illumination exhibits a competitive responsivity of 1.47 A W^(−1)and a high detectivity of 1.2×10^(11)Jones,as well as a fast response speed of 54/71μs,thanks to the strong light absorption of GaN NRAs and the efficient photogenerated carrier separation in type-II ***,the strain-tunable photodetection performances of device have been ***,the device at−0.78%strain and zero bias reveals a significantly enhanced photoresponse with a responsivity of 2.47 A W^(−1),a detectivity of 2.6×10^(11)Jones,and response times of 40/45μs,which are superior to the state-of-the-art self-powered flexible *** work presents a valuable avenue to prepare tunable vdWs heterostructures for self-powered flexible photodetection,which performs well in flexible sensors.

关键词： Vertical nanorod arrays van der Waals heterostructure Piezophototronic effect Self-powered photodetection Flexible sensors

Influence of heat treatment on microstructure of a newβ-solidifyingγ-TiAl alloy

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Journal of Iron and Steel Research International 2025年第1期32卷 239-248页

作者： Li Quan Xiao-bing Li Peng Xue Jun-jie Hao Kun Qian Bo Chen Jian-zhong Li Kui Liu School of Metallurgy Northeastern UniversityShenyang110819LiaoningChina Department of materials science and Technology Ji Hua LaboratoryFoshan528200GuangdongChina

The high strength and stability of the full-lamellar structure guarantee the industrial application of theβ-solidifyingγ-TiAl ***,it is a huge challenge to design an alloy with good hot-deformability as well as the full-lamellar *** low-cost Ti-42.5Al-2Mn-0.4Mo-0.1B-0.1C(at.%)alloy was designed,which undergoes bothβandαsingle-phase region during the *** is found that the full-lamellar structure can be obtained by the solution heat treatment at 1230℃ for 20 min and then aging treatment at 800℃ for 3 ***,a new microstructure,namely,the pearlitic-like microstructure(PM)induced by theα_(2)/γ→βo+γcellular reaction was observed when the aging temperature is increased to above 800℃.The volume fraction of the PM is gradually increased from 0%to 25.5%,65%,and 94%according to elevated aging temperature from 800 to 900,1000,and 1050℃,*** mechanism of the reducedα_(2)/γlamellae and PM formation was discussed regarding the heterogeneous distribution ofβstabilizing elements and the interface energy stored inα_(2)/γlamellae.

关键词： β-γ-TiAl Alloy design Two-step heat treatment Full-lamellar structure Cellular reaction

Near-perfect replication on amorphous alloys through active force modulation based on machine learning/neural network parameter prediction

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science China(Physics,Mechanics & Astronomy) 2025年第1期68卷 177-187页

作者： Senkuan Meng Zheng Wang Ruisong Zhu Ruijie Liu Jiang Ma Lina Hu Weihua Wang Key laboratory for Liquid-Solid Structural Evolution and Processing of materials(Ministry of Education) School of Materials Science and EngineeringShandong UniversityJinan 250061China College of Mechatronics and Control Engineering Shenzhen UniversityShenzhen 518060China Songshan Lake materials laboratory Dongguan 523808China Institute of Physics Chinese Academy of SciencesBeijing 100190China

As a microforming technique,micro/nano-structural replication possesses advantages of high precision and *** the remarkable superplasticity in the supercooled liquid region,amorphous alloys or metallic glasses(MGs)are regarded as ideal materials for miniature ***,due to the intrinsic metastable nature of supercooled liquids,the design of imprinting processes for MGs poses a *** the past,process parameters have largely relied on trial-and-error *** this work,a low-frequency active force modulation system is employed to apply a stable,precise,and real-time feedback stress field for imprinting of MG ***-frequency vibrations can facilitate the filling of microstructures on the template surface by reducing the effective viscosity of the supercooled *** the dataset composed of orthogonal experiments,a machine learning strategy based on back-propagation(BP)neural networks was utilized to construct a 3D parameter space for temperature,stress,and time,and to predict the corresponding filling ***,the optimal combination of imprinting process parameters was identified,and its filling ratio was experimentally validated to reach as high as *** near-perfect replication of microstructures confirms the superiority of the active force modulation system and the data-driven strategy of machine learning-assisted parameter *** the same time,this one-step microforming process provides a new approach to addressing the accuracy-cost trade-off dilemma in precision manufacturing.

关键词： metallic glass amorphous alloy microforming imprinting machine learning

Unraveling the impacts of intermolecular interaction on morphology evolution for highly efficient organic solar cells and modules

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science China Chemistry 2025年第1期68卷 264-272页

作者： Xueqing Ma Yingying Cheng Yuqiang Liu Xinming Zheng Guangliu Ran Hongxiang Li Xinyue Cui Andong Zhang Wenkai Zhang Pei Cheng Wenchao Huang Zhishan Bo Beijing Key laboratory of Energy Conversion and Storage materials College of ChemistryBeijing Normal UniversityBeijing 100875China College of Textiles and Clothing State Key Laboratory of Bio-fibers and Eco-textilesQingdao UniversityQingdao 266071China Key State laboratory of Advanced Technology for materials Synthesis and Processing School of Materials Science and EngineeringWuhan University of TechnologyWuhan 430070China Department of Physics and Applied Optics Beijing Area Major laboratory Center for Advanced Quantum StudiesBeijing Normal UniversityBeijing 100875China State Key laboratory of Polymer materials Engineering College of Polymer Science and EngineeringSichuan UniversityChengdu 610065China

Understanding the effect of intermolecular interaction on the growth dynamic of active layers is critical for advancing organic solar cells(OSCs).However,the diverse structure of donors and acceptors makes the research *** with customizable structures and properties could simplify this ***,we meticulously tailor two additives of 3,4-ethylenedioxythiophene(EDOT)and 2,5-dibromo-3,4-ethylenedioxythiophene(DBEDOT),possessing distinct intermolecular interaction features to elaborate the inherent *** is found that varied interaction strengths can alter film formation *** enhanced intermolecular interaction between the DBEDOT and non-fullerene acceptor BTP-e C9-4F results in pre-aggregation and longer crystallization duration of BTP-e C9-4F,facilitating the formation of films with compact molecular packing and decent phase ***,exciton dissociation and charge transport become more ***,devices processed with DBEDOT exhibit a remarkable power conversion efficiency of 19.35%in small-area OSCs and 14.11%in bladecoated 5 cm×5 cm organic solar ***,OSCs can maintain 80%of their initial efficiency after continuous annealing at 85℃for over 2,100 h.

关键词： organic solar cell non-fullerene acceptor film growth molecular packing intermolecular interaction

Robust free-base and metalated corrole radicals with reduction-induced emission

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Chinese Chemical Letters 2025年第2期36卷 426-431页

作者： Pengfei Li Chulin Qu Fan Wu Hu Gao Chengyan Zhao Yue Zhao Zhen Shen State Key laboratory of Coordination Chemistry Collaborative Innovation Center of Advanced MicrostructuresSchool of Chemistry and Chemical EngineeringNanjing University School of Chemistry and materials science Nanjing Normal University College of materials science and Engineering Nanjing Forestry University

Preparing free-base porphyrinoid radicals that can function as coordination ligands is a challenging task. Here we report the synthesis of a stable, free-base benzocorrole(BC) radical containing only two inner NH protons via a retro-Diels-Alder conversion. The radical character of BC was fully supported by crystallographic analysis, spectroscopic evidence, and theoretical calculations. This neutral radical ligand allowed easy insertion of Zn(Ⅱ), Ga(Ⅲ), and Pd(Ⅱ) ions to produce radical complexes. All these radicals exhibited luminescence-on responses under weak reducing atmosphere, corresponding to the conversion to their aromatic anions. The red fluorescence was observed for BC and its Zn(Ⅱ) and Ga(Ⅲ) complexes,and the near-infrared phosphorescence(>900 nm) was detected for Pd(Ⅱ) complex at room ***, Ga(Ⅲ) corrole exhibited a variation in fluorescence in response to axial coordination. Our findings provide a promising radical platform for coordination and developing novel functional materials with switchable spin and emission.

关键词： Luminescence Macrocyclic ligands Porphyrinoids Radicals Redox chemistry

The study of antibacterial activity of cationic poly(β-amino ester)regulating by amphiphilic balance

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Chinese Chemical Letters 2025年第2期36卷 332-336页

作者： Chong Liu Ling Li Jiahui Gao Yanwei Li Nazhen Zhang Jing Zang Cong Liu Zhaopei Guo Yanhui Li Huayu Tian School of materials science and Engineering Changchun University of Science and Technology School of materials science and Engineering Xiamen University of Technology Key laboratory of Polymer Ecomaterials Changchun Institute of Applied Chemistry Chinese Academy of Sciences College of Chemistry and Chemical Engineering Xiamen University

It is well known that cationic polymers have excellent antimicrobial capacity accompanied with high biotoxicity, to reduce biotoxicity needs to decrease the number of cationic groups on polymers, which will influence antimicrobial activity. It is necessary to design a cationic polymer mimic natural antimicrobial peptide with excellent antibacterial activity and low toxicity to solve the above dilemma. Here,we designed and prepared a series of cationic poly(β-amino ester)s(PBAEs) with different cationic contents, and introducing hydrophobic alkyl chain to adjust the balance between antimicrobial activity and biotoxicity to obtain an ideal antimicrobial polymer. The optimum one of synthesized PBAE(hydrophilic cationic monomer:hydrophobic monomer = 5:5) was screened by testing cytotoxicity and minimum inhibitory concentration(MIC), which can effectively kill S. aureus and E. coli with PBAE concentration of15 μg/m L by a spread plate bacteriostatic method and dead and alive staining test. The way of PBAE killing bacterial was destroying the membrane like natural antimicrobial peptide observed by scanning electron microscopy(SEM). In addition, PBAE did not exhibit hemolysis and cytotoxicity. In particular, from the result of animal tests, the PBAE was able to promote healing of infected wounds from removing mature S. aureus and E. coli on the surface of infected wound. As a result, our work offers a viable approach for designing antimicrobial materials, highlighting the significant potential of PBAE polymers in the field of biomedical materials.

关键词： Amphiphilic balance Antimicrobial Cationic polymers Michael addition polymerization Poly(β-amino ester)s

Tailoring Cathode-Electrolyte Interface for High-Power and Stable Lithium-Sulfur Batteries

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Nano-Micro Letters 2025年第4期17卷 181-211页

作者： Mengting Liu Ling-Jiao Hu Zhao-Kun Guan Tian-Ling Chen Xin-Yu Zhang Shuai Sun Ruoli Shi Panpan Jing Peng-Fei Wang Center of Nanomaterials for Renewable Energy State Key Laboratory of Electrical Insulation and Power EquipmentSchool of Electrical EngineeringXi’an Jiaotong UniversityXi’an 710049People’s Republic of China Low-Dimensional materials and Photo/Electrochemical Technology Lab School of Materials Science and EngineeringShaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic MaterialsShaanxi University of Science&TechnologyXi’an 710021People’s Republic of China

Global interest in lithium-sulfur batteries as one of the most promising energy storage technologies has been sparked by their low sulfur cathode cost,high gravimetric,volumetric energy densities,abundant resources,and environmental ***,their practical application is significantly impeded by several serious issues that arise at the cathode-electrolyte interface,such as interface structure degradation including the uneven deposition of Li_(2)S,unstable cathode-electrolyte interphase(CEI)layer and intermediate polysulfide shuttle ***,an optimized cathode-electrolyte interface along with optimized electrodes is required for overall ***,we comprehensively outline the challenges and corresponding strategies,including electrolyte optimization to create a dense CEI layer,regulating the Li_(2)S deposition pattern,and inhibiting the shuttle effect with regard to the solid-liquid-solid pathway,the transformation from solid-liquid-solid to solid-solid pathway,and solid-solid pathway at the cathode-electrolyte *** order to spur more perceptive research and hasten the widespread use of lithium-sulfur batteries,viewpoints on designing a stable interface with a deep comprehension are also put forth.

关键词： Lithium-sulfur batteries Shuttle effect Cathode-electrolyte interface Structural enhancement Reaction pathway

Integrating Cu+/Cu0 sites on porous nitrogen-doped carbon nanofibers for stable and efficient CO2 electroreduction to multicarbon products

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Journal of Energy Chemistry 2025年第2期101卷 453-462页

作者： Yicheng Chao Jiahao Zhang Qinyue Wu Xinfei Fan Xie Quan Yanming Liu Key laboratory of Industrial Ecology and Environmental Engineering (MOE) School of Environmental Science and Technology Dalian University of Technology College of Environmental science and Engineering Dalian Maritime University Frontier science Center for Smart materials Dalian University of Technology

The Cu+/Cu0sites of copper-based catalysts are crucial for enhancing the production of multicarbon(C2+)products from electrochemical CO2reduction reaction（eCO2RR）.However,the unstable Cu+and insufficient Cu+/Cu0active sites lead to their limited selectivity and stability for C2+***,we embedded copper oxide（CuOx） particles into porous nitrogen-doped carbon nanofibers（CuOx@PCNF）by pyrolysis of the electrospun fiber film containing ZIF-8 and Cu2O *** porous nitrogendoped carbon nanofibers protected and dispersed Cu+species,and its micro porous structure enhanced the interaction between CuOxand reactants during *** obtained CuOx@PCNF created more effective and stable Cu+/Cu0active *** showed a high Faradaic efficiency of 62.5% for C2+products in Hcell,which was 2 times higher than that of bare CuOx（～31.1%）.Furthermore,it achieved a maximum Faradaic efficiency of 80.7% for C2+products in flow *** situ characterization and density functional theory（DFT） calculation confirmed that the N-doped carbon layer protected Cu+from electrochemical reduction and lowered the energy barrier for the dimerization of**** and exposed Cu+/Cu0active sites enhanced the enrichment of*CO and promoted the C-C coupling reaction on the catalyst surface,which facilitated the formation of C2+products.

关键词： Carbon nanofibers Cu+/Cu0 sites C–C coupling Electrocatalytic CO2 reduction Multicarbon products

A general stabilizing strategy based on vitamin C for n-type organic semiconductors

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science China materials 2025年第1期68卷 303-304页

作者： Hui Huang College of materials science and Opto-Electronic Technology Center of Materials Science and Optoelectronics EngineeringUniversity of Chinese Academy of SciencesBeijing 101408China

Organic semiconductors (OSCs), as an emerging next-generation semiconductor material, hold promising prospects in fields such as flexible displays, electronic skins, smart healthcare,and the Internet of Things, due to their excellent flexibility,solution processability, and tunable band structures [1,2]. These molecules are often classified into n-type and p-type, depending on whether the prevalent charge carriers are electrons or holes[3].

关键词： tunable semiconductors smart

Stretchable All-Small-Molecule Organic Solar Cells Enabled by Polymer Elastomer Confinement

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Chinese Journal of Polymer science 2025年第2期43卷 271-277页

作者： Chen-Yi Zhang Yu-Qiang Liu Hong-Xiang Li Xin-Yue Cui Zheng-Dong Wei Yue-Heng Liu Ming-Hua Li An-Dong Zhang Pei Cheng Zhi-Shan Bo College of Textiles&Clothing State Key Laboratory of Bio-fibers and Eco-textilesQingdao UniversityQingdao266071China State Key laboratory of Polymer materials Engineering College of Polymer Science and EngineeringSichuan UniversityChengdu610065China College of materials science and Engineering Qingdao UniversityQingdao266071China Beijing Key laboratory of Energy Conversion and Storage materials College of ChemistryBeijing Normal UniversityBeijing100875China

Intrinsic stretchability is a promising attribute of polymer organic solar cells(OSCs).However,rigid molecular blocks typically exhibit poor tensile properties,rendering polymers vulnerable to mechanical *** this study,we introduce a different approach utilizing all-small-molecule donors and acceptors to fabricate stretchable *** elastomer,styrene-b-ethylene-butylene-styrene(SEBS),was embedded to modulate film crystallization and *** effectively confines the growth process of donors and acceptors,leading to enhancement of the crystallization quality,thus contributing to enhanced device ***,SEBS can absorb and release mechanical stress during stretching,thereby preventing mechanical degradation of donors and *** mechanical properties of the OSCs were significantly improved by the incorporation of ***,the crack-onset strain increased from 1.03% to 5.99% with SEBS *** findings present a straightforward strategy for achieving stretchable OSCs using all small molecules,offering a different perspective for realizing stretchable devices.

关键词： All-small-molecule Organic solar cells Elastomer Stretchability Flexibility