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Thermo-hydro-mechanical (THM) coupled simulation of the land subsidence due to aquifer thermal energy storage (ATES) system in soft soils

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第6期16卷 1952-1966页

作者： Yang Wang Fengshou Zhang Fang Liu Department of Geotechnical Engineering College of Civil EngineeringTongji UniversityShanghai200092China key laboratory of Geotechnical and Underground Engineering of Ministry of Education Tongji UniversityShanghai200092China Shanghai Engineering and Technology Research Center of shallow geothermal energy Shanghai200072China

Aquifer thermal energy storage(ATES)system has received attention for heating or cooling buildings.However,it is well known that land subsidence becomes a major environmental concern for ATES projects.Yet,the effect of temperature on land subsidence has received practically no attention in the past.This paper presents a thermo-hydro-mechanical(THM)coupled numerical study on an ATES system in Shanghai,China.Four water wells were installed for seasonal heating and cooling of an agriculture greenhouse.The target aquifer at a depth of 74e104.5 m consisted of alternating layers of sand and silty sand and was covered with clay.Groundwater level,temperature,and land subsidence data from 2015 to 2017 were collected using field monitoring instruments.Constrained by data,we constructed a field scale three-dimensional(3D)model using TOUGH(Transport of Unsaturated Groundwater and Heat)and FLAC3D(Fast Lagrangian Analysis of Continua)equipped with a thermo-elastoplastic constitutive model.The effectiveness of the numerical model was validated by field data.The model was used to reproduce groundwater flow,heat transfer,and mechanical responses in porous media over three years and capture the thermo-and pressure-induced land subsidence.The results show that the maximum thermoinduced land subsidence accounts for about 60%of the total subsidence.The thermo-induced subsidence is slightly greater in winter than that in summer,and more pronounced near the cold well area than the hot well area.This study provides some valuable guidelines for controlling land subsidence caused by ATES systems installed in soft soils.

关键词： Aquifer thermal energy storage(ATES) Land subsidence TOUGH-FLAC3D Thermo-elastoplastic constitutive model

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The mechanism of microwave rock breaking and its potential application to rock-breaking technology in drilling

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Petroleum Science 2022年第3期19卷 1110-1124页

作者： Ming-Zhong Gao Ben-Gao Yang Jing Xie Si-Qi Ye Jun-Jun Liu Yi-Ting Liu Rui-Feng Tang Hai-Chun Hao Xuan Wang Xiang-Yue Wen Xue-Min Zhou Guangdong Provincial key laboratory of Deep Earth Sciences and geothermal energy Exploitation and Utilization College of Civil and Transportation EngineeringShenzhen UniversityShenzhenGuangdong518060China State key laboratory of Hydraulics and Mountain River Engineering College of Water Resource&HydropowerSichuan UniversityChengduSichuan610065China

The exploration and development of oil and gas resources have shifted from shallow to deep and ultradeep.The difficulty of rock breaking has also increased,introducing new challenges to traditional rock-breaking technology.Hence,there is an urgent need to develop new rock-breaking technologies to improve the development efficiency of deep oil and gas resources.Therefore,this study focused on the new microwave rock-breaking technology and conducted experimental and numerical simulation research on typical deep,hard rock granite.The research results showed that granite in the microwave field exhibited high-temperature melting and fracture,and the highest temperature could reach 550°C.Under the irradiation of circulating microwaves,a minimum irradiation time threshold of 3 min was needed to cause irreversible damage to the rock.The numerical simulation results showed that the interaction of thermal stress and in situ stress would cause the inside of the rock stratum to separate into a disturbed deterioration area,disturbed unloading area and initial stress area.These results are expected to provide the necessary technical guidance and theoretical support for the research and development of high-efficiency rock-breaking drilling for deep hard rock.

关键词： Microwave Well drilling High efficiency Granite

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Investigation of Electrical Parameters of Fresh Water and Produced Mixed Injection in High-Salinity Reservoirs

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Fluid Dynamics & Materials Processing 2023年第10期19卷 2695-2706页

作者： Jun Li Guofeng Cheng Hongwei Xiao Xiang Li Lizhi Wang Hui Xu Yu Wang Nannan Liu Shangping Chen Xing Shi PetroChina Research Institute of Petroleum Exploration&Development Beijing100083China Changqing Oilfield No.5 Oil Production Plant PetroChinaXi’an710000China Exploration and Development Research Institute of Daqing Oilfield Co. Ltd.Daqing163712China Key Laboratory of Shallow Geothermal Energy Ministry of Natural Resources of the People’s Republic of ChinaBeijing100195China Jiangsu key laboratory of Oil-Gas Storage and Transportation Technology School of Petroleum and Natural Gas EngineeringChangzhou UniversityChangzhou213164China Sinopec International Petroleum Exploration and Production Corporation Beijing100029China

Assuming a reservoir with a typical salt-lake background in the Qaidam Basin as a testbed,in this study the var-iation law of the rock electrical parameters has been determined through water displacement experiments with different salinities.As made evident by the results,the saturation index increases with the degree of water injec-tion.When the salinity of the injected water is lower than 80000 ppm,the resistivity of the rock sampleﬁrst decreases,then it remains almost constant in an intermediate stage,andﬁnally it grows,thereby giving rise to a‘U’proﬁle behavior.As the salinity decreases,the water saturation corresponding to the inﬂection point of the resistivity becomes lower,thereby leading to a wider‘U’type range and a higher terminal resistivity.For dif-ferent samples,higher initial resistivity of the sample in the oil-bearing state,and higher resistivity after low-sali-nity water washing are obtained when a thicker lithology is considered.

关键词： High salinity reservoir mixed injection saturation index resistivity electrical parameters

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Bacterial succession in epiphytic biofilms and deciduous layer sediments during Hydrilla verticillata decay: A field investigation

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Journal of Environmental Sciences 2020年第7期32卷 193-201页

作者： Tingting Si Hezhou Chen Zheng Qiu Lisha Zhang Okugbe Ebiotubo Ohore Songhe Zhang Ministry of Education key laboratory of Integrated Regulation and Resource Development on shallow Lakes College

Submersed macrophytes decay is an important natural process and has important role in mass and energy flow in aquatic ecosystems.However,little is known about the dynamical changes in nutrients release and bacterial community during submersed macrophyte decay in natural environment.In this study,a field observation was conducted in a wetland dominated with Hydrilla verticillata for 36 days.Increase of H2O2 and malondialdehyde(MDA)content and decrease of soluble proteins concentration were detected in leaves during H.verticillata decay.Meanwhile,ammonium-N,soluble microbial products(SMP)and TOC concentration increased in overlying water.According to bacterial 16 S r RNA Illumina sequencing analysis,the Shannon values were lower in epiphytic biofilms than deciduous layer sediments.The relative abundances of Proteobacteria,Cyanobacteria and Actinobacteria were higher in epiphytic biofilms than in deciduous layer sediments(P0.6)were identified from 122 and 112 genera in epiphytic biofilms and deciduous layer sediments,respectively.According to co-occurrence patterns,eight hubs were mainly from phyla Proteobacteria,Acidobacteria and Parcubacteria in epiphytic biofilms;while 37 hubs from the 14 phyla(Proteobacteria,Bacteroidetes,Acidobacteria,Chloroflexi,et al.)were detected in deciduous layer sediments.Our results indicate that bacterial community in deciduous layer sediments was more susceptible than in epiphytic biofilms during decay process.These data highlight the role of microbial community in deciduous layer sediments on nutrients removal during H.verticillata decay and will provide useful information for wetland management.

关键词： Submersed macrophyte Decay Biofilm Bacterial community Co-occurrence network

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Insight into the interaction between trimethoprim and soluble microbial products produced from biological wastewater treatment processes

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Journal of Environmental Sciences 2023年第2期124卷 130-138页

作者： Runze Xu Fang Fang Longfei Wang Jingyang Luo Jiashun Cao key laboratory of Integrated Regulation and Resource Development on shallow Lakes Ministry of EducationCollege of EnvironmentHohai UniversityNanjing 210098China

Soluble microbial products(SMPs),dissolved organic matter excreted by activated sludge,can interact with antibiotics in wastewater and natural water bodies.Interactions between SMPs and antibiotics can influence antibiotic migration,transformation,and toxicity but the mechanisms involved in such interactions are not fully understood.In this study,integrated spectroscopy approaches were used to investigate the mechanisms involved in interactions between SMPs and a representative antibiotic,trimethoprim(TMP),which has a low biodegradation rate and has been detected in wastewater.The results of liquid chromatography-organic carbon detection-organic nitrogen detection indicated that the SMPs used in the study contained 15% biopolymers and 28% humic-like substances(based on the total dissolved organic carbon concentration)so would have contained sites that could interact with TMP.A linear relationship of fluorescent intensities of tryptophan protein-like substances in SMP was observed(R^(2)>0.99),indicating that the fluorescence enhancement between SMP and TMP occurred.Fourier-transform infrared spectroscopy and X-ray photoelectron spectroscopy indicated that carboxyl,carbonyl,and hydroxyl groups were the main functional groups involved in the interactions.The electrostatic andπ-πinteractions were discovered by the UV-vis spectra and 1H nuclear magnetic resonance spectra.Structural representations of the interactions between representative SMP subcomponents and TMP were calculated using density functional theory,and the results confirmed the conclusions drawn from the 1H nuclear magnetic resonance spectra.The results help characterize SMP–TMP complexes and will help understand antibiotic transformations in wastewater treatment plants and aquatic environments.

关键词： Activated sludge process Interaction mechanism Antibiotics Soluble microbial products(SMP) Spectral methods

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The profiles of chiral pesticides in peri-urban areas near Yangtze River: Enantioselective distribution characteristics and correlations with surface sediments

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Journal of Environmental Sciences 2022年第11期34卷 199-210页

作者： Wenjun Zhang Tingting Li Jiayi Tang Xiaoli Liu Yuhang Liu Xiao Zhong key laboratory of Integrated Regulation and Resources Development on shallow Lakes of Ministry of Education College of EnvironmentHohai UniversityNanjing 210098China

Chiral pesticides account for 30% of pesticides. Pesticides are inevitably leached into the groundwater by runoff. At the watershed level, the distribution characteristics of enantiomers in sediments collected from the river network of an agricultural area near the middle and lower reaches of the Yangtze River were tested, and their potential correlations with the physicochemical properties and microbial communities of the sediments were analyzed. The sediment pollution was serious at sites 8 and 9, with their pollution source possibly being agricultural or industrial sewage. Moreover, there were higher cumulative contents of pesticide residues at sites 4, 8, and 9. Specifically, Cycloxaprid was the most detected chiral pesticide in the study area, followed by Dinotefuran and Diclofop-methyl. Additionally,Ethiprole and Difenoconazole had strong enantioselectivity in the study area. Interestingly,the enantiomers of some chiral pesticides, such as Tebuconazole, had completely different distributions at different sites. Pearson correlation analysis showed that sediment catalase and microbial biomass carbon were important factors for enantioselectivity of chiral pesticides. The effect of sediment physicochemical properties on enantioselective distribution was achieved by influencing the microorganisms in the sediment. Furthermore, the enantioselective distribution of Tebuconazole was closely related to the genus Arenimonas.Overall, the enantioselective distribution of most of the chiral pesticides was positively correlated with the prokaryotic microbial community. This study provides empirical support for agricultural non-point source pollution caused by chiral pesticides, and also lays a research foundation for exploring the factors that affect the fate of chiral pesticides in the environment.

关键词： Non-point source pollution Enantiomers Redundancy analysis Sediment enzymes Microbial community

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Experimental study on the mechanical and failure behaviors of deep rock subjected to true triaxial stress:A review

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International Journal of Mining Science and Technology 2022年第5期32卷 915-950页

作者： Heping Xie Jun Lu Cunbao Li Minghui Li Mingzhong Gao Guangdong Provincial key laboratory of Deep Earth Sciences and geothermal energy Exploitation and Utilization College of Civil and Transportation EngineeringShenzhen UniversityShenzhen 518000China Shenzhen key laboratory of Deep Underground Engineering Science and Green energy Shenzhen UniversityShenzhen 518000China Institute of Deep Earth Sciences and Green energy Shenzhen UniversityShenzhen 518000China

It has become an inevitable trend of human development to seek resources from the deep underground.However,rock encountered in deep underground engineering is usually in an anisotropic stress state(σ_(1)>σ>σ_(3))due to the influences of geological structures and engineering disturbances.It is therefore essential to study the mechanical,seepage,and dynamic disaster behaviors of deep rock under true triaxial stress to ensure the safe operation of deep rock engineering and the efficient exploitation of deep resources.In recent years,experimental techniques and research on true triaxial rock mechanics have achieved fruitful results that have promoted the rapid development of deep rock mechanics;thus,it is necessary to systematically review and summarize these developments.This work first introduced several typical true triaxial testing apparatus and then reviewed the corresponding research progress on rock deformation,strength,failure mode,brittleness,and energy as well as the 3D volumetric fracturing(dynamic disaster)properties of deep rocks under true triaxial stress.Then,several commonly used true triaxial rock strength criteria and their applicability,the permeability characteristics and mathematical models of deep reservoir rocks,and the disaster-causing processes and mechanisms of disturbed volumetric fracturing(rockburst,compound dynamic disasters)in deep rock engineering were described.This work may provide an essential reference for addressing the true triaxial rock mechanics issues involved in deep rock engineering,especially regarding the stability of surrounding rock at depth,disaster prevention and control,and oil and gas exploitation.

关键词： True triaxial stress Deep rock mass Mechanical properties Strength criterion Permeability characteristics Dynamic disaster

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Investigation of adsorption/desorption behavior of Cr(Ⅵ) at the presence of inorganic and organic substance in membrane capacitive deionization(MCDI)

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Journal of Environmental Sciences 2019年第4期31卷 303-314页

作者： Lin Chen Chengyi Wang Shanshan Liu Liang Zhu key laboratory of Integrated Regulation and Resources Development of shallow Lakes Hohai University College of Environment Hohai University

The adsorption and desorption behavior of Cr(Ⅵ) in membrane capacitive deionization(MCDI) was investigated systematically in the presence of bovine serum albumin(BSA) and KCl with different concentrations, respectively. Results revealed that Cr(Ⅵ) absorption was enhanced and the adsorption amount for Cr(Ⅵ) increased from 155.7 to 190.8 mg/g when KCl concentration increased from 100 to 200 mg/L in the adsorption process, which was attributed to the stronger driving force. However, the adsorption amount sharply decreased to 90.2 mg/g when KCl concentration reached up to 1000 mg/L suggesting the negative effect for Cr(Ⅵ) removal that high KCl concentration had. As for the effect of BSA on ion adsorption, the amount for Cr(Ⅵ) significantly declined to 78.3 mg/g and p H was found to be an important factor contributing to this significant reduction. Then, the desorption performance was also conducted and it was obtained that the presence of KCl had negligible effect on Cr(Ⅵ) desorption, while promoted by the addition of BSA. The incomplete desorption was obtained and the residual chromium ions onto the electrode after desorption was detected via energy-dispersive X-ray spectroscopy(EDS). Based on above analysis, the enhanced removal mechanism for Cr(Ⅵ) in MCDI was found to be consisted of ion adsorption onto electrode surface, the redox reaction of Cr(Ⅵ) into Cr(III)and precipitation, which was demonstrated by X-ray photoelectron spectroscopy(XPS) and scanning electron microscope(SEM).

关键词： Adsorption Incomplete desorption Redox reaction Membrane capacitive deionization

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Distribution and relationship between antimicrobial resistance genes and heavy metals in surface sediments of Taihu Lake,China

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Journal of Environmental Sciences 2019年第3期31卷 323-335页

作者： Okugbe E.Ohore Felix Gyawu Addo Songhe Zhang Nini Han Kwaku Anim-Larbi Ministry of Education key laboratory of Integrated Regulation and Resource Development on shallow Lakes College of Environment Hohai University

Heavy metals, pharmaceuticals, and other wastes released into the environment can significantly influence environmental antibiotic resistance. We investigated the occurrence of 22 antimicrobial resistance genes(ARGs) and 10 heavy metal concentrations, and the relationship between ARGs and heavy metals in surface sediment from seven sites of Lake Taihu. The results showed significant correlations(p < 0.05) between sediment ARG levels,especially for tetracycline and sulfonamides(e.g., tet(A), tet(D), tet(E), tet(O), sul1, sul2 and int-1) and specific heavy metals(Fe, Mn, Cr, Cu, Zn, among others) in the Lake. In the surface sediments, heavy metals showed an interaction with resistance genes, but the strength of interaction was diminished with increasing depth. For most of the heavy metals, the concentration of elements in the top sediments was higher than that in other depths.Tetracycline resistance genes(tet(A), tet(B), tet(D), tet(E) and tet(O), β-lactam resistance genes(SHV, TEM, CTX, OXA and OXY) and sulfonamide resistance genes(sulA, sul1, sul2, sul3 and int-1) were detected. They showed a trend which inferred a statistically significant increase followed by decreases in the relative abundance of these ARGs(normalized to 16 S rRNA genes) with increasing depth. This study revealed that tet(A), tet(O), TEM, OXY, int-1, sul1 and sul3 were widespread in surface sediments with high abundance, indicating that these genes deserve more attention in future work.

关键词： Antibiotic resistance genes Heavy metals Surface sediments Taihu Lake Wastewater treatment plants Pollution

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Size effect of fracture characteristics for anisotropic quasi-brittle geomaterials

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International Journal of Mining Science and Technology 2023年第2期33卷 201-213页

作者： Cunbao Li Dongchao Yang Heping Xie Li Ren Jun Wang Guangdong Provincial key laboratory of Deep Earth Sciences and geothermal energy Exploitation and Utilization Institute of Deep Earth Sciences and Green EnergyShenzhen UniversityShenzhen 518060China Shenzhen key laboratory of Deep Engineering Sciences and Green energy College of Civil and Transportation EngineeringShenzhen UniversityShenzhen 518060China MOE laboratory of Deep Earth Science and Engineering Sichuan UniversityChengdu 610065China

Understanding the size effect exhibited by the fracture mechanism of anisotropic geomaterials is important for engineering practice. In this study, the anisotropic features of the nominal strength, apparent fracture toughness, effective fracture energy and fracture process zone(FPZ) size of geomaterials were first analyzed by systematic size effect fracture experiments. The results showed that the nominal strength and the apparent fracture toughness decreased with increasing bedding plane inclination angle.The larger the specimen size was, the smaller the nominal strength and the larger the apparent fracture toughness was. When the bedding inclination angle increased from 0° to 90°, the effective fracture energy and the effective FPZ size both first decreased and then increased within two complex variation stages that were bounded by the 45° bedding angle. Regardless of the inherent anisotropy of geomaterials,the nominal strength and apparent fracture toughness can be predicted by the energy-based size effect law, which demonstrates that geomaterials have obvious quasi-brittle characteristics. Theoretical analysis indicated that the true fracture toughness and energy dissipation can be calculated by linear elastic fracture mechanics only when the brittleness number is higher than 10;otherwise, size effect tests should be adopted to determine the fracture parameters.

关键词： Size effect Inherent anisotropy Fracture toughness Fracture energy Effective FPZ size Quasi-brittle geomaterials

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