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Enhancing the photocatalytic efficiency by the molecular modification effect derived from pollutant adsorption on highly crystalline BiOBr

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Journal of Environmental Sciences 2025年第2期148卷 263-273页

作者： Yang Jin Tongyin Liu Yanpeng Mao Fan Li Chun Hu National Engineering laboratory for Reducing Emissions from Coal Combustion Engineering Research Center of Environmental Thermal Technology of Ministry of EducationShandong Key Laboratory of Energy Carbon Reduction and Resource UtilizationSchool of Energy and Power EngineeringShandong UniversityJinan 250061China Beijing Enterprises water GroupInvestment Limited Beijing 100102China Institute of Environmental Research at Greater Bay Key Laboratory for Water Quality and Conservation of the Pearl River DeltaMinistry of EducationGuangzhou UniversityGuangzhou 510006China key laboratory of Drinking water Science and Technology Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China

The adsorption of pollutants can not only promote the direct surface reaction,but also modify the catalyst itself to improve its photoelectric characteristics,which is rarely studied for water treatment with inorganic photocatalyst.A highly crystalline BiOBr(c-BiOBr)was synthesized by a two-step preparation *** to the calcination,the highly crystalline enhanced the interface interaction between pollutant and *** complex of organic pollutant and[Bi_(2)O_(2)]^(2+)could promote the active electron transfer from the adsorbed pollutant to c-BiOBr for the direct pollutant degradation by holes(h^(+)).Moreover,the pollutant adsorption actually modified c-BiOBr and promoted more unpaired electrons,which would coupling with the photoexcitation to promote generate more O_(2)^(•-).The molecular modification effect derived from pollutant adsorption significantly improved the removal of *** work strongly deepens the understanding of the molecularmodification effect from the pollutant adsorption and develops a novel and efficient approach for water treatment.

关键词： Highly crystalline BiOBr Pollutant adsorption Molecular modification Photocatalysis water treatment

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Comparative characterization of two natural humic acids in the pearl river Basin, China and their environmental implications

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Journal of Environmental Sciences 2010年第11期22卷 1695-1702页

作者： Juan Liu Jin Wang Yongheng Chen Holger Lippold Johanna Lippmann-Pipke key laboratory of water safety and protection in the pearl river delta Ministry of Education Guangzhou University Guangzhou 510006 China. Forschungzentrum Dresden Rossendorf Institute of Radiochemistry Research Site Leipzig Leipzig 04318 Germany

Two humic acids （HAs） were isolated from contaminated river sediments present under comparative conditions in the pearl river Basin, China. YFHA （the HA extracted at an open pyrite mining area in Yunfu） exhibited a lower absorption intensity for certain bands in the Fourier transform infrared spectra, a lower E 4 /E 6 value （the UV absorbances at 465 nm （E 4 ） and 665 nm （E 6 ））, a lower apparent molecular weight, a lower polarity and a lower oxygen functionality in comparison with GZHA （the HA isolated at an urban living area in Guangzhou）. All these differences indicated a higher degree of humification of YFHA than GZHA. Overall, the enrichment patterns of permanent heavy metals in the studied HAs were similar to those in corresponding sediments. In particular, YFHA exhibited high enrichment of trace element Tl, a characteristic concomitant from the mining of the pyrite minerals. The adsorption isotherms of two HAs for goethite and pyrolusite, two representative geological materials, conformed to the Langmuir equation. Based on the qualitative relationships between the Langmuir constants of the adsorption isotherms and the chemical characteristics of HAs, the main mechanism of HA adsorption on these materials was suggested to be hydrophobic interaction. This study highlighted the promising use of HA as a peculiar bio-indicator of uncommon trace metal contaminations. The HA adsorption mechanism on representative geological materials further provided a theoretical basis for the study on the unusual metal behavior in complex environmental settings.

关键词： humic acid permanent metal load adsorption goethite pyrolusite

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Polydopamine-modified biochar supported polylactic acid and zero-valent iron affects the functional microbial community structure for 1,1,1-trichloroethane removal in simulated groundwater

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Chinese Chemical Letters 2025年第1期36卷 420-426页

作者： Haitao Yin Liang Meng Li Li Jiamu Xiao Longrui Liang Nannan Huang Yansong Shi Angang Zhao Jingwen Hou School of Environmental and Geographical Sciences Shanghai Normal UniversityShanghai 200234China Yangtze river delta Urban Wetland Ecosystem National Field Scientific Observation and Research Station Shanghai 201722China Instrumental Analysis Center Shanghai Jiao Tong UniversityShanghai 200240China

In-situ enhanced bioreduction by functional materials is a cost-effective technology to remove chlorinated hydrocarbons in ***,a novel polydopamine(PDA)-modified biochar(BC)-based composite containing nanoscale zero-valent iron(n ZVI)and poly-l-lactic acid(PLLA)(PB-PDA-Fe)was synthesized to enhance the removal of 1,1,1-trichloroethane(1,1,1-TCA)in simulated groundwater with actual site *** impact on functional microbial community structure in system was also *** typical characterizations revealed uniform dispersion of PLA and n ZVI particles on the BC surface,being smoother after PDA *** composite exhibited a significantly higher performance on 1,1,1-TCA removal(82.38%,initial concentration 100 mg/L)than Fe-PDA and PB-PDA *** diversity and richness of the microbial community in the composite treatment consistently decreased during incubation due to a synergistic effect between PLLA-BC and n ***,Pedobacter,Sphaerochaeta,Shewanella,and Clostridium were identified as enriched genera by the composite through DNA-stable isotope probing(DNA-SIP),playing a crucial role in the bioreductive dechlorination *** the above results demonstrate that this novel composite selectively enhances the activity of microorganisms with extracellular respiration functions to efficiently dechlorinate 1,1,*** findings could contribute to understanding the responsive microbial community by carbon-iron composites and expedite the application of in-situ enhanced bioreduction for effective remediation of chlorinated hydrocarbon-contaminated groundwater.

关键词： Biochar-based composite Bioreductive dechlorination 1,1,1-TCA Extracellular respiration microorganisms Groundwater

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Experimental study on flocculation and sedimentation characteristics of cohesive fine sediment measured using ultrasound in the pearl river Estuary

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International Journal of Sediment Research 2023年第6期38卷 880-890页

作者： Qinqin Liu Xiaojian Liu Jian Chen Peng Hou Yong He Qisong Wang Xiaowei Zhu Qiang Wang Huan Gao pearl river Hydraulic Research Institute Pearl River Water Resources Commission of the Ministry of Water Resources key laboratory of the pearl river Estuary Regulation and protection of the Ministry of water Resources School of water Conservancy North China University of Water Resources and Electric Power Department of the College of water Conservancy and Hydropower Engineering Hohai University

Flocculation-settling of cohesive fine sediment is the main cause of sediment deposition and changes in topography and geomorphology in ***,studies on estuary morphology have often focused on a single influencing factor,and sediment deposition characteristics under disturbances in sediment concentration,moisture content,and external forces have rarely been considered *** authors propose an ultrasound-assisted flocculation-settling method to analyze the various factor affecting cohesive *** current study examined the sedimentation patterns of cohesive sediment with a sediment content concentration of 30%-80% through ultrasound *** results show that when the sediment concentration is 40%-50%,the best effect on flocculation and sedimentation is induced by ultrasound *** corresponding settling height at the clear-muddy water interface is 3.05-3.45 cm,and the settling rate is 0.161-0.173 cm/***,using ultrasound waves,a moisture content of the sediment concentration of 30%-80% was analyzed based on wet and dry *** a sediment concentration of 50% as an example,the maximum values of the variation in the water contents of the upper,middle,and lower layers of the wet basis were 0.82%,0.51%,and0.37%,respectively,whereas those of the upper,middle,and lower layers of the dry basis were 4.77%,1.07%,and 0.60%,***,the moisture content of dry and wet sediment varied as follows:Wupper> Wmiddle> *** current research results can provide a theoretical basis and technical reference for siltation in channels,harbors,and reservoirs;the evolution of submarine deltas and coastal beaches;transportation of fluid mud;and the treatment of hyper-concentrated sediment flows.

关键词： Cohesive sediment Flocculation-settling Moisture content Ultrasound experiments

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Enhanced Fenton-like process over Cu/L(+)-ascorbic acid co-doping mesoporous silica for toxicity reduction of emerging contaminants

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Frontiers of Environmental Science & Engineering 2024年第4期18卷 49-60页

作者： Yuhang Liu Wenxuan Deng Xiaojun Wu Chun Hu Lai Lyu key laboratory for water Quality and Conservation of the pearl river delta(Ministry of Education) Institute of Environmental Research at Greater BayGuangzhou UniversityGuangzhou 510006China

Effective removal of emerging contaminants(ECs)to minimize their impacts on human health and the natural environment is a global *** the removal of ECs in water,we fabricated a seaweed spherical microsphere catalyst with Cu cation-πstructures by in situ doping of Cu species and ascorbic acid in mesoporous silica(Cu-C-MSNs)via a hydrothermal *** results indicate that bisphenol A(BPA)is substantially degraded within 5 min under natural conditions,with its biological toxicity considerably ***,industrial wastewater could also be effectively purified by Cu-C-MSNs/H_(2)O_(2) *** presence of metal sites and the complexation of ECs via cation-πinteraction andπ-πstacking on the catalyst surface were directly responsible for the polarization distribution of electrons,thus activating H_(2)O_(2) and dissolved oxygen(DO).The removal of contaminants could be attributed primarily to 1)the activation of H_(2)O_(2) into ^(·)OH to attack the contaminants and 2)self-cleavage because of the transfer of electrons from the contaminants to the *** study provides an innovative solution for the effective treatment of ECs and has positive implications for easing global environmental crises.

关键词： Cation-πstructures Polarization electric field Fenton-like process Contaminants cleavage

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Dual-reaction-center catalytic process continues Fenton's story

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Frontiers of Environmental Science & Engineering 2020年第5期14卷 65-73页

作者： Chao Lu Kanglan Deng Chun Hu Lai Lyu Institute of Environmental Research at Greater Bay Area Key Laboratory for Water Quality and Conservation of the Pearl River Delta(Ministry of Education)Guangzhou UniversityGuangzhou 510006China

Triggered by global water quality safety issues,the research on wastewater treatment and water purification technology has been greatly developed in recent *** Fenton technology is particularly powerful due to the rapid attack on pollutants by the generated hydroxyl radicals(·OH).However,both heterogeneous and homogeneous Fenton/Fenton-like technologies follow the classical reaction mechanism,which depends on the oxidation and reduction of the transition metal ions at single *** even after a century of development,this reaction still suffers from its inherent bottlenecks in practical *** recent years,our group has been focusing on studying a novel heterogeneous Fenton catalytic process,and we developed the dual-reaction-center(DRC)system for the first *** the DRC system,H2O2 and O2 can be efficiently reduced to reactive oxygen species(ROS)in electron-rich centers,while pollutants are captured and oxidized by the electron-deficient *** obtained electrons from pollutants are diverted to the electron-rich centers through bonding *** process breaks through the classic Fenton mechanism,and improves the performance and efficiency of pollutant removal in a wide pH ***,we provide a brief overview of Fenton's story and focus on combing the discovery and development of the DRC technology and mechanism in recent *** construction of the DRC and its performance in the pollutant degradation and interfacial reaction process are described in *** look forward to bringing a new perspective to continue Fenton's story through research and development of DRC technology.

关键词： Dual reaction centers Fenton Pollutant utilization Electron transfer

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Cationic surface polarization centers on ionic carbon nitride for efficient solar-driven H_(2)O_(2) production and pollutant abatement

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Chinese Chemical Letters 2024年第10期35卷 383-388页

作者： Zhenyu Hu Zhenchun Yang Shiqi Zeng Kun Wang Lina Li Chun Hu Yubao Zhao MOE key laboratory for water Quality and Conservation of the pearl river delta Institute of Environmental Research at Greater BayGuangzhou UniversityGuangzhou510006China

Solar-driven H_(2)O_(2)production and emerging organic pollutants(EOPs)elimination are of great significance from the perspective of environmental *** efficiency of the photocatalytic reaction system is the key challenge to be *** this work,the strategy of constructing surface ionic local polarization centers to enhance the exciton dissociation of the polymeric photocatalytic is *** bipyridinium cation(TMAP)is complexed on a K^(+)-incorporated carbon nitride(CNK)framework,and the combination of local polarization centers both on the surface(bipyridinium cation)and bulk(K+cation)contributes to a superior photocatalytic H_(2)O_(2)production performance,affording a remarkable H_(2)O_(2)generation rate of 46.8μmol h^(-1)mg^(-1)and a high apparent quantum yield(AQY)value of 77.5%under irradiation of 405 nm *** substantiated experimentally by steady state/transient spectroscopy techniques,the surface local polarization centers increase the population of the long-lived trapped electrons,and thereby promote the interfacial charge transfer process for chemical conversion *** strategy is potentially applicable to the design of a wide range of efficient solar-to-chemical conversion systems.

关键词： Local polarization Oxygen reductionreaction Hydrogen peroxide production Pollutantdegradation Polymeric carbon nitride

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One-year survey of opportunistic premise plumbing pathogens and free-living amoebae in the tap-water of one northern city of China

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Journal of Environmental Sciences 2019年第3期31卷 20-31页

作者： Lizhong Liu Xueci Xing Chun Hu Haibo Wang key laboratory of Drinking water Science and Technology Research Center for Eco-Environmental Sciences Chinese Academy of Sciences University of Chinese Academy of Sciences key laboratory for water Quality and Conservation of the pearl river delta Ministry of Education Institute of Environmental Research at Greater Bay Guangzhou University

In this study, qPCR was used to quantify opportunistic premise plumbing pathogens(OPPPs) and free-living amoebae in 11 tap water samples collected over four seasons from a city in northern China. Results demonstrated that the average numbers of gene copies of Legionella spp. and Mycobacterium spp. were significantly higher than those of Aeromonas spp.(p 0.05). Moderate negative correlations between the chlorine concentration and the gene copy numbers of OPPPs were observed by Spearman analysis(rsranged from -0.311 to -0.710, p water.

关键词： Opportunistic premise plumbing pathogens(OPPPs) Free-living amoebae(FLA) Drinking water distribution systems(DWDS) Tap-water Quantitative PCR(qPCR)

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O_3-BAC-Cl_2: A multi-barrier process controlling the regrowth of opportunistic waterborne pathogens in drinking water distribution systems

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Journal of Environmental Sciences 2019年第2期31卷 142-153页

作者： Lizhong Liu Xueci Xing Chun Hu Haibo Wang key laboratory of Drinking water Science and Technology Research Center for Eco-Environmental SciencesChinese Academy of Sciences University of Chinese Academy of Sciences key laboratory for water Quality and Conservation of the pearl river delta Ministry of EducationInstitute of Environmental Research at Greater BayGuangzhou University

Simulated drinking water distribution system(DWDS) treated with O_3-BAC-Cl_2(ozonebiological activated carbon-chlorine) was constructed to study its effects on the regrowth of five typical opportunistic pathogens(OPs). It was found that O_3-BAC-Cl_2 could significantly reduce the regrowth of target OPs in the effluents of DWDS compared with Cl_2 and O_3-Cl_2 with the same residual chlorine levels. However, the effect of O_3-BAC-Cl_2 on the average numbers of target OPs gene markers in the biofilms of DWDS was not apparent, suggesting that OPs in the biofilms of DWDS were tolerant to the upstream disinfection process. The quantification of target OPs in the BAC-filter column demonstrated that OPs decreased with the increase of depth, which was likely due to the organic nutrient gradient and microbial competition inside the BAC-filter. Increase in the ozone dose could further reduce the OPs at the bottom of the BAC-filter. Spearman correlation analysis demonstrated that some significant correlations existed between target microorganisms, suggesting potential microbial ecological relationships. Overall, our results demonstrated that the BAC-filter may act as a "battlefield"suppressing the OPs through microbial competition. O_3-BAC-Cl_2 could be an effective multibarrier process to suppress the proliferation of OPs in the bulk water of DWDS. However, OPs protected by the biofilms of DWDS should receive further attention because OPs may be detached and released from the biofilms.

关键词： Opportunistic pathogens (OPs) O3-BAC-Cl2 DWDS qPCR

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Geochemical distribution, fractionation, and sources of heavy metals in dammed-river sediments: the Longjiang river, Southern China

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Acta Geochimica 2019年第2期38卷 190-201页

作者： Xiaolong Lan Zengping Ning Yizhang Liu Qingxiang Xiao Haiyan Chen Enzong Xiao Tangfu Xiao State key laboratory of Environmental Geochemistry Institute of Geochemistry Chinese Academy of Sciences University of Chinese Academy of Sciences key laboratory for water Quality and Conservation of the pearl river delta Ministry of Education School of Environmental Science and Engineering Guangzhou University

In the present study, six sediment cores were collected from six river-dammed reservoirs to reveal the geochemical distribution of heavy metals(As, Cd, Pb, Sb,and Zn) in the Longjiang river, South China, which is highly impacted by nonferrous metal mining and smelting activities. The sediments were geochemically characterized, combining geochemical analysis, sequential extractions, and210 Pb chronology. The results indicated that the river sediments were severely polluted by heavy metals in the order of Cd [ Zn & Pb & Sb [ As. These heavy metals generally exhibited relatively low enrichment in the upstream sediments because of the limited anthropogenic impact, but their abundances drastically increased in the midstream sediments due to local smelting activities. In downstream sediments, the heavy metal concentrations(except for Cd) decreased, owing to the effect of dam interception and detrital inputs. Cadmium levels tended to increase in downstream sediments, which were attributed to the intensive discharge of Cd during the pollution event in 2012. The sedimentary records were traced back to1985, and a significant decrease of heavy metal enrichments could be found after the year 2000, suggesting the enhancement of environmental management in this *** statistical results indicated that local metal smelting and mining activities were the main anthropogenic contributors for the enrichment of heavy metals in the dammed-river sediments. High enrichment factor and nonresidual fractions of heavy metals in local sediments may pose a direct threat to aquatic organisms. Cd presents significant danger because of its extreme enrichment and high labile fractions.

关键词： Heavy metals Fractionation 210pb dating Smelting and mining activities Sediment cores The Longjiang river

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