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Performance Evaluation of Solar Chimney Draft: Application to Ventilation

Smart Grid and Renewable Energy 2024年第4期15卷 107-122页

作者： Boukaré Ouedraogo Adama Ouedraogo Arouna Kabore Kalifa Palm Dieudonné Joseph Bahiebo laboratoire denergies Thermiques Renouvelables (LETRE) Universit Joseph KI-ZERBO: UFR/SEA Ouagadougou Burkina Faso laboratoire de chimie Analytique Physique Spatiale et Energtique (LACAPSE) Universit Norbert ZONGO Koudougou Burkina Faso Centre Universitaire Polytechnique de Kaya (CUP-Kaya) Universit Joseph KI-ZERBO Ouagadougou Burkina Faso laboratoire des Systmes denergie Renouvelable et Environnement Institut de Recherche en Sciences Appliques et Technologies (IRSAT) Centre National de la Recherche Scientifique et Technologique (CNRST) Ouagadougou Burkina Faso

Ventilation is one of the factors contributing to energy consumption in buildings and food preservation. The solar chimney proves to be an alternative for reducing conventional energy consumption. Thus, in this study, the performance of a solar chimney with two active faces for thermally drawing air from a chamber for preserving agri-food products was evaluated. These performances were experimentally assessed through data measurements: temperatures and velocities within the chimney, and their analysis using Excel and MATLAB. The obtained results were compared with those from literature to verify their validity. From this study, it is found that the maximum temperature at the chimney outlet reaches 49.4˚C with an average value of 43.7˚C. Additionally, the heating evolution of the chimney air presents four (04) identical phases in pairs, reflecting the chimney’s operation throughout day. The temperature difference between the outlet and inlet of the chimney reaches a maximum of 17˚C with an average of 12.6˚C. Regarding airflow, the maximum air velocity at the chimney outlet is 0.8 m/s, and the average velocities have consistently been greater than or equal to 0.46 m/s. Thus, it can be concluded that the solar chimney is capable of providing ventilation for the preservation chamber through thermal draft.

关键词： Solar Chimney Natural Ventilation Thermal Draft Airflow Chimney Effect

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Optimized Adsorption of Small and Medium Molecules by a Biosorbent Based on Hevea Hulls

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Journal of Materials Science and Chemical Engineering 2024年第9期12卷 69-83页

作者： Djedjess Essoh Jules César Meledje Yapo Hermann Aristide Yapi David Léonce Kouadio Djamatchè Paul Valéry Akesse Kolo Yeo laboratoire des Sciences Physiques Fondamentales et appliques Ecole Normale Suprieure dAbidjan Abidjan Cte dIvoire Mathmatiques physiques chimie Physique UFR Environnement Universit Jean Lorougnon Gud Daloa Cte dIvoire

In the context of the recovery of agricultural waste, many researches have focused on the preparation of adsorbents from natural waste from fruit trees, egg shells, palm waste or sawdust. This work aims to optimize the preparation of a biosorbent from rubber hulls by studying its ability to adsorb small and medium molecules. The influence of parameters such as drying temperature (X1), particle size (X2), stirring time (X3) and sodium hypochloride mass (X4) was studied. The results indicate that the model used for biosorbent optimization on methylene blue and iodine index is significant. In addition, this model has greater adsorption capabilities on small molecules than with large molecules. Statistical analysis of the data shows that temperature is the most influential factor in the adsorption of small molecules. On the other hand, particle size has a significant influence on the adsorption of large molecules. The optimum biosorbent preparation values are 1.0 for drying temperature (X1), −1.0 for biosorbent grain size (X2), 1.0 for stirring time (X3) and 1.0 for sodium hypochloride mass (X4).

关键词： Optimization Biosorbent Methylene Blue Index Iodine Index Rubber Hulls

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Analysis of the Quality of Physical and Chemical Parameters of Groundwater in Three Localities in the Sub-Prefecture of Zanzra (Ivory Coast)

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Journal of Materials Science and Chemical Engineering 2024年第4期12卷 1-17页

作者： Djedjess Essoh Jules-César Meledje Bi Irié Marc Gouli Drissa Ouattara Kra Vanh Eric-Simon Zran Adjourma Konate Albert Trokourey laboratoire de chimie des Eaux (LCE) de l’ Ecole Normale Sup&#233rieure d&#8217Abidjan Abidjan C&#244te d&#8217Ivoire laboratoire de Constitution et Ré action de la Mati&#232re (LCRM) &#224 l&#8217UFR SSMT-Universit&#233 F&#233lix Houphou&#235t-Boigny (UFHB) de Cocody Abidjan C&#244te d&#8217Ivoire

The availability of groundwater of acceptable quality has become a difficult challenge to meet in many countries, particularly Côte d’Ivoire. The State of Côte d’Ivoire and rural populations are building hydraulic infrastructure for this purpose. However, the quality of water coming from these infrastructures remains to be determined. This study therefore aims to analyze certain physicochemical parameters of the groundwater of Gloazra, Kouezra and Trahonfla. These are temperature, pH, electrical conductivity, TDS, salinity level, hardness, alkalinity, chloride content and bicarbonate. To determine the pH, electrical conductivity, temperature, TDS, and salinity rate, an electrochemical analysis was carried out. The titrimetric analysis made it possible to determine the chloride and bicarbonate content, alkalinity, and hardness. The results indicate that the studied groundwater is soft and acidic with good mineralization. This water does not present a health hazard to consumers but can affect hydraulic equipment and household containers.

关键词： Ivory Coast Gloazra Trahonfla Kouezra Physicochemical Parameters Water WHO Standards

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Electrochemical Study of the Corrosion Inhibitory Capacity of Calcined Attapulgite in Reinforced Concrete Medium

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Advances in Materials Physics and Chemistry 2024年第5期14卷 76-94页

作者： Malang Bodian Kinda Hannawi Dame Keinde Modou Fall Aveline Darquennes Prince William Agbodjan Faculté des Sciences et Techniques D&#233partement de Chimie Universit&#233 Cheikh Anta Diop de Dakar (S&#233n&#233gal) Laboratoire de Chimie Physique Organique et d&#8217Analyse Environnementales (LCPOAE) Dakar Senegal Dé partement de G&#233nie Civil Universit&#233 de Rennes INSA Rennes Laboratoire de G&#233nie Civil et G&#233nie M&#233canique (LGCGM) Rennes France Dé partement de G&#233nie Civil Universit&#233 Cheikh Anta Diop Ecole Sup&#233rieure Polytechnique de Dakar (S&#233n&#233gal) Laboratoire de Mat&#233riaux de G&#233nie Civil (LMGC) Dakar Senegal

The durability of reinforced concrete structures is greatly influenced by the corrosion of the reinforcement. In addition to air pollution related to the repair of corroded structures, chloride ions are the main factors of corrosion of reinforced concrete structures. This study aims to valorize a clay inhibitor against reinforcement corrosion in reinforced concrete. This clay (Attapulgite) was incorporated into reinforced concretes at different percentages of substitution of calcined attapulgite (0%, 5% and 10%) to cement in the formulation. The corrosion inhibitory power of attapulgite is evaluated in reinforced concretes subjected to the action of chloride ions at different intervals in the NaCl solution (1 day, 21 days and 45 days) by electrochemical methods (zero current chronopotentiometry, polarization curves and electrochemical impedance spectroscopy). This study showed that in the presence of chloride ions, the composition based on 10% attapulgite has an appreciable inhibitory effect with an average inhibitory efficiency of 82%.

关键词： Attapulgite Electrochemical Methods Inhibitor Reinforced Concrete

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New 4-imino-4H-Chromeno[2,3-d]Pyrimidin-3(5H)-Amine: Synthesis, Cytotoxic Effects on Tumoral Cell Lines and in Silico ADMET Properties

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International Journal of Organic Chemistry 2024年第3期14卷 107-122页

作者： Marwa Dhiabi Sirine Karoui Mehdi Fakhfakh Souhir Abid Emmanuelle Limanton Rémy Le Guével Thierry Charlier Ludovic Paquin Jean-Pierre Bazureau Houcine Ammar laboratoire de chimie Applique: Htrocycles Corps et Polymres Facult des Sciences de Sfax Universit de Sfax Sfax Tunisie Institut des Sciences Chimiques de Rennes Universit de Rennes Campus de Beaulieu Rennes Cedex France department of Chemistry (Science and Arts): Al Qurayat Al-Jouf University Al Jawf Saudi Arabia S2Wave Platform ScanMAT UAR CNRS Universit de Rennes Campus de Beaulieu Rennes Cedex France ImPACcell Platform Biosit SFR UMS CNRS Inserm Campus de Villejean Rennes France Institut de Recherche en Sant Environnement et Travail IRSET Inserm UMR_S Rennes France

The synthesis of new 4-imino-4H-chromeno[2,3-d]pyrimidin-3(5H)-amine in four steps including one step under microwave dielectric heating is reported. The structural identity of the synthesized compounds was established according to their spectroscopic analysis, such as FT-IR, NMR and mass spectroscopy. These new compounds were tested for their antiproliferative activities on seven representative human tumoral cell lines (Huh7 D12, Caco2, MDA-MB231, MDA-MB468, HCT116, PC3 and MCF7) and also on fibroblasts. Among them, only the compounds 6c showed micromolar cytotoxic activity on tumor cell lines (1.8 50 50 > 25 μM). Finally, in silico ADMET studies ware performed to investigate the possibility of using of the identified compound 6c as potential anti-tumor compound.

关键词： 2-Amino-4H-Chromene 4H-Chromeno[2 3-d]Pyrimidin-3(5H)-Amine Microwave Irradiation Tumoral Cell Line in Silico ADMET

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National Soil Organic Carbon Stocks Inventories under Different Mangrove Forest Types in Gabon

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Open Journal of Forestry 2024年第2期14卷 127-140页

作者： Rolf Gaël Mabicka Obame Neil-Yohan Musadji Jean Hervé Mve Beh Lydie-Stella Koutika Jean Aubin Ondo Farrel Nzigou Boucka Michel Mbina Mounguengui Claude Geffroy Dé partement de Phytotechnologie Institut National d&#8217Agronomie et de Biotechnologies Universit&#233 des Sciences et Techniques de Masuku Franceville Gabon Dé partement des Sciences Fondamentales de l&#8217Ing&#233nieur Institut National d&#8217Agronomie et de Biotechnologies Universit&#233 des Sciences et Techniques de Masuku Franceville Gabon Institut Agronomiques et Forestiè res Centre National des Recherches Scientifiques et Technologiques Libreville Gabon Research Centre on the Durability and the Productivity of Industrial Plantations (CRDPI) Pointe Noire Republic of Congo laboratoire Pluridisciplinaire des Sciences &#201cole Normale Sup&#233rieure Libreville Gabon Agence Gabonaise d’ &#201tude et d&#8217Observation Spatiale Immeuble les Arcades Libreville Gabon Dé partement de G&#233ologie Faculte des Sciences Universit&#233 des Sciences et Techniques de Masuku Franceville Gabon Institut de chimie des Milieux et Maté riaux de Poitiers (IC2MP) Universit&#233 de Poitiers Poitiers France

Gabonese’s estuary is an important coastal mangrove setting and soil plays a key role in mangrove carbon storage in mangrove forests. However, the spatial variation in soil organic carbon (SOC) storage remain unclear. To address this gap, determining the SOC spatial variation in Gabonese’s estuarine is essential for better understanding the global carbon cycle. The present study compared soil organic carbon between northern and southern sites in different mangrove forest, Rhizophora racemosa and Avicennia germinans. The results showed that the mean SOC stocks at 1 m depth were 256.28 ± 127.29 MgC ha−1. Among the different regions, SOC in northern zone was significantly (p p deeper layers contained higher SOC stocks (254.62 ± 128.09 MgC ha−1) than upper layers (55.42 ± 25.37 MgC ha−1). The study highlights that low deforestation rate have led to less CO2 (705.3 Mg CO2e ha−1 - 922.62 Mg CO2e ha−1) emissions than most sediment carbon-rich mangroves in the world. These results highlight the influence of soil texture and mangrove forest types on the mangrove SOC stocks. The first national comparison of soil organic carbon stocks between mangroves and upland tropical forests indicated SOC stocks were two times more in mangroves soils (51.21 ± 45.00 MgC ha−1) than primary (20.33 ± 12.7 MgC ha−1), savanna and cropland (21.71 ± 15.10 MgC ha−1). We find that mangroves in this study emit lower dioxide-carbon equivalent emissions. This study highlights the importance of national inventories of soil organic carbon and can be used as a baseline on the role of mangroves in carbon sequestration and climate change mitigation but the variation in SOC stocks indicates the need for further national data.

关键词： Mangroves Forest Soil Organic Carbon Stocks Rizophora Racemose Avicenia germinans Gabon

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Pyrolysis of olive residue/low density polyethylene mixture：Part Ⅰ Thermogravimetric kinetics

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燃料化学学报 2008年第6期36卷 672-678页

作者： ABOULKAS A E1 HARFI K El BOUADILI A laboratoire de Recherche sur la Reactivites des materiaux et l Optimisation des Procedes ＂REMATOP＂ Departement de chimie Faculte des Sciences Semlalia Universite Cadi Ayyad BP 2390 40001 Marrakech Maroc departement de chimie Faculte polydisciplinaire de Beni-Mellal Universite Sultan Moulay Slimane BP 592 23000 Beni-Mellal Maroc laboratoire de chimie Organique et Analytique Departement de chimie Faculte des Sciences et Techniques de Beni-Mellal Universite Sultan Moulay Slimane BP 523 23000 Beni-Mellal Maroc

This paper demonstrates the thermal pyrolysis of olive residue,low density polyethylene(LDPE) and olive residue/LDPE mixture in an inert atmosphere of N2 using thermogravimetric analysis(TGA).Measurements were carried out in the temperature range 300K^973K at heating rates of 2K/min,10K/min,20K/min and 50K/*** on the results obtained,three temperature regimes were selected for studying the non-isothermal kinetics of olive residue/LDPE *** first two were dominated by the olive residue pyrolysis,while the third was linked to the LDPE pyrolysis,which occurred at much higher *** between the experimental and calculated TG/DTG profiles were considered as a measurement of the extent of interactions occurring on *** maximum degradation temperatures of each component in the mixture were higher than those the individual components;thus an increase in thermal stability was *** kinetic parameters associated with thermal degradation were determined using Friedman isoconversional method.

关键词：高温分解反应低密度聚乙烯动力学 LDPE

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RING OPENING POLYMERIZATION OF TETRAHYDROFURAN CATALYSED BY MAGHNITE-H^+

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Chinese Journal of Polymer Science 2012年第1期30卷 56-62页

作者： Khadidja Benkenfoud Amine Harrane Mohammed Belbachir laboratoire de chimie des Polymeres departement de chimie Faculte des SciencesUniversite d'Oran Es-SeniaBP No 1524 El M'Naouar31000 OranAlgeria

The cationic ring-opening polymerization of tetrahydrofiiran using maghnite-H~＋ is ***-H~＋,is a non-toxic solid catalyst issued from proton exchanged montmorillonite ***,also called ＂poly（butandiol） ether＂,with acetate and hydroxyl end groups was successfully *** of reaction temperature, weight ratio of initiator/monomer and reaction time on the conversion of monomer and on the molecular weight are investigated.A cationic mechanism of the reaction was *** chemistry can be considered as a suitable route for preparing poly（THF） as a soft segment for thermoplastic elastomers.

关键词： Montmorillonite Maghnite Ring opening polymerization THF

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Physico-Chemical Properties of Soils from Diguel and Koudalwa Tchad,and Phytoremediation Potentials of Acasia and Kinkeliba Plants in Removing Cr and Cu from These Soils

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Journal of Environmental Science and Engineering(A) 2024年第5期13卷 165-177页

作者： Dieudonne Caleb Dahaina Jean Claude Doumnang Mbaigane Bobet Ouanmini Cornelius Tsamo department of Chemistry Faculty of Exact and Applied SciencesUniversity of N’DjamenaBP 1027N’DjamenaChad laboratoire de Géologie Géomorphologie et TélédétectionFacultédes Sciences Exactes et AppliquéesUniversitéde N’DjaménaBP 1027N’DjamenaChad laboratoire de chimie Ecole Normale Supérieure de BongorBP 13BongorTchad department of Chemistry Higher Teachers’Training CollegeUniversity of MarouaP.O.Box 55 MarouaCameroon department of Agricultural and Environmental Engineering College of TechnologyUniversity of BamendaP.O.BOX 39BambiliCameroon

The aim of this study to investigate the physico-chemical properties of soils from Diguel and Koudalwa Tchad,and phytoremediation potentials of acasia and kinkeliba plants in removing Cr and Cu from these *** was sampled from the tannery plant in Diguel and agricultural land around crude oil activities in *** were characterized by the following properties:pH,(Electrical Conductivity),TDS(Total Dissolved Solids),salinity,bulk density,OM(Organic Matter),nitrate,phosphate,clay,silt,sand,and textural *** acasia and kinkeliba plants were used to decontaminate Cu and Cr from sample soils for 30 days *** bulk density of all the soil samples from Kouldawa was higher compared to Diguil,ranging from 1.421 to 1.64 g/cm^(3)compared to 1.21 to 1.51 g/cm^(3)for *** of the soils in Kouldawa are mineral soils,while those of Diguel are mostly mineral soil with some *** soils are richer in nitrate(577.9 to 2,687.32 mg/kg in Diguel and 33.64 to 197.64 mg/kg in Kouldawa)and phosphate than soils from *** from the studied areas are not saline except for a subsurface soil in Diguel(salinity,4.21;EC,4.280 dS/m;TDS,3,040 mg/L).The highest amount of Cr and Cu removed by acasia is 78%and 53.12%compared to 73.8%and 52.21%by *** soil can be very suitable for agriculture and Kouldawa soils for *** and kinkeliba can be effectively used to decontaminate the studied soils from heavy metal pollution.

关键词： Soil physico-chemical properties phytoremediation heavy metals Tchad.

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Effects of acid treatments on Moroccan Tarfaya oil shale and pyrolysis of oil shale and their kerogen

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燃料化学学报 2009年第6期37卷 659-667页

作者： ABOULKAS A El HARFI K laboratoire de Recherche sur la Reactivites des materiaux et IOptimisation des Procedes 《REMATOP》 Departement de chimie Faculte des Sciences Semlalia Universite Cadi Ayyad BP 2390 40001 Marrakech Maroc laboratoire lnterdisciplinaire de Recherche en Sciences et Techniques Faculte polydisciplinaire de Beni-Mellal Universite Sultan Moulay Slimane BP 592 23000 Beni-Mellal Maroc

In this study,the kerogen of oil shale from Moroccan Tarfaya deposits was isolated and the changes in the initial organic matter during the removal of the mineral matrix were *** extraction of the oil shale increases the intensity of the peaks in the X-ray *** spectra and X-ray diffractograms reveal the presence of mineral,calcite,quartz,kaolinite,and pyrite in the mineral matrix of the oil *** and hydrofluoric acids dissolution do not alter the organic *** nonisothermal weight loss measurements indicate that thermal decomposition of the isolated kerogen can be described by first-order reaction.A single kinetic expression is valid over the temperature range of kerogen pyrolysis between 433K and ***,the results indicate that the removal of mineral matter causes a decrease in the activation energies of the pyrolysis reactions of oil shale.

关键词：页岩矿物方解石氢氟酸

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