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Magmatic-hydrothermal Evolution and Mineralization Mechanisms of the Wangjiazhuang Cu(-Mo)Deposit in the Zouping Volcanic Basin,Shandong Province,China:Constraints from Fluid Inclusions

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Acta Geologica Sinica(English Edition) 2024年第3期98卷 679-700页

作者： SHU Lei YANG Renchao SHEN Kun YANG Deping MAO Guangzhou LI Min LIU Pengrui MA Xiaodong Shandong Provincial key laboratory of Depositional Mineralization and Sedimentary Minerals Shandong University of Science and TechnologyQingdaoShandong 266590China key laboratory of Gold Mineralization Processes and Resource Utilization MNR/Key Laboratory of Metallogenic Geological Processes and Resource UtilizationShandong Province/Shandong Institute of Geological SciencesJinan 250013China laboratory for Marine Mineral Resources Qingdao Marine Science and Technology CenterQingdaoShandong 266237China

The Wangjiazhuang Cu(-Mo)deposit,located within the Zouping volcanic basin in western Shandong Province,China,is unique in this area for having an economic *** order to expound the metallogenetic characteristics of this porphyry-like hydrothermal deposit,a detailed fluid inclusion study has been conducted,employing the techniques of representative sampling,fluid inclusion petrography,microthermometry,Raman spectroscopy,LA-ICP-MS analysis of single fluid inclusions,as well as cathode fluorescence spectrometer analysis of host mineral *** deposit contains mainly two types of orebodies,***-dissemination-stockwork orebodies in the K-Si alteration zone and pegmatiticquartz sulfide veins above *** addition,minor breccia ore occurs *** types of fluid inclusions in the deposit and altered quartz monzonite are identified:L-type one-or two-phase aqueous inclusions,V-type vapor-rich inclusions with V/L ratios greater than 50%-90%,D-type multiphase fluid inclusions containing daughter minerals or solids and S-type silicate-bearing fluid inclusions containing mainly muscovite and *** petrography and fluid inclusion study has revealed a three-stage mineralization process,driven by magmatic-hydrothermal fluid activity,as ***,a hydrothermal fluid,separated from the parent magma,infiltrated into the quartz monzonite,resulting in its extensive K-Si alteration,as indicated by silicate-bearing fluid inclusions trapped in altered quartz *** is followed by the early mineralization,the formation of quartz veinlets and dissemination-stockwork *** the main mineralization stage,due to the participation and mixing of meteoric groundwater with magmatic-sourced hydrothermal fluid,the cooling and phase separation caused deposition of metals from the hydrothermal *** a result,the pegmatitic-quartz sulfide-vein ores *** the late mineralization stage,decreasing fluid salinity led to the formation of L-type aqueous

关键词： fluid inclusions fluid immiscibility mineralization mechanisms Wangjiazhuang Cu(-Mo)deposit

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A clean disposal method of carbide slag with carbon emission reduction:Used as a flux for iron ore sintering Author links open overlay panel

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Particuology 2024年第8期91卷 303-314页

作者： Hanxiao Meng Jiankang Wang Xiang Liu Kelang Jin Lei Zhang Hao Zhou State key laboratory of Clean Energy Utilization Institute for Thermal Power EngineeringZhejiang UniversityHangzhou310027China

Limestone or quicklime is a necessary flux in the iron ore sintering *** production and application process will cause CO_(2) emissions and various environmental pollution,but this has not attracted enough *** slag(CS)is a calcium-rich solid waste produced in acetylene production,the harmless disposal of which is still incomplete,resulting in soil and groundwater *** study investigated the granulation characteristics and sintering performance of the sintering mixture with different proportions of *** results show that replacing limestone with an appropriate proportion of CS is promising and beneficial to the formation of high-quality bonding *** CS accounts for 75%of the total mass of CS and limestone,the tumbler index increases by 8.10%and the comprehensive index decreases only from 100 to 96.16,which is within the acceptable *** application of CS in iron ore sintering can achieve a clean disposal of it and a considerable carbon emission reduction,as the main component of which is Ca(OH)_(2).

关键词： Ironore sintering Carbide slag Flux Carbon emission Comprehensive index

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Characteristics and Genesis of Acid Drainage contamination from a Rock Tunneling Project Site

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Journal of Earth Science 2024年第1期35卷 190-200页

作者： Yanyun Li Zejiao Luo Shihua Qi Hubei key laboratory of Yangtze River Basin Environmental Aquatic Science School of Environmental StudiesChina University of GeosciencesWuhan 430078China State key laboratory of Biogeology and Environmental Geology China University of GeosciencesWuhan 430078China

While acid mine drainage(AMD)issues have become a topic of global concern,few studies have focused on acid drainage problems of non-mining *** conducted field research and a series of laboratory experiments to investigate the characteristics,release processes and formation of acid drainage *** rock samples and adjacent surface water,groundwater,soil and sediment samples were collected at a railway tunnel construction site in central China,and various parameters,such as the p H,mineral ion concentrations,and heavy metal concentrations,were *** on the measured concentrations,surface water and sediments were seriously contaminated by acids,sulfate salts and heavy *** in surface water showed a decreasing tendency as the distance from the spoils increased,while that in sediments showed a greater influence of coprecipitation and adsorption processes of heavy metal *** eluviation experiments of three rock samples indicated that R2(silty fine sandstone)was the most likely major acid drainage *** ferrooxidans was cultured and isolated from contaminated water to study the oxidation conditions during the release *** significant release of acid drainage when air and bacteria were both in the culture container suggested that oxygen and bacteria were necessary to produce acid drainage from spoils.

关键词： acid mine drainage heavy metals leaching oxidation

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Optimization of water-urban-agricultural-ecological land use pattern:A case study of Guanzhong Basin in the southern Loess Plateau of Shaanxi Province,China

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China Geology 2024年第3期7卷 480-493页

作者： Sai Wang Bin Wu Hai-xue Li Min-min Zhao Lei Yuan Xi Wu Tao Ma Fu-cheng Li Shuang-bao Han Center for Hydrogeology and Environmental Geology Survey China Geological SurveyMinistry of Natural ResourcesTianjin 300304China Center for groundwater Exploration and Development Engineering Research China Geological SurveyMinistry of Natural ResourcesTianjin 300304China School of Environmental Studies China University of GeosciencesWuhan430078China State Environmental Protection key laboratory of Source Apportionment and Control of Aquatic Pollution Hubei Key Laboratory of Yangtze Catchment Environmental Aquatic ScienceChina University of GeosciencesWuhan430078China

Extensive land use will cause many environmental *** is an urgent task to improve land use efficiency and optimize land use *** recent years,due to the flow decrease,the Guanzhong Basin in Shaanxi Province is confronted with the problem of insufficient water resources *** on the Coupled Ground-Water and Surface-Water Flow Model(GSFLOW),this paper evaluates the response of water resources in the basin to changes in land use patterns,optimizes the land use pattern,improves the ecological and economic benefits,and the efficiency of various spatial development,providing a reference for ecological protection and high-quality development of the Yellow River *** research shows that the land use pattern in the Guanzhong Basin should be further *** the condition of considering ecological and economic development,the percentage change of the optimum area of farmland,forest,grassland,water area,and urban area compared with the current land use area ratio is+2.3,+2.4,-6.1,+0.2,and+1.6,*** economic and ecological value of land increases by14.1%and 3.1%,respectively,and the number of water resources can increase by 2.5%.

关键词： Coupled Ground-Water and Surface-Water Flow Model(GSFLOW) Land use patterns Water resources optimization Ecological and economic benefits Coupling model Hydrological environmental engineering Guanzhong Basin Southern Loess Plateau Yellow River basin

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Spatial distribution,morphology,and risk assessment of microplastics in sediment from the Pearl River Estuary,China

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Emerging Contaminants 2024年第3期10卷 409-418页

作者： Kaiqiang Xu Asfandyar Shahab Jorg Rinklebe He Xiao Jieyue Li Feng Ye Yanhong Li Dunqiu Wang Michael S.Bank Gangjian Wei College of Environmental Science and Engineering Guilin University of TechnologyGuilin541004China Guangxi key laboratory of Environmental Pollution Control Theory and Technology Guilin541004China University of Wuppertal School of Architecture and Civil EngineeringInstitute of Foundation EngineeringWater-and Waste-ManagementLaboratory of Soil-and Groundwater-ManagementPauluskirchstraße 742285WuppertalGermany Institute of Marine Research 5817BergenNorway University of Massachusetts Amherst AmherstMA01003USA State key laboratory of Isotope Geochemistry Guangzhou Institute of GeochemistryChinese Academy of SciencesGuangzhou510640China

Microplastics(MPs)(64.12%)of detected MPs were<0.85 mm and primarily consisted of pellets(36.84%)and fragments(29.65%).Three polymer types of MPs were identified by Fourier Transform Infrared Spectroscopy(FT-IR)includ... 详细信息

Microplastics(MPs)(64.12%)of detected MPs werecontamination in PRE sediment as category Ⅲ,indicating severe ecosystem *** results may serve as an effective model for other estuaries facing similar pollution regimes and provides valuable information for marine sediment risk assessment.

关键词： Microplastics Distributional characteristics Surface morphology Risk assessment Pearl River Estuary

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Thermal and hydrological processes in permafrost slope wetlands affect thermosyphon embankment stability

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Advances in Climate Change Research 2024年第4期15卷 680-694页

作者： Bo-Wen TAI Qing-Bai WU Xiao-Ming XU State key laboratory of Frozen Soil Engineering Key Laboratory of Cryospheric Science and Frozen Soil EngineeringNorthwest Institute of Eco-Environment and ResourcesChinese Academy of SciencesLanzhou 730000China School of Engineering Science University of Chinese Academy of SciencesBeijing 100049China

To ensure the long-term service performance of infrastructure such as railways,highways,airports and oil pipelines built on permafrost slope wetland sites,it is imperative to systematically uncover the long-term heat-water changes of soil in slope wetlands environment under climate *** specifically,considering valuable field data from 2001 to 2019,the long-term heat and water changes in active layers of the slope wetland site along the Qinghai-Xizang Railway(QXR)are illustrated,the effect of thermosyphon measures in protecting the permafrost environment is evaluated,and the influences of climate warming and hydrological effects on the stability of slope wetland embankments are systematically *** permafrost at the slope wetland site is rapidly degrading,demonstrating a reduction in active layer thickness of>3.7 cm per year and a permafrost temperature warming of>0.006℃ per *** thermosiphon embankment developed by QXR has a specific cooling period;thus,to mitigate the long-term impacts of climate warming on the thermal stability of permafrost foundation,it is essential to implement strengthening measures for the thermosiphon embankment,such as adding a crushed-rock layer or sunshade board on the slope of thermosiphon embankment to creating a composite cooling ***-term seasonal groundwater seepage intensifies frost damage to the slope wetland embankment,while long-term seasonal supra-permafrost water and groundwater seepage exacerbates uneven transverse deformation of slope wetland ***-term climate warming and slope effects have altered the surface water and groundwater hydrological processes of slope wetlands,potentially leading to an increased occurrence of slope embankment *** results are crucial for improving our understanding of heat and water variation processes in the active layer of slope wetland sites located in permafrost regions and ensuring long-term service safety for the QXR.

关键词： Heat and water process Active layer Slope wetland Permafrost environment Thermosyphon embankment

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Application of "Three-in-One" Strategy Based on MOF-199 in Determination of Phenylenediamine Isomers and Cr(Ⅵ)

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Journal of Analysis and Testing 2024年第1期8卷 28-39页

作者： Yueci Xiang Jiantao Wei Huipeng Sun Ruiyi Zhao Zehua Han Shuangtong Wu Xiaoyan Liu Haixia Zhang State key laboratory of Applied Organic Chemistry and College of Chemistry and Chemical Engineering Lanzhou UniversityLanzhou 730000China

Industry progressing caused the pollutants into the surface and groundwater,including organic pollutants such as phenylenediamine(PD)and heavy metals such as Cr(Ⅵ).Herein,a simple"three-in-one"strategy based on MOF-199 was *** MOF-199 catalytic system could be used for the rapid detection of Cr(Ⅵ)and o-phenylenediamine(OPD)in linear ranges of 0.5-50.0μmol/L and 7.0-250.0μmol/L,with the limits of detection of 0.1 and 0.5μmol/L,*** method can also efficiently discriminate PD isomers in just 15 ***,Cr(Ⅵ)was reduced to Cr(Ⅲ)and the elimination of OPD was carried *** simple synthesis,high sensitivity,easy operation,and low cost,this method presented a potential platform for on-site detection of pollutants in water samples.

关键词： On-site detection “Three-in-one”strategy Phenylenediamine isomers

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Effects of the Rainfall-Triggered Lisse Effect on the Stability of Loess Slopes

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Journal of Earth Science 2024年第4期35卷 1254-1262页

作者： Zhizhou Yang Donghui Cheng Jun Xia School of Water and Environment Chang’an UniversityXi’an710054China key laboratory of Subsurface Hydrology and Ecological Effects in Arid Region of the Ministry of Education Chang’an UniversityXi’an710054China key laboratory of Eco-Hydrology and Water Security in Arid and Semi-Arid Regions of the Ministry of Water Resources Chang’an UniversityXi’an710054China key laboratory of Water Cycle&Related Land Surface Processes Institute of Geographic Sciences and Natural Resources ResearchChinese Academy of SciencesBeijing100101China State key laboratory of Water Resources&Hydropower Engineering Sciences Wuhan UniversityWuhan430000China

This paper coupled a water-air two-phase hydrodynamic(WATPH)model with the Iverson’s method to analyze the influence of the Lisse effect on the fast groundwater pressure(P_(w))response and the slope ***,the sensitivities of the driving force and loess soil parameters were *** showed that the WATPH model simulated the height and rise of the depth to the water table reasonably *** depth to water table before rainfall(H0)had a significant impact on the Lisse effect and the slope *** the H_(0) was less than approximately 1 m,the rainfall triggered a significant Lisse effect and decreased the slope factor of safety(F_(s)).When the rainfall intensity(R_(i))was higher than the saturated hydraulic conductivity(K_(s)),the Lisse effect and the F_(s) slightly changed with the increase of the R_(i),and the slope tended to be unstable with continuous *** increasing K_(s),the Lisse effect noticeably increased,and the minimum F_(s) quickly *** analysis of the normalized sensitivity coefficient revealed that H_(0) had a dramatic impact on the Lisse effect and loess slope *** different R_(i) and K_(s) values had prominent influences on the Lisse effect and slight impacts on F_(s).

关键词： Lisse effect landslides safety factor rainfall

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Feasibility of compacted attapulgite/diatomite amended clayey soils as gas barrier materials

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第9期16卷 3707-3717页

作者： Heng Zhuang Wei-Yi Xia Jia-Ming Wen Min Wang Ying-Zhen Li Ning-Jun Jiang Konstantin S.Rodygin Yan-Jun Du Jiangsu key laboratory of Low Carbon and Sustainable Geotechnical Engineering Institute of Geotechnical EngineeringSoutheast UniversityNanjing211189China Jiangsu Province Ecology and Environment Protection Engineering Research Center of groundwater Pollution Prevention and Control Jiangsu Environmental Engineering Technology Co.Ltd.Nanjing210036China Zijin(Changsha)Engineering Technology Co. Ltd.Changsha410006China Institute of Chemistry Saint Petersburg State UniversityStary Petergof198504Russia

Compacted clay liners are extensively used as barriers to control the upward diffusion of vapors of volatile or semi-volatile organic contaminants released from unsaturated contaminated soils at industrycontaminated *** study aimed to investigate the gas diffusion barrier performance of compacted clayey soils amended with three agents including attapulgite and diatomite individually,and attapulgite/diatomite *** properties including water retention,volumetric shrinkage,gas diffusion,and unconfined compressive strength were evaluated through a series of laboratory tests of amended compacted clayey *** results demonstrate that the decrease in volume proportions of interaggregate pores leads to an increase in unconfined compressive strength(qu).Both hydrophilic groups and microstructures of attapulgite and diatomite result in an increase in water retention percent(Wt)of compacted clayey soil specimens after amendment regardless of the type of agent or initial water content(w0).Furthermore,the ratio of the gas diffusion coefficient(De)to the gas diffusion coefficient in the air(Da)was significantly reduced owing to a decrease in volume proportions of inter-aggregate pores,hydrophilic group,and microstructures of attapulgite and *** electron microscope analyses revealed that rod-shaped attapulgite filled the inter-aggregate pores formed by clay particles,whereas the disc-shaped diatomite particles,characterized by micropores,failed to obstruct the interaggregate pores due to their larger particle *** intrusion porosimetry(MIP)analyses showed a reduction in pore volume in the inter-aggregate pores,leading to a reduction in the total pore volume for both the attapulgite and attapulgite/diatomite mixture amended clays,which is in accordance with the scanning electron microscope(SEM)*** findings are pertinent to the practical application of compacted clay liners as gas barriers against the upward migration of volatile or s

关键词： Compacted clay liner Attapulgite/diatomite mixture Diffusion barrier Water retention

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groundwater contaminant source identification considering unknown boundary condition based on an automated machine learning surrogate

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Geoscience Frontiers 2024年第1期15卷 402-416页

作者： Yaning Xu Wenxi Lu Zidong Pan Chengming Luo Yukun Bai Shuwei Qiu key laboratory of groundwater Resources and Environment Ministry of EducationJilin UniversityChangchun 130021China Jilin Provincial key laboratory of Water Resources and Environment Jilin UniversityChangchun 130021China College of New Energy and Environment Jilin UniversityChangchun 130021China School of Water Resources and Environment Hebei GEO UniversityShijiazhuang 050031China

groundwater contamination source identification(GCSI)is a prerequisite for contamination risk evaluation and efficient groundwater contamination remediation *** boundary condition generally is set as known variables in previous GCSI ***,in many practical cases,the boundary condition is complicated and cannot be estimated accurately in *** the boundary condition as known variables may seriously deviate from the actual situation and lead to distorted identification *** the results of GCSI are affected by multiple factors,including contaminant source information,model parameters,boundary condition,***,if the boundary condition is not estimated accurately,other factors will also be estimated *** study focuses on the unknown boundary condition and proposed to identify three types of unknown variables(contaminant source information,model parameters and boundary condition)*** simulation-optimization(S-O)method is applied to GCSI,the huge computational load is usually reduced by building surrogate ***,when building surrogate models,the researchers need to select the models and optimize the hyperparameters to make the model powerful,which can be a lengthy *** automated machine learning(AutoML)method was used to build surrogate model,which automates the model selection and hyperparameter optimization in machine learning engineering,largely reducing human operations and saving *** accuracy of AutoML surrogate model is compared with the surrogate model used in eXtreme Gradient Boosting method(XGBoost),random forest method(RF),extra trees regressor method(ETR)and elasticnet method(EN)respectively,which are automatically selected in AutoML *** results show that the surrogate model constructed by AutoML method has the best accuracy compared with the other four *** study provides reliable and strong support for GCSI.

关键词： groundwater contamination source Boundary condition Automated machine learning Surrogate model

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