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Selection of appropriate organic additives for enhancing Zn and Cd phytoextraction by hyperaccumulators

Journal of Environmental Sciences 2006年第6期18卷 1113-1118页

作者： WU Qi-tang DENG Jin-chuan LONG Xin-xian MOREL Jean-louis SCHWARTZ Christophe College of Natural Resource and Environment South China Agricultural University Guangzhou 510642 China laboratoire sol et environnement ENSAIA-INRA 54505 Vandoeuvre-les-Nancy France

Chelant-enhanced phytoextraction is one of the most promising technologies to remove heavy metals from soil. The key of the technology is to choose suitable additives in combination with a suitable plant. In the present study, laboratory batch experiment of metal solubilization, cress seeds germination were undertaken to investigate the metal-mobilizing capability and the phytotoxicity of organic additives, including ethylene diamine triacetic acid （EDTA）, citric acid, acetic acid, oxalic acid, glutamine and monosodium glutamate waste liquid （MGWL） from food industry. Experiments in pots were carried out to study the effects of the additives on Zn and Cd phytoextraction. Furthermore, a leaching experiment with lysimeter was performed to evaluate the environmental risks of additive-induced leaching to underground water. The results showed that EDTA had a strong mobilizing ability for Zn and Cd, followed by mixed reagent （MR） and MGWL. MGWL and acetic acid at 5 mmol equivalent per liter resulted in seed germination index less than 2%. Experiments in pots verified the phytotoxicity of acetic acid and MGWL. Addition of the mixed reagent at 6--10 mmol/kg significantly increased Zn phytoextraction by Thlaspi caerulescens. The same for EDTA and the mixed reagent at 10 mmol/kg by Sedum dfredii. But only mixed reagents could significantly increase Cd phytoextraction by the studied hyperaccumulators. This suggested that the strong chelant was not always the good agent to enhance phytoextraction. S. alfredii combined with 2--10 mmol/kg soil MR was preferred for phytoremediation of Cd/Zn contaminated soils in southern China, this could result in high phytoextraction of Cd/Zn and reduce the leaching risk to underground water than EDTA assisted phytoextration.

关键词： enhanced phytoextraction heavy metals Thlaspi caerulescens Sedum alfredii EDTA organic acids mixed reagent leaching risk

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Enhanced dielectric performance of Dy-substituted YMn2O5 for high-frequency applications

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Progress in Natural Science:Materials International 2021年第5期31卷 762-771页

作者： H.Chouaibi K.Khirouni E.Dhahri laboratoire de Physique Appliquée Faculté des Sciences Université de Sfax laboratoire de Physique des Matériaux et des Nanomatériaux Appliquée à l'environnement Faculté des Sciences de Gabès Cité Erriadh Université de Gabès

The dielectric performances as well as the effects of Dy3+ions content at A sites of YMn2O5(YMO) [x=0(YDM0)and x=0.4(YDM0.4)] polycrystalline samples were *** compounds were synthesized via sol-gel method.X-Ray diffraction and Raman measurements proved the high quality of the compounds that crystallized in an orthorhombic structure with the Pbam space ***,impedance spectroscopy and electrical modulus studies revealed that both samples exhibited a non-Debye’s type of *** decrease of impedance for YDM0.4compared to the pure YDM0,may be attributed to the decrease in charge transfer *** the fit of impedance spectra,they confirmed that both compounds were simultaneously capacitive and ***,the activation energies obtained from Modulus and complex impedance were proven to be neighboring,suggesting that the relaxation process refers to electron *** each compound,the evolution of ε’and tan & with temperature indicated a clearer relaxor behavior,namely the existence of two *** first one detected at low temperature is related to the charge carriers hopping between Mn3+and Mn4+and the second at high temperature is associated with oxygen *** reduced hopping rate with Dy3+substitution for Y3+ions at A sites is responsible for the decrease in dielectric constant and dielectric *** significant findings demonstrate that these materials can be invested in a fruitful use in UV photo-detector and power applications in high frequency as microwave,millimeter wave signal processing,for civilian,military and space applications.

关键词： Multiferroic Relaxation phenomenon High dielectric constant Relaxor behavior

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Combined Effects of Compost,Supraxone and Lambda-Super on Soil Microbial Activity under Pluvial Cultivation of Sesame(Sesamum indicum L.)in Burkina Faso

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Journal of Geoscience and Environment Protection 2019年第1期7卷 107-117页

作者： Paul W.Savadogo Yacouba Zi Abdoul K.Sanou Hassan B.Nacro Francois Lompo et Michel P.Sedogo laboratoire sol-Eau-plante Institut de l’Environnement et de Recherches Agricoles(INERA)OuagadougouBurkina Faso Institut du Développement Rural Laboratoire d’Etude et de Recherche sur la Fertilité des Sols(LERF)Université Nazi BoniBobo-DioulassoBurkina Faso

Sesame cultivation is strategic for the economy of Burkina Faso. Indeed, after cotton, sesame is the second most important agricultural product for exportation. However, its production is limited by plant diseases and pest attacks. Facing this situation, large amounts of pesticides are used to boost productivity. But, these chemicals have a negative impact on soil fertility. In this instance, the effects of Supraxone and Lambda-super in the presence of compost on soil microbial activity under rainfed sesame cultivation in a peasant environment were studied. The experiment design was a block of Fisher (BCR) comparing the non-treated parcel (TNT) to the parcel amended only with compost (C) and to the parcel amended with compost and treated with the pesticides (C + P), respectively. Soil samples were taken at depths of 0 - 20 cm before sowing at 41st and 81st days after sowing. Respiratory activity and soil microbial biomass were monitored respectively by respirometric tests and by the fumigation-incubation method. The results show that the addition of compost into the soil with or without supraxone treatment and Lambda-super resulted in an increase in microbial biomass and soil respiratory quotient. These results show that the provision of compost in sufficient quantity corrects the inhibitory effect of soil biological activity by pesticides.

关键词： Supraxone Lambda-Super Sesamum indicum L. Burkina Faso Respiratory Quotient Microbial Biomass

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Soil Macrofauna Behaviour in the Presence of Pesticides and Organic Amendments

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Journal of Geoscience and Environment Protection 2017年第3期5卷 202-212页

作者： Rayim Wendé Alice Nare Paul Windinpsidi Savadogo Mamoudou Traore André Gountan Hassan Bismarck Nacro Michel Papaoba Sedogo Département des Substances Naturelles Institut de Recherche en Sciences Appliquées et Technologies (IRSAT) Ouagadou-gou Burkina Faso laboratoire sol-Eau-Plante Institut de l’Environnement et de Recherches Agricoles (INERA) Ouagadougou Burkina Faso laboratoire d’etude et de Recherche sur la Fertilité des sols (LERF) Université Polytechnique de Bobo Dioulasso (UPB) Bobo Dioulasso Burkina Faso

Insects attack vegetable crop, leading to an overuse of pesticides. Organic amendments are recommended to increase soil fertility. The impact of two insecticides, on soil macrofauna under rainfed cultivation of tomato (Lycopersicon esculentum L.) with or without organic amendments was evaluated. The insecticides were Lambda Super (lambda-cyhalothrin) and Dursban (chlorpyrifos ethyl) and organic amendments were compost, pig manure and cattle manure. An experimental device in split-plot with three replicate was installed. Pesticides were applied periodically each week during the experiment. The results have showed that with organic amendments, Lambda super increased the earthworm population compared to the control. Indeed, we found 42 individuals/m2 with compost;1 individuals/m2 with pig manure and 27 individuals/m2 with cattle manure but the control was 0 individuals/m2 in the presence of Lambda super without organic amendment. Similarly, Dursban increased the population of earthworms in the presence of organic amendment with 11, 37 and 91 individuals/m2 respectively for compost, pig manure and cattle manure. Lambda super with compost has led to a total elimination of termites. In the presence of Dursban, a decrease in the number of termites was observed when adding cattle manure (11 individuals/ m2) compared to the control containing only Dursban (21 individuals/m2). Better distribution of macrofauna was obtained with treatment with Dursban and compost (E = 0.99 for earthworms and E = 0.96 for termites). All organic amendments used in our study stimulated earthworm population, but more in the presence of Lambda super or Dursban.

关键词： Pesticides Organic Amendment Soil Macrofauna Burkina Faso

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Study of the Evolution of Properties of Concrete Containing Used Tire Aggregates

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Geomaterials 2024年第4期14卷 49-58页

作者： Mamery Adama Serifou Ouaga Jean Bruce Nataniel Gboga Bleh Raoul Ulrich Kouassi Edjikémé Emeruwa laboratoire des Sciences du sol de lEau et de Gomatriaux UFR des Sciences de la Terre et des Ressources Minires Universit Flix Houphout Boigny Abidjan Cte dIvoire Institut National Polytechnique Flix Houphout-Boigny Yamoussoukro Cte dIvoire laboratoire de Gomatriaux et de Gotechnique Dpartement des Sciences de la Terre UFR Environnement Universit Jean Lorougnon Gud Daloa Cte dIvoire

Concrete is generally composed of cement, water, gravel, and sand. However, some research focuses on substituting aggregates with waste materials. In this study, used tires are used as a substitute for gravel. Characteristics such as tensile strength, compressive strength, and porosity were monitored at 7, 14, and 28 days of maturation. The results show that aggregates made from used tires are suitable for concrete production and can replace natural gravel. Regarding the formed concrete, low substitution rates lead to improved concrete properties, but only at an early age. A reaction between the cement and rubber could be the underlying cause. Additionally, the products of this reaction may mitigate the evolution of the compressive strength of the concrete over time.

关键词： Concrete Used Tire Porosity Mechanical Strength

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Evaluation of the Level of Pollution by Heavy Metals of Market Garden Soils along the Chari River in Ndjamena: Case of the 9th and 7th Districts

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Agricultural Sciences 2024年第8期15卷 939-961页

作者： Kotva Wana Mackaye Hassane Taisso Likius Andossa Béral Djétenbé laboratoire Gosciences Dpartement des Sciences de la Terre Facult des Sciences Universit de NDjamena NDjamena Chad laboratoire Gosciences Dpartement des Sciences de la Terre Facult des Sciences Universit de Mongo Mongo Chad laboratoire sol et environnement (LASEN) Dpartement des Sciences de la Terre Facult des Sciences Universit de Ngaoundr Ngaoundr Cameroun

The main aim of this study was to characterize the metal content of soils used for market gardening along the Chari river: the 7th and 9th districts of NDjaména. To achieve this, two sites were selected: Gassi and Walia, and two control sites (Gassi and Walia). A total of fifty (50) soil samples were taken (24 from the Gassi site, 24 from the Walia site and 2 as control soils) and then analyzed to determine a number of physico-chemical parameters (pH, OM and electrical conductivity) and heavy metal concentrations in the various soils. The TME content (As, Cd, Cu, Cr, Ni, Pb, Hg and Zn) of the soils was determined by plasma-coupled Atomic Emission Spectrometry. In order to assess the level of contamination in Gassi and Walia soils, the geoaccumulation index (GeoIndex), contamination factor and degree of contamination were calculated. Results for physico-chemical parameters revealed that pH ranged from acidic (4.6) to moderately neutral (6.5), electrical conductivity was higher in cultivated soils (mean 292.14 μs/cm) than in control soils (mean 149.33 μs/cm), and soils were rich in organic matter. Overall, heavy metal concentrations in cultivated soils were higher than in control soils. The pollution estimate shows that soils in the area have no moderate contamination. The increase in TME concentrations in cultivated soils is thought to be due to the input of agricultural inputs to the soil. However, these levels are below the Average shale reference and Canadian guidelines for agricultural soil quality. Principal component analysis shows that metals are positively and significantly correlated with each other, and negatively and moderately significantly correlated with each other.

关键词： Contamination Agricultural Soils City of N’Djaména etM Gassi Walia

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Salicylic Acid Regulates Pollen Tip Growth ：hrough an NPR3/NPR4-1ndependent Pathway

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Molecular Plant 2016年第11期9卷 1478-1491页

作者： Duoyan Rong Nan Luo Jean Claude Mollet Xuanming Liu Zhenbiao Yang State Key Laboratory of Chemo/Biosensing and Chemometrics Hunan Province Key Laboratory of Plant Functional Genomics and Developmental Regulation College of Biology Hunan University Changsha 410082 China Department of Botany and Plant Sciences and Center for Plant Cell Biology Institute of Integrated Genome Biology University of California Riverside CA 92521 USA Normandie Univ UniRouen Laboratoire Glycobiologie et Matrice Extracellulaire V6getale Institute for Research and Innovation in Biomedicine Vegetal Agronomie Sol et Innovation 76821 Mont-Saint-Aignan France

Tip growth is a common strategy for the rapid elongation of cells to forage the environment and/or to target to long-distance destinations. In the model tip growth system of Arabidopsis pollen tubes, several small- molecule hormones regulate their elongation, but how these rapidly diffusing molecules control extremely localized growth remains mysterious. Here we show that the interconvertible salicylic acid （SA） and meth- ylated SA （MESA）, well characterized for their roles in plant defense, oppositely regulate Arabidopsis pollen tip growth with SA being inhibitory and MeSA stimulatory. The effect of SA and MeSA was independent of known NPR3/NPR4 SA receptor-mediated signaling pathways. SA inhibited clathrin-mediated endocytosis in pollen tubes associated with an increased accumulation of less stretchable demethylated pectin in the apical wall, whereas MeSA did the opposite. Furthermore, SA and MeSA alter the apical activation of ROP1 GTPase, a key regulator of tip growth in pollen tubes, in an opposite manner. Interestingly, both MeSA methylesterase and SA methyltransferase, which catalyze the interconversion between SA and MESA, are localized at the apical region of pollen tubes, indicating of the tip-localized production of SA and MeSA and consistent with their effects on the apical cellular activities. These findings suggest that local generation of a highly diffusible signal can regulate polarized cell growth, providing a novel mechanism of cell polarity control apart from the one involving protein and mRNA polarization.

关键词： SA (salicylic acid) MeSA (methyl salicylic acid) endocytosis FM4-64 CRIB4-GFP ROP activity

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Influence of a Mineral Filler on the Fire Behaviour and Mechanical Properties of a Wood Waste Composite Material Stabilized with Expanded Polystyrene

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Open Journal of Applied Sciences 2020年第12期10卷 834-843页

作者： Koffi Clément Kouadio Brahiman Traoré Serge Pacome Kaho Conand Honoré Kouakou Edjikémé Emeruwa laboratoire du sol de l’eau et de Géomatériaux (UFR-STRM) Université Felix Houphouet-Boigny Abidjan Cote d’Ivoire

The use of vegetable fibers composites in structures sometimes presents significant fires risks because of their high flammability. This work aims to study the impact of the addition of mineral filler (clay) on the fire behaviour of wood-polystyrene composites and their mechanical properties. Thus, composites containing 25% of expanded polystyrene binder have been produced. On this base material, proportions of clay ranging from 0% to 15% were gradually added. These samples were elaborated by compaction and for some them, submitted to thermoforming after drying. Both kinds of sample were subjected to flame persistence test;flexural strength and compressive strength test were also measured. The results show that composites without mineral filler ignite continuously until the total consumption and when the mineral filler content increases the combustion time decreases. The addition of the mineral filler allows these composites to pass from class M3 of moderately flammable combustible materials to class M2 of hardly flammable materials, according to the M classification of construction and furnishing materials. The measurement of the mechanical properties shows that the strengths increase when the filler content goes from 0% to 10% and then decrease. This leads to set the optimum content of mineral filler around 10%.

关键词： Composite Expanded Polystyrene Flame Test Flammability Mechanical Properties

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Carbon and Nitrogen Mineralisation of a Lixisol in South Sudan Zone of Burkina Faso

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Agricultural Sciences 2023年第11期14卷 1547-1560页

作者： Abdramane Sanon Alain P. K. Gomgnimbou Kalifa Coulibaly Fidele K. Zongo Tièro-Wè Chris Julius Dabire Wilfiried Sanou Hassan B. Nacro Centre National de la Recherche Scientifique et Technologique (CNRST) Institut de l’Environnement et de Recherche Agricole (INERA) Laboratoire Sol-Eau-Plante (SEP) Station de Farako-Ba Bobo-Dioulasso Burkina Faso laboratoire d’étude et de recherche sur la fertilité du sol (LERF) Institut du Développement Rural (IDR) Université Nazi Boni Bobo-Dioulasso Burkina Faso Centre universitaire de Tenkodogo Université Thomas Sankara Ouagadougou Burkina Faso Unité de Formation et de Recherches en Sciences de la Vie et de laTerre Université Joseph KI-Zerbo Ouagadougou Burkina Faso

In today’s environment where agriculture needs to produce sustainably, local fertilizer resources must be encouraged to achieve multiple crop performance and environmental goals. The purpose of this study was to investigate the effects of combined inputs of biowaste and inorganic fertilisers on the mineralization of carbon and nitrogen of a Lixisol under continuous upland rice growing conditions. To this end, agronomic trials were set up in 2018 and 2019, using a Fisher randomized complete block design with 6 treatments and four replications at Farako-ba research station. The treatments were: T1 (Control), T2 (NPK + Urea), T3 (7500 kgha of Chicken droppings);T4 (7500 kg/ha of chicken droppings + 100 kg/ha of urea);T5 (7500 kg/ha of chicken droppings + 500 kg/ha of Burkina Phosphate);T6 (7500 kg/ha of chicken droppings + 500 kg/ha of Burkina Phosphate + 100 kg/ha of urea). Highest respirometry was observed in treatments T3, T4 and T6 and treatment T4 significantly increased the mineralization coefficient by 15% after 21 days of incubation. T4 and T6 resulted in increases in ammonium ion of 74.15% and 100%, respectively, compared to the control. Likewise, treatments T4 and T6 resulted in a significant increase in nitrate ion of 104.83 and 103.25%, respectively. Biowaste combined with inorganic fertilizers may have a capacity to improve the availability of leachate nutrients under upland rice conditions.

关键词： Bio-Waste Rice Carbone Nitrogen and Mineralisation

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Long term effects of treated wastewater irrigation on calcisol fertility: A case study of Sfax-Tunisia

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Agricultural Sciences 2012年第5期3卷 702-713页

作者： Nebil Belaid Catherine Neel Monem Kallel Tarek Ayoub Abdelmoneim Ayadi Michel Baudu CRDA-Sfax Rue Commandant Bejaoui 3018 Sfax Tunisie Ecole Nationale d’Ingénieurs de Sfax Laboratoire de Radio-Analyses et Environnement (LRAE) ENIS BP W 3038 Sfax Tunisie Ecole Nationale d’Ingénieurs de Sfax Laboratoire Eau Energie Environnement (L.3E) ENIS BP W 3038 Sfax Tunisie Université de Limoges FST Groupement de Recherche Eau Sol Environnement (GRESE) 123 Avenue Albert Thomas 87060 Limoges Cedex France

The use of treated wastewater (TW) for irrigation is increasingly being considered as a technical solution to minimize soil degradation and to restore nutrient content of soils. Indeed, TW usually contain large amounts of nutrient elements. The objective of this study is to evaluate the impact of long-term irrigation by TW on soil fertility under real field conditions. In the vicinity of the city of Sfax, a semi-arid region, a calcisol field has been irrigated for more 15 years with organic sodic TW;soil was modeled at three different depths (0 - 30, 30 - 60 and 60 - 90 cm) and along soil pits in the TW irrigated zone and in a nearby non-irrigated zone (control). Several parameters have been measured: soils pH, CEC, exchangeable cations, nitrate and ammonia, total contents of nitrogen, phosphorus and other essential macro and micro nutrients, electrical conductivity, soil organic carbon and dissolved organic carbon. C/N ratio and SUVA were calculated for each soil layer. The calculation of the isovolumic mass balance on soil profile scale was used to measure macro and micro nutrients supply. The TW irrigation has led to important supply in organic carbon (+100%), phosphorus (+80%) and in most essential nutrients (N, Mn, Zn). Due to the high rate of irrigation and low CEC of the studied soil, the added nutrient cations and nitrate are removed with leaching waters compared to the non-irrigated control soil. Moreover, Sfax’s TW bring about important amounts of salts and Na. Therefore the beneficial addition of nutrients could quickly be inhibited by the excessive supply of salts and available nitrogen. Apart from future crops production risk, groundwater degradation quality and soil fertility will be endangered over the long term.

关键词： Arid Region Wastewater Irrigation Fertility El Hajeb-Sfax

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