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Tailoring thermoelectric properties of Zr(0.43)Hf(0.57)NiSn half-Heusler compound by defect engineering

Rare Metals 2020年第6期39卷 659-670页

作者： Krzysztof Galazka Wenjie Xie Sascha Populoh Myriam H.Aguirre Songhak Yoon Gesine Büttner Anke Weidenkaff Institute of Plasma Physics and Laser Microfusion Warsaw 01-497Poland department of Materials Science Technische Universitat DarmstadtDarmstadt 64287Germany Laboratory for Solid State Chemistry and Catalysis EmpaDlibendorf 8600Switzerland Instituto de Nanociencia de Aragon Universidad de ZaragozaSaragossa 50018Spain departamento de Fisica de la Materia Condensada Universidad de ZaragozaSaragossa 50009Spain laboratorio de microscopias avanzadas Universidad de ZaragozaSaragossa 50018Spain Fraunhofer Research Institution for Materials Recycling and Resource Strategies IWKS Hanau 63457Germany

The thermoelectric transport properties of Zr0.43Hf0.57 NiSn half-Heusler compounds were investigated for samples sintered with different spark plasma sintering(SPS)periods:8,32 and 72 *** means of scanning transmission electron microscopy with a highangular annular dark-field detector(STEM-HAADF),it was found that sintering time affected the defect concentration,namely the amount of Ni interstitial atoms,and created locally ordered inclusions of full-Heusler *** structural information,phase composition and electrical transport properties could be consistently explained by the assumption that Ni interstitials give rise to an impurity band situated about 100 meV below the bottom of the conduction band via a self-doping *** impurity band was found to merge with the conduction band for the sample with intermediate SPS *** effect was ascribed to the gradual dissolution of full-Heusler phase inclusions and production of interstitial Ni defects,which eventually vanished for the sample with the longest sintering *** was demonstrated that the modification of the density of states near the edge of the conduction band and enhanced overall charge carrier concentration provided by defect engineering led to overall 26%increase in the thermoelectric figure of merit(ZT)with respect to the other samples.

关键词： Thermoelectric Half-Heusler Interstitial defect engineering

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deciphering the role of PGC-1α in neurological disorders: from mitochondrial dysfunction to synaptic failure

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Neural Regeneration Research 2022年第2期17卷 237-245页

作者： Jessica D.Panes Aline Wendt Oscar Ramirez-Molina Patricio A.Castro Jorge Fuentealba laboratorio de Screening de Compuestos Neuroactivos(LSCN) Departamento de FisiologiaFacultad de Ciencias BiologicasUniversidad de ConcepcionConcepcionChile Centro de Investigaciones avanzadas en Biomedicina(CIAB-UdeC) Facultad de Ciencias BiologicasUniversidad de ConcepcionConcepcionChile departamento de Fisiologia Facultad de Ciencias BiologicasUniversidad de ConcepcionConcepcionChile

The onset and mechanisms underlying neurodegenerative diseases remain uncertain. The main features of neurodegenerative diseases have been related with cellular and molecular events like neuronal loss, mitochondrial dysfunction and aberrant accumulation of misfolded proteins or peptides in specific areas of the brain. The most prevalent neurodegenerative diseases belonging to age-related pathologies are Alzheimer's disease, Huntington's disease, Parkinson's disease and amyotrophic lateral sclerosis. Interestingly, mitochondrial dysfunction has been observed to occur during the early onset of several neuropathological events associated to neurodegenerative diseases. The master regulator of mitochondrial quality control and energetic metabolism is the transcriptional coactivator peroxisome proliferator-activated receptor gamma coactivator 1-alpha(PGC-1α). Additionally, it has been observed that PGC-1α appears to be a key factor in maintaining neuronal survival and synaptic transmission. In fact, PGC-1α downregulation in different brain areas(hippocampus, substantia nigra, cortex, striatum and spinal cord) that occurs in function of neurological damage including oxidative stress, neuronal loss, and motor disorders has been seen in several animal and cellular models of neurodegenerative diseases. Current evidence indicates that PGC-1α upregulation may serve as a potent therapeutic approach against development and progression of neuronal damage. Remarkably, increasing evidence shows that PGC-1α deficient mice have neurodegenerative diseases-like features, as well as neurological abnormalities. Finally, we discuss recent studies showing novel specific PGC-1α isoforms in the central nervous system that appear to exert a key role in the age of onset of neurodegenerative diseases and have a neuroprotective function in the central nervous system, thus opening a new molecular strategy for treatment of neurodegenerative diseases. The purpose of this review is to provide an up-t

关键词： Alzheimer's disease amyotrophic lateral sclerosis Huntington's disease mitochondrial dysfunction Parkinson's disease PGC-1α synaptic function vascular dementia

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Catalysts for the hydrogen evolution reaction in alkaline medium:Configuring a cooperative mechanism at the Ag-Ag_(2)S-MoS_(2) interface

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Journal of Energy Chemistry 2022年第11期31卷 481-488,I0013页

作者： Avraham Bar-Hen Simon Hettler Ashwin Ramasubramaniam Raul Arenal Ronen Bar-Ziv Maya Bar Sadan department of Chemistry Ben-Gurion University of the NegevBeer-Sheva 8410501Israel department of Chemistry Nuclear Research Center NegevP.O.Box 9001Beer-Sheva 84190Israel laboratorio de Microscopías avanzadas Universidad de Zaragoza50018 ZaragozaSpain Instituto de Nanociencia y Materiales de Aragon CSIC-U.de ZaragozaCalle Pedro Cerbuna 1250009 ZaragozaSpain department of Mechanical and Industrial Engineering University of MassachusettsAmherstMA 01003United States ARAID Foundation 50018 ZaragozaSpain

designing electrocatalysts for HER in alkaline conditions to overcome the sluggish kinetics associated with the additional water dissociation step is a recognized challenge in promoting the hydrogen *** this end,delicately tuning the atomic-scale structure and surface composition of nanoparticles is a common strategy and,specifically,making use of hybrid structures,can produce synergistic effects that lead to highly active ***,we present a core-shell catalyst of Ag@MoS_(2)that shows promising results towards the hydrogen evolution reaction(HER)in both 0.5 M H_(2)SO_(4)and 0.5 M *** this hybrid structure,the MoS_(2)shell is strained and defective,and charge transfer occurs between the conductive core and the shell,contributing to the electrocatalytic *** shelling process results in a large fraction of Ag_(2)S in the cores,and adjusting the relative fractions of Ag,Ag_(2)S,and MoS_(2)leads to improved catalytic activity and fast charge-transfer *** suggest that the enhancement of alkaline HER is associated with a cooperative effect of the interfaces,where the Ag(Ⅰ)sites in Ag_(2)S drive the water dissociation step,and the formed hydrogen subsequently recombines on the defective MoS_(2)*** study demonstrates the benefits of hybrid structures as functional nanomaterials and provides a scheme to activate MoS_(2)for HER in alkaline conditions.

关键词： Water splitting Core-shell Catalytic mechanism Electrocatalysis 2D materials

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Te-seeded growth of few-quintuple layer Bi2Te3 nanoplates

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Nano Research 2014年第9期7卷 1243-1253页

作者： Yanyuan Zhao Maria de la Mata Richard L. J. Qiu Jun Zhang Xinglin wen Cesar Magen Xuan P. A. Gao Jordi Arbiol Qihua Xiong Division of Physics and Applied Physics School of Physical and Mathematical Sciences Nanyang Technological UniversitySingapore 637371 Institut de Ciencia de Materials de Barcelona ICMAB-CSIC E-08193 Bellaterra CAT Spain department of Physics Case Western Reserve University Cleveland Ohio 44106 USA laboratorio de Microscopfas avanzadas (LMA) Instituto de Nanociencia de Aragon (INA) - ARAID and Departamento de Fisica de la Materia Condensada Universidad de Zaragoza 50018 Zaragoza Spain Institucio Catalana de Recerca i Estudis Avancats (ICREA) 08010 Barcelona CAT Spain NOVITAS Nanoelectronics Centre of Excellence School of Electrical and Electronic Engineering Nanyang Technological University Singapore 639798

We report on a Te-seeded epitaxial growth of ultrathin Bi2Te3 nanoplates （down to three quintuple layers （QL）） with large planar sizes （up to tens of micrometers） through vapor transport. Optical contrast has been systematically investigated for the as-grown Bi2Te3 nanoplates on the SiO2/Si substrates, experimentally and computationally. The high and distinct optical contrast provides a fast and convenient method for the thickness determination of few-QL Bi2Te3 nanoplates. By aberration-corrected scanning transmission electron microscopy, a hexagonal crystalline structure has been identified for the Te seeds, which form naturally during the growth process and initiate an epitaxial growth of the rhombohedral- structured Bi2Te3 nanoplates. The epitaxial relationship between Te and Bi2T% is identified to be perfect along both in-plane and out-of-plane directions of the layered nanoplate. Similar growth mechanism might be expected for other bismuth chalcogenide layered materials.

关键词： Te nucleation seed epitaxial growth Bi2Te3 few-quintuple layer TEM cross-section optical contrast

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